Beilstein J. Org. Chem.2022,18, 1424–1434, doi:10.3762/bjoc.18.148
hydrazone groups. The use of N-TAAD derivatives as potential ligands and receptors was showcased through forming boron chelates and host–guest complexes with water and simple alcohols.
Keywords: azaadamantanes; cyclotrimerization; hydrazones; inclusion complexes; molecular recognition; Introduction
, the preparation of trisubstituted adamantanes is challenging because multiple functionalization of the parent hydrocarbon is not selective, while the synthesis from acyclic precursors requires multistep synthetic routes [10][14]. The use of azaadamantanes is more advantageous as they are prepared via
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Graphical Abstract
Figure 1:
Adamantane-based tripodal scaffolds and current work.