Laser ablation in liquids for shape-tailored synthesis of nanomaterials: status and challenges

• Natalie Tarasenka

Beilstein J. Nanotechnol. 2025, 16, 1963–1997, doi:10.3762/bjnano.16.137

• . Similarly, spherical CuS NPs were produced upon ablation of a Cu target in the same experimental conditions. Therefore, the authors suggest the participation of Cu as a catalyst for the growth of ZnS nanowires. Even more complex reaction pathways were suggested by Tian et al. [25] for the formation of PbS

Piezoelectricity of layered double hydroxides: perspectives regarding piezocatalysis and nanogenerators

• Evgeniy S. Seliverstov,
• Evgeniya A. Tarasenko and
• Olga E. Lebedeva

Beilstein J. Nanotechnol. 2025, 16, 1812–1817, doi:10.3762/bjnano.16.124

• materials, in some cases having an advantage over three-dimensional bulk counterparts [4]. Traditionally, LDHs are known as adsorbents, anion exchangers, catalysts, and catalyst precursors, but the wide range of their properties is not limited to this, as the discovery of piezoelectric properties has shown

• /Al-LDHs. The crystal structure of LDHs is fairly flexible, enabling adjustment of their cationic composition. One widely used method for preparing LDH-based catalysts is cation doping further increasing their catalytic activity. A cobalt-doped Zn/Al-LDH (ZnCo/Al-LDH) piezoelectric catalyst was used

• for activating peroxymonosulfate (PMS) to degrade norfloxacin [9]. The obtained catalyst demonstrated effective degradation within 15 min, achieving a degradation efficiency of 91.50% and a rate constant of 0.1644 min−1. In this study, the main PMS activation mechanism was non-radical. The

Ambient pressure XPS at MAX IV

• Mattia Scardamaglia,
• Ulrike Küst,
• Alexander Klyushin,
• Rosemary Jones,
• Jan Knudsen,
• Robert Temperton,
• Andrey Shavorskiy and
• Esko Kokkonen

Beilstein J. Nanotechnol. 2025, 16, 1677–1694, doi:10.3762/bjnano.16.118

• here. Instead, we focus on a study by Vesselli and co-workers that directly addresses catalytic activity in a biomimetic SAC system [20][21]. In their work, a cobalt single-atom biomimetic model catalyst is based on a self-assembled monolayer of Co-porphyrins grown on an almost free-standing graphene

• simultaneously. This is summarized in Figure 5 where the 2D intensity plot vs temperature of O 1s and N 1s or C 1s, for hBN or graphene, respectively, are reported. Time-resolved catalysis Catalysts are inherently dynamic systems. The optimal catalyst should have a nanostructure that enhances activation kinetics

• , contain active sites that are dynamically stabilized, and be in a state of deviation from chemical equilibrium under reaction conditions. Therefore, fully describing a functional catalyst requires addressing a range of dynamics across multiple temporal scales. To examine such a dynamic at the atomic level

Nanotechnology-based approaches for the removal of microplastics from wastewater: a comprehensive review

• Nayanathara O Sanjeev,
• Manjunath Singanodi Vallabha and
• Rebekah Rubidha Lisha Rabi

Beilstein J. Nanotechnol. 2025, 16, 1607–1632, doi:10.3762/bjnano.16.114

• include ultraviolet-induced oxidation, ozone-based oxidation, photocatalysis (activated by UV, solar, or visible light), electrochemical oxidation, and persulfate-activated oxidation [57]. In photocatalysis, photons excite the catalyst, generating electron–hole pairs that trigger redox reactions with the

• semiconductor catalyst. In contrast, for reduction to occur, the redox potential must be lower than the conduction band edge. This is because, upon excitation, holes generated in the valence band participate in oxidation reactions, whereas the electrons excited to the conduction band drive the reduction

Photocatalytic degradation of ofloxacin in water assisted by TiO₂ nanowires on carbon cloth: contributions of H₂O₂ addition and substrate absorbability

