Involvement of two uptake mechanisms of gold and iron oxide nanoparticles in a co-exposure scenario using mouse macrophages

• Dimitri Vanhecke,
• Dagmar A. Kuhn,
• Dorleta Jimenez de Aberasturi,
• Sandor Balog,
• Ana Milosevic,
• Dominic Urban,
• Diana Peckys,
• Niels de Jonge,
• Wolfgang J. Parak,
• Alke Petri-Fink and
• Barbara Rothen-Rutishauser

Beilstein J. Nanotechnol. 2017, 8, 2396–2409, doi:10.3762/bjnano.8.239

• ]. Therefore, the occurrence of NP diffusion through pores in the membrane as well as passive uptake by van der Waals or steric interactions (subsumed as adhesive interactions) [25] cannot be excluded. The majority of uptake studies were conducted with one defined NP type only. However, since humans are more

Optical contrast and refractive index of natural van der Waals heterostructure nanosheets of franckeite

• Patricia Gant,
• Foad Ghasemi,
• David Maeso,
• Carmen Munuera,
• Elena López-Elvira,
• Riccardo Frisenda,
• David Pérez De Lara,
• Gabino Rubio-Bollinger,
• Mar Garcia-Hernandez and
• Andres Castellanos-Gomez

Beilstein J. Nanotechnol. 2017, 8, 2357–2362, doi:10.3762/bjnano.8.235

• visible spectrum through a fit of the acquired spectra to a model based on the Fresnel law. Keywords: complex refractive index; franckeite; optical contrast; optical identification; van der Waals heterostructure; Introduction Mechanical exfoliation is a very powerful technique to produce a large variety

• is one of the few known examples of a naturally occurring van der Waals heterostructure (another example of these materials is the cylindrite [19], see Supporting Information File 1). Unlike most of the studied heterostructures (that are manually assembled layer-by-layer) franckeite, in its natural

• form, presents alternating SnS2-like and PbS-like layers stacked on top of each other (Figure 1), overcoming the major drawbacks of synthetic van der Waals heterostructures: the difficulty to align the crystal lattices of the different materials with atomic accuracy and the presence of ambient

Material property analytical relations for the case of an AFM probe tapping a viscoelastic surface containing multiple characteristic times

• Enrique A. López-Guerra and
• Santiago D. Solares

Beilstein J. Nanotechnol. 2017, 8, 2230–2244, doi:10.3762/bjnano.8.223

• excitation suddenly imposed during the impact. The third term is the relaxation modulus, and the fourth term is the adhesive portion of the van der Waals (vdW) interaction, in which HA is the Hamaker constant, R is the radius of the cylindrical punch, and a0 is the interatomic distance (ca. 0.2 nm) [39]. In

• method [39]. Here the total attractive van der Waals potential (EvdW) was calculated for the specific case of a flat-end cylindrical punch interacting with a flat semi-infinite half-space, and subsequently the interaction force was obtained through differentiation: For the adhesion portion during

Preparation and characterization of polycarbonate/multiwalled carbon nanotube nanocomposites

• Claudio Larosa,
• Niranjan Patra,
• Marco Salerno,
• Lara Mikac,
• Remo Merijs Meri and
• Mile Ivanda

Beilstein J. Nanotechnol. 2017, 8, 2026–2031, doi:10.3762/bjnano.8.203

• used p-xylene and dichloromethane solvent to mix MWCNTs and prevent their agglomeration induced by strong van der Waals forces. Previous work carried out on PC/MWCNT composites with focus on the mechanical properties showed an increase in the storage modulus obtained from indentation measurements at

• solvent helps to overcome the van der Waals interaction in the nanotubes, eventually leading to better dispersion. Figure 3 shows the normalized FTIR absorption spectra of principal absorbance bands of the investigated PC/MWCNT nanocomposite films. FTIR spectroscopy demonstrated to be a useful tool to

A systematic study of the controlled generation of crystalline iron oxide nanoparticles on graphene using a chemical etching process

