Atmospheric water harvesting using functionalized carbon nanocones

• Fernanda R. Leivas and
• Marcia C. Barbosa

Beilstein J. Nanotechnol. 2023, 14, 1–10, doi:10.3762/bjnano.14.1

• pressure, and critical temperature, despite being a simple model [15][53]. The SHAKE algorithm was employed to keep the rigidity of water molecules. The oxygen–carbon Lennard-Jones (LJ) pair-wise non-bonded interaction, εO−C = 0.126 kcal/mol and σO−C = 3.279 Å, was calculated using the Lorentz–Berthelot

• mixing rules [54]. For the interaction between hydrophilic sites and water, the same σ of oxygen–carbon interaction was fixed (σO−HS = σO−C), but the potential well εO−HS = εi was varied. The LJ cutoff distance was 12 Å, and the long-range electrostatic interaction was treated by the particle–particle

• the nanocone. If the nanocone is fully hydrophobic, no water crosses the nanocone. Therefore, hydrophilic rings are necessary for the water to enter and flow through the nanocone. We employ the Lennard-Jones potential to calculate the interaction between the nanocone wall and water. Within this

Electrical and optical enhancement of ITO/Mo bilayer thin films via laser annealing

• Abdelbaki Hacini,
• Ahmad Hadi Ali,
• Nurul Nadia Adnan and
• Nafarizal Nayan

Beilstein J. Nanotechnol. 2022, 13, 1589–1595, doi:10.3762/bjnano.13.133

• and a repetition rate of 1 Hz. Different energies from 80 to 240 mJ with a step of 40 mJ were used. The samples were placed in a closed metal cube under nitrogen during annealing to avoid contamination and interaction with particles. A converging lens was placed between the laser and the sample, and

Observation of collective excitation of surface plasmon resonances in large Josephson junction arrays

• Roger Cattaneo,
• Mikhail A. Galin and
• Vladimir M. Krasnov

Beilstein J. Nanotechnol. 2022, 13, 1578–1588, doi:10.3762/bjnano.13.132

• interaction via shared electromagnetic fields and currents [26]. For conventional overlap JJs the scale of such interaction is short (nanoscale) because it is limited by the corresponding screening lengths in superconducting electrodes [27]. However, for planar JJs the direct interaction can be of long range

• due to the presence of long-range stray fields [28]. Indirect coupling is caused by interaction of JJs with a common external resonator [7][8][29][30][31][32][33][34][35]. The resonator imprints the phase order onto the junction array and, thus, can synchronize JJs without direct interjunction

• interjunction interaction. Samples We study arrays of Nb/NbxSi1−x/Nb JJs fabricated on oxidized Si substrates and connected in series by Nb electrodes. The NbxSi1−x interlayer with the composition x ≃ 0.14 was deposited by co-sputtering from Nb and Si sources. Details about the fabrication procedure can be

From a free electron gas to confined states: A mixed island of PTCDA and copper phthalocyanine on Ag(111)

• Alfred J. Weymouth,
• Emily Roche and
• Franz J. Giessibl

Beilstein J. Nanotechnol. 2022, 13, 1572–1577, doi:10.3762/bjnano.13.131

• molecules were close to each other implying little direct interaction [17]. Stadtmüller et al. extensively studied the P2C phase with STM, dI/dV measurements, and DFT calculations [18]. They showed that while an isolated CuPc molecule on Ag(111) has a level that is half-filled, this level shifts above the

Single-step extraction of small-diameter single-walled carbon nanotubes in the presence of riboflavin

• Polina M. Kalachikova,
• Anastasia E. Goldt,
• Eldar M. Khabushev,
• Timofei V. Eremin,
• Timofei S. Zatsepin,
• Elena D. Obraztsova,
• Konstantin V. Larionov,
• Liubov Yu. Antipina,
• Pavel B. Sorokin and
• Albert G. Nasibulin

