Properties of graphene deposited on GaN nanowires: influence of nanowire roughness, self-induced nanogating and defects

• Jakub Kierdaszuk,
• Piotr Kaźmierczak,
• Justyna Grzonka,
• Aleksandra Krajewska,
• Aleksandra Przewłoka,
• Wawrzyniec Kaszub,
• Zbigniew R. Zytkiewicz,
• Marta Sobanska,
• Maria Kamińska,
• Andrzej Wysmołek and
• Aneta Drabińska

Beilstein J. Nanotechnol. 2021, 12, 566–577, doi:10.3762/bjnano.12.47

• containing graphene on nanowires have been used in solar cells to increase their efficiency. In particular, it has been shown that the application of nanowires in solar cells decreases light reflection by scattering of light in between nanowires [7][8]. Nanowires have also a high cross-section of light

• absorption [9]. However, the interaction between corrugated nanowire substrate and graphene could substantially increase the scattering of carriers in a graphene electrode and decrease its conductivity. Therefore, detailed studies of the interaction between nanowire substrate and graphene are crucial to gain

Surface-enhanced Raman scattering of water in aqueous dispersions of silver nanoparticles

• Paulina Filipczak,
• Krzysztof Hałagan,
• Jacek Ulański and
• Marcin Kozanecki

Beilstein J. Nanotechnol. 2021, 12, 497–506, doi:10.3762/bjnano.12.40

• before and after Raman measurements confirmed their stability under the measurement conditions (the photo- and thermal stability of the investigated samples was discussed in [37]). The observed enhancement effect could be explained by (i) differences in the selective light absorption in the visible part

• of selective light absorption by different samples on the Raman spectrum, the reabsorption correction procedure was performed (details of the data treatment are described in the Section SI1 of the Supporting Information of [35]). The Raman signal of the AgNPs samples was corrected by the

Rapid controlled synthesis of gold–platinum nanorods with excellent photothermal properties under 808 nm excitation

• Jialin Wang,
• Qianqian Duan,
• Min Yang,
• Boye Zhang,
• Li Guo,
• Pengcui Li,
• Wendong Zhang and
• Shengbo Sang

Beilstein J. Nanotechnol. 2021, 12, 462–472, doi:10.3762/bjnano.12.37

• . Keywords: AuNRs; local surface plasmon resonance (LSPR); photothermal conversion efficiency; photothermal transduction agents; platinum; Introduction On the surface of noble metal nanoparticles, when the wavelength of incident light resonates with the light absorption wavelength of the nanoparticles, a

• absorption in the UV–vis range. Hence, these nanoparticles can be applied as excellent PTAs. The PCE of PTAs is directly related to the light absorption capacity. For plasmon nanoparticles, their absorption will be significantly enhanced when the illumination laser wavelength is equal to their LSPR

Unravelling the interfacial interaction in mesoporous SiO₂@nickel phyllosilicate/TiO₂ core–shell nanostructures for photocatalytic activity

• Bridget K. Mutuma,
• Xiluva Mathebula,
• Isaac Nongwe,
• Bonakele P. Mtolo,
• Boitumelo J. Matsoso,
• Rudolph Erasmus,
• Zikhona Tetana and
• Neil J. Coville

Beilstein J. Nanotechnol. 2020, 11, 1834–1846, doi:10.3762/bjnano.11.165

• the bandgap energy value of TiO2 (3.2 eV) to approx. 2.7 eV for Ni2+-doped TiO2 was reported by Devi and co-workers [51]. They associated the shift in light absorption to the charge transfer between the interacting ions. Although there are only a few studies on nickel phyllosilicates, a prior

• electronegativity and ionic radius between the metal ions and titania can alter the concentration of oxygen vacancies in the TiO2 lattice. Hence, the higher electronegativity of Ni2+ in NiPS [43] can induce defect sites within the structure and, consequently, alter light absorption and charge-transfer processes [51