• Peter Krauß,
• Jörg Engstler and
• Jörg J. Schneider

Beilstein J. Nanotechnol. 2017, 8, 2017–2025, doi:10.3762/bjnano.8.202

• dense growth of CNTs, yet random areas of VACNTs still exist under these growth conditions (Figure S8, Supporting Information File 1). We speculate that in areas where VACNT growth occurs, the catalyst particle size and density are in the range that a dense growth, supported by van der Waals

Advances and challenges in the field of plasma polymer nanoparticles

• Andrei Choukourov,
• Pavel Pleskunov,
• Daniil Nikitin,
• Valerii Titov,
• Artem Shelemin,
• Mykhailo Vaidulych,
• Anna Kuzminova,
• Pavel Solař,
• Jan Hanuš,
• Jaroslav Kousal,
• Ondřej Kylián,
• Danka Slavínská and
• Hynek Biederman

Beilstein J. Nanotechnol. 2017, 8, 2002–2014, doi:10.3762/bjnano.8.200

• situation is related to the weak van der Waals forces acting between NPs and substrate so that a NP layer can be easily destroyed by a tiny mechanical impact. This drawback can be overcome by depositing a capping layer that should be sufficiently robust to fix the NPs on the surface yet sufficiently thin so

Imidazolium-based ionic liquids used as additives in the nanolubrication of silicon surfaces

• Patrícia M. Amorim,
• Ana M. Ferraria,
• Rogério Colaço,
• Luís C. Branco and
• Benilde Saramago

Beilstein J. Nanotechnol. 2017, 8, 1961–1971, doi:10.3762/bjnano.8.197

• substrate. Enhanced interactions between the cation and or the anion and the hydrophilic silicon substrate, due to van der Waals forces (long side chains), hydrogen bonding (ethanol functional groups) and, more importantly, chemical bonding involving the hydrophilic sulfate and Si, promote the formation of

Intercalation of Si between MoS₂ layers

• Rik van Bremen,
• Qirong Yao,
• Soumya Banerjee,
• Deniz Cakir,
• Nuri Oncel and
• Harold J. W. Zandvliet

Beilstein J. Nanotechnol. 2017, 8, 1952–1960, doi:10.3762/bjnano.8.196

• of silicon was also demonstrated on graphite, a van der Waals material, with the idea to suppress the interaction with the substrate and as such to preserve the Dirac properties [22]. Unfortunately, graphite is metallic, which could also affect the electronic bands of silicene in the vicinity of the

• Fermi level. Van der Waals materials with a band gap do not suffer from this limitation. Molybdenum disulfide (MoS2) is a member of the transition metal dichalcogenide (TMD) family that belongs to the class of van der Waals materials. Bulk MoS2 has a band gap of 1.29 eV, which increases to 1.90 eV for a

• semi-local functionals, such as GGA, fail to describe weakly interacting systems, we also take into account the van der Waals interaction [39][40]. Brillouin-zone integrations for structure relaxations are approximated by using the special k-point sampling of the Monkhorst–Pack scheme with a Γ-centered

α-Silicene as oxidation-resistant ultra-thin coating material

• Ali Kandemir,
• Fadil Iyikanat,
• Cihan Bacaksiz and
• Hasan Sahin

Beilstein J. Nanotechnol. 2017, 8, 1808–1814, doi:10.3762/bjnano.8.182

• generalized gradient approximation of the Perdew–Burke–Ernzerhof (GGA-PBE) [26] functional was used in conjunction with a semi-empirical scheme for including van der Waals (vdW) interaction dispersive forces developed by Grimme [27]. The structural relaxations were performed with a plane wave cut-off energy

Non-intuitive clustering of 9,10-phenanthrenequinone on Au(111)

• Ryan D. Brown,
• Rebecca C. Quardokus,
• Natalie A. Wasio,
• Jacob P. Petersen,
• Angela M. Silski,
• Steven A. Corcelli and
• S. Alex Kandel

Beilstein J. Nanotechnol. 2017, 8, 1801–1807, doi:10.3762/bjnano.8.181

• in dipole–dipole interactions being overwhelmed by stronger intermolecular interactions (i.e., van der Waals forces and hydrogen bonding) during growth processes [32][33][34][35]. However, the arrangement of molecules in the tetramer does not allow for half of the carbonyl groups present to form C–H

Adsorption and diffusion characteristics of lithium on hydrogenated α- and β-silicene

• Fadil Iyikanat,
• Ali Kandemir,
• Cihan Bacaksiz and
• Hasan Sahin

Beilstein J. Nanotechnol. 2017, 8, 1742–1748, doi:10.3762/bjnano.8.175

• calculations. The van der Waals (vdW) correction to the GGA functional was included by using the DFT-D2 method of Grimme [50]. To properly simulate the structures, a 3×3-reconstructed hydrogenated silicene phase was placed on top of a 4×4 supercell of a two-layer Ag(111) surface. A 3×3×1 Γ-centered k-point

Group-13 and group-15 doping of germanane

• Nicholas D. Cultrara,
• Maxx Q. Arguilla,
• Shishi Jiang,
• Chuanchuan Sun,
• Michael R. Scudder,
• R. Dominic Ross and
• Joshua E. Goldberger

Beilstein J. Nanotechnol. 2017, 8, 1642–1648, doi:10.3762/bjnano.8.164

• layered van der Waals materials [20][21][22]. Germanane, a hydrogen-terminated graphane analogue of germanium, has garnered considerable attention in the field of 2D materials on account of its direct band gap [5][23][24], large predicted electron mobility, and the ability to controllably tune the

Two-dimensional carbon-based nanocomposites for photocatalytic energy generation and environmental remediation applications

• Suneel Kumar,
• Ashish Kumar,
• Ashish Bahuguna,
• Vipul Sharma and
• Venkata Krishnan

Beilstein J. Nanotechnol. 2017, 8, 1571–1600, doi:10.3762/bjnano.8.159

• properties with unsaturated N-atoms for anchoring active sites [69]. Furthermore, the stacked 2D layered structure of g-C3N4 consists of single-layer nitrogen heteroatom-substituted graphite nanosheets, formed through sp2 hybridization of C and N atoms, and various layers are bound together by van der Waals

A nanocomplex of C₆₀ fullerene with cisplatin: design, characterization and toxicity

• Svitlana Prylutska,
• Svitlana Politenkova,
• Kateryna Afanasieva,
• Volodymyr Korolovych,
• Kateryna Bogutska,
• Andriy Sivolob,
• Larysa Skivka,
• Maxim Evstigneev,
• Viktor Kostjukov,
• Yuriy Prylutskyy and
• Uwe Ritter

Beilstein J. Nanotechnol. 2017, 8, 1494–1501, doi:10.3762/bjnano.8.149

• negatively charged C60 molecules and attraction of the C60 fullerenes due to hydrophobic and van der Waals forces. Thereby, the negative potential of C60+Cis clusters is an important factor responsible for the stabilization of this aqueous system. The structural and energetic peculiarities of C60+Cis

• in aqueous environment and calculated the time-averaged energies of interaction. The net van der Waals, electrostatic and hydrophobic energies were obtained as follows, ΔGvdw ≈ −0.6 kJ/mol, ΔGel ≈ 0.9 kJ/mol and ΔGhyd ≈ −9.0 kJ/mol, respectively. The near-zero magnitudes of the net ‘vdw’ and ‘el

Spin-chemistry concepts for spintronics scientists

• Konstantin L. Ivanov,
• Alexander Wagenpfahl,
• Carsten Deibel and
• Jörg Matysik

Beilstein J. Nanotechnol. 2017, 8, 1427–1445, doi:10.3762/bjnano.8.143

Adsorption and electronic properties of pentacene on thin dielectric decoupling layers

• Sebastian Koslowski,
• Daniel Rosenblatt,
• Alexander Kabakchiev,
• Klaus Kuhnke,
• Klaus Kern and
• Uta Schlickum

