Photoelectrochemical water oxidation over TiO₂ nanotubes modified with MoS₂ and g-C₃N₄

• Phuong Hoang Nguyen,
• Thi Minh Cao,
• Tho Truong Nguyen,
• Hien Duy Tong and
• Viet Van Pham

Beilstein J. Nanotechnol. 2022, 13, 1541–1550, doi:10.3762/bjnano.13.127

• materials (Figure 1b). This agrees with the results of previous publications in which hydrothermal methods were applied [24][25][26]. The SEM image of the g-C3N4 material shows the uniform nanosheets that were fabricated by the melamine pyrolysis method (Figure 1c). After the deposition of 2D materials MoS2

• and g-C3N4 onto the TNAs substrate, we examined the morphology of these heterostructures by using SEM (Figure 2). There are some small pieces that are randomly distributed on the surface of TNAs in Figure 2a, which were attributed to be MoS2. There is a similar result in the SEM image of g-C3N4/TNAs

A TiO₂@MWCNTs nanocomposite photoanode for solar-driven water splitting

• Anh Quynh Huu Le,
• Ngoc Nhu Thi Nguyen,
• Hai Duy Tran,
• Van-Huy Nguyen and
• Le-Hai Tran

Beilstein J. Nanotechnol. 2022, 13, 1520–1530, doi:10.3762/bjnano.13.125

• defects in the initial MWCNTs are hardly affected by the TiO2 nanoparticles. The TEM image also confirms that TiO2 nanoparticles only attach to some defects on the MWCNTs (Figure 3c) [17]. FTIR spectra of MWCNTs, TiO2, and the TiO2@MWCNTs nanocomposite are shown in Figure 6a. Regarding the spectrum of

Rapid and sensitive detection of box turtles using an electrochemical DNA biosensor based on a gold/graphene nanocomposite

• Abu Hashem,
• M. A. Motalib Hossain,
• Ab Rahman Marlinda,
• Mohammad Al Mamun,
• Khanom Simarani and
• Mohd Rafie Johan

Beilstein J. Nanotechnol. 2022, 13, 1458–1472, doi:10.3762/bjnano.13.120

•  2a, the wrinkled area represents folded Gr sheets [52]. In Figure 2b, octahedron-like gold particles [53] are clearly visible in the corresponding FESEM image. The particle size of AuNPs seems to be larger than expected, which may be due to self-aggregation during the formation of the nanocomposite

• . UV–vis spectra were used to determine the presence of Gr and AuNPs/Gr in the composite. From the image (Figure 2e), Gr has a peak at 262 nm, which has been shifted to 256 nm (Figure 2e) in the composite, possibly due to interactions between AuNPs and Gr. Additionally, the distinct peak at 516 nm in

Facile preparation of Au- and BODIPY-grafted lipid nanoparticles for synergized photothermal therapy

• Yuran Wang,
• Xudong Li,
• Haijun Chen and
• Yu Gao

Beilstein J. Nanotechnol. 2022, 13, 1432–1444, doi:10.3762/bjnano.13.118

• in H2O. The binding of hydrophobic BDP onto Au-LNPs might affect the light absorption of Au nanoclusters. The loading efficiency of BDP in AB-LNPs determined by using UV–vis measurements (λex = 600 nm) is 51 ± 1.2% (n = 3). A TEM image of AB-LNPs is shown in Figure 1c. Particles with diameters of ca

• characterization of AB-LNPs. (a) Size distribution of Au-LNPs and AB-LNPs. Digital photo of AB-LNPs showing distinct Tyndall effects. (b) UV–vis spectra of BDP and AB-LNPs. (c) TEM image of AB-LNPs. Photothermal properties of AB-LNPs. (a) Photothermal heating curves for AB-LNPs at different BDP concentrations with

Orally administered docetaxel-loaded chitosan-decorated cationic PLGA nanoparticles for intestinal tumors: formulation, comprehensive in vitro characterization, and release kinetics