• Iram Hussain,
• Lisha Zhang,
• Zhizhen Ye and
• Jin-Ming Wu

Beilstein J. Nanotechnol. 2025, 16, 1567–1579, doi:10.3762/bjnano.16.111

• retained over 90% of its efficiency even after 6 cycles demonstrates the stability of the CC/NW-450 °C photocatalyst. SEM and XRD data of the catalyst after the recycling experiment are shown in Figure S8 in Supporting Information File 1, from which no remarkable change can be seen because of its high

• structural stability. High photocatalytic activity over multiple cycles, along with simple, low-cost, and stable operation, are the key parameters for their promising applications in practical wastewater treatment, in which the frequent replacement or regeneration of the catalyst must be avoided. Influence

• catalyst alone, indicating that the limited •OH radical generation was effectively quenched by n-butanol. As H2O2 concentration increased to 10 mM, a slight improvement in degradation was observed, suggesting that •OH radical production began to exceed the scavenging capacity of n-butanol. The most

Influence of laser beam profile on morphology and optical properties of silicon nanoparticles formed by laser ablation in liquid

• Natalie Tarasenka,
• Vladislav Kornev,
• Alena Nevar and
• Nikolai Tarasenko

Beilstein J. Nanotechnol. 2025, 16, 1533–1544, doi:10.3762/bjnano.16.108

• temperature [5][22] or pressure [23], or the presence of a catalyst [24]. Consequently, alternative approaches for the formation of Si nanowires by laser ablation in liquid environment and under ambient conditions are of high interest. In this work, we have applied a method based on the change of the spatial

Cross-reactivities in conjugation reactions involving iron oxide nanoparticles

• Shoronia N. Cross,
• Katalin V. Korpany,
• Hanine Zakaria and
• Amy Szuchmacher Blum

Beilstein J. Nanotechnol. 2025, 16, 1504–1521, doi:10.3762/bjnano.16.106

• commonly used click reactions and shows high specificity [15][16]. The Cu(I) catalyst increases the coupling rate of azides and alkynes by up to seven orders of magnitude, forming triazole rings, which possess exceptional chemical stability [16]. For these reasons, the CuAAC has been utilized extensively

• ) catalyst (Figure 3B.ii), and one in which IONP-3,4-DHBA (no alkynes) was subjected to the full CuAAC reaction (Figure 3B.iii). We see that, in both controls, there is no detectable Cy5 loading on the IONPs, which suggests that the loading of Cy5-azide is, in fact, through the CuAAC, thus providing strong

• /NHS activation. In the absence of the Cu(I) catalyst, we see no trace of Cy5 on the EDC-free control (Figure 3C.ii), which confirms that Cy5-azide is loading to the control through the CuAAC. This further provides evidence that, in the absence of EDC/NHS activation, PPA must still somehow bind to IONP

Laser processing in liquids: insights into nanocolloid generation and thin film integration for energy, photonic, and sensing applications

• Akshana Parameswaran Sreekala,
• Pooja Raveendran Nair,
• Jithin Kundalam Kadavath,
• Bindu Krishnan,
• David Avellaneda Avellaneda,
• M. R. Anantharaman and
• Sadasivan Shaji

Beilstein J. Nanotechnol. 2025, 16, 1428–1498, doi:10.3762/bjnano.16.104

Parylene-coated platinum nanowire electrodes for biomolecular sensing applications

• Chao Liu,
• Peker Milas,
• Michael G. Spencer and
• Birol Ozturk

Beilstein J. Nanotechnol. 2025, 16, 1392–1400, doi:10.3762/bjnano.16.101

• water as a catalyst, then the final product gluconolactone was generated [28][29]. These reactions were illustrated in Scheme 2. Similarly, peaks were observed to be same during the reverse scan [29]. Based on curve shape and reaction mechanism, the peaks from the reverse curve around 50 mV were

Ferroptosis induction by engineered liposomes for enhanced tumor therapy

• Alireza Ghasempour,
• Mohammad Amin Tokallou,
• Mohammad Reza Naderi Allaf,
• Mohsen Moradi,
• Hamideh Dehghan,
• Mahsa Sedighi,
• Mohammad-Ali Shahbazi and
• Fahimeh Lavi Arab