Beilstein J. Nanotechnol. 2022, 13, 1564–1571, doi:10.3762/bjnano.13.130

• between the SWCNTs and gel media. Our experimental findings are supported by ab initio calculations demonstrating the impact of the riboflavin wrapping pattern around the SWCNTs on their interaction with the allyl dextran gel. Keywords: carbon nanotubes; photoluminescence spectroscopy; riboflavin; size

• through π–π interaction and with neighboring isoalloxazine groups via hydrogen bonding, promotes the ordered assembly of riboflavin molecules on the surface of SWCNTs [9][17]. Papadimitrakopoulos et al. described the helical wrapping of flavin mononucleotide through π–π interaction between the

• coaxial helices [18]. Our observations suggest that a similar wrapping pattern takes place due to the interaction between isoalloxazine rings on the surface of nanotubes, which promotes selective extraction of (6,5)-nanotubes. Riboflavin wrapping around SWCNTs of different chiralities was simulated

Induced electric conductivity in organic polymers

• Konstantin Y. Arutyunov,
• Anatoli S. Gurski,
• Vladimir V. Artemov,
• Alexander L. Vasiliev,
• Azat R. Yusupov,
• Danfis D. Karamov and
• Alexei N. Lachinov

Beilstein J. Nanotechnol. 2022, 13, 1551–1557, doi:10.3762/bjnano.13.128

• methods [8][9]. Quantum chemical studies of PDP [10] have shown that its molecular structure is unstable with regard to interaction with an excess (thermal) electron and can result in a transition to a metastable state. However, in that state, e.g. induced by external electric field, the system is

• interface are completely or partially elongated. Also, film formation at such low concentrations strongly depends on the energy interaction of macromolecules with the substrate surface, which explains the weak dependence of the film thickness on the solution concentration. With an increase in concentration

Photoelectrochemical water oxidation over TiO₂ nanotubes modified with MoS₂ and g-C₃N₄

• Phuong Hoang Nguyen,
• Thi Minh Cao,
• Tho Truong Nguyen,
• Hien Duy Tong and
• Viet Van Pham

Beilstein J. Nanotechnol. 2022, 13, 1541–1550, doi:10.3762/bjnano.13.127

• exhibit only single semicircular shape, which shows the charge transfer resistance equivalent to the polarization resistance. This result also demonstrates a unique interaction of the electrode surface and the electrolyte solution. Furthermore, the g-C3N4 sample shows the semicircle with the largest

• radius, followed by TNAs and MoS2, which indicates the low interaction of these materials with the electrolyte. However, after coupling, the g-C3N4/TNAs sample shows a semicircle with smaller radius compared than that of g-C3N4 or TNAs. The Nyquist plot of the MoS2/TNAs sample shows the smallest

• semicircle radius of all samples. This result indicates an increase in carrier density during the reaction with the electrolyte solution, leading to a decrease in resistance of the g-C3N4/TNAs and MoS2/TNAs samples. This could be explained by the enhanced optical interaction, causing an increase of the

Non-stoichiometric magnetite as catalyst for the photocatalytic degradation of phenol and 2,6-dibromo-4-methylphenol – a new approach in water treatment

• Joanna Kisała,
• Anna Tomaszewska and
• Przemysław Kolek

Beilstein J. Nanotechnol. 2022, 13, 1531–1540, doi:10.3762/bjnano.13.126

• , approximately 50% and 98% of DBMP was degraded via direct photolysis and photocatalysis, respectively (after 60 min). The efficiency of phenol photocatalysis was low (ca. 40% for M1 and ca. 30% for M2, after 60 min). This may be due to the lack of interaction between the catalysts’ surfaces and phenol. The

• influenced by the interaction between the DBMP molecule and the magnetite surface. When bonded to the catalyst’s surface, molecules can react with the electrons being generated. Therefore, we postulate a mixed reductive–oxidative mechanism of DBMP degradation on magnetite. In conclusion, magnetite can be an