• Sedat Ünal,
• Osman Doğan and
• Yeşim Aktaş

Beilstein J. Nanotechnol. 2022, 13, 1393–1407, doi:10.3762/bjnano.13.115

• an artificial mucus layer. (B) Representative image of the experiment (n = 3, ± SD) (*; p < 0.05). Release kinetics curves obtained with the DDSolver software for NPs (The blue stars indicate the best fit models). Anticancer activity of DCX-loaded and blank PLGA nanoparticles and free DCX on HT-29

LED-light-activated photocatalytic performance of metal-free carbon-modified hexagonal boron nitride towards degradation of methylene blue and phenol

• Nirmalendu S. Mishra and
• Pichiah Saravanan

Beilstein J. Nanotechnol. 2022, 13, 1380–1392, doi:10.3762/bjnano.13.114

• -light-driven photocatalytic activity of MBN-80 over the nonresponsive photoinactive HBN. (a) HR-XRD plots for HBN and MBN-80, (b–d) SEM images for HBN, MBN-25, MBN-50, and (e, f) MBN-80. HRTEM images for (g, h) MBN-80 nanosheets, (i) HAADF STEM image, and (j–m) elemental mapping of B, N, C, and O in MBN

Dry under water: air retaining properties of large-scale elastomer foils covered with mushroom-shaped surface microstructures

• Matthias Mail,
• Stefan Walheim,
• Thomas Schimmel,
• Wilhelm Barthlott,
• Stanislav N. Gorb and
• Lars Heepe

Beilstein J. Nanotechnol. 2022, 13, 1370–1379, doi:10.3762/bjnano.13.113

• method as well as the results are shown in Figure 2. For the analysis of the shape of the air–water interface, cross sections trough the image stacks have been generated by using the software Leica TFS. 3.2 Static lifetime tests of air layer submerged deeper than hmax In a second experiment, which was

• , the silvery shine indicates the kept air. c) SEM image of the surface structure of the Salvinia leaf. d) SEM image of the MSM. Confirmation of the persistence of the air layer in low water depth and analysis of the shape of the air–water interface by confocal laser scanning microscopy (CLSM

• submerging the sample in 5 mm water depth. A top view image as well as a cross section of the air–water interface is shown. The dark parts in the top view image represent the MSM, the bright parts show the air–water interface in between. Also in the cross section the air–water interface is represented by the

Straight roads into nowhere – obvious and not-so-obvious biological models for ferrophobic surfaces

• Wilfried Konrad,
• Christoph Neinhuis and
• Anita Roth-Nebelsick

Beilstein J. Nanotechnol. 2022, 13, 1345–1360, doi:10.3762/bjnano.13.111

• open longitudinally. Panel (b) shows a scanning electron microscope image of two adjacent conduits (denoted “1” and “2”). The conduits are connected by pits (some are highlighted by the green area) containing the pit membrane, which is a special nanoporous membrane. (c) Detailed image showing a pit

Near-infrared photoactive Ag-Zn-Ga-S-Se quantum dots for high-performance quantum dot-sensitized solar cells

• Roopakala Kottayi,
• Ilangovan Veerappan and
• Ramadasse Sittaramane

Beilstein J. Nanotechnol. 2022, 13, 1337–1344, doi:10.3762/bjnano.13.110

• X-ray spectrum analysis confirms the 1:1:1:1.5:1.5 stoichiometric ratio of, respectively, Ag, Zn, Ga, S, and Se. These two results indicate the formation of I-II-III-VI3-type alloyed crystals (AgZnGaS1.5Se1.5 nanocrystals). TEM image analysis reveals the QD nature of the synthesized Ag-Zn-Ga-S-Se

• ), (002), (101), (102), (110), (112), (203), (210), and (211) planes of the hexagonal crystals (JCPDS: 00-025-0383). The crystallite size of these QDs was found to be 5.03 nm using the Scherrer equation [22]. Figure 2a shows a HRTEM image of AZGSSe QDs. The average mean diameter was found to be 5.11 nm

