Doxorubicin-loaded gold nanorods: a multifunctional chemo-photothermal nanoplatform for cancer management

• Uzma Azeem Awan,
• Abida Raza,
• Shaukat Ali,
• Rida Fatima Saeed and
• Nosheen Akhtar

Beilstein J. Nanotechnol. 2021, 12, 295–303, doi:10.3762/bjnano.12.24

• , such as DOX [18]. Advanced synergistic therapies, such as the combination of chemotherapy and photothermal therapy, have been applied to enhance the overall therapeutic efficacy [19]. This includes magnetic cores capped with gold nanorods, silica nanorattle gold shells, and DNA-based platforms loaded

Differences in surface chemistry of iron oxide nanoparticles result in different routes of internalization

• Barbora Svitkova,
• Vlasta Zavisova,
• Veronika Nemethova,
• Martina Koneracka,
• Miroslava Kretova,
• Filip Razga,
• Monika Ursinyova and
• Alena Gabelova

Beilstein J. Nanotechnol. 2021, 12, 270–281, doi:10.3762/bjnano.12.22

• understood yet. Herein, we present a mechanistic study of cellular internalization pathways of two magnetic iron oxide nanoparticles (MNPs) differing in surface chemistry into A549 cells. The MNP uptake was investigated in the presence of different inhibitors of endocytosis and monitored by spectroscopic and

• involved in the internalization of polyethylene glycol-coated MNPs. Our data indicate that surface engineering can contribute to an enhanced delivery efficiency of nanoparticles. Keywords: bovine serum albumin; cellular uptake; magnetic iron oxide nanoparticles; polyethylene glycol; surface coating

• ; Introduction Magnetic iron oxide nanoparticles (MNPs) as chemically inert material have been increasingly employed as contrast agents in magnetic resonance imaging (MRI), positron emission tomography (PET), and near-infrared fluorescence (NIRF) imaging [1]. The superparamagnetic properties of MNPs make them

Gold(I) N-heterocyclic carbene precursors for focused electron beam-induced deposition

• Cristiano Glessi,
• Aya Mahgoub,
• Cornelis W. Hagen and
• Mats Tilset

Beilstein J. Nanotechnol. 2021, 12, 257–269, doi:10.3762/bjnano.12.21

• and some volatile fragments. The technique has been employed in applications such as the fabrication of nanoconnectors [5], extreme ultra-violet lithography (EUVL) mask repair [6], AFM probe tips [7][8][9], nanodevices for plasmonics [10], gas sensors [11][12], optoelectronics [13], and magnetic [14

Extended iron phthalocyanine islands self-assembled on a Ge(001):H surface

• Rafal Zuzak,
• Marek Szymonski and
• Szymon Godlewski

Beilstein J. Nanotechnol. 2021, 12, 232–241, doi:10.3762/bjnano.12.19

• context of a future application in photovoltaics [58][59]. A few of the phthalocyanines with different central metal atoms exhibit magnetic properties [60] and thus attract growing attention. Having this in mind, we have sublimed FePc molecules on a Ge(001):H surface and studied the formation of molecular

A review on the green and sustainable synthesis of silver nanoparticles and one-dimensional silver nanostructures

• Sina Kaabipour and
• Shohreh Hemmati

Beilstein J. Nanotechnol. 2021, 12, 102–136, doi:10.3762/bjnano.12.9

ZnO and MXenes as electrode materials for supercapacitor devices

• Ameen Uddin Ammar,
• Ipek Deniz Yildirim,
• Feray Bakan and
• Emre Erdem

Beilstein J. Nanotechnol. 2021, 12, 49–57, doi:10.3762/bjnano.12.4

• the major defect centers and give an EPR signal around g ≈ 1.96 [2][3][4][5]. Compared to ge ≈ 2.0023, this resonance requires a higher magnetic field and, thus, a higher microwave frequency. In other words, higher microwave and Zeeman energy are required for this kind of allowed electronic transition

Free and partially encapsulated manganese ferrite nanoparticles in multiwall carbon nanotubes

• Saja Al-Khabouri,
• Salim Al-Harthi,
• Toru Maekawa,
• Mohamed E. Elzain,
• Ashraf Al-Hinai,
• Ahmed D. Al-Rawas,
• Abbsher M. Gismelseed,
• Ali A. Yousif and
• Myo Tay Zar Myint

Beilstein J. Nanotechnol. 2020, 11, 1891–1904, doi:10.3762/bjnano.11.170

• electronic and magnetic properties. The preparation method of partially encapsulated manganese ferrite enables the formation of a hybrid nanoparticle/tube system, which exhibits properties of manganese ferrite nanoparticles inside and attached to the external surface of the tubes. The effect of having