A TiO₂@MWCNTs nanocomposite photoanode for solar-driven water splitting

• Anh Quynh Huu Le,
• Ngoc Nhu Thi Nguyen,
• Hai Duy Tran,
• Van-Huy Nguyen and
• Le-Hai Tran

Beilstein J. Nanotechnol. 2022, 13, 1520–1530, doi:10.3762/bjnano.13.125

• calculated as 3.14 and 2.51 eV, respectively. The results show that the lower bandgap of TiO2@MWCNTs catalyst could derive from vacancies on the MWCNTs or the interaction between TiO2 and MWCNTs [25]. Moreover, the C–O–Ti linkages on the TiO2@MWCNs contribute to the extension of the absorption of light at a

In search of cytotoxic selectivity on cancer cells with biogenically synthesized Ag/AgCl nanoparticles

• Mitzi J. Ramírez-Hernández,
• Mario Valera-Zaragoza,
• Omar Viñas-Bravo,
• Ariana A. Huerta-Heredia,
• Miguel A. Peña-Rico,
• Erick A. Juarez-Arellano,
• David Paniagua-Vega,
• Eduardo Ramírez-Vargas and
• Saúl Sánchez-Valdes

Beilstein J. Nanotechnol. 2022, 13, 1505–1519, doi:10.3762/bjnano.13.124

• temperature [22][23][24]. In this way, the ability of secondary metabolites of plant extracts to reduce precursor metal salts to particles with zero charge, and at the same time stabilize nanoparticles already formed, has been demonstrated. Despite this, the phenomenon of interaction of the chemical species

• crops increases the availability of Cl− in the soil and in the leaves of the plant. In this case, it is proposed that the synthesis of AgCl occurred by the interaction of the chloride ions present in the pineapple peel with the silver ions of AgNO3 as other authors have pointed out [31][32]. The high

• crystallite size as a function of temperature is more noticeable for Ag than for AgCl, where an increasing trend in Ag crystallite size is observed up to 80 °C. It is speculated that at this temperature, the separation of salt ions and the interaction with reducing biological compounds are favorable, which

Frequency-dependent nanomechanical profiling for medical diagnosis

• Santiago D. Solares and
• Alexander X. Cartagena-Rivera

Beilstein J. Nanotechnol. 2022, 13, 1483–1489, doi:10.3762/bjnano.13.122

• applications can be explained by a number of reasons. First, ambiguity is generally present in the assumptions, methods, and data analysis of AFM measurements, which are limited to the interaction of a probe of relatively simple apex geometry (e.g., a spherical tip) with a surface, whose properties may differ

• , tendons, ligaments, and bones have a direct impact on the patient’s locomotion or athletic performance. As the length scale of the probe increases, so do the probe–sample interaction forces observed during the measurement, and the characterization returns greater mechanical information about deeper and

Coherent amplification of radiation from two phase-locked Josephson junction arrays

• Mikhail A. Galin,
• Vladimir M. Krasnov,
• Ilya A. Shereshevsky,
• Nadezhda K. Vdovicheva and
• Vladislav V. Kurin

Beilstein J. Nanotechnol. 2022, 13, 1445–1457, doi:10.3762/bjnano.13.119

• .13.119 Abstract We analyze experimentally and theoretically mutual phase locking and electromagnetic interaction between two linear arrays with a large number of Josephson junctions. Arrays with different separation, either on the same chip or on two separate substrates are studied. We observe a large

• exceed the factor of two expected for a simple constructive interference of two oscillators. The larger gain is explained by an additional consequence of mutual interaction between two large arrays. Mutual phase locking of large arrays does not only result in constructive interference outside the arrays

• generates the two-dimensional resonant mode that should lead to the increased output power. Therefore, along with the interaction between individual JJs, there is also a mutual coupling between different arrays (including JJs and electrodes) [14]. In the ideal case of two perfectly phase-locked arrays with

