Metal-organic framework-based nanomaterials for CO₂ storage: A review

• Ha Huu Do,
• Iqra Rabani and
• Hai Bang Truong

Beilstein J. Nanotechnol. 2023, 14, 964–970, doi:10.3762/bjnano.14.79

• mechanism of CO2 on MOFs featuring OMSs. Wu et al. revealed that the interactions between the OMSs of Mg-MOF-74 and HKUST-1 and CO2 molecules are primarily of physical nature [24]. This type of adsorption mechanism offers the advantage of low energy requirements in material regeneration. Another significant

Prediction of cytotoxicity of heavy metals adsorbed on nano-TiO₂ with periodic table descriptors using machine learning approaches

• Joyita Roy,
• Souvik Pore and
• Kunal Roy

Beilstein J. Nanotechnol. 2023, 14, 939–950, doi:10.3762/bjnano.14.77

• have been used in different industries, and the market is developing rapidly [2]. According to a recent analysis, approximately 1300 consumer products containing NPs were marketed in 2012. As a common metal oxide nanoparticle material, nanoscale titanium dioxide (nano-TiO2) has been evaluated for

• diverse applications. TiO2 has been shown to be a promising material for practical applications because it is highly photoreactive, inexpensive, non-toxic, chemically and biologically inert, and photostable. Also, nano-TiO2 exhibits high specific surface area and anti-corrosion and photocatalytic

• living cells, and their cytotoxicity may inhibit cell growth cycles, leading to death of organisms. Considering this fact, the cytotoxicity of TiO2 in combination with other pollutants has been evaluated. TiO2 is the most commonly manufactured nanoparticle material. It is assumed that because of the

Upscaling the urea method synthesis of CoAl layered double hydroxides

• Camilo Jaramillo-Hernández,
• Víctor Oestreicher,
• Martín Mizrahi and
• Gonzalo Abellán

Beilstein J. Nanotechnol. 2023, 14, 927–938, doi:10.3762/bjnano.14.76

• . Considering the experimental conditions for the production of pure CoAl-based LDH, we decided to compare the synthesis performance in terms of the space–time yield (STY). The STY value, defined as the amount of material (in kg) that can be produced per volume (in m3) per day, provides a good parameter to

• collected over the bulk material with a Quantum Design superconducting quantum interference device (SQUID) MPMS-XL-5. The magnetic susceptibility of the samples was corrected considering the diamagnetic contributions of their atomic constituents as deduced from Pascal’s constant tables and the sample holder

• . The DC data were recorded under external applied fields of 100 or 1000 Oe in the 2–300 K temperature range. The AC data were collected under an applied field of 3.95 Oe at 997, 333, 110, 10, and 1 Hz. All magnetic measurements were carried out in eicosane, since this diamagnetic material allows for a

Ni, Co, Zn, and Cu metal-organic framework-based nanomaterials for electrochemical reduction of CO₂: A review

• Ha Huu Do and
• Hai Bang Truong

Beilstein J. Nanotechnol. 2023, 14, 904–911, doi:10.3762/bjnano.14.74

• ]. The first work on electrocatalytic CO2 reduction was published in 1870 using a Zn material to produce HCOOH [17][18]. Subsequent investigations have yielded numerous studies focusing on the development of electrocatalysts for CO2RR. In 1994, Hori et al. highlighted that the selectivity of products

• both their metal sites and organic components. Furthermore, their catalytic properties can be readily modified through functionalization. For instance, Fu et al. grafted –NH2 groups onto MIL-125(Ti) material to enhance CO2RR for the production of HCOO− [33]. The outcome indicated that NH2-MIL-125(Ti

• products, as shown in Figure 1. In addition to the properties of the catalyst material, other parameters, such as potential, pH, solvent, and temperature, also determine the formation of desired products. MOFs nanomaterials for electrocatalytic reduction of CO2 Ni-based MOFs nanomaterials Two-dimensional

N-Heterocyclic carbene-based gold etchants

• Robert B. Chevalier,
• Justin Pantano,
• Matthew K. Kiesewetter and
• Jason R. Dwyer

Beilstein J. Nanotechnol. 2023, 14, 865–871, doi:10.3762/bjnano.14.71

• clearly undesirable that an effort to form a stable monolayer could result in removal of underlying material, but similarly undesirable effects have been reported in the gold–thiol SAM literature. For example, gold–sulfur interactions can lead to a weaker bonding of gold surface atoms to the bulk. This

• observation contrasts with the localized depletion of gold during etching by solutions of 1 in DCM and THF, as shown in the electron micrographs in Figure 3b,c. The formation of voids in the gold film allowed for comparison of this material loss between different samples without the need to standardize

Industrial perspectives for personalized microneedles

• Remmi Danae Baker-Sediako,
• Benjamin Richter,
• Matthias Blaicher,
• Michael Thiel and
• Martin Hermatschweiler