• agents [4]. In addition, encapsulating magnetic nanoparticles inside carbon nanotubes enables the handling of the tubes via magnetic forces, thereby avoiding the alteration of their electronic or mechanical properties when using them in nanoelectronics [5]. Moreover, carbon nanotubes filled with magnetic

• materials have the potential to be used for the transport of drugs to specific locations in the body as well as in medical diagnosis without the need for surgical interference [6]. Pal et al. synthesized Fe3O4 encapsulated in carbon nanostraws and reported an enhancement in the magnetic properties, which

Kondo effects in small-bandgap carbon nanotube quantum dots

• Patryk Florków,
• Damian Krychowski and
• Stanisław Lipiński

Beilstein J. Nanotechnol. 2020, 11, 1873–1890, doi:10.3762/bjnano.11.169

• quantum dots in the presence of spin–orbit coupling in the strong-correlations regime. A finite-U slave-boson mean-field approach is used to study many-body effects. Different degeneracies are restored in a magnetic field and Kondo effects of different symmetries arise, including SU(3) effects of

• different types. Full spin–orbital degeneracy might be recovered at zero field and, correspondingly, the SU(4) Kondo effect sets in. We point out the possibility of the occurrence of electron–hole Kondo effects in slanting magnetic fields, which we predict to occur in magnetic fields with an orientation

• , mechanical, and magnetic properties carbon nanotubes (CNTs) are of great interest in molecular electronics and spintronics with potential applications, for example, as field-effect transistors, nanoelectromechanical devices, logic gates, spin valves, spin diodes, and spin batteries [1][2][3][4][5][6][7][8][9

Scanning transmission imaging in the helium ion microscope using a microchannel plate with a delay line detector

• Eduardo Serralta,
• Nico Klingner,
• Olivier De Castro,
• Michael Mousley,
• Santhana Eswara,
• Serge Duarte Pinto,
• Tom Wirtz and
• Gregor Hlawacek

Beilstein J. Nanotechnol. 2020, 11, 1854–1864, doi:10.3762/bjnano.11.167

• phenomena occurring during the projectile–target interaction and can increase the signal-to-noise ratio [23]. Since most likely a considerable fraction of the transmitted particles at this energy range is neutral [24][25], magnetic or electrostatic spectrometers cannot be used. Therefore, ion energy-loss

• combines the helium ion microscopy techniques with SIMS using a magnetic sector spectrometer, STIM with this new detector, and cryo-microscopy capabilities in a single instrument and will be described in detail elsewhere. In comparison to a commercial HIM, this microscope has a larger vacuum chamber that

Molecular dynamics modeling of the influence forming process parameters on the structure and morphology of a superconducting spin valve

• Alexander Vakhrushev,
• Aleksey Fedotov,
• Vladimir Boian,
• Roman Morari and
• Anatolie Sidorenko

Beilstein J. Nanotechnol. 2020, 11, 1776–1788, doi:10.3762/bjnano.11.160

• nondissipative elements of spintronics, it is possible to create new superconducting nanoelectronics devices that consume minimum energy and have a high operation speed [8][9][10][11][12][13]. One type of magnetic nanostructure with wide potential use is the spin valve [14][15], consisting of several magnetic

• films separated by a magneto-resistive layer. Due to the exchange interaction with the adjacent antiferromagnetic nanofilm, one of the layers has constant magnetization. For the adjacent nanofilm, the direction of magnetization can be controlled by an external magnetic field. The weak link of the

• ferromagnetic layers causes a restructuring of the magnetic moment configuration under low-power magnetic fields and switches the spin valve from a high to a low resistance state. When a superconducting film is used as a magneto-resistive interlayer, a superconducting spin valve is obtained. Furthermore, these

Imaging and milling resolution of light ion beams from helium ion microscopy and FIBs driven by liquid metal alloy ion sources

• Nico Klingner,
• Gregor Hlawacek,
• Paul Mazarov,
• Wolfgang Pilz,
• Fabian Meyer and
• Lothar Bischoff

Beilstein J. Nanotechnol. 2020, 11, 1742–1749, doi:10.3762/bjnano.11.156

• of 10 kV scanned by the ExB voltage using a constant magnetic field. The numbers below the ion label specify the total ion mass m in u. Examples using different ions: a) 30 keV He+, field of view (FOV): 1.5 × 1.5 µm2, trench width: 4 nm, b) 40 keV Li+, FOV: 2.5 × 2.5 µm2, trench width: 6 nm, c) 25