Absorption and photoconductivity spectra of amorphous multilayer structures

• Oxana Iaseniuc and
• Mihail Iovu

Beilstein J. Nanotechnol. 2020, 11, 1757–1763, doi:10.3762/bjnano.11.158

• of the photocurrent spectra is attributed to the different values of the optical bandgap of the involved amorphous layers (Eg ≈ 2.0 eV for As0.40S0.30Se0.30 and Ge0.09As0.09Se0.82 and Eg ≈ 3.0 eV for Ge0.30As0.04S0.66). The obtained experimental results are discussed taking into account the light

• absorption depending on the nature and the thickness of each amorphous layer, on the wavelength, and on contact phenomena at the interfaces between different layers and between the amorphous layers and the metal electrodes with different work functions. Keywords: amorphous multilayer structures

Wafer-level integration of self-aligned high aspect ratio silicon 3D structures using the MACE method with Au, Pd, Pt, Cu, and Ir

• Mathias Franz,
• Romy Junghans,
• Paul Schmitt,
• Adriana Szeghalmi and
• Stefan E. Schulz

Beilstein J. Nanotechnol. 2020, 11, 1439–1449, doi:10.3762/bjnano.11.128

• metals (Au, Pt, Pd, Cu, and Ir) were investigated to derive a set of technologies as platform for specific applications. Especially, the shape of the 3D structures and the resulting reflectance have been investigated. The Si nanostructures fabricated using Au nanoparticles show a perfect light absorption

Excitonic and electronic transitions in Me–Sb₂Se₃ structures

• Nicolae N. Syrbu,
• Victor V. Zalamai,
• Ivan G. Stamov and
• Stepan I. Beril

Beilstein J. Nanotechnol. 2020, 11, 1045–1053, doi:10.3762/bjnano.11.89

• , may be associated with the Dember effect. The photoconductivity and photo-EMF spectra in the absorption edge region show a broad band with maximum values at 1.187 eV (Е⟂с) and 1.167 eV (Е||с) (Figure 3A) which are associated with the light absorption at the direct transitions in the interband gap

Effect of Ag loading position on the photocatalytic performance of TiO₂ nanocolumn arrays

• Jinghan Xu,
• Yanqi Liu and
• Yan Zhao

Beilstein J. Nanotechnol. 2020, 11, 717–728, doi:10.3762/bjnano.11.59

• solar energy harvesting in photovoltaic and photocatalytic applications owing to their extremely high visible-light absorption and tuned effective band gap. In this work, Ag-loaded TiO2 nanocolumn (Ag-TNC) arrays were fabricated based on anodic aluminum oxide (AAO) template by combining atomic layer

• narrowed under the action of LSPR and hot electron injection, and the samples have absorption peaks in the visible part. In Figure 6d, since Ag covers TiO2, the light absorption of ACT3 is substantially generated by Ag, so the sample has no bandgap. The photocatalytic reaction takes place on the surface of

• , c3) wavelength 457 nm AFT3 longitudinal section, c4) wavelength 320 nm AFT3 longitudinal section. (a) Schematic diagram of electron–hole separation and energy conversion of Ag–TiO2 structures under UV–vis illumination. b) AFT structure light absorption diagram. c) Schematic diagram of energy

Preparation and in vivo evaluation of glyco-gold nanoparticles carrying synthetic mycobacterial hexaarabinofuranoside

• Gennady L. Burygin,
• Polina I. Abronina,
• Nikita M. Podvalnyy,
• Sergey A. Staroverov,
• Leonid O. Kononov and
• Lev A. Dykman

Beilstein J. Nanotechnol. 2020, 11, 480–493, doi:10.3762/bjnano.11.39

• . Another advantage of using these GNPs is their strong light absorption due to localized surface plasmon resonance (LSPR) around 520 nm while colloids of GNPs smaller than 3 nm do not exhibit an LSPR and are barely colored. It is known that the color of GNP colloids dramatically depends on size and shape

Coating of upconversion nanoparticles with silica nanoshells of 5–250 nm thickness

• Cynthia Kembuan,
• Maysoon Saleh,
• Bastian Rühle,
• Ute Resch-Genger and
• Christina Graf