Beilstein J. Nanotechnol. 2025, 16, 1325–1349, doi:10.3762/bjnano.16.97

• independently of GSH deficiency (or GSH depletion). Hemin initiates this reaction as an iron catalyst to respond to the excess H2O2 [29]. Another way of triggering ferroptosis is the oxidation of unsaturated lipids by an iron redox couple, which can also lead to ferroptosis. This process of inducing ferroptosis

• ferrocene (a green Fenton catalyst) was calculated to be about 43.4%. Liposome-PEG loaded with ferrocene showed increased ferrocene release in the presence of H2O2 and under acidic conditions while preventing significant leakage of ferrocene during circulation of body fluids. It has been suggested that

Deep-learning recognition and tracking of individual nanotubes in low-contrast microscopy videos

• Vladimir Pimonov,
• Said Tahir and
• Vincent Jourdain

Beilstein J. Nanotechnol. 2025, 16, 1316–1324, doi:10.3762/bjnano.16.96

• , horizontally aligned carbon nanotubes (HA-CNTs) were synthesized inside a miniature chemical vapor deposition (CVD) cell with an optical window (Linkam TS1500). ST-cut quartz and iron nanoparticles served as substrate and catalyst, respectively. Ethanol and argon were, respectively, used as carbon precursor

• a deep learning model to recognize and track both growing nanotubes (dark segments) and structural changes (bright segments) in such differential videos. The model was also trained at recognizing optical marks and catalyst lines (Figure 2) [20]. Kinetic data extraction proceeded in the following

• [24] (Supporting Information File 1, Table S1). The fully trained model detected segments corresponding to nanotube growth and structural changes, as well as optical marks and catalyst lines (Supporting Information File 1, Figure S5, and Supporting Information File 3). This process was conducted frame

Crystalline and amorphous structure selectivity of ignoble high-entropy alloy nanoparticles during laser ablation in organic liquids is set by pulse duration

• Robert Stuckert,
• Felix Pohl,
• Oleg Prymak,
• Ulrich Schürmann,
• Christoph Rehbock,
• Lorenz Kienle and
• Stephan Barcikowski

Beilstein J. Nanotechnol. 2025, 16, 1141–1159, doi:10.3762/bjnano.16.84

• on density functional theory calculations of binding energies and machine learning algorithms for an efficient catalyst design [15][17][19]. The synthesis of HEA NPs has been realized by many methods, including carbothermal shock synthesis (CTS) [20][21], chemical reduction [22][23], fast-moving bed

Soft materials nanoarchitectonics: liquid crystals, polymers, gels, biomaterials, and others

• Katsuhiko Ariga

Beilstein J. Nanotechnol. 2025, 16, 1025–1067, doi:10.3762/bjnano.16.77

Heat-induced transformation of nickel-coated polycrystalline diamond film studied in situ by XPS and NEXAFS

• Olga V. Sedelnikova,
• Yuliya V. Fedoseeva,
• Dmitriy V. Gorodetskiy,
• Yuri N. Palyanov,
• Elena V. Shlyakhova,
• Eugene A. Maksimovskiy,
• Anna A. Makarova,
• Lyubov G. Bulusheva and
• Aleksandr V. Okotrub

Beilstein J. Nanotechnol. 2025, 16, 887–898, doi:10.3762/bjnano.16.67

• coating of diamond surface with a metal catalyst has been explored to reduce the temperatures required for the initiation of the graphitization process. Nickel [17][18][19][20][21][22][23][24], iron [25][26][27][28], copper [29][30], gallium [31], and molybdenum [32] allow the fabrication of graphene-on

• SCD surface into graphene requires annealing at temperatures above 800 °C [21]. The annealing of nanocrystalline diamond (NCD) films in the presence of a Ni catalyst has been recently explored [22][23][24]. It was shown that graphitization of Ni-coated NCD films begins at a relatively lower

