Polymer nanoparticles from low-energy nanoemulsions for biomedical applications

• Santiago Grijalvo and
• Carlos Rodriguez-Abreu

Beilstein J. Nanotechnol. 2023, 14, 339–350, doi:10.3762/bjnano.14.29

• liquid phase. They are out-of-equilibrium nanocolloids in which phase separation is expected from thermodynamics, but is delayed by the presence of surfactants adsorbed on the droplets surface. Accordingly, nanoemulsion formation depends on the way the sample is prepared, for example, on the order of

Bismuth-based nanostructured photocatalysts for the remediation of antibiotics and organic dyes

• Akeem Adeyemi Oladipo and
• Faisal Suleiman Mustafa

Beilstein J. Nanotechnol. 2023, 14, 291–321, doi:10.3762/bjnano.14.26

• treat contaminated water and wastewater, including adsorption, bioremediation, precipitation, electrocoagulation, filtration, membrane separation, flocculation, centrifugation, advanced oxidation processes based on photocatalysis, and chemical coagulation [4][5][6][7][8][9][10][11]. Each of these

• carrier separation, high photo-transporter mobility, appropriate physical and chemical properties, sufficient band alignment to meet the kinetic requirements of the target reaction, and anti-corrosion stability in reactive environments [18][19][20]. Figure 1 depicts the mechanism of the photocatalyst. In

• surface charge, low carrier density, small electron effective mass, long electron mean free path, and extremely low band overlap energy, bismuth can transition from a semimetal to a semiconductor by shrinking its crystallite size [25][71][72][73][74][75][76][77]. To hasten the separation of photogenerated

Biocatalytic synthesis and ordered self-assembly of silica nanoparticles via a silica-binding peptide

• Mustafa Gungormus

Beilstein J. Nanotechnol. 2023, 14, 280–290, doi:10.3762/bjnano.14.25

• methods for manufacturing ordered structures of nanoparticles is an ongoing challenge. Ordered structures of SiO2 nanoparticles have gained increased attention due to the great potential they offer in filtering, separation, drug delivery, optics, electronics, and catalysis. Biomolecules, such as peptides

• gained increased attention due to the great potential they offer in filtering, separation, drug delivery, optics, electronics, and catalysis [1][2][3][4][5]. Nanoparticles with ordered 3D structures, such as supra-particles or super lattices, can possess properties that are not observed in the bulk

A distributed active patch antenna model of a Josephson oscillator

• Vladimir M. Krasnov

Beilstein J. Nanotechnol. 2023, 14, 151–164, doi:10.3762/bjnano.14.16

• . The array factor takes into account the interference of electromagnetic fields from the two slots in the far field. It depends on the separation between the slots, a, the relative phase shift, β, and the direction (φ,Θ). Since radiation from a patch antenna is induced by magnetic current lines, it is

Formation of nanoflowers: Au and Ni silicide cores surrounded by SiO_x branches

• Feitao Li,
• Siyao Wan,
• Dong Wang and
• Peter Schaaf

Beilstein J. Nanotechnol. 2023, 14, 133–140, doi:10.3762/bjnano.14.14

• between the positions of pure Au and Ni since only one main reflex should be observed when the two elements are completely mixed [20][23][25]. The annealing temperatures are above the miscibility gap [23][50]. Thus, the partial mixing comes from the phase separation of Au and Ni during cooling [25

• interdiffusion of Au, Ni, and Si. Au/Si phase separation occurs during cooling [3][55], and Ni silicide may remain stable down to room temperature [41][42][43][44][45][46], finally forming particles with two contrasts. Besides, Ni may also diffuse into the Si substrate, leading to the formation of the Ni

Intermodal coupling spectroscopy of mechanical modes in microcantilevers

• Ioan Ignat,
• Bernhard Schuster,
• Jonas Hafner,
• MinHee Kwon,
• Daniel Platz and
• Ulrich Schmid

Beilstein J. Nanotechnol. 2023, 14, 123–132, doi:10.3762/bjnano.14.13

• –T3, which has a regime transition. Inset: Coupling rates determined from linewidth changes or eigenmode separation against half the linewidth of cavity mode T3. (b) Matrix showing the coupling rates of all mode combinations. Contoured squares represent combinations between flexural modes only. (c

Characterisation of a micrometer-scale active plasmonic element by means of complementary computational and experimental methods

• Ciarán Barron,
• Giulia Di Fazio,
• Samuel Kenny,
• Silas O’Toole,
• Robin O’Reilly and
• Dominic Zerulla