Facile preparation of Au- and BODIPY-grafted lipid nanoparticles for synergized photothermal therapy

• Yuran Wang,
• Xudong Li,
• Haijun Chen and
• Yu Gao

Beilstein J. Nanotechnol. 2022, 13, 1432–1444, doi:10.3762/bjnano.13.118

• interaction between Au-LNPs and BDP. No obvious change of the zeta potentials of AB-LNPs was found in two different media after 7 days (Figure 3b), suggesting that AB-LNPs maintained the nanoparticle structure in PBS and RPMI-1640 + 10% FBS for 7 days. Drug release properties of AB-LNPs To investigate whether

Double-layer symmetric gratings with bound states in the continuum for dual-band high-Q optical sensing

• Chaoying Shi,
• Jinhua Hu,
• Xiuhong Liu,
• Junfang Liang,
• Jijun Zhao,
• Haiyan Han and
• Qiaofen Zhu

Beilstein J. Nanotechnol. 2022, 13, 1408–1417, doi:10.3762/bjnano.13.116

• Figure 8d. It can be found that the sensitivity of both modes decreases with the increase in h. This is because an increase in h increases light trapping inside the cavity, decreasing light–matter interaction and sensitivity. On the contrary, the FOM values of the two modes do not have the same trend

Orally administered docetaxel-loaded chitosan-decorated cationic PLGA nanoparticles for intestinal tumors: formulation, comprehensive in vitro characterization, and release kinetics

• Sedat Ünal,
• Osman Doğan and
• Yeşim Aktaş

Beilstein J. Nanotechnol. 2022, 13, 1393–1407, doi:10.3762/bjnano.13.115

• -PLGA NPs had positive surface charge with CS coating. The formulations have the potential to deliver the encapsulated drug to the bowel according to the in vitro release studies in three different simulated GIT fluids for approximately 72 h. Mucin interaction and penetration into the artificial mucus

• colonic microflora. It has been reported that nanoparticles prepared with polymers such as chitosan, whose surface charge is positive, remain longer in the mucus due to electrostatic interaction with the negative charge of the aqueous mucin layer [15][29][30][31]. Docetaxel (DCX) is obtained semi

• into the nanoparticles as a model anticancer agent. CS coating was used to impart positive surface charge to negatively charged PLGA nanoparticles and to increase their interaction in the intestinal lumen. To date, an orally applicable and effective treatment approach to colon tumors has not been

LED-light-activated photocatalytic performance of metal-free carbon-modified hexagonal boron nitride towards degradation of methylene blue and phenol

• Nirmalendu S. Mishra and
• Pichiah Saravanan

Beilstein J. Nanotechnol. 2022, 13, 1380–1392, doi:10.3762/bjnano.13.114

• HBN and MBN-80 were determined to be −1.66 V and −1.52 V, respectively. The respective potentials vs Ag/AgCl were converted to NHE. The CBMBN shifted to a lower edge potential (by 0.14 V) due to the interaction with the adjacent nitrogen/boron atoms through C–B and C–N bonds [17]. Furthermore, this

• a 48.56% removal with a mineralization efficiency of 20.17% and AQE of 2.67%. This could be explained by the fact that the interaction of the photocatalyst with a specified pollutant varies with respect to its chemical behaviour. In the case of MB, an electrostatic interaction was observed (owing to

• the negatively charged MBN-80 and positively charged MB dye moieties) and that triggered the photocatalysis reaction. In the case of phenol, it contains a phenyl group (–C6H5) with a neutral charge and thus the interaction between this group and the photocatalyst is limited. Also, the phenol is not a

Supramolecular assembly of pentamidine and polymeric cyclodextrin bimetallic core–shell nanoarchitectures

• Alexandru-Milentie Hada,
• Nina Burduja,
• Marco Abbate,
• Claudio Stagno,
• Guy Caljon,
• Louis Maes,
• Nicola Micale,
• Massimiliano Cordaro,
• Angela Scala,
• Antonino Mazzaglia and
• Anna Piperno