• findings that the metal catalyst induces the formation of disordered carbon on the diamond surface during annealing [21][22][23]. All spectra also show a weak feature at 285.5 eV, which corresponds to the electron transitions from C 1s to unoccupied π* states in sp2-hybridized carbon species (π*(sp2)). It

Insights into the electronic and atomic structures of cerium oxide-based ultrathin films and nanostructures using high-brilliance light sources

• Paola Luches and
• Federico Boscherini

Beilstein J. Nanotechnol. 2025, 16, 860–871, doi:10.3762/bjnano.16.65

• its sensitivity, the method, when combined with other techniques, has provided quantitative information on the number of electrons transferred per particle to the support (Figure 2), enabling the optimization of the size of the supported active Pt catalyst [27]. This is a crucial factor in minimizing

• active sites in catalysts is a crucial problem in view of the optimization of catalyst efficiency and selectivity. The possibility of carrying out spectroscopic studies under conditions as close as possible to ambient pressure has largely contributed to this goal. The application of these methods to

• model catalyst”, pages 8-13, Copyright (2019), with permission from Elsevier. This content is not subject to CC BY 4.0. (a) Ce–O interatomic distances for 2 ML and 10 ML CeO2 films evaluated by fitting Ce L3-edge EXAFS with the electric field parallel (dCe−O PAR) and perpendicular (dCe−O PER) to the

Facile one-step radio frequency magnetron sputtering of Ni/NiO on stainless steel for an efficient electrode for hydrogen evolution reaction

• Ha Huu Do,
• Khac Binh Nguyen,
• Phuong N. Nguyen and
• Hoai Phuong Pham

Beilstein J. Nanotechnol. 2025, 16, 837–846, doi:10.3762/bjnano.16.63

• energy of hydrogen/water adsorption. Also, inexpensiveness and high durability are positive aspects regarding large-scale applications. For instance, Oshchepkov and coworkers revealed that the efficacy of NiO in cleaving H–OH bonds accelerated the formation of hydrogen on a Ni metal catalyst [17]. Yan

• electrocatalytic applications [30]. For instance, Wang et al. deposited nickel–iron on SS, which was used as a high-performance electrode for water oxidation [31]. Hence, in this study, we utilized commercial 304 SS and coated it with the Ni/NiO catalyst through a one-step radio frequency (RF) magnetron sputtering

• exhibited a moderate O2 content (11.96 wt %), which could bring the highest HER efficiency. The Ni/NiO ratio is the most crucial parameter in the Ni/NiO catalyst system, influencing the electrode’s HER efficiency, which Yan and coworkers proved [18]. The Raman spectrum of the Ni/NiO/SS-10 electrode

Feasibility analysis of carbon nanofiber synthesis and morphology control using a LPG premixed flame

• Iftikhar Rahman Bishal,
• Muhammad Hilmi Ibrahim,
• Norikhwan Hamzah,
• Mohd Zamri Mohd Yusop,
• Faizuan Bin Abdullah,
• I Putu Tedy Indrayana and
• Mohd Fairus Mohd Yasin

Beilstein J. Nanotechnol. 2025, 16, 581–590, doi:10.3762/bjnano.16.45

• . An optimum height above burner of 10 mm at which the temperature is around 650 °C was used in the synthesis process. Zirconia beads impregnated with nickel nitrate catalyst have been employed. Dense CNF growth with an average diameter of 77.9 nm was observed at an equivalence ratio of 1.8; as the

• nucleation rate, which in turn increases the catalyst particle size and the amount of free carbon atoms, producing CNFs with larger diameters and amorphous carbon. According to Raman analysis, the grown CNFs have a high number of defects, which may be good for applications where defective nanomaterials are

• optimization of CNT/CNF synthesis in flame environments. An ethylene/air co-flow, non-premixed flame was used with a catalyst substrate of iron, nickel, and platinum wires of 0.1–0.25 mm diameter. The study found that carbon monoxide is a major contributor to CNT formation in flames, and the model also showed

Zeolite materials with Ni and Co: synthesis and catalytic potential in the selective hydrogenation of citral