• ]. Studies of Ag-Zn-Ga-S-Se QD-sensitized TiO2 NFs The surface morphology of AZGSSe/TiO2 was examined through HRTEM and EDX analysis. The HRTEM image (Figure 5a) shows the presence of AZGSSe QDs on the TiO2 NFs. The EDX spectrum (Figure 5b) shows the peaks of Ti, O, Ag, Zn, Ga, S, and Se. These analyses

Bending and punching characteristics of aluminum sheets using the quasi-continuum method

• Man-Ping Chang,
• Shang-Jui Lin and
• Te-Hua Fang

Beilstein J. Nanotechnol. 2022, 13, 1303–1315, doi:10.3762/bjnano.13.108

• were discussed under various conditions. The stress–displacement curve and stress/strain image were used to analyze various mechanical properties. Effect of crystal orientation on the nano-punching process Before discussing the influence of different crystal orientations on the nano-punching process

Growing up in a rough world: scaling of frictional adhesion and morphology of the Tokay gecko (Gekko gecko)

• Anthony J. Cobos and
• Timothy E. Higham

Beilstein J. Nanotechnol. 2022, 13, 1292–1302, doi:10.3762/bjnano.13.107

• and Microanalysis at UC Riverside (Figure 1). Each image was saved at multiple magnifications to facilitate more accurate measurements of setal length, setal diameter and setal density. Setal length was measured on the second (penultimate) scansor from the base of stalk to the tip along the midline of

• in its natural habitat in Vietnam (photo courtesy of Lee Grismer. This content is not subject to CC BY 4.0.) (A), a Tokay gecko in the lab on a glass surface (photo by Timothy Higham, and has not been published previously) (B), an SEM image of the distal portion of the digit (C), an SEM image of the

• 2000 grit sandpaper surface (D), and a 3D image of the 2000 grit sandpaper surface using confocal laser scanning microscopy (E). The relationship between morphological characters and SVL of 15 individuals. The relationship between toepad area (digit IV) and SVL (y = 2.03x − 6.46, r2 = 0.95) (A). The

Enhanced electronic transport properties of Te roll-like nanostructures

• E. R. Viana,
• N. Cifuentes and
• J. C. González

Beilstein J. Nanotechnol. 2022, 13, 1284–1291, doi:10.3762/bjnano.13.106

•  1b, with a mean diameter of around 550 nm. Due to the tip at the end of the nanostructures, the diameters were measured approximately at the center part, where the size is uniform. The wall thickness of the nanostructures was found between 45 and 55 nm. Figure 1c shows a high-magnification SEM image

• ) SEM images at different magnifications of the roll-like Te nanostructures and (d) the EDS spectra of the sample. The inset of panel (b) shows the histogram of the diameter distribution of the nanostructures. TEM image and SAED patterns of (a,b ) the flat end and (c, d) the tip of a roll-like t-Te one

• -dimensional nanostructure. (a) HRTEM image of the roll-like t-Te one-dimensional nanostructure with FFT patterns from different regions of the sample. (b) EDS spectrum of the corresponding nanostructure. The transfer characteristic (Ids–Vg) of a single roll-like t-Te NW-1 one-dimensional nanostructure back

Laser-processed antiadhesive bionic combs for handling nanofibers inspired by nanostructures on the legs of cribellate spiders

• Sebastian Lifka,
• Kristóf Harsányi,
• Erich Baumgartner,
• Lukas Pichler,
• Dariya Baiko,
• Karsten Wasmuth,
• Johannes Heitz,
• Marco Meyer,
• Anna-Christin Joel,
• Jörn Bonse and
• Werner Baumgartner

Beilstein J. Nanotechnol. 2022, 13, 1268–1283, doi:10.3762/bjnano.13.105

• [16]). (b) Photography of the cosmopolitan feather-legged lace weaver Uloborus plumipes (body size up to 0.6 cm [17]). (c) Scanning electron micrograph of the calamistrum of Jamberoo johnnoblei (body size up to 0.8 cm [18]). (d) FIB-cut high resolution SEM image through the nanoripples on the