Beilstein J. Nanotechnol. 2023, 14, 857–864, doi:10.3762/bjnano.14.70

• microneedles are most often directly printed onto the medical device and aligned to specific features, such as pores, on the device. Direct microneedle printing has its own set of extensive requirements (e.g., biocompatibility of the material, mechanical robustness, and surface adhesion). Also, FDA’s 510(k

• on a “Quantum X shape” lithography system (Nanoscribe GmbH & Co, Karlsruhe, Germany) following printing and post-printing protocols from NanoGuide. Post-printing protocols begin by removing unpolymerized material via two-step washing with either propylene glycol methyl ether acetate or mr-Dev for 15

Biomimetics on the micro- and nanoscale – The 25th anniversary of the lotus effect

• Matthias Mail,
• Kerstin Koch,
• Thomas Speck,
• William M. Megill and
• Stanislav N. Gorb

Beilstein J. Nanotechnol. 2023, 14, 850–856, doi:10.3762/bjnano.14.69

• biological processes and surface interactions involved in the bioselective adhesion of mammalian cells. The second topic of the review was on repellence of microbes on protein-based material surfaces, highlighting the importance of materials made of recombinant spider silk proteins. Biomaterials that

• material through a few steps. In the first step, a molten polypropylene layer is laminated onto a carrier film and run over rollers to cool down. Then the combined laminate is forced through a gap between a hot sandblasted roller and a cold smooth one. The surface roughness and temperature difference

• satisfactory nearly superhydrophobic material which the authors used to create an effective oil–water separation product they called nanopads. What this paper demonstrates, in addition to the not insignificant contribution it makes to the science of structured surfaces, is that with a bit of creativity and a

Ultralow-energy amorphization of contaminated silicon samples investigated by molecular dynamics

• Grégoire R. N. Defoort-Levkov,
• Alan Bahm and
• Patrick Philipp

Beilstein J. Nanotechnol. 2023, 14, 834–849, doi:10.3762/bjnano.14.68

• sputtering processes are the same as in [26]. In this publication, the focus is on impact energy variations. We should expect significant variations in sputtering yields, damage formation, and amount of material displaced. We will also study fragmentation, implantation, and sputtering of water molecules

A wearable nanoscale heart sound sensor based on P(VDF-TrFE)/ZnO/GR and its application in cardiac disease detection

• Yi Luo,
• Jian Liu,
• Jiachang Zhang,
• Yu Xiao,
• Ying Wu and
• Zhidong Zhao

Beilstein J. Nanotechnol. 2023, 14, 819–833, doi:10.3762/bjnano.14.67

• polymer material with a wide frequency bandwidth, good biocompatibility, and softness. It is one of the preferred materials for flexible piezoelectric sensors [12]. However, compared to rigid piezoelectric materials such as PZT, pure P(VDF-TrFE) has inferior piezoelectric properties [13]. Researchers have

• generally associated with better piezoelectric performance of the material. To further validate the enhancement of the β phase, Fourier-transform infrared (FTIR) analysis was conducted (Figure 7a). The FTIR spectrum of the piezoelectric film exhibited distinct absorption bands. Peaks observed at 600, 763

• voltage and to a reduced filament diameter. Moreover, since GR has a sheet-like structure with good electrical conductivity, adding a trace amount of GR material can further enhance the solution's conductivity and promote the dispersion of ZnO particles, resulting in finer and smoother nanofiber filaments

Nanostructured lipid carriers containing benznidazole: physicochemical, biopharmaceutical and cellular in vitro studies

• Giuliana Muraca,
• María Esperanza Ruiz,
• Rocío C. Gambaro,
• Sebastián Scioli-Montoto,
• María Laura Sbaraglini,
• Gisel Padula,
• José Sebastián Cisneros,
• Cecilia Yamil Chain,
• Vera A. Álvarez,
• Cristián Huck-Iriart,
• Guillermo R. Castro,
• María Belén Piñero,
• Matias Ildebrando Marchetto,
• Catalina Alba Soto,
• Germán A. Islan and
• Alan Talevi

Beilstein J. Nanotechnol. 2023, 14, 804–818, doi:10.3762/bjnano.14.66

• bulk material, considering the disarrangement caused by the incorporation of the drug and the surfactant. For that reason, it might require less energy to melt in comparison to the pure crystalline substance [25]. Thermogravimetric curves of myristyl myristate, poloxamer 188, and BNZ showed one thermal

• 5 mg of the dry sample after freeze drying the formulations was used. Scans were run in the range from 0 to 250 °C at a heating rate of 10 °C/min. The degree of crystallinity (% crystallinity index, CI) was calculated using the following equation [55]: where ΔHNLC and ΔHbulk material are the melting

• . Supporting Information This file includes a summary of the goodness-of-fