Prediction of Co and Ru nanocluster morphology on 2D MoS₂ from interaction energies

• Cara-Lena Nies and
• Michael Nolan

Beilstein J. Nanotechnol. 2021, 12, 704–724, doi:10.3762/bjnano.12.56

• charges. Single-atom adsorption Co and Ru atoms adsorb exothermically at all three adsorption sites. A single Co atom adsorbs most strongly at site atop_Mo, with an energy gain of −5.82 eV, followed by site hollow and site atop_S, with energy gains of −5.55 eV and −4.21 eV, respectively. A single Ru atom

• adsorbs preferentially at site atop_Mo with an energy gain of −3.92 eV, followed by site hollow and site atop_S, with energy gains of −3.40 eV and −2.47 eV, respectively. Similarly to Cu, for both Co and Ru, site atop_Mo is the most favourable adsorption site. This is likely due to the adatom position

• , (b) ML rearrangements including incorporation of metal atoms into the S layer and (c) formation of metal–S clusters. Incorporation of adatoms into the surface layer is known to increase the metal–substrate interaction, as is the lack of metal–metal bonds [48]. A gain in the metal–substrate

Nanogenerator-based self-powered sensors for data collection

• Yicheng Shao,
• Maoliang Shen,
• Yuankai Zhou,
• Xin Cui,
• Lijie Li and
• Yan Zhang

Beilstein J. Nanotechnol. 2021, 12, 680–693, doi:10.3762/bjnano.12.54

• deployment and maintenance of sensors will bring challenges for intelligent transportation systems. PENGs/TENGs can gain energy from vibrations without the need for an energy grid. In 2013, Lin et al. [3] proposed a transparent and flexible PENG (TFNG) based on a flexible polydimethylsiloxane (PDMS

Fate and transformation of silver nanoparticles in different biological conditions

• Barbara Pem,
• Marija Ćurlin,
• Darija Domazet Jurašin,
• Valerije Vrček,
• Rinea Barbir,
• Vedran Micek,
• Raluca M. Fratila,
• Jesus M. de la Fuente and
• Ivana Vinković Vrček

Beilstein J. Nanotechnol. 2021, 12, 665–679, doi:10.3762/bjnano.12.53

• PVP-AgNPs, as observed in Figure 2b, occurred already in the circulation as blood represents a chloride-rich medium. To gain more detailed insight into the biotransformation of AgNPs, differently coated AgNPs were incubated for 30 min at a concentration of 100 mg Ag/L in PBS, whole blood (WB), blood

• AgNPs in artificial biological media In order to gain more coherent insight into the transformation of different AgNPs in biological media, we examined changes in their size, surface charge, and dissolution in simpler media (i.e., CCM, m(CCM+BSA), mCYS, m(CYS+BSA), mGSH, m(GSH+BSA), ALF, and AGF, see

• AgNPs enter the body where they gain a protein corona, aggregate, and dissolve to Ag+. Ionic silver may precipitate in the anion-rich environment of different tissues, where Ag binds to S, resulting in nanocrystals. Aggregation and corona–NP destabilisation can also lead to precipitation. Whole blood

A review of defect engineering, ion implantation, and nanofabrication using the helium ion microscope

• Frances I. Allen

Beilstein J. Nanotechnol. 2021, 12, 633–664, doi:10.3762/bjnano.12.52

• backscattered electrons from the substrate and the secondary electrons they generate. In contrast, for ion beam lithography, the sensitivity gain can be orders of magnitude higher and the proximity effect is dramatically reduced, due to the much lower propensity of the ions to backscatter. However, before the

Properties of graphene deposited on GaN nanowires: influence of nanowire roughness, self-induced nanogating and defects

• Jakub Kierdaszuk,
• Piotr Kaźmierczak,
• Justyna Grzonka,
• Aleksandra Krajewska,
• Aleksandra Przewłoka,
• Wawrzyniec Kaszub,
• Zbigniew R. Zytkiewicz,
• Marta Sobanska,
• Maria Kamińska,
• Andrzej Wysmołek and
• Aneta Drabińska

Beilstein J. Nanotechnol. 2021, 12, 566–577, doi:10.3762/bjnano.12.47

• absorption [9]. However, the interaction between corrugated nanowire substrate and graphene could substantially increase the scattering of carriers in a graphene electrode and decrease its conductivity. Therefore, detailed studies of the interaction between nanowire substrate and graphene are crucial to gain

The preparation temperature influences the physicochemical nature and activity of nanoceria

• Robert A. Yokel,
• Wendel Wohlleben,
• Johannes Georg Keller,
• Matthew L. Hancock,
• Jason M. Unrine,
• D. Allan Butterfield and
• Eric A. Grulke

Beilstein J. Nanotechnol. 2021, 12, 525–540, doi:10.3762/bjnano.12.43

• . Solvothermally synthesized nanoceria dissolve in acidic environments, accelerated by carboxylic acids. NM-212 dissolution has been reported to be minimal. To gain insight into the role of high-temperature exposure on nanoceria dissolution, product susceptibility to carboxylic acid-accelerated dissolution, and

The impact of molecular tumor profiling on the design strategies for targeting myeloid leukemia and EGFR/CD44-positive solid tumors

• Nikola Geskovski,
• Nadica Matevska-Geshkovska,
• Simona Dimchevska Sazdovska,
• Marija Glavas Dodov,
• Kristina Mladenovska and
• Katerina Goracinova

Beilstein J. Nanotechnol. 2021, 12, 375–401, doi:10.3762/bjnano.12.31

• macrophages protrude through the vascular endothelial wall to gain access and monitor blood circulation [24]. Hussain et al demonstrated that perisinusoidal macrophages are responsible for the accumulation of the chylomicrons in the BM and, hence, play a crucial role in the delivery of lipids, as a source of

Structural and optical characteristics determined by the sputtering deposition conditions of oxide thin films

• Petronela Prepelita,
• Florin Garoi and
• Valentin Craciun

Beilstein J. Nanotechnol. 2021, 12, 354–365, doi:10.3762/bjnano.12.29

• was possible to gain information related to the thickness of our samples. The high-resolution elementary microanalysis of the cross section perpendicular to the surface of the thin films was performed in manual mode, where the adjustment device allowed the manual setting of the tilt angle from −90° to

Nickel nanoparticle-decorated reduced graphene oxide/WO₃ nanocomposite – a promising candidate for gas sensing

• Ilka Simon,
• Alexandr Savitsky,
• Rolf Mülhaupt,
• Vladimir Pankov and
• Christoph Janiak

Beilstein J. Nanotechnol. 2021, 12, 343–353, doi:10.3762/bjnano.12.28

• mbar for several days. Then rGO was dispersed with Ni(COD)2 in [BMIm][NTf2] to gain 0.5 wt % metal nanoparticles and 0.5 wt % rGO. In order to stir the reaction mixture during the microwave decomposition, 0.5 wt % rGO could not be exceeded. The obtained nanomaterial was analyzed using powder X-ray

Intracranial recording in patients with aphasia using nanomaterial-based flexible electronics: promises and challenges

• Qingchun Wang and
• Wai Ting Siok

Beilstein J. Nanotechnol. 2021, 12, 330–342, doi:10.3762/bjnano.12.27

• heat and cause damage to the brain, especially during long-term implantation. Further investigations are required to design electronics that are compatible with the human brain for intracranial recording. Fortunately, with the advancement of brain imaging technology, it is highly possible to gain a

Exploring the fabrication and transfer mechanism of metallic nanostructures on carbon nanomembranes via focused electron beam induced processing

• Christian Preischl,
• Linh Hoang Le,
• Elif Bilgilisoy,
• Armin Gölzhäuser and
• Hubertus Marbach

Beilstein J. Nanotechnol. 2021, 12, 319–329, doi:10.3762/bjnano.12.26

• metallic nanostructures fabricated via EBID and Fe(CO)5 remain unchanged, besides oxidation. This result was achieved by using a SAM consisting of 1,1′,4′,1′′-terphenyl-4-thiol (TPT) on a Au substrate [21]. In this work, we want to gain more insight into the underlying processes yielding such hybrid

• [33]. The bright circular shape around the structure depicted in Figure 4c can be explained by an incomplete dissolution process. After removing the sample from the Fe(NO3)3 solution this type of deformed structure remains. To gain further insight into the effect of the Fe(NO3)3 solution onto the

Scanning transmission helium ion microscopy on carbon nanomembranes

• Daniel Emmrich,
• Annalena Wolff,
• Nikolaus Meyerbröker,
• Jörg K. N. Lindner,
• André Beyer and
• Armin Gölzhäuser

Beilstein J. Nanotechnol. 2021, 12, 222–231, doi:10.3762/bjnano.12.18

• within a set of images. The grid of the Everhart–Thornley detector was kept at 500 V while photomultiplier gain, brightness, and image intensity were adjusted for each set of images to keep the signal on all images within the dynamic range of the detector. Images were acquired at a dwell time of 0.5 µs

A review on the biological effects of nanomaterials on silkworm (Bombyx mori)

• Sandra Senyo Fometu,
• Guohua Wu,
• Lin Ma and
• Joan Shine Davids

Beilstein J. Nanotechnol. 2021, 12, 190–202, doi:10.3762/bjnano.12.15

• , which significantly accelerated their body weight gain when compared to the control group and to larvae treated with different concentrations of TiO2 NPs (40, 80, and 160 mg/L) after 168 h. During the larval stages, silkworms feed on mulberry leaves which have all the required nutrients needed for their

Toward graphene textiles in wearable eye tracking systems for human–machine interaction

• Ata Jedari Golparvar and
• Murat Kaya Yapici

Beilstein J. Nanotechnol. 2021, 12, 180–189, doi:10.3762/bjnano.12.14

• for portable applications. For adjusting the gain in the post-amplification stage, a digitally programmable voltage divider (MAX5421, Maxim, USA) was used so that the gain can be configured at the software level through a graphical user interface (GUI). As a common practice in portable devices

• Instruments, USA) was implemented at the receiver end, enabling user-friendly operation, calibration, gain adjustment, and event monitoring. In the current version of the embedded system, the Bluetooth coverage is ca. 5 m. The power consumption of the circuitry is ca. 80 mW when the Bluetooth device is not

• graphene textile and the dimensions of the miniaturized-PCB on the rear side of the electrode. Overview of the system prototype showing the detailed hardware-level schematic of the portable, battery-powered, EOG acquisition unit including on-board filtering and gain stages, power management section

Paper-based triboelectric nanogenerators and their applications: a review

• Jing Han,
• Nuo Xu,
• Yuchen Liang,
• Mei Ding,
• Junyi Zhai,
• Qijun Sun and
• Zhong Lin Wang

Beilstein J. Nanotechnol. 2021, 12, 151–171, doi:10.3762/bjnano.12.12

• moisture-retention capacity. This provides an efficient method to prepare paper electrodes for TENGs. Paper has also been proven to be a natural TENG friction layer. Due to that, it shows a tendency of easily losing electrons (i.e., electropositive) when contacting a material that can easily gain electrons

• density. Since paper is mainly composed of cellulose, which generally shows a tendency of losing electrons (electropositive), it is preferred to pair paper with a friction material that can easily gain electrons (electronegative) according to the triboelectric series [83][99][100]. Figure 4 depicts a

Fusion of purple membranes triggered by immobilization on carbon nanomembranes

• René Riedel,
• Natalie Frese,
• Fang Yang,
• Martin Wortmann,
• Raphael Dalpke,
• Daniel Rhinow,
• Norbert Hampp and
• Armin Gölzhäuser

Beilstein J. Nanotechnol. 2021, 12, 93–101, doi:10.3762/bjnano.12.8

• a higher rate of multilayers and PM clusters. To decrease the number of clusters, both OD and drop size have been reduced as larger drops lead to higher coverage rates due to increasing amounts of WT PM per unit area. In order to improve the deposition and to gain well-oriented WT PM, as shown in

Bulk chemical composition contrast from attractive forces in AFM force spectroscopy

• Dorothee Silbernagl,
• Media Ghasem Zadeh Khorasani,
• Natalia Cano Murillo,
• Anna Maria Elert and
• Heinz Sturm

Beilstein J. Nanotechnol. 2021, 12, 58–71, doi:10.3762/bjnano.12.5

• approach of spatially resolved force spectroscopy data. Second, we demonstrated that by giving up the spatial information of a force map (spatial domain) we gain information about the property distribution (property domain). By taking advantage of this statistical approach, we showed that the maximum

Effect of different silica coatings on the toxicity of upconversion nanoparticles on RAW 264.7 macrophage cells

• Cynthia Kembuan,
• Helena Oliveira and
• Christina Graf

Beilstein J. Nanotechnol. 2021, 12, 35–48, doi:10.3762/bjnano.12.3

• not result in a stronger increase in cell granularity, such as a higher release of ions and a related reduction in cell viability, as indicated by the ion-release experiments and MTT data (Figure 2 and Figure 3, respectively). Cell cycle analysis To gain a deeper understanding of the effect of silica

Bio-imaging with the helium-ion microscope: A review

• Matthias Schmidt,
• James M. Byrne and
• Ilari J. Maasilta

Beilstein J. Nanotechnol. 2021, 12, 1–23, doi:10.3762/bjnano.12.1

• aspects of microbe–mineral interactions, such as the formation of intra- or extracellular mineral precipitates, or intracellular organelles associated with energy gain or electron transfer [92]. However, over recent years, the number of articles related to geomicrobiology and containing HIM data has

Self-standing heterostructured NiC_x-NiFe-NC/biochar as a highly efficient cathode for lithium–oxygen batteries