Functional nanostructures for electronics, spintronics and sensors

• Anatolie S. Sidorenko

Beilstein J. Nanotechnol. 2020, 11, 1704–1706, doi:10.3762/bjnano.11.152

• hetero-epitaxial S/F nanostructures. The elaborated and fabricated nanostructures can be utilized in superconducting memory and logic circuits as Josephson magnetic random access memory (MRAM) elements for a superconducting computer. Other articles, more conceptual in nature, where the authors proposed

Cu₂O nanoparticles for the degradation of methyl parathion

• Juan Rizo,
• David Díaz,
• Benito Reyes-Trejo and
• M. Josefina Arellano-Jiménez

Beilstein J. Nanotechnol. 2020, 11, 1546–1555, doi:10.3762/bjnano.11.137

• different NPs sizes (16, 29 and 45 nm), determined with X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM), were synthesized using a modified Benedict’s reagent. 1H nuclear magnetic resonance (NMR) results show that the hydrolytic degradation of MP leads to the formation of

Adsorption and self-assembly of porphyrins on ultrathin CoO films on Ir(100)

• Feifei Xiang,
• Tobias Schmitt,
• Marco Raschmann and
• M. Alexander Schneider

Beilstein J. Nanotechnol. 2020, 11, 1516–1524, doi:10.3762/bjnano.11.134

• -hexagonal layer with lattice parameter a2BL CoO = 3.0–3.1 Å [18]. STM images of both films show the positions of the oxygen atoms as bright protrusions [20]. Computational Methods Non-magnetic ab initio calculations were performed using the Vienna Ab-initio Simulation Package (VASP) [32] employing the PBE

Helium ion microscope – secondary ion mass spectrometry for geological materials

• Matthew R. Ball,
• Richard J. M. Taylor,
• Joshua F. Einsle,
• Fouzia Khanom,
• Christelle Guillermier and
• Richard J. Harrison

Beilstein J. Nanotechnol. 2020, 11, 1504–1515, doi:10.3762/bjnano.11.133

• –SIMS for geological materials are also provided. Results and Discussion Methods All analyses were performed using an ORION NanoFab HIM with an attached V500 double focussing magnetic sector mass spectrometer [14]. The gas field ion source (GFIS) of the ORION instrument produces a highly focussed single

• value of m/z for which no secondary ions were expected, for the measurement of a “background count rate”, with a fixed, low magnetic field of around 100 mT. The primary beam was rastered over the sample to simultaneously map ion counts on each detector with a typical dwell time per pixel of 4 ms

• , in contrast, has its highest mass resolving power at low masses (around 400 M/ΔM) with a low magnetic field applied within the mass spectrometer, making it an ideal tool for mapping these elements. Lithium mapping Figure 7 shows a comparison of the SEM–EDS signal obtained from a sample of Li-bearing

A wideband cryogenic microwave low-noise amplifier

• Boris I. Ivanov,
• Dmitri I. Volkhin,
• Ilya L. Novikov,
• Dmitri K. Pitsun,
• Dmitri O. Moskalev,
• Ilya A. Rodionov,
• Evgeni Il’ichev and
• Aleksey G. Vostretsov

Beilstein J. Nanotechnol. 2020, 11, 1484–1491, doi:10.3762/bjnano.11.131

• frequency of f0 = 7.0554 GHz and experimentally characterized the qubit responce. First, one-tone spectroscopy was carried out. The transmission of a sweeping microwave signal through the sample in a frequency range of 7.05–7.06 GHz for different DC bias currents, producing an external magnetic field, was

• measured. The obtained curve is shown in Figure 6. Here, the horizontal axis is a sweeping DC magnetic field in current values, the vertical axis is the sweeping frequency of a probing microwave signal and the color intensity graph shows the normalized transmission amplitude |S21| in units of dB, where 0

• corresponds to a normalized maximum transmission. Due to the magnetic flux quantization the qubit characteristic has periodic behavior. The maximum shift of the resonance frequency corresponds to a so called “sweet spot” and the distance between two sweet spots corresponds to the magnetic flux quantum Φ0. We

Antimicrobial metal-based nanoparticles: a review on their synthesis, types and antimicrobial action

• Matías Guerrero Correa,
• Fernanda B. Martínez,
• Cristian Patiño Vidal,
• Camilo Streitt,
• Juan Escrig and
• Carol Lopez de Dicastillo

Beilstein J. Nanotechnol. 2020, 11, 1450–1469, doi:10.3762/bjnano.11.129

• modification, intrinsic properties and the type of targeted microorganism [18]. A special category of metallic NPs is superparamagnetic iron-oxide nanoparticles (SPIONs) (e.g., magnetite (Fe3O4) and maghemite (γ-Fe2O3) NPs) whose antimicrobial activity increases upon the application of an external magnetic

• antimicrobial studies revealed good antimicrobial activity against E. coli, S. flexneri, and S. aureus cells [123]. Superparamagnetic iron-oxide nanoparticles Superparamagnetic iron oxide nanoparticles are a special class of metal-oxide NPs with magnetic properties and excellent biocompatibility. Their shape

• , size and magnetic nature enables them to kill microorganisms through the application of an external magnetic field, resulting in an increase of the therapeutic antimicrobial properties, especially when compared to conventional antimicrobial compounds [136]. Ferromagnetic nanoparticles are probably the

Superconductor–insulator transition in capacitively coupled superconducting nanowires

• Alex Latyshev,
• Andrew G. Semenov and
• Andrei D. Zaikin

Beilstein J. Nanotechnol. 2020, 11, 1402–1408, doi:10.3762/bjnano.11.124

• experiments [7][8][9][10]. Likewise, quantum phase slips in superconducting nanowires yield shot noise of the voltage [11] which originates from the process of quantum tunneling of magnetic flux quanta across the wire. One can also proceed beyond the voltage–voltage correlator and evaluate all cumulants of

• transmission lines. Capacitive coupling between these two nanowires is accounted for by the mutual capacitance Cm. The corresponding contribution to the system Hamiltonian that keeps track of both electric and magnetic energies in these coupled transmission lines reads where x is the coordinate along the wires

• expressed in terms of the dual operators and [14] which obey the canonical commutation relation and are related to the charge density and the local phase operators, and respectively, by means of the following equations Physically, represents the magnetic flux operator, while the operator is

Transient coating of γ-Fe₂O₃ nanoparticles with glutamate for its delivery to and removal from brain nerve terminals

• Konstantin Paliienko,
• Artem Pastukhov,
• Michal Babič,
• Daniel Horák,
• Olga Vasylchenko and
• Tatiana Borisova

Beilstein J. Nanotechnol. 2020, 11, 1381–1393, doi:10.3762/bjnano.11.122

• trauma, and epilepsy. Also, glutamate is a potential tumor growth factor. Using radiolabeled ʟ-[14C]glutamate and magnetic fields, we developed an approach for monitoring the biomolecular coating (biocoating) with glutamate of the surface of maghemite (γ-Fe2O3) nanoparticles. The nanoparticles decreased

• identified. Glutamate-coated γ-Fe2O3 nanoparticles can be used for glutamate delivery to the nervous system or for glutamate adsorption (but with lower effectiveness) in stroke, brain trauma, epilepsy, and cancer treatment following by its subsequent removal using a magnetic field. γ-Fe2O3 nanoparticles with

• due to their magnetism and chemical stability [9][10][11][12][13]. Among a variety of other nanoparticles, superparamagnetic iron oxide nanoparticles are used for magnetic resonance imaging in cancer theranostics and magnetic hyperthermia [9][10][11][14]. Controlled magnetic fields can lead to induced

Controlling the proximity effect in a Co/Nb multilayer: the properties of electronic transport

• Sergey Bakurskiy,
• Mikhail Kupriyanov,
• Nikolay V. Klenov,
• Igor Soloviev,
• Andrey Schegolev,
• Roman Morari,
• Yury Khaydukov and
• Anatoli S. Sidorenko

Beilstein J. Nanotechnol. 2020, 11, 1336–1345, doi:10.3762/bjnano.11.118

• effective critical temperature of the magnetic superconductor is significantly smaller than of the bulk semiconductor material. This property of the system is demonstrated in Figure 3. Figure 3a presents the temperature dependence of the pair potential in different superconducting layers for P (solid lines

• distribution appears in the screening of F-layers in multilayer structures from an outer magnetic field due to the Meissner effect. The inner F-layers are strongly screened while the opposite is observed for the outer layers. This means that the remagnetization of the layers in an increasing homogeneous

• external magnetic field do not occur simultaneously, but instead gradually from the outer to the inner layers of the structure. The calculated distribution of the anomalous Green’s function, F, allows for the estimation of the screening properties of the hybrid structure. The spatial distribution of the

Magnetohydrodynamic stagnation point on a Casson nanofluid flow over a radially stretching sheet