Beilstein J. Nanotechnol. 2017, 8, 1388–1395, doi:10.3762/bjnano.8.140

• [1][2] but furthermore to probe its electronic properties [3]. Aromatic molecules deposited onto a metal surface are known to interact through their π-orbitals via van der Waals interactions with the free electron gas at the metal surface [4]. This can lead to a charge-transfer process with or

Deposition of exchange-coupled dinickel complexes on gold substrates utilizing ambidentate mercapto-carboxylato ligands

• Martin Börner,
• Laura Blömer,
• Marcus Kischel,
• Peter Richter,
• Georgeta Salvan,
• Dietrich R. T. Zahn,
• Pablo F. Siles,
• Maria E. N. Fuentes,
• Carlos C. B. Bufon,
• Daniel Grimm,
• Oliver G. Schmidt,
• Daniel Breite,
• Bernd Abel and
• Berthold Kersting

Beilstein J. Nanotechnol. 2017, 8, 1375–1387, doi:10.3762/bjnano.8.139

• surely validate the atom connectivity of the [Ni2L(L’)]+ complex and the binding mode of the coligands. Figure 2 shows ORTEP and van der Waals representations of the structure of the [Ni2L(HL4)]+ cation in 6, with the mercaptohexanoate unit bridging the two Ni(II) ions in a symmetrical fashion as

• that van der Waals interactions exist between the Au surface and the alkyl (methylene and methyl) groups of the supporting ligands. Transport measurements In orienting experiments, the deposition of complex 2 on gold was further investigated by transport measurements using an approach based on self

• over a monolayer of chemisorbed molecules of 2 previously synthesized on a thin gold film deposited onto a silicon pillar (for details, see Supporting Information File 1). Ambidentate ligands with soft (–SH, –PPh2) and hard (–CO2H) donor functions. ORTEP (left) and van der Waals representations (right

Charge transport in organic nanocrystal diodes based on rolled-up robust nanomembrane contacts

• Vineeth Kumar Bandari,
• Lakshmi Varadharajan,
• Longqian Xu,
• Abdur Rehman Jalil,
• Mirunalini Devarajulu,
• Pablo F. Siles,
• Feng Zhu and
• Oliver G. Schmidt

Beilstein J. Nanotechnol. 2017, 8, 1277–1282, doi:10.3762/bjnano.8.129

• usually realized by thermal evaporation in vacuum. The molecules have van der Waals interaction with an inert substrate which makes them weakly bonded to the substrate [11]. As a result, by controlling the molecules deposition parameters, such as deposition rate and the substrate temperature, it is

Characterization of ferrite nanoparticles for preparation of biocomposites

• Urszula Klekotka,
• Magdalena Rogowska,
• Dariusz Satuła and
• Beata Kalska-Szostko

Beilstein J. Nanotechnol. 2017, 8, 1257–1265, doi:10.3762/bjnano.8.127

• set of particles. In particular, noncovalent interactions are the most important in terms of biological aspects [5]. A drawback of applying magnetic nanoparticles is that they possess a strong tendency to agglomerate due to not only van der Waals or electrostatic forces but also magnetic interactions

Preparation of thick silica coatings on carbon fibers with fine-structured silica nanotubes induced by a self-assembly process

• Benjamin Baumgärtner,
• Hendrik Möller,
• Thomas Neumann and
• Dirk Volkmer

Beilstein J. Nanotechnol. 2017, 8, 1145–1155, doi:10.3762/bjnano.8.116

• separate (non-immobilized) silica particles. In principle, catalytic active polyamines can be localized on the surface of carbon fibers by covalent linkage or by weak van der Waals forces. The latter will be demonstrated for the self-assembly of long-chain polyamines, namely LPEI, in the following chapter

• with surface-confined LPEI aggregates While the short-chain polyamine TEPA was covalently bound to the carbon fiber surface, the suitability of linear poly(ethylenimine) for a self-assembly process can be used to localize the polyamine on the fiber surface via van der Waals forces. This way, a coating

Adsorption characteristics of Er₃N@C₈₀on W(110) and Au(111) studied via scanning tunneling microscopy and spectroscopy