Studies of probe tip materials by atomic force microscopy: a review

• Ke Xu and
• Yuzhe Liu

Beilstein J. Nanotechnol. 2022, 13, 1256–1267, doi:10.3762/bjnano.13.104

• mechanical properties of the cantilever beam directly affect the performance, measurement resolution, and image quality of the AFM instrument. AFM probe tips [9][10] are generally fabricated with coatings, carbon nanotubes, magnetic nanoparticles, or even protein functionalization. A combination of probe

• Figure 1a and Figure 1b, the F(z) curve and the high-resolution NC-AFM image were used as criteria to test the conditions of the constructed nano-tip. It can be seen from the Figure 1 that the tip remains intact, and the atomic and molar periodicity in the images is resolved with high quality. This work

• target nanotubes to Si tips under scanning electron microscopy; and attaching nanotubes to Si tips by carbon deposition. The strong adhesion of carbon deposition produces nanotube tips capable of surviving multiple surface collisions. The ability to image the fine structure of double-stranded DNA

A super-oscillatory step-zoom metalens for visible light

• Yi Zhou,
• Chao Yan,
• Peng Tian,
• Zhu Li,
• Yu He,
• Bin Fan,
• Zhiyong Wang,
• Yao Deng and
• Dongliang Tang

Beilstein J. Nanotechnol. 2022, 13, 1220–1227, doi:10.3762/bjnano.13.101

• emission depletion microscopy (STED) can realize the localization of single fluorescent molecules with 1 nm accuracy [2], albeit with the disadvantages of required fluorescence labeling and slow image reconstruction. Super-resolution microscopy based on structured light illumination (SIM) can realize a

• spatial resolution of λ/5 [3]. However, it requires additional designed illumination patterns and image reconstruction. Near-field scanning optical microscopy can achieve super-resolution imaging by detecting surface evanescent fields of objects [4]. Near-field focusing lenses [5] based on surface

• high optical loss and are not suitable for far-field imaging. As a result, it is still a huge challenge to achieve unlabeled far-field imaging without image post processing. Optical super-oscillation is a unique optical phenomenon in which an optical signal can oscillate faster locally than its maximum

Design of surface nanostructures for chirality sensing based on quartz crystal microbalance

• Yinglin Ma,
• Xiangyun Xiao and
• Qingmin Ji

Beilstein J. Nanotechnol. 2022, 13, 1201–1219, doi:10.3762/bjnano.13.100

Application of nanoarchitectonics in moist-electric generation

• Jia-Cheng Feng and
• Hong Xia

Beilstein J. Nanotechnol. 2022, 13, 1185–1200, doi:10.3762/bjnano.13.99

• microscopy (SEM) image of an individual single-walled carbon nanotube (SWNT) device. (c) Dependence of the induced voltage difference, ΔV, on the quantity of water injected into the chamber. ΔV increases with the quantity of water inside the chamber and tends to saturate at 500 μL. It is nearly symmetric for

• content is not subject to CC BY 4.0. (d) Single-walled carbon nanotubes convert collected energy into voltage output with repeatability. (e) An image of a suspended SWNT rope. (f) Schematic diagram of an ethanol evaporation energy collection device. Figure 1d–f were reproduced from [44], Liu, Z. et al

• ; W. Guo), Copyright 2014 Springer Nature. This content is not subject to CC BY 4.0. (a) SEM image of the porous carbon film. (b) The porous carbon film power generation device and its performance are depicted schematically. Figure 3a, 3b, and 3f were reproduced from [9], Ding, Tianpeng et al., “All

Microneedle-based ocular drug delivery systems – recent advances and challenges

• Piotr Gadziński,
• Anna Froelich,
• Monika Wojtyłko,
• Antoni Białek,
• Julia Krysztofiak and
• Tomasz Osmałek