• Ganji Narender,
• Kamatam Govardhan and
• Gobburu Sreedhar Sarma

Beilstein J. Nanotechnol. 2020, 11, 1303–1315, doi:10.3762/bjnano.11.114

• article proposes a numerical model to investigate the impact of the radiation effects in the presence of heat generation/absorption and magnetic field on the magnetohydrodynamics (MHD) stagnation point flow over a radially stretching sheet using a Casson nanofluid. The nonlinear partial differential

• example, the fabrication of porous media, open and closed cavities and the implementation of magnetic effects, nanofluids and micrometer-sized channels have been employed to enhance thermal convection processes. Choi and collaborators [5] have used the term “nanofluid” for the first time to refer to a

• magnetic properties of electrically conducting fluids are studied is called magnetohydrodynamics (MHD). Magnetic fluids, liquids, metals and mixtures containing water, salt and other electrolytes are examples of materials that can be investigated via MHD. Hannes Alfen was the first to introduce the term

Structure and electrochemical performance of electrospun-ordered porous carbon/graphene composite nanofibers

• Yi Wang,
• Yanhua Song,
• Chengwei Ye and
• Lan Xu

Beilstein J. Nanotechnol. 2020, 11, 1280–1290, doi:10.3762/bjnano.11.112

• magnetic stirring for 2 h to obtain a 2 wt % homogeneous electrospinning solution. Preparation of carbon/graphene composite nanofibers The ordered porous CGCNFs were prepared by MPEM and then submitted to carbonization under a N2 atmosphere at 1100 °C, as shown in Figure 1. The MPEM apparatus is composed

An atomic force microscope integrated with a helium ion microscope for correlative nanoscale characterization

• Santiago H. Andany,
• Gregor Hlawacek,
• Stefan Hummel,
• Charlène Brillard,
• Mustafa Kangül and
• Georg E. Fantner

Beilstein J. Nanotechnol. 2020, 11, 1272–1279, doi:10.3762/bjnano.11.111

• for nanomechanical property mapping, as well as for electrical and magnetic characterization of the sample after focused ion beam materials modification with the HIM. The experimental setup is described and evaluated through a series of correlative experiments, demonstrating the feasibility of the

• used, in situ, in between exposures to assess the shrinkage, stiffness change or sputtering of the resist. More applications such as conductive AFM, piezo-force microscopy or magnetic force microscopy are within reach of the presented technology and would make AFM–HIM appealing to the microelectronics

• topography of the photoresist PMMA. Many more examples can be envisioned. The He ion beam is known to change the mechanical [37], electrical [38], and magnetic properties of materials [39]. AFM can be used to measure mechanical properties using contact resonance [40][41] or off-resonance tapping techniques

Proximity effect in [Nb(1.5 nm)/Fe(x)]₁₀/Nb(50 nm) superconductor/ferromagnet heterostructures

• Yury Khaydukov,
• Sabine Pütter,
• Laura Guasco,
• Roman Morari,
• Gideok Kim,
• Thomas Keller,
• Anatolie Sidorenko and
• Bernhard Keimer

Beilstein J. Nanotechnol. 2020, 11, 1254–1263, doi:10.3762/bjnano.11.109

• Nanotechnologies ASM, MD2028 Kishinev, Moldova 10.3762/bjnano.11.109 Abstract We have investigated the structural, magnetic and superconduction properties of [Nb(1.5 nm)/Fe(x)]10 superlattices deposited on a thick Nb(50 nm) layer. Our investigation showed that the Nb(50 nm) layer grows epitaxially at 800 °C on

• phenomena are π–Josephson junctions [4][5][6][7] with a π-phase difference of superconducting correlations between two neighboring interfaces, long-range triplet superconductivity [8][9][10][11][12][13][14][15][16] generated in S/F systems with a non-collinear (NC) magnetic configuration of the F system

• controlled via the manipulation of the magnetic order in the F subsystem [21][22][23][24][25][26]. One possible way to exert such a control is via interaction of superconductivity and interlayer exchange coupling (IEC) of F layers through a normal metal (NM) spacer. The IEC in a F/N/F system can be tuned by

Ultrasensitive detection of cadmium ions using a microcantilever-based piezoresistive sensor for groundwater

• Dinesh Rotake,
• Anand Darji and
• Nitin Kale

Beilstein J. Nanotechnol. 2020, 11, 1242–1253, doi:10.3762/bjnano.11.108

• only on absorption and fluorescence change and need dynamic acquisition [23]. A magnetic field powered pressure sensor proposed by Khan et al. [24] is capable of measuring pressure in the range of kilopascals but the suitability for the very low pressure caused by HMIs needs to be examined. A reduced