Beyond Moore’s technologies: operation principles of a superconductor alternative

• Igor I. Soloviev,
• Nikolay V. Klenov,
• Sergey V. Bakurskiy,
• Mikhail Yu. Kupriyanov,
• Alexander L. Gudkov and
• Anatoli S. Sidorenko

Beilstein J. Nanotechnol. 2017, 8, 2689–2710, doi:10.3762/bjnano.8.269

Exploring wear at the nanoscale with circular mode atomic force microscopy

• Olivier Noel,
• Aleksandar Vencl and
• Pierre-Emmanuel Mazeran

Beilstein J. Nanotechnol. 2017, 8, 2662–2668, doi:10.3762/bjnano.8.266

• friction, energy dissipation and worn material at the local scale or to exhibit local heterogeneity of the material. To summarize, CM-AFM applied to wear experiments regarding different applications such as tribochemistry and wear of thin films presents numerous advantages compared to conventional AFM wear

Photobleaching of YOYO-1 in super-resolution single DNA fluorescence imaging

• Joseph R. Pyle and
• Jixin Chen

Beilstein J. Nanotechnol. 2017, 8, 2296–2306, doi:10.3762/bjnano.8.229

• under the microscope showing that sample preparation and our microscope work performed as expected (Figure 3b). In order to measure the heterogeneity among DNA molecules, DNA molecules were immobilized on the substrate at a lower density than in Figure 3. This lower density allows the DNA molecules to

Low uptake of silica nanoparticles in Caco-2 intestinal epithelial barriers

• Dong Ye,
• Mattia Bramini,
• Delyan R. Hristov,
• Sha Wan,
• Anna Salvati,
• Christoffer Åberg and
• Kenneth A. Dawson

Beilstein J. Nanotechnol. 2017, 8, 1396–1406, doi:10.3762/bjnano.8.141

• of view, but also complicates the interpretation of imaging snapshots which do not sample all the variation of the population. Again, a different methodology will be needed to understand and capture this heterogeneity in detail. There could be broader implications of the low degree of internalisation

Surface-enhanced Raman spectroscopy of cell lysates mixed with silver nanoparticles for tumor classification

• Mohamed Hassoun,
• Iwan W.Schie,
• Tatiana Tolstik,
• Sarmiza E. Stanca,
• Christoph Krafft and
• Juergen Popp

Beilstein J. Nanotechnol. 2017, 8, 1183–1190, doi:10.3762/bjnano.8.120

• specific antigens [21][22][23]. The disadvantages of approach (1) include the poor reproducibility due to nonspecific binding of nanoparticles, the long time needed for nanoparticles uptake by cells, and the heterogeneity of nanoparticles inside cells. Approach (2) is complicated because of complex

A new approach to grain boundary engineering for nanocrystalline materials

• Shigeaki Kobayashi,
• Sadahiro Tsurekawa and
• Tadao Watanabe

Beilstein J. Nanotechnol. 2016, 7, 1829–1849, doi:10.3762/bjnano.7.176

• that segregation-induced embrittlement in polycrystalline materials can be well controlled by optimizing the grain boundary microstructure, especially by GBCD, the grain boundary connectivity, and the heterogeneity of the grain size distribution. This is true even when local in nature, as revealed by

• thin film specimens, i.e., the heterogeneity of grain size distribution, GBCD, and grain boundary connectivity, or triple junction character distribution. To our knowledge, no literature is available which has reported such detailed information about grain boundary microstructure based on fractal

Manufacturing and investigation of physical properties of polyacrylonitrile nanofibre composites with SiO₂, TiO₂ and Bi₂O₃ nanoparticles

• Tomasz Tański,
• Wiktor Matysiak and
• Barbara Hajduk

Beilstein J. Nanotechnol. 2016, 7, 1141–1155, doi:10.3762/bjnano.7.106

• characterised by numerous structural defects, usually occurring on their surface (Figure 5). In addition, with an increase in the concentration of the used reinforcing phases in the produced nanocomposites an increase of defects and an increased heterogeneity of the fibre morphology was identified. X-ray