Beilstein J. Nanotechnol. 2022, 13, 1361–1369, doi:10.3762/bjnano.13.112

• classifying them in plasmonic NPs (size > 5 nm) and nanoclusters (size < 5 nm). When dimensions exceed 5 nm, NPs exhibit a unique optical phenomenon called localized surface plasmon resonance (LSPR) which represents the collective oscillation of conduction band electrons after interaction between NPs and an

Straight roads into nowhere – obvious and not-so-obvious biological models for ferrophobic surfaces

• Wilfried Konrad,
• Christoph Neinhuis and
• Anita Roth-Nebelsick

Beilstein J. Nanotechnol. 2022, 13, 1345–1360, doi:10.3762/bjnano.13.111

• , the interfaces at a pillared surface may not be stable. As a consequence, there is no guarantee that an extensive empirical investigation of various test objects will be successful in identifying a suitable surface. To summarise, the interaction between S. molesta or Collembola and water does not

• constitute a good model for the interaction between liquid iron and blast furnace tuyères because of the following considerations: As described above, existing mathematical models are highly idealised and cover only partial aspects of the interaction between plant or animal, water and air layer. The

• structure, which can easily be described in terms of analytic functions. When a sheet of liquid iron flows over the tuyère surface, a complex interaction between the gas in the recesses and the liquid evolves. It is, of course, hopeless to try to describe the interaction dynamics in terms of analytic

Recent trends in Bi-based nanomaterials: challenges, fabrication, enhancement techniques, and environmental applications

• Vishal Dutta,
• Ankush Chauhan,
• Ritesh Verma,
• C. Gopalkrishnan and
• Van-Huy Nguyen

Beilstein J. Nanotechnol. 2022, 13, 1316–1336, doi:10.3762/bjnano.13.109

• photocatalytic performance and stability for the photooxidative elimination of NO. The ohmic interaction between OV–(BiO)2CO3 and Bi0 has been shown to promote the synthesis of •O2− and •OH species. It was found that •O2− had a significant impact on the photocatalytic elimination of NO. In another approach

Bending and punching characteristics of aluminum sheets using the quasi-continuum method

• Man-Ping Chang,
• Shang-Jui Lin and
• Te-Hua Fang

Beilstein J. Nanotechnol. 2022, 13, 1303–1315, doi:10.3762/bjnano.13.108

• . In order to accurately calculate the energy of the nonuniform deformation region, the EAM is used to calculate the interaction of the nonlocal atoms [55]. Moreover, to avoid repeated calculations at the coupled regions, the QC method performs continuous coupled calculations to modify the ghost force

Laser-processed antiadhesive bionic combs for handling nanofibers inspired by nanostructures on the legs of cribellate spiders

• Sebastian Lifka,
• Kristóf Harsányi,
• Erich Baumgartner,
• Lukas Pichler,
• Dariya Baiko,
• Karsten Wasmuth,
• Johannes Heitz,
• Marco Meyer,
• Anna-Christin Joel,
• Jörn Bonse and
• Werner Baumgartner

Beilstein J. Nanotechnol. 2022, 13, 1268–1283, doi:10.3762/bjnano.13.105

• special fingerprint-like surface nanostructure. In this work, we present a theoretical model of the interaction of linear nanofibers with a sinusoidally corrugated surface. This model allows for a prediction of the adhesive interaction and, thus, the design of a suitable surface structure to prevent

• because nanofibers strongly adhere to any surface due to van der Waals forces [9]. For a cylindrical fiber with radius R interacting with the plane surface of a semi-infinite body, the energy per unit length due to van der Waals interaction is given as [9]: with the Hamaker constant AH, which is according

• to [9]: Here, the mass densities (ρ1 and ρ2) of the interacting bodies and the London coefficient c, which describes the particle–particle interaction, are multiplied. The van der Waals energy UvdW of the fiber obtained due to the interaction is the integral of the above interaction function µ over