• Shengyu Jing,
• Xu Gong,
• Shan Ji,
• Linhui Jia,
• Bruno G. Pollet,
• Sheng Yan and
• Huagen Liang

Beilstein J. Nanotechnol. 2020, 11, 1809–1821, doi:10.3762/bjnano.11.163

• were evenly distributed in the selected area. In other words, N-doped carbon was formed as a support material. The images also show that Fe and Ni uniformly covered the entire particles, forming Fe and Ni alloy particles. To gain further information on the chemical state and element composition on the

The influence of an interfacial hBN layer on the fluorescence of an organic molecule

• Christine Brülke,
• Oliver Bauer and
• Moritz M. Sokolowski

Beilstein J. Nanotechnol. 2020, 11, 1663–1684, doi:10.3762/bjnano.11.149

• (varying by a factor of up to ca. 7). This indicates that the specific local surface quality, for example, the surface roughness at the spot where the Raman scattering occurred, influences the intensity of the Raman modes. Hence, we cannot draw quantitative conclusions here. Nevertheless, we gain some

Design of V-shaped cantilevers for enhanced multifrequency AFM measurements

• Mehrnoosh Damircheli and
• Babak Eslami

Beilstein J. Nanotechnol. 2020, 11, 1525–1541, doi:10.3762/bjnano.11.135

• , and A2 = 2 nm. The gain was adjusted to maintain the quality of the images. The image size is 10 µm times 10 µm. Bimodal AFM images of PS-LDPE samples. Left column: MULTI75G, middle column: TR400Long, right column: TR400Short. (a), (b), and (c) are height images. (d), (e), and (f) are phase images

• . All images were recorded at the same spot with a scan rate of 1 Hz, a setpoint ratio of 65%, a first eigenmode amplitude of A1 = 10 nm, and A2 = 2 nm. The gain was adjusted to maintain the quality of the images. The image size is 5 µm times 5 µm. Properties of Au and PS for AFM simulation. Range of

Adsorption and self-assembly of porphyrins on ultrathin CoO films on Ir(100)

• Feifei Xiang,
• Tobias Schmitt,
• Marco Raschmann and
• M. Alexander Schneider

Beilstein J. Nanotechnol. 2020, 11, 1516–1524, doi:10.3762/bjnano.11.134

• between functionalized porphyrins has also been observed on metal surfaces [27]. Discussion To gain insight into the reasons behind the experimental findings, DFT calculations were performed. Both, 1 and 2 were structurally relaxed on the 1BL CoO film in order to find the adsorption geometry. The lowest

• orthogonal configuration towards a 45° tilting angle. This indicated an energy gain upon flattening of the molecule and allows for an interaction between the cyano group and the substrate. Consequently, we tested the relaxation of 2 in several attempts starting with configurations where the phenyl rings were

A wideband cryogenic microwave low-noise amplifier

• Boris I. Ivanov,
• Dmitri I. Volkhin,
• Ilya L. Novikov,
• Dmitri K. Pitsun,
• Dmitri O. Moskalev,
• Ilya A. Rodionov,
• Evgeni Il’ichev and
• Aleksey G. Vostretsov

Beilstein J. Nanotechnol. 2020, 11, 1484–1491, doi:10.3762/bjnano.11.131

• amplifier was designed and characterized in a cryogen-free dilution refrigerator at the 3.8 K temperature stage. The obtained power dissipation of the amplifier is below 20 mW. In the frequency range from 6 to 12 GHz its gain exceeds 30 dB. The equivalent noise temperature of the amplifier is below 6 K for

• gain (G). The superconducting qubit measurement setup requires particular low-noise amplifiers applicable for cryogenic temperatures. An important point is that cryogenic low-noise amplifiers (cLNAs) are wideband noise sources itself. In the superconducting qubit experimental setup the noise generated

• heterojunction bipolar technology (HBT). Recently, it has been shown that cryogenic amplifiers based on SiGe HBT [16][17][18] can provide low noise levels and high gain at 4 K. They are suitable for superconducting qubit readout [25][26] and radio astronomy systems [12][14]. In order to obtain high gain values

Protruding hydrogen atoms as markers for the molecular orientation of a metallocene

• Linda Laflör,
• Michael Reichling and
• Philipp Rahe

Beilstein J. Nanotechnol. 2020, 11, 1432–1438, doi:10.3762/bjnano.11.127

• of small organic 3D molecules from NC-AFM data [10]. Adapting these approaches to a broad range of 3D molecules bears the strong potential not only to gain insight into the on-surface adsorption properties of molecules, but also to unravel the intramolecular geometry. A prototypical class of