Beilstein J. Nanotechnol. 2022, 13, 1167–1184, doi:10.3762/bjnano.13.98

• Commons Attribution 4.0 International License, https://creativecommons.org/licenses/by/4.0/). Stereomicroscopic image of the microneedle patch (e) and magnification of the microneedles (f), scalebars represent 1 mm and 200 µm respectively. Figure 4 was reproduced from [160] (“Microneedle ocular patch

• not subject to CC BY 4.0. Microscopic image of dissolving MNs manufactured by Albadr and co-workers. Figure 5 was reproduced from [176] (© 2021 A. A. Albadr et al., distributed under the terms of the Creative Commons Attribution 4.0 International License, https://creativecommons.org/licenses/by/4.0

• /). Microscopic image of the MNs obtained by Amer and Chen. Figure 6 was adapted from [178], M. Amer; R. K. Chen, "Hydrogel-Forming Microneedle Arrays for Sustained and Controlled Ocular Drug Delivery", Journal of Engineering and Science in Medical Diagnostics and Therapy, with permission from ASME. Copyright

A cantilever-based, ultrahigh-vacuum, low-temperature scanning probe instrument for multidimensional scanning force microscopy

• Hao Liu,
• Zuned Ahmed,
• Sasa Vranjkovic,
• Manfred Parschau,
• Andrada-Oana Mandru and
• Hans J. Hug

Beilstein J. Nanotechnol. 2022, 13, 1120–1140, doi:10.3762/bjnano.13.95

• . Clearly, the deflection sensor noise does no longer limit the minimally detectable force derivative for bandwidths up to and beyond 1 kHz. Such high measurement bandwidths can for example, be used to measure with high speed a large-scale image showing atomic steps of the Au(111) surface with thin NaCl

Green synthesis of zinc oxide nanoparticles toward highly efficient photocatalysis and antibacterial application

• Vo Thi Thu Nhu,
• Nguyen Duy Dat,
• Le-Minh Tam and
• Nguyen Hoang Phuong

Beilstein J. Nanotechnol. 2022, 13, 1108–1119, doi:10.3762/bjnano.13.94

• maximum (FWHM). The morphology and size of ZnO NPs were illustrated using FESEM and HRTEM. The FESEM image shown in Figure 4 indicates that ZnO NPs have a relatively homogeneous size. The HR-TEM results and particle size distributions obtained from the HR-TEM images are shown in Figure 5. The HR-TEM

• hexagonal wurtzite structure form. The HR-TEM image showed the interplanar spacing of 0.251 ± 0.003 nm corresponding to the (101) crystal plane of ZnO, and the size of ZnO NPs is in the range of 30–100 nm. The bandgap energy of synthesized ZnO was 3.15 eV. Synthesized ZnO NPs showed high photocatalytic

• . The E. coli bacteria with concentrations of 105 and 104 CFU/mL was almost completely destroyed after 6 h by ZnO with concentrations of 1, 5, and 10 mg/mL. Schematic illustration of the synthesis of ZnO nanoparticles. DTA/TG diagram of the zinc resinate sample. XRD diagram of ZnO NPs. FESEM image of

Biomimetic chitosan with biocomposite nanomaterials for bone tissue repair and regeneration

• Se-Kwon Kim,
• Sesha Subramanian Murugan,
• Pandurang Appana Dalavi,
• Sebanti Gupta,
• Sukumaran Anil,
• Gi Hun Seong and
• Jayachandran Venkatesan

Beilstein J. Nanotechnol. 2022, 13, 1051–1067, doi:10.3762/bjnano.13.92

• , treating bone calvarial defects with a natural, mechanical, and biochemical environment with accomplished osteoblast differentiation and proliferation has been addressed by using chitosan–graphene nanocomposite materials. The bone structure. The magnified image shows the physiological arrangement of the

• been detected. Figure 2b depicts an optical microscopy image of Masson-Goldner staining which shows that acemannan and chitosan accelerates the formation of new bone. Figure 2 was reprinted with permission from [99], Copyright 2019 American Chemical Society. This content is not subject to CC BY 4.0. (a