The influence of phthalocyanine aggregation in complexes with CdSe/ZnS quantum dots on the photophysical properties of the complexes

• Irina V. Martynenko,
• Anna O. Orlova,
• Vladimir G. Maslov,
• Anatoly V. Fedorov,
• Kevin Berwick and
• Alexander V. Baranov

Beilstein J. Nanotechnol. 2016, 7, 1018–1027, doi:10.3762/bjnano.7.94

• photophysical properties of the complexes. For the first time this concentration dependence has been well described by the developed model taking into account the heterogeneity of QD–monomer and QD–aggregate complexes. We show that a reduction in the concentration of phthalocyanine aggregates in complex with

Large-scale fabrication of achiral plasmonic metamaterials with giant chiroptical response

• Morten Slyngborg,
• Yao-Chung Tsao and
• Peter Fojan

Beilstein J. Nanotechnol. 2016, 7, 914–925, doi:10.3762/bjnano.7.83

• broad signal [13]. This is presumably related to the heterogeneity and 3D nature of the ECM structures, which is less dominant in the hole arrays fabricated by focused ion beam lithography. In spite of this, the CD linewidths of the present ECMs are comparable to those of gammadion PCMs, which have been

• previously used for biosensor applications [10]. Furthermore, compared to PCMs fabricated by another scalable technique [29], the CD linewidths of the honeycomb ECMs are more narrow. Hence the heterogeneity and 3D structure has not limited the use of the honeycomb ECMs for biosensing applications. While the

Correlative infrared nanospectroscopic and nanomechanical imaging of block copolymer microdomains

• Benjamin Pollard and
• Markus B. Raschke

Beilstein J. Nanotechnol. 2016, 7, 605–612, doi:10.3762/bjnano.7.53

• channel alone. These variations suggest that regions of multicomponent chemical composition, such as the interfacial mixing regions between microdomains, are correlated with high spatial heterogeneity in nanoscale material properties. Keywords: block copolymers, force–distance nanomechanical spectroscopy

• , hybrid imaging, near-field infrared spectroscopy, scanning probe microscopy; Introduction Functional soft-matter and polymer systems often exhibit novel phenomena due to nanoscale chemical heterogeneity and the resulting intermolecular interactions. Infrared vibrational scattering scanning near-field

The eNanoMapper database for nanomaterial safety information

• Nina Jeliazkova,
• Charalampos Chomenidis,
• Philip Doganis,
• Bengt Fadeel,
• Roland Grafström,
• Barry Hardy,
• Janna Hastings,
• Markus Hegi,
• Vedrin Jeliazkov,
• Nikolay Kochev,
• Pekka Kohonen,
• Cristian R. Munteanu,
• Haralambos Sarimveis,
• Bart Smeets,
• Pantelis Sopasakis,
• Georgia Tsiliki,
• David Vorgrimmler and
• Egon Willighagen

Beilstein J. Nanotechnol. 2015, 6, 1609–1634, doi:10.3762/bjnano.6.165

Experiences in supporting the structured collection of cancer nanotechnology data using caNanoLab

• Stephanie A. Morris,
• Sharon Gaheen,
• Michal Lijowski,
• Mervi Heiskanen and
• Juli Klemm

Beilstein J. Nanotechnol. 2015, 6, 1580–1593, doi:10.3762/bjnano.6.161

• development, must consider the heterogeneity of nanomaterial data and varied needs based on application (e.g., research focus – environmental vs medical vs energy). Even within a given research area, multi-disciplinary contributions to the field further complicate the development of management systems that

Chemoselective silicification of synthetic peptides and polyamines

• Maryna Abacilar,
• Fabian Daus and
• Armin Geyer

Beilstein J. Nanotechnol. 2015, 6, 103–110, doi:10.3762/bjnano.6.10

• nanostructure forms a template for the localized silicon dioxide precipitation in LCPA-rich but silaffin-poor areas [20]. From the numerous physical and experimental parameters, which differ from the literature experiments, only the chemical parameter of micro-heterogeneity is resolved in our experiments, which