• Sebastian Schimmel,
• Zhixiang Sun,
• Danny Baumann,
• Denis Krylov,
• Nataliya Samoylova,
• Alexey Popov,
• Bernd Büchner and
• Christian Hess

Beilstein J. Nanotechnol. 2017, 8, 1127–1134, doi:10.3762/bjnano.8.114

• clear change of the reconstruction of the Au(111) surface. Considering the fact that the surface reconstruction of the pristine Au(111) is driven by a remarkable energy gain on 20 meV per Au-atom [22], and that van der Waals bond molecular layers on Au(111) typically leave the herringbone reconstruction

• unchanged [23] our observation of a modification of the reconstruction implies a molecular substrate interaction stronger than typical van der Waals interaction. A certain degree of hybridization of the molecules and Au(111) surface electronic structure is therefore conjectured. In order to investigate this

• probably accompanied with charge transfer. Therefore the bonding character is conjectured to exceed the strength of van der Waals interaction. Topographic image (U = 2 V; I = 0.5 nA) of Er3N@C80 on W(110). The molecules appear as bright round structures on the straight monoatomic steps of W(110). The

Growth, structure and stability of sputter-deposited MoS₂ thin films

• Reinhard Kaindl,
• Bernhard C. Bayer,
• Roland Resel,
• Thomas Müller,
• Viera Skakalova,
• Gerlinde Habler,
• Rainer Abart,
• Alexey S. Cherevan,
• Dominik Eder,
• Maxime Blatter,
• Fabian Fischer,
• Jannik C. Meyer,
• Dmitry K. Polyushkin and
• Wolfgang Waldhauser

Beilstein J. Nanotechnol. 2017, 8, 1115–1126, doi:10.3762/bjnano.8.113

• covalently bonded, hexagonally coordinated S–Mo–S layers, bonded to neighbouring layers by weak van der Waals forces [1][2][3]. One of the unique features of MoS2 is the polymorphism with distinct electronic characteristics [4]. Depending on the arrangement of S atoms, several distinct symmetries may form

Stable Au–C bonds to the substrate for fullerene-based nanostructures

• Taras Chutora,
• Jesús Redondo,
• Bruno de la Torre,
• Martin Švec,
• Pavel Jelínek and
• Héctor Vázquez

Beilstein J. Nanotechnol. 2017, 8, 1073–1079, doi:10.3762/bjnano.8.109

• energies of these two structures is (in the absence of van der Waals forces) close to zero. This indicates that changes in the electronic structure arising from the vacancy when it is oriented towards vacuum do not significantly affect the metal–molecule contact. In contrast to the value of the defect-down

• structure, previous calculations on C60/Au(111) have established that the binding energy results almost solely from van der Waals interactions [43]. Finally, we also considered the case of a double vacancy. Calculations for the binding of a C58 molecule with the defect pointing towards the metal result in a

Scaling law to determine peak forces in tapping-mode AFM experiments on finite elastic soft matter systems

• Horacio V. Guzman

Beilstein J. Nanotechnol. 2017, 8, 968–974, doi:10.3762/bjnano.8.98

• these theoretical approximations have been applied to derive a parametrical equation for determining the peak force based on the addition of repulsive Hertzian and attractive van der Waals interactions in low-damping environments [21]. Here we have conceived a multivariate regression analysis to obtain

Triptycene-terminated thiolate and selenolate monolayers on Au(111)

• Jinxuan Liu,
• Martin Kind,
• Björn Schüpbach,
• Daniel Käfer,
• Stefanie Winkler,
• Wenhua Zhang,
• Andreas Terfort and
• Christof Wöll

Beilstein J. Nanotechnol. 2017, 8, 892–905, doi:10.3762/bjnano.8.91

• nature of the backbones of the SAM-building molecules [1][4]. It is well-known that long-chained alkyl moieties [9] promote the formation of well-ordered thiolate monolayers on gold via van der Waals forces. Another example for highly crystalline monolayers are biphenyl [10][11][12] and terphenyl [13][14