Studies of probe tip materials by atomic force microscopy: a review

• Ke Xu and
• Yuzhe Liu

Beilstein J. Nanotechnol. 2022, 13, 1256–1267, doi:10.3762/bjnano.13.104

• the tip approaches the sample surface, an interaction force is generated that deflects (bends or stretches) the probe cantilever. As the AFM probe moves across the sample surface (in the X and Y directions), morphological information is obtained over the entire scan area. Its tip structure and the

• shown to be removed one by one from the sample surface by tip indentation of the scanning tunneling microscope (STM). The probing of the interaction forces by AFM and thus the analysis of van der Waals (vdW) forces can provide valuable information on the evolution of the tip size. Carbon nanotube probes

• interaction force between the particle and the surface. A new colloidal AFM probe was proposed by Daboss et al. [14]. These conductive spherical boron-doped diamond (BDD)-AFM probes allow electrochemical force spectroscopy. The physical robustness of these bifunctional probes and the excellent electrochemical

Role of titanium and organic precursors in molecular layer deposition of “titanicone” hybrid materials

• Arbresha Muriqi and
• Michael Nolan

Beilstein J. Nanotechnol. 2022, 13, 1240–1255, doi:10.3762/bjnano.13.103

• calculations we have calculated the interaction energies of the TiCl4 molecule on the selected surfaces. These energies are −0.29 eV for the anatase TiO2, −0.22 eV for the rutile TiO2 and 0.87 eV for the Al2O3. These energies indicate that TiCl4 will adsorb favourably, although with a small energy gain, on the

• . Calculated interaction and ligand loss energies of TiCl4 on the anatase TiO2 surface and rutile TiO2 surface are presented in Table 1. Energetics for the ligand loss reactions are calculated relative to the first model of TiCl4 interacting with the surface, and present an overall reaction energy. The overall

• calculated interaction energies on the anatase TiO2, rutile TiO2 and the Al2O3 surfaces are −0.88 eV, −0.74 eV and −1.47 eV, respectively. Thus, Ti(DMA)4 adsorbs favourably on the three oxide surfaces. Next, the thermodynamics of the first, second and third ligand loss reactions of the Ti(DMA)4 precursor are

A super-oscillatory step-zoom metalens for visible light

• Yi Zhou,
• Chao Yan,
• Peng Tian,
• Zhu Li,
• Yu He,
• Bin Fan,
• Zhiyong Wang,
• Yao Deng and
• Dongliang Tang

Beilstein J. Nanotechnol. 2022, 13, 1220–1227, doi:10.3762/bjnano.13.101

• time-consuming for a calculation, we employed the following method to improve the simulation speed: First, we simulated the interaction between the light and the metasurface structure by CST and extracted the optical field at 0.3 μm from the back surface of the SSL. Then, we utilized the scalar angular

Design of surface nanostructures for chirality sensing based on quartz crystal microbalance

• Yinglin Ma,
• Xiangyun Xiao and
• Qingmin Ji

Beilstein J. Nanotechnol. 2022, 13, 1201–1219, doi:10.3762/bjnano.13.100

• based on noncovalent interactions, including hydrogen bonding, metal coordination, van der Waals forces, π–π interaction, and electrostatic interaction. Moreover, the structural “fitting” effect may also have distinct adsorption behaviors for enantiomers. Therefore, the design of effective chiral

• blocking layer between R-Nap and BSA. This suggested that this stronger interaction with R-Nap rather than with S-Nap should arise from different steric hindrance effects between BSA and R/S-Nap. The result was consistent with the QCM measurements. Polymer-based films for chirality sensing Polymers have

• rims. The key to the chiral recognition by CDs is the formation of diastereomeric host–guest complexes based on different interaction affinities. The complexation may occur via inclusion of the guest chiral molecule into the cavity of CDs by π–π interactions, dipole–dipole, ion-pairing, hydrogen