The impact of the confinement of reactants on the metal distribution in bimetallic nanoparticles synthesized in reverse micelles

• Concha Tojo,
• Elena González and
• Nuria Vila-Romeu

Beilstein J. Nanotechnol. 2014, 5, 1966–1979, doi:10.3762/bjnano.5.206

• obtained in homogeneous reaction media. It was extended to synthesis inside micelles without taking into account the heterogeneity of reaction media. It is understood that reverse micelles are reaction vessels in which classical assumptions cannot always be used. For example, it was demonstrated that the

Cathode lens spectromicroscopy: methodology and applications

• T. O. Menteş,
• G. Zamborlini,
• A. Sala and
• A. Locatelli

Beilstein J. Nanotechnol. 2014, 5, 1873–1886, doi:10.3762/bjnano.5.198

• excitation in the imaging column. By placing a small aperture in the illumination column or at the image plane of the objective lens, the probed area can be limited to a micrometer-sized region, thus giving rise to the micro-probe operation. When the length scale of the structural heterogeneity is below the

The influence of molecular mobility on the properties of networks of gold nanoparticles and organic ligands

• Edwin J. Devid,
• Paulo N. Martinho,
• M. Venkata Kamalakar,
• Úna Prendergast,
• Christian Kübel,
• Tibebe Lemma,
• Jean-François Dayen,
• Tia. E. Keyes,
• Bernard Doudin,
• Mario Ruben and
• Sense Jan van der Molen

Beilstein J. Nanotechnol. 2014, 5, 1664–1674, doi:10.3762/bjnano.5.177

• excitation used here. Although there are clear commonalities, the spectra of the 2D single layer array and SAc-BPP powder spectra exhibit notable differences. The individual spectral features are broader in the SERS spectrum, consistent with the higher heterogeneity in the microenvironment the S-BPP

Ionic liquid-assisted formation of cellulose/calcium phosphate hybrid materials

• Ahmed Salama,
• Mike Neumann,
• Christina Günter and
• Andreas Taubert

Beilstein J. Nanotechnol. 2014, 5, 1553–1568, doi:10.3762/bjnano.5.167

• particles observed in the TEM. Indeed, citrate has been suggested as a strong growth modifier for calcium phosphate from aqueous solution [76]. In contrast, the heterogeneity of the samples obtained with NaOH could be due to solubility issues of NaOH in the IL; as ILs are known to only poorly solubilize

In vitro interaction of colloidal nanoparticles with mammalian cells: What have we learned thus far?

• Moritz Nazarenus,
• Qian Zhang,
• Mahmoud G. Soliman,
• Pablo del Pino,
• Beatriz Pelaz,
• Susana Carregal-Romero,
• Joanna Rejman,
• Barbara Rothen-Rutishauser,
• Martin J. D. Clift,
• Reinhard Zellner,
• G. Ulrich Nienhaus,
• James B. Delehanty,
• Igor L. Medintz and
• Wolfgang J. Parak

Beilstein J. Nanotechnol. 2014, 5, 1477–1490, doi:10.3762/bjnano.5.161

• less heterogeneity is present in the NP material and the easier the results (i.e., the correlation between the properties of the NPs and the observed interaction of NPs with cells) can be interpreted [13][18][86]. With limitations, a correlation of the spontaneous endocytotic uptake of NPs to the

Unlocking higher harmonics in atomic force microscopy with gentle interactions

• Sergio Santos,
• Victor Barcons,
• Josep Font and
• Albert Verdaguer

Beilstein J. Nanotechnol. 2014, 5, 268–277, doi:10.3762/bjnano.5.29

• absence of an external excitation of higher harmonics. Higher harmonic phase shifts further provide the means to directly decouple the true topography from that induced by compositional heterogeneity. Keywords: atomic force microscopy; chemistry; composition; heterogeneity; higher harmonics; phase

• establish a possible loss of contrast due to fundamental sources of noise. It is also shown that true topography and apparent topography, which is induced by chemical heterogeneity, can be decoupled at once by monitoring the phase contrast of higher harmonics. Results and Discussion Consider the equation of