Beilstein J. Nanotechnol. 2023, 14, 110–122, doi:10.3762/bjnano.14.12

• ] investigated the effects of gap size using a fine tunable mechanical separation as a means to control the intensity of a travelling SPP on silver. In contrast, in the present work, the modulation of the device’s response is obtained through changes in the optical constants via electrical signals. It is well

Two-step single-reactor synthesis of oleic acid- or undecylenic acid-stabilized magnetic nanoparticles by thermal decomposition

• Mykhailo Nahorniak,
• Pamela Pasetto,
• Jean-Marc Greneche,
• Volodymyr Samaryk,
• Sandy Auguste,
• Anthony Rousseau,
• Nataliya Nosova and
• Serhii Varvarenko

Beilstein J. Nanotechnol. 2023, 14, 11–22, doi:10.3762/bjnano.14.2

• purchased from Merck KGaA (Darmstadt, Germany). Oleic acid (OA, 98%) was bought from Lachema (Brno, Czech Republic). For magnetic separation, a permanent cylindrical neodymium magnet (NdFeB; 45 × 15 mm), with an induction on the surface of 1.2 T, was used. To characterize the size, morphology, hydrodynamic

• -octadecene. The stirring was continued for 30 min. The resulting reaction mass was transferred into a 250 mL reactor equipped with a mechanical stirrer and washed five times with propanone (150 mL each time) followed by nanoparticle deposition by magnetic separation on a NdFeB magnet under argon. The

Observation of collective excitation of surface plasmon resonances in large Josephson junction arrays

• Roger Cattaneo,
• Mikhail A. Galin and
• Vladimir M. Krasnov

Beilstein J. Nanotechnol. 2022, 13, 1578–1588, doi:10.3762/bjnano.13.132

• found in [9][34][36][37]. The meander array (Figure 1a) has seven identical (vertical) sections with N = 1000 JJs in each and with an overall size in the vertical direction of 6.25 mm. Each section consists of 125 horizontal segments with a length of 230 μm, a width of 10 μm, and a separation of 40 μm

• (Figure 1c) contains five straight sections (lines) with N = 332 JJs in each. The spacing between the lines is 6 μm. Sizes and separation of the JJs is the same as for the meander array. The two outermost lines in the linear array and all seven sections of the meander array can be measured independently

• steps with small separation in voltage. The linear array, Figure 1d, exhibits several evenly spaced steps. The I–V characteristics are hysteretic, with the retrapping current being significantly smaller than the switching current. The hysteresis leads to a metastability, which allows for the observation

Single-step extraction of small-diameter single-walled carbon nanotubes in the presence of riboflavin

• Polina M. Kalachikova,
• Anastasia E. Goldt,
• Eldar M. Khabushev,
• Timofei V. Eremin,
• Timofei S. Zatsepin,
• Elena D. Obraztsova,
• Konstantin V. Larionov,
• Liubov Yu. Antipina,
• Pavel B. Sorokin and
• Albert G. Nasibulin

Beilstein J. Nanotechnol. 2022, 13, 1564–1571, doi:10.3762/bjnano.13.130

• facilitate chirality separation. Conventional surfactants such as sodium dodecyl sulfate (SDS) and sodium deoxycholate (DOC), as well as polyethylene glycol-based compositions, are used to obtain high-quality dispersions of individual SWCNTs [3][4][5][10]. Although given surfactants show exemplary

• performance in both individualization and chirality separation of carbon nanotubes, excessive surfactant concentrations are usually required for their complete individualization [2][8][11]. Such excess subsequently introduces an additional step of surfactant removal to recover the SWCNTs in a pristine state

• solubilize SWCNTs, no data on chirality separation of SWCNTs using pure aqueous riboflavin is available to date. Here, we report the dispersion of single-walled carbon nanotubes by aqueous riboflavin solution to extract a small-diameter fraction of SWCNTs from polydisperse samples by highly-efficient single

Photoelectrochemical water oxidation over TiO₂ nanotubes modified with MoS₂ and g-C₃N₄

• Phuong Hoang Nguyen,
• Thi Minh Cao,
• Tho Truong Nguyen,
• Hien Duy Tong and
• Viet Van Pham

Beilstein J. Nanotechnol. 2022, 13, 1541–1550, doi:10.3762/bjnano.13.127

• light, which can be explained as follows: The photocurrent density of MoS2/TNAs promptly increased because of the efficient separation of the e−–h+ pairs at the interfaces between TNAs and MoS2 [58] and the rapid transfer of the photo-induced electrons from MoS2 to the TNAs electrode [59]. This result

A TiO₂@MWCNTs nanocomposite photoanode for solar-driven water splitting

• Anh Quynh Huu Le,
• Ngoc Nhu Thi Nguyen,
• Hai Duy Tran,
• Van-Huy Nguyen and
• Le-Hai Tran

Beilstein J. Nanotechnol. 2022, 13, 1520–1530, doi:10.3762/bjnano.13.125

• been developed to increase the absorption of visible solar light [6][7]. Notably, carbon nanotubes (CNTs) are a promising material for visible-light absorption [8]. A combination of TiO2 with CNTs can effectively enhance the separation of e−/h+ pairs based on the high electric conductivity of CNTs

In search of cytotoxic selectivity on cancer cells with biogenically synthesized Ag/AgCl nanoparticles

• Mitzi J. Ramírez-Hernández,
• Mario Valera-Zaragoza,
• Omar Viñas-Bravo,
• Ariana A. Huerta-Heredia,
• Miguel A. Peña-Rico,
• Erick A. Juarez-Arellano,
• David Paniagua-Vega,
• Eduardo Ramírez-Vargas and
• Saúl Sánchez-Valdes

Beilstein J. Nanotechnol. 2022, 13, 1505–1519, doi:10.3762/bjnano.13.124

• crystallite size as a function of temperature is more noticeable for Ag than for AgCl, where an increasing trend in Ag crystallite size is observed up to 80 °C. It is speculated that at this temperature, the separation of salt ions and the interaction with reducing biological compounds are favorable, which

Coherent amplification of radiation from two phase-locked Josephson junction arrays

• Mikhail A. Galin,
• Vladimir M. Krasnov,
• Ilya A. Shereshevsky,
• Nadezhda K. Vdovicheva and
• Vladislav V. Kurin

Beilstein J. Nanotechnol. 2022, 13, 1445–1457, doi:10.3762/bjnano.13.119

• .13.119 Abstract We analyze experimentally and theoretically mutual phase locking and electromagnetic interaction between two linear arrays with a large number of Josephson junctions. Arrays with different separation, either on the same chip or on two separate substrates are studied. We observe a large

• substrate with the thickness 0.38 mm. It contains three closely located straight strips with a separation of only 4 μm. Each strip has the length L = 5 mm and the width w = 14 μm and contains 332 JJs distributed uniformly along the strip. The junction area is 8 × 8 μm2. Contact electrodes are connected to

• significantly larger separation of 238 μm between the adjacent linear arrays. In total, it contains 17 similar lines with 380 JJs and a total length of L = 5.7 mm. The junction area is 6 × 6 μm2. Below, we will show data for the case when the rightmost “array-a” is biased with a variable dc current and the

LED-light-activated photocatalytic performance of metal-free carbon-modified hexagonal boron nitride towards degradation of methylene blue and phenol

• Nirmalendu S. Mishra and
• Pichiah Saravanan

Beilstein J. Nanotechnol. 2022, 13, 1380–1392, doi:10.3762/bjnano.13.114

• variation in the structural morphology results in development of multiple active sites that ensure adsorption and effective charge transfer [10]. On the other hand, HBN has been utilised as a support material in the formation of heterojunctions owing to its large surface area and separation of charge

• . The mechanistic insights on the transfer and separation of charge carriers along with the photodegradation performance and reactive oxygen species (ROS) trapping have been enunciated in detail. The apparent quantum efficiency (AQE) further substantiated the potential of MBN to be used as a visible

• attributed to the unpaired electrons. The MBN-80 sample shows the highest EPR spin intensity, meaning greater concentration of unpaired electrons along with higher electron delocalization which are highly favourable towards enhanced separation and generation of charge carriers [26][27]. Additionally, surface

Dry under water: air retaining properties of large-scale elastomer foils covered with mushroom-shaped surface microstructures

• Matthias Mail,
• Stefan Walheim,
• Thomas Schimmel,
• Wilhelm Barthlott,
• Stanislav N. Gorb and
• Lars Heepe

Beilstein J. Nanotechnol. 2022, 13, 1370–1379, doi:10.3762/bjnano.13.113

• Effect, the capability to keep a stable air layer when submerged under water. Such air layers are of great importance, e.g., for drag reduction (passive air lubrication), antifouling, sensor applications or oil–water separation. Some biological models, e.g., the floating fern Salvinia or the backswimmer

Recent trends in Bi-based nanomaterials: challenges, fabrication, enhancement techniques, and environmental applications

• Vishal Dutta,
• Ankush Chauhan,
• Ritesh Verma,
• C. Gopalkrishnan and
• Van-Huy Nguyen