Spindle-like MIL101(Fe) decorated with Bi₂O₃ nanoparticles for enhanced degradation of chlortetracycline under visible-light irradiation

• Chen-chen Hao,
• Fang-yan Chen,
• Kun Bian,
• Yu-bin Tang and
• Wei-long Shi

Beilstein J. Nanotechnol. 2022, 13, 1038–1050, doi:10.3762/bjnano.13.91

• report [53]. As shown in Figure 2b, pristine Bi2O3 shows nanoparticles with diameters of approx. 10–20 nm. In the SEM image of the composite BOM-20 (Figure 2c), Bi2O3 nanoparticles are tightly attached on the surface of MIL101(Fe). Note that MIL101(Fe) in BOM-20 presents a spindle-like shape instead of

• ). Figure 3d shows an HRTEM image of BOM-20 composites. The lattice fringes of 0.37 nm correspond to the (120) facet of α-Bi2O3 [55]. Meanwhile, the tight contact interface between Bi2O3 and MIL101(Fe) can be clearly observed. Furthermore, the elemental mapping images of BOM-20 (Figure 3e–h) reveal the

• LC–MS, the photocatalytic degradation pathway of CTC was speculated. This work provides an idea for designing and synthesizing MOF-based Z-scheme heterojunction photocatalysts. XRD patterns of MIL101, Bi2O3, and BOM-20. SEM images of (a) MIL101(Fe), (b) Bi2O3, and (c,d) BOM-20. TEM image of (a

Effects of focused electron beam irradiation parameters on direct nanostructure formation on Ag surfaces

• Jānis Sniķeris,
• Vjačeslavs Gerbreders,
• Andrejs Bulanovs and
• Ēriks Sļedevskis

Beilstein J. Nanotechnol. 2022, 13, 1004–1010, doi:10.3762/bjnano.13.87

• surface as functions of time following chamber decontamination by nitrogen plasma cleaning. Constant EB parameters are: U = 30 kV, I = 55 pA, d = 14 nm, t = 30 s, and α = 0°. A representative AFM image of a nanostructure on an Ag surface after sustaining damage from N plasma cleaning. Constant EB

Interaction between honeybee mandibles and propolis

• Leonie Saccardi,
• Franz Brümmer,
• Jonas Schiebl,
• Oliver Schwarz,
• Alexander Kovalev and
• Stanislav Gorb

Beilstein J. Nanotechnol. 2022, 13, 958–974, doi:10.3762/bjnano.13.84

• studied using a SEM (Hitachi S-4800, Hitachi High-Technologies Corp., Tokyo, Japan) at 3 kV accelerating voltage. Images of the spoon-shaped mandible tip were taken systematically and later assembled into one high resolution image. Higher magnified pictures were taken in characteristic areas of the

• (Hitachi S-4800, Hitachi High-Technologies Corp., Tokyo, Japan) equipped with a cryopreparation system (Gatan ALTO 2500, Gatan, Inc., Abingdon, UK) at 3 kV accelerating voltage. Image processing SEM images were processed using Gimp, version 2.10.14. All adjustments were applied to the whole image. Color

• ) Cryo-SEM micrograph of mandible cuticle. The arrowhead indicates the step between two scales. (B) 3D laser scanning microscope image of medial surface of the mandible in the channel area. (C) Profile of scales in along the red arrow in (B). (D) Profile of scales along the blue arrow in (B). Scale bars

Design of a biomimetic, small-scale artificial leaf surface for the study of environmental interactions

• Miriam Anna Huth,
• Axel Huth,
• Lukas Schreiber and
• Kerstin Koch

Beilstein J. Nanotechnol. 2022, 13, 944–957, doi:10.3762/bjnano.13.83

• image, (b) height image. The white line indicates where the cross section in (c) was made. (c) Cross section. On the left side of each image: glass after the removal of the coating, on the right side: structure of the wax coating. Chemical composition of wheat wax. GH: greenhouse plants (n = 15); OD