• ), 0.8×10-19 J (squares) and 1.2 × 10−19 J (triangles). These variations induce variations in peak force of 29 (circles), 8 (squares) and 3 (trinagles) pN. (a–c) Illustration of a cantilever oscillating above a surface and recovering the true height Δzc = h when there are no compositional heterogeneity

Design criteria for stable Pt/C fuel cell catalysts

• Josef C. Meier,
• Carolina Galeano,
• Ioannis Katsounaros,
• Jonathon Witte,
• Hans J. Bongard,
• Angel A. Topalov,
• Claudio Baldizzone,
• Stefano Mezzavilla,
• Ferdi Schüth and
• Karl J. J. Mayrhofer

Beilstein J. Nanotechnol. 2014, 5, 44–67, doi:10.3762/bjnano.5.5

Atomic force microscopy recognition of protein A on Staphylococcus aureus cell surfaces by labelling with IgG–Au conjugates

• Elena B. Tatlybaeva,
• Hike N. Nikiyan,
• Alexey S. Vasilchenko and
• Dmitri G. Deryabin

Beilstein J. Nanotechnol. 2013, 4, 743–749, doi:10.3762/bjnano.4.84

• bacterial cell surfaces by using colloidal gold nanoparticles as labels (Figure 4a). A moderate heterogeneity of the dimensional characteristics of the IgG–Au conjugates was revealed by AFM image analysis. Thus, conjugates were found both as single, spherically shaped objects, 80 ± 12 nm in size, and

AFM as an analysis tool for high-capacity sulfur cathodes for Li–S batteries

• Renate Hiesgen,
• Seniz Sörgel,
• Rémi Costa,
• Linus Carlé,
• Ines Galm,
• Natalia Cañas,
• Brigitta Pascucci and
• K. Andreas Friedrich

Beilstein J. Nanotechnol. 2013, 4, 611–624, doi:10.3762/bjnano.4.68

• distribution is present in this area, with a sulfur-rich region in the centre. No indication of this heterogeneity is visible in the topographical images. As observed in the recording of the TUNA™ current (where the average steady state current is displayed, Figure 6e), little or no steady current flow was

Photoelectrochemical and Raman characterization of In₂O₃ mesoporous films sensitized by CdS nanoparticles

• Mikalai V. Malashchonak,
• Sergey K. Poznyak,
• Eugene A. Streltsov,
• Anatoly I. Kulak,
• Olga V. Korolik and
• Alexander V. Mazanik

Beilstein J. Nanotechnol. 2013, 4, 255–261, doi:10.3762/bjnano.4.27

• heterogeneity (Figure 6). As can be seen from Figure 6, the CdS phonon energy decreases with increasing the number of SILAR cycles (i.e., the nanocrystal size). This effect can be explained in the following way: according to wavevector-relaxation [17] and continuum [18][19] models, the decrease of the size of

Growth behaviour and mechanical properties of PLL/HA multilayer films studied by AFM

• Cagri Üzüm,
• Johannes Hellwig,
• Narayanan Madaboosi,
• Dmitry Volodkin and
• Regine von Klitzing

Beilstein J. Nanotechnol. 2012, 3, 778–788, doi:10.3762/bjnano.3.87

• structure, heterogeneity or roughness. The film thickness range reported in the mentioned study [4] is nearly threefold larger than ours, which may result in significant structural differences. Despite some fluctuations, E in our study ranges between 10 and 40 kPa, being in the same order of magnitude with

An NC-AFM and KPFM study of the adsorption of a triphenylene derivative on KBr(001)

• Antoine Hinaut,
• Adeline Pujol,
• Florian Chaumeton,
• David Martrou,
• André Gourdon and
• Sébastien Gauthier

Beilstein J. Nanotechnol. 2012, 3, 221–229, doi:10.3762/bjnano.3.25

• a different aspect, being more heterogeneous on the MLv domains. This heterogeneity is not clearly correlated to the topographic images. Another example of images of a high-coverage deposit, annealed to 150 °C, is shown in Figure 6. Some well-resolved defects appear in the MLh domain in the upper