Beilstein J. Org. Chem.2016,12, 2906–2915, doi:10.3762/bjoc.12.290
corresponding SN2-type products 6a–d in 63 to 70% isolated yields. Alternatively, the alcohol 5 produced the corresponding acetate 7 which, mediated by Ce(III), was successfully converted into the corresponding γ-aminoallylphosphonates 8a–d.
Keywords: allylic substitution; γ-aminoallylphosphonate; Arbuzov
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Graphical Abstract
Scheme 1:
Synthesis of allylphosphonates from acyclic MBH adducts.