• Inocente Rodríguez-Iznaga,
• Yailen Costa Marrero,
• Tania Farias Piñeira,
• Céline Fontaine,
• Lexane Paget,
• Beatriz Concepción Rosabal,
• Arbelio Penton Madrigal,
• Vitalii Petranovskii and
• Gwendoline Lafaye

Beilstein J. Nanotechnol. 2025, 16, 520–529, doi:10.3762/bjnano.16.40

• Ni2+ isolated cations, attributed to synergistic interactions that weakened the cation–framework binding. Catalytic activity tests showed that nickel species were primarily responsible for citronellal formation. Among all materials, the bimetallic CoNiIE catalyst, prepared by IE, was the only one to

• and cinnamaldehyde [3][14][15]. Zeolites modified with nickel and cobalt have shown promising results in selective hydrogenation reactions, owing to their high dispersion of active sites and tunable acidity. For instance, a zeolite-supported Ni catalyst has demonstrated selectivity in furfural

• hydrogenation and the formation of citronellal are higher for catalysts containing nickel compared to those containing cobalt (Figure 6). This suggests that the most active catalytic sites for the conversion of citral to citronellal are associated with nickel species. Notably, the bimetallic CoNiZIE catalyst is

Effect of additives on the synthesis efficiency of nanoparticles by laser-induced reduction

• Rikuto Kuroda,
• Takahiro Nakamura,
• Hideki Ina and
• Shuhei Shibata

Beilstein J. Nanotechnol. 2025, 16, 464–472, doi:10.3762/bjnano.16.35

• water electrolysis catalyst than IrO2 [32]. The combination and composition of elements are important to achieve superior properties to those of pure metal nanoparticles. The typical method for nanoparticles synthesis such as chemical reduction with thermal equilibrium reaction is basically limited to

Quantification of lead through rod-shaped silver-doped zinc oxide nanoparticles using an electrochemical approach

• Ravinder Lamba,
• Gaurav Bhanjana,
• Neeraj Dilbaghi,
• Vivek Gupta and
• Sandeep Kumar

Beilstein J. Nanotechnol. 2025, 16, 422–434, doi:10.3762/bjnano.16.33

• of oxygen on the surface by means of the formation of oxygen vacancies, leading to enhanced catalytic activity. Also, the small doping of Ag introduces more active sites on the catalyst surface, potentially improving the overall catalytic activity [12][13]. This study demonstrates an efficient and

ReactorAFM/STM – dynamic reactions on surfaces at elevated temperature and atmospheric pressure

• Tycho Roorda,
• Hamed Achour,
• Matthijs A. van Spronsen,
• Marta E. Cañas-Ventura,
• Sander B. Roobol,
• Willem Onderwaater,
• Mirthe Bergman,
• Peter van der Tuijn,
• Gertjan van Baarle,
• Johan W. Bakker,
• Joost W. M. Frenken and
• Irene M. N. Groot

Beilstein J. Nanotechnol. 2025, 16, 397–406, doi:10.3762/bjnano.16.30

• AFM; model catalysts; nc-AFM; operando catalysis; qPlus tuning fork sensor; Introduction Operando catalysis is the field of research that monitors the structure, composition, and morphology of a catalyst while simultaneously investigating its activity, reactivity, and selectivity under industrially

• whether a given catalyst becomes reactive, is referred to as the pressure gap. To provide an interpretive framework for catalysts under industrial conditions, new experimental and theoretical analysis tools are required. While recent years have witnessed a tremendous effort in this direction [3], many of

• these techniques are photon-based [4][5][6][7][8][9]. Even though they provide valuable insights, the development of surface-sensitive techniques that can image the catalyst at the atomic scale under high-pressure and high-temperature conditions remains crucial. In attempting to close the pressure gap

Engineered PEG–PCL nanoparticles enable sensitive and selective detection of sodium dodecyl sulfate: a qualitative and quantitative analysis