Beilstein J. Nanotechnol. 2022, 13, 1316–1336, doi:10.3762/bjnano.13.109

• environmental restoration and energy conversion is photocatalysis powered by solar light. Traditional photocatalysts have limited practical uses due to inadequate light absorption, charge separation, and unknown reaction mechanisms. Discovering new visible-light photocatalysts and investigating their

• thanks to the significant charge carrier dispersion provided by hybrid orbitals involving the Bi 6s orbital, as seen in Figure 2. Photoinduced electron–hole separation and charge carrier transfer in Bi-based materials are facilitated by a unique layered structure that creates an IEF. A magnetic field is

• pollutants such as tetracycline hydrochloride, bisphenol A (BPA), and RhB was used to measure the photocatalytic activity of the bismuth oxyiodides. The activity decreased in the sequence Bi4O5I2–Bi5O7I > Bi4O5I2 > BiOI, which is linked to charge separation efficiency and band structure. Engineered Bi

Laser-processed antiadhesive bionic combs for handling nanofibers inspired by nanostructures on the legs of cribellate spiders

• Sebastian Lifka,
• Kristóf Harsányi,
• Erich Baumgartner,
• Lukas Pichler,
• Dariya Baiko,
• Karsten Wasmuth,
• Johannes Heitz,
• Marco Meyer,
• Anna-Christin Joel,
• Jörn Bonse and
• Werner Baumgartner

Beilstein J. Nanotechnol. 2022, 13, 1268–1283, doi:10.3762/bjnano.13.105

• of tearing or generally damaging the nonwoven at separation from a target or a tool. As one can imagine, even small damages of the nonwoven during production could lead to severe problems in the application. Refinement and consequent application of the theoretical model described here might help to

• inter-line separation of Δ = 5 µm. The linear laser beam polarization was kept parallel to the scan direction. Immediately after laser processing, the samples were cleaned for 5 min in acetone in an ultrasonic bath and stored in a desiccator. Figure 10 indicates the presence of the LIPSS at the entire

Roll-to-roll fabrication of superhydrophobic pads covered with nanofur for the efficient clean-up of oil spills

• Patrick Weiser,
• Robin Kietz,
• Marc Schneider,
• Matthias Worgull and
• Hendrik Hölscher

Beilstein J. Nanotechnol. 2022, 13, 1228–1239, doi:10.3762/bjnano.13.102

• . These are well-suited for the cleanup of small oil spills. Keywords: hot embossing; lotus effect; nanofur; nanopads; oil spill cleanup; oil water separation; roll-to-roll; R2R; superhydrophobicity; Introduction Self-cleaning surfaces utilizing the famous lotus effect have gained significant importance

• for commercial applications. Furthermore, we demonstrate the subsequent processing of the thin polymeric nanofur into an exemplary product, namely so-called nanopads. These are an aid for the efficient cleaning of oil spills due to the efficient oil–water separation ability of nanofur [23]. The

• hot-embossing machine [31]. (The videos in Supporting Information File 3 and Supporting Information File 4 show the capability of oil–water separation of nanofur.) Once contaminated with oil, the contact angle with water decreases to below 90°. This makes sense since the contact angle is now

Design of surface nanostructures for chirality sensing based on quartz crystal microbalance

• Yinglin Ma,
• Xiangyun Xiao and
• Qingmin Ji

Beilstein J. Nanotechnol. 2022, 13, 1201–1219, doi:10.3762/bjnano.13.100

• industry, detection and separation of enantiomers are essential for their safe usage. With appropriate detectors and transduction signals, various analysis instruments and techniques have been used for chirality detection or chiral separation. They include circular dichroism (CD) [9], nuclear magnetic

• intensive attention in various applications and also show great potential for selective separation and sensing applications [55]. Through adjusting building blockings, sensing hosts of supermolecular structures with different channel sizes, shapes, and functional sites could be fabricated, which provides

• -butyldimethylsilyl)-β-cyclodextrin (Ac-β-CD). Combined with gas chromatography analysis, chiral separation factors could be estimated. Et-β-CD showed a more sensitive QCM response to R-limonene. It was also found that a higher chiral recognition factor was gained at the lowest limonene concentration due to more

Application of nanoarchitectonics in moist-electric generation

• Jia-Cheng Feng and
• Hong Xia

Beilstein J. Nanotechnol. 2022, 13, 1185–1200, doi:10.3762/bjnano.13.99

• control, and the abundant surface charges enable the charge separation of water molecules after the addition of moisture, which contributes to a more efficient generation of electric energy [1][2][34][35][36][37][38]. In 2003, Ghosh [22] reported that the fluid in single-walled carbon nanotubes can