Beilstein J. Nanotechnol. 2019, 10, 2410–2421, doi:10.3762/bjnano.10.231

• narrow emission bands in the ultraviolet/visible/NIR upon excitation in the NIR range where light absorption and scattering from biological tissues is minimal as well as long fluorescence lifetimes in the microsecond range that are insensitive to oxygen, a high chemical stability and a low cytotoxicity

Polyvinylpyrrolidone as additive for perovskite solar cells with water and isopropanol as solvents

• Chen Du,
• Shuo Wang,
• Xu Miao,
• Wenhai Sun,
• Yu Zhu,
• Chengyan Wang and
• Ruixin Ma

Beilstein J. Nanotechnol. 2019, 10, 2374–2382, doi:10.3762/bjnano.10.228

• remarkable light absorption capacity [5] and the tunable band gap [6] of inorganic–organic lead halide perovskite crystals make them suitable for the production of organic semiconductors [7], photodetectors [8], and photovoltaics [5]. In 2009, Kojima et al. achieved a breakthrough in using mesoporous TiO2 as

• UV–vis light absorption measurements were performed by using a spectrophotometer (Shimadzu UV-3101 PC). The external quantum efficiency (EQE) measurements were obtained on a Keithley 2000 multimeter as a function of the wavelength from 350 to 800 nm on the basis of a Spectral Products DK240

Improved adsorption and degradation performance by S-doping of (001)-TiO₂

• Xiao-Yu Sun,
• Xian Zhang,
• Xiao Sun,
• Ni-Xian Qian,
• Min Wang and
• Yong-Qing Ma

Beilstein J. Nanotechnol. 2019, 10, 2116–2127, doi:10.3762/bjnano.10.206

• defects such as oxygen vacancies. The absorption spectrum of the 2-S0.5 sample shows a peak at 460 nm. The visible-light absorption of the samples with RS/Ti ≥ 1, where S2− replaces O2− and S6+ replaces Ti4+, is caused by cooperative effects of the oxygen vacancies and the substituted S elements. The

Nanostructured and oriented metal–organic framework films enabling extreme surface wetting properties

• Andre Mähringer,
• Julian M. Rotter and
• Dana D. Medina

Beilstein J. Nanotechnol. 2019, 10, 1994–2003, doi:10.3762/bjnano.10.196

• use of a MOF allows for encoding further desired surface properties such as light absorption and electrical conductivity. This can be valuable for applications such as photo-electrocatalysis water splitting where a high textural surface area, water contact and light absorption are required. A

Biocatalytic oligomerization-induced self-assembly of crystalline cellulose oligomers into nanoribbon networks assisted by organic solvents

• Yuuki Hata,
• Yuka Fukaya,
• Toshiki Sawada,
• Masahito Nishiura and
• Takeshi Serizawa

Beilstein J. Nanotechnol. 2019, 10, 1778–1788, doi:10.3762/bjnano.10.173

• below). To check the possible denaturation of CDP by the organic solvents as an explanation for the decreased monomer conversions, circular dichroism (CD) spectra of CDP solutions containing 10 vol % MeCN or EtOH were measured after incubation at 60 °C (Figure 4). Note that the light absorption of DMSO

Construction of a 0D/1D composite based on Au nanoparticles/CuBi₂O₄ microrods for efficient visible-light-driven photocatalytic activity

• Weilong Shi,
• Mingyang Li,
• Hongji Ren,
• Feng Guo,
• Xiliu Huang,
• Yu Shi and
• Yubin Tang

Beilstein J. Nanotechnol. 2019, 10, 1360–1367, doi:10.3762/bjnano.10.134

• NPs, the visible-light absorption of the CBO photocatalyst is enhanced. At the same time, the hot electrons excited by Au NPs can be injected into the conduction band of CBO, thus increasing the photogenerated charge in the reaction process. In addition, in the 0D/1D heterostructure the Au

Photoactive nanoarchitectures based on clays incorporating TiO₂ and ZnO nanoparticles

• Eduardo Ruiz-Hitzky,
• Pilar Aranda,
• Marwa Akkari,
• Nithima Khaorapapong and
• Makoto Ogawa

