Beilstein J. Org. Chem.2019,15, 1523–1533, doi:10.3762/bjoc.15.155
isothiocyanates, as valuable building blocks from isocyanides and sulfur is proposed, as well. The synthetic procedure suits the demand of a modern organic chemist, as it tolerates a wide range of functional groups, it is atom economic and easily scalable.
Keywords: ditihiocarbamate; elemental sulfur
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Graphical Abstract
Scheme 1:
Synthetic routes to O-thiocarbamates and dithiocarbamates.