• Soni Prajapati and
• Ranjana Singh

Beilstein J. Nanotechnol. 2025, 16, 385–396, doi:10.3762/bjnano.16.29

• vigorously stirred in a silicon oil bath at 130 °C. Subsequently, a syringe introduced 2 mL of ε-caprolactone and 1 mL of stannous octoate (as a reaction catalyst) into the molten mPEG. The polymerization reaction was conducted under vacuum with continuous stirring at 130 °C for 24 h. After the

• nanoparticles that can interact with both aqueous and non-aqueous environments. The synthesis begins with the interaction of the metal oxide initiator, tin(II) 2-ethylhexanoate (Sn(oct)2), with the monomers ethylene oxide and ε-caprolactone. Sn(oct)2 acts as a catalyst, activating the monomers by generating

• , respectively. The presence of carbon and oxygen peaks confirms the composition of the PEG–PCL polymer matrix, while the tin peak is attributable to the stannous octoate catalyst used during the synthesis of the nanoparticles. The absence of unexpected peaks in the XPS spectra indicates that no significant

Pulsed laser in liquid grafting of gold nanoparticle–carbon support composites

• Madeleine K. Wilsey,
• Teona Taseska,
• Qishen Lyu,
• Connor P. Cox and
• Astrid M. Müller

Beilstein J. Nanotechnol. 2025, 16, 349–361, doi:10.3762/bjnano.16.26

• reactions and can create unwanted side products [7]. Long-term surfactant stability and associated catalyst agglomeration or detachment are another issue. Post-synthetic attachment of catalyst nanoparticles is poorly scalable, creates large amounts of organic hazardous waste, and results in wastage of

• unattached catalyst material, which is especially problematic with precious catalysts. Overall, separate nanoparticle synthesis–attachment produces composites with adhesion, durability, electrical contact, and concomitant energy efficiency issues. Here, we report a new one-step pulsed laser grafting process

• methodology is more rapid and efficient than existing processes because it obviates the heating, cooling, and separation steps of traditional chemical nanoparticle syntheses. It additionally eliminates post-synthetic attachment of catalyst nanoparticles that results in wastage of unattached catalyst material

Emerging strategies in the sustainable removal of antibiotics using semiconductor-based photocatalysts

• Yunus Ahmed,
• Keya Rani Dutta,
• Parul Akhtar,
• Md. Arif Hossen,
• Md. Jahangir Alam,
• Obaid A. Alharbi,
• Hamad AlMohamadi and
• Abdul Wahab Mohammad

Beilstein J. Nanotechnol. 2025, 16, 264–285, doi:10.3762/bjnano.16.21

• effectively promotes the degradation of antibiotics from contaminated water. Researchers have conducted experiments to evaluate the efficacy of various photocatalysts in eliminating different antibiotics from their respective environments. Research on catalyst composition and application has evolved through

• hydrogen electrode (NHE)). In this reductive pathway, the photoexcited electrons have the ability to interact with electron acceptors, like O2, which can be found on the catalyst surface or dissolved in water. This reaction reduces O2, forming a superoxide radical anion (O2•−) (O2 + e− → O2•−) [35][55

• ]. Additionally, H2O2 can be generated by transferring electrons from the conduction band to the adsorbed O2. Because the CB of the catalyst has a higher negative potential than the O2/H2O2 system (+0.682 eV vs NHE), the generated H2O2 subsequently reacts with electrons generated by light to yield active HO

Clays enhanced with niobium: potential in wastewater treatment and reuse as pigment with antibacterial activity

• Silvia Jaerger,
• Patricia Appelt,
• Mario Antônio Alves da Cunha,
• Fabián Ccahuana Ayma,
• Ricardo Schneider,
• Carla Bittencourt and
• Fauze Jacó Anaissi

Beilstein J. Nanotechnol. 2025, 16, 141–154, doi:10.3762/bjnano.16.13

• +) favoring of the BEOx catalyst hindered its photocatalytic activity [8]. In a study by Asencios et al. (2019) [8], niobium-modified clay was explored for the photocatalysis of rhodamine B dye, yielding removal rates close to 95%. Additionally, Lacerda et al. (2020) [25] achieved up to 90% efficiency in the