Beilstein J. Org. Chem.2013,9, 647–654, doi:10.3762/bjoc.9.73
under vacuo (method A) or by addition of NaBPh4 (method B). Possible catalytic and deactivation mechanisms are proposed.
Keywords: aliphatic polyesters; green polymerization reaction; imidazolium-2-carboxylates; N-heterocarbene precursor; organocatalysis; Introduction
Poly(ε-caprolactone) (PCL) and
concept was extended to the synthesis of aliphatic polycarbonates, involving the transesterification of DMC with linear alkane diols under solvent-free conditions, and based on a two-step polymerization process [50]. The high reactivity of imidazolium-2-carboxylates can be explained by their facile
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Graphical Abstract
Figure 1:
Molecular representations of N-heterocyclic carbenes and BMIM-2-CO2.