• (Figure 10k–n). When being combined with optoelectronic devices, photo-excited carriers and moisture-induced charge separation promote each other. The open-circuit voltage of the MEG from the photoelectric effect is increased by more than 10%, and the short-circuit current is increased by 300% (Figure 10p

Rapid fabrication of MgO@g-C₃N₄ heterojunctions for photocatalytic nitric oxide removal

• Minh-Thuan Pham,
• Duyen P. H. Tran,
• Xuan-Thanh Bui and
• Sheng-Jie You

Beilstein J. Nanotechnol. 2022, 13, 1141–1154, doi:10.3762/bjnano.13.96

• visible light region, including nonmetal and noble-metal doping, metal deposition, and formation of heterojunctions [21][22]. The construction of heterojunction structures has shown its effectiveness in improving photocatalytic performance by enhancing the separation of charge carriers and optimizing the

Spindle-like MIL101(Fe) decorated with Bi₂O₃ nanoparticles for enhanced degradation of chlortetracycline under visible-light irradiation

• Chen-chen Hao,
• Fang-yan Chen,
• Kun Bian,
• Yu-bin Tang and
• Wei-long Shi

Beilstein J. Nanotechnol. 2022, 13, 1038–1050, doi:10.3762/bjnano.13.91

• Bi2O3 and MIL101(Fe), respectively. The enhanced photocatalytic activity is attributed to the formation of a Z-scheme heterojunction between Bi2O3 and MIL101(Fe), which is conducive to the rapid separation of photogenerated carriers and the enhancement of photogenerated electron and hole redox capacity

• cavities, and excellent thermal stability [20][21]. These advantages make it appalling to adsorption [22], gaseous capture/separation [23], sensing [24], and drug release applications [25]. Moreover, some MOFs can be excited under UV or visible light and exhibit light harvesting properties due to ligand

• use carbon nanotubes or carbon quantum dots to modify MIL101(Fe) to enhance its conductivity and broaden its visible-light response [37][38]. Another strategy is to construct MIL101-based heterostructures with the aid of narrow-gap semiconductors to promote the separation and transfer of

Theoretical investigations of oxygen vacancy effects in nickel-doped zirconia from ab initio XANES spectroscopy at the oxygen K-edge

• Dick Hartmann Douma,
• Lodvert Tchibota Poaty,
• Alessio Lamperti,
• Stéphane Kenmoe,
• Abdulrafiu Tunde Raji,
• Alberto Debernardi and
• Bernard M’Passi-Mabiala

Beilstein J. Nanotechnol. 2022, 13, 975–985, doi:10.3762/bjnano.13.85

• varying concentrations. Specifically, our model system consist of a supercell composed of a zirconia (ZrO2) matrix containing two nickel dopants (2Ni), which substitute two Zr atoms at a finite separation. We found the 2Ni atoms to be most stable in a ferromagnetic configuration in the absence of oxygen

• possible separation from the dopants. This is to minimize as much as possible the distortion of the Ni symmetry in zirconia due to the presence of vacancies. The two oxygen atoms to be removed successively for the construction of Ni-doped ZrO2 containing single and double vacancies are represented by green

• atoms and oxygen vacancies at varying concentrations. The zirconia matrix contains two nickel atoms substituting two zirconium atoms at a finite separation. In our model system, the concentration of nickel dopant atoms is equivalent to 6.25 atom %. We found the two nickel atoms to be most stable when

Comparing the performance of single and multifrequency Kelvin probe force microscopy techniques in air and water

• Jason I. Kilpatrick,
• Emrullah Kargin and
• Brian J. Rodriguez

Beilstein J. Nanotechnol. 2022, 13, 922–943, doi:10.3762/bjnano.13.82

• the performance of KPFM techniques in both air and water environments. To do this, we examine three performance criteria, namely minimum detectable CPD, minimum required bias, and SNR as a function of tip–sample separation, z, under the specified conditions as outlined in Table 2 in Appendix I

• . These metrics are examined for three cases: the first harmonic electrostatic response occurring off resonance, ωoff, where ωoff ≪ ω1, on ω1, and on ω2. For modes that include a mechanical excitation at amplitude Am of the lever, z is taken to be the mean tip–sample separation. First, we compare single

• of the ED modes at the minimum tip–sample separation, where z = Am, but is significantly worse at large separations. The values for ED on ω2 are slightly lower than ω1 but this corresponds with poorer values. Whilst ED is practical at z > 100 nm on the eigenmodes, HM modes are limited to operation