Beilstein J. Nanotechnol. 2019, 10, 1140–1156, doi:10.3762/bjnano.10.114

• the experimentally observed differences in the photoactivity are not yet clear due to the effect of complex parameters including light absorption, charge recombination, changes in the available surface area and chemical reactivity [44][45]. Another characteristic of ZnO is its lower chemical stability

CuInSe₂ quantum dots grown by molecular beam epitaxy on amorphous SiO₂ surfaces

• Henrique Limborço,
• Pedro M.P. Salomé,
• Rodrigo Ribeiro-Andrade,
• Jennifer P. Teixeira,
• Nicoleta Nicoara,
• Kamal Abderrafi,
• Joaquim P. Leitão,
• Juan C. Gonzalez and
• Sascha Sadewasser

Beilstein J. Nanotechnol. 2019, 10, 1103–1111, doi:10.3762/bjnano.10.110

• , 20663 Casablanca, Morocco 10.3762/bjnano.10.110 Abstract The currently most efficient polycrystalline solar cells are based on the Cu(In,Ga)Se2 compound as a light absorption layer. However, in view of new concepts of nanostructured solar cells, CuInSe2 nanostructures are of high interest. In this work

Synthesis of novel C-doped g-C₃N₄ nanosheets coupled with CdIn₂S₄ for enhanced photocatalytic hydrogen evolution

• Jingshuai Chen,
• Chang-Jie Mao,
• Helin Niu and
• Ji-Ming Song

Beilstein J. Nanotechnol. 2019, 10, 912–921, doi:10.3762/bjnano.10.92

• crystals on the surface of CCN nanosheets via a hydrothermal method. This unique architecture was able to efficiently promote the transfer and separation of photon-generated charges, enhance light absorption, and significantly increase photocatalytic H2 production. Detailed characterization was performed

• preparation process. UV–vis diffuse reflectance spectroscopy (DRS) was used to investigate the optical absorption properties of g-C3N4, CCN and the series of CISCCN composites. As shown in Figure 6a, g-C3N4 exhibits an absorption edge at approximately 426 nm. For the CCN sample, however, the light absorption

• background strengthens in the longer wavelength region (λ > 450 nm), which can be obviously noticed. The light absorption in the prepared CCN sample is greatly improved, owing to the formation of large delocalized π bonds. Compared with pure CCN, all the CISCNN composites exhibit wider absorption in the

Polydopamine-coated Au nanorods for targeted fluorescent cell imaging and photothermal therapy

• Boris N. Khlebtsov,
• Andrey M. Burov,
• Timofey E. Pylaev and
• Nikolai G. Khlebtsov

Beilstein J. Nanotechnol. 2019, 10, 794–803, doi:10.3762/bjnano.10.79

• obtained composite nanoparticles that have two important theranostic modalities. First, due to the strong light absorption by the AuNR core, the nanoparticles are suitable for photothermal treatment in the NIR tissue transparency window. Second, the nanocomposite shows strong fluorescence under visible

Ultraviolet patterns of flowers revealed in polymer replica – caused by surface architecture

• Anna J. Schulte,
• Matthias Mail,
• Lisa A. Hahn and
• Wilhelm Barthlott

Beilstein J. Nanotechnol. 2019, 10, 459–466, doi:10.3762/bjnano.10.45

• strongly absorbing surfaces. Keywords: biomimetics; hierarchical structures; light absorption; light harvesting; light reflection; Introduction The outer epidermal surface of plants, the cuticle, forms the first and crucial boundary to the abiotic environment [1][2]. In most cases, this cuticle is a

Reduced graphene oxide supported C₃N₄ nanoflakes and quantum dots as metal-free catalysts for visible light assisted CO₂ reduction

• Md Rakibuddin and
• Haekyoung Kim

Beilstein J. Nanotechnol. 2019, 10, 448–458, doi:10.3762/bjnano.10.44

• significant findings, there have been few studies focused on the improvement of the visible light absorption of g-C3N4/rGO hybrid materials [28][29][30][31] and g-C3N4 QDs, and their CO2 photoreduction ability has not yet been reported. Hence, in our present study, metal-free hybrid catalysts consisting of

• due to its quantum size. Additionally, the production of HCHO is improved almost five-fold (10.3 mmol h−1 g−1) in the presence of rGO with CN-5. It is expected that the QD size of the CN-5 sample promotes a higher number of catalytic active sites and enhanced light absorption, and the rGO provides

Geometrical optimisation of core–shell nanowire arrays for enhanced absorption in thin crystalline silicon heterojunction solar cells

• Robin Vismara,
• Olindo Isabella,
• Andrea Ingenito,
• Fai Tong Si and
• Miro Zeman

Beilstein J. Nanotechnol. 2019, 10, 322–331, doi:10.3762/bjnano.10.31

• characteristic radial junction configuration can lead to higher device performance, by increasing light absorption and, at the same time, improving the collection efficiency of photo-generated charge carriers. This work investigates the performance of ultra-thin solar cells characterised by nanowire arrays on a

• intensity inside the device, resulting in the enhancement of light absorption [4]. Of particular interest is the employment of elongated nanostructures, such as nanowire arrays. While their nanoscale dimensions can excite various types of resonances of the EM field within the absorber, such as wave-guiding

• optical simulation of NW-based solar cells demonstrated that NWs amplify Fabry–Perót resonances and, at the same time, excite wave-guided modes inside the thin absorber layers. A study of the effect of the NW geometrical parameters on light absorption was carried out. For a given periodicity (Λ = 800 nm

The nanoscaled metal-organic framework ICR-2 as a carrier of porphyrins for photodynamic therapy

• Jan Hynek,
• Sebastian Jurík,
• Martina Koncošová,
• Jaroslav Zelenka,
• Ivana Křížová,
• Tomáš Ruml,
• Kaplan Kirakci,
• Ivo Jakubec,
• František Kovanda,
• Kamil Lang and
• Jan Demel

Beilstein J. Nanotechnol. 2018, 9, 2960–2967, doi:10.3762/bjnano.9.275

• light absorption at the surface of microcrystalline particles, which results in a small portion of the molecules actively taking place in the photosensitizing process. One of the successful strategies to overcome these effects is the use of MOFs as nanoparticles, which also provides easier

Hybrid Au@alendronate nanoparticles as dual chemo-photothermal agent for combined cancer treatment

• Anouchka Plan Sangnier,
• Romain Aufaure,
• Laurence Motte,
• Claire Wilhelm,
• Erwann Guenin and
• Yoann Lalatonne

Beilstein J. Nanotechnol. 2018, 9, 2947–2952, doi:10.3762/bjnano.9.273

• within the biological transparency windows of 650–950 nm or 1000–1350 nm, to minimize light absorption by surrounding biological tissues [27]. The principal limitation of PTT is that it requires direct light irradiation, which reduces its effect against disseminated metastatic tumors. A promising

• , in the form of PTT, we first evaluated the specific photothermal properties of Au@alendronate NPs. In cancer therapy, it is desirable to use NPs that are active in the near-infrared (NIR) region to minimize light absorption of the laser radiation by surrounding tissues [27][34]. The plasmonic

Time-resolved universal temperature measurements using NaYF₄:Er³⁺,Yb³⁺ upconverting nanoparticles in an electrospray jet

• Kristina Shrestha,
• Arwa A. Alaulamie,
• Ali Rafiei Miandashti and
• Hugh H. Richardson

Beilstein J. Nanotechnol. 2018, 9, 2916–2924, doi:10.3762/bjnano.9.270

• components of the system, T is temperature, t is time, QI and Qext are the rates of energy supplied and flowing out of the system respectively. The energy supplied to the system is by light absorption of water at 980 nm and is given by Equation 2. P0 is the laser power at 980 nm (0.27 W), σabs is the

• excitation at the tip of the Taylor cone sets up a WGM cavity increasing the optical path length by the Q-factor of the cavity [39]. The increased path length results in more light absorption at the tip of the Taylor cone and an increased instead of a decreased temperature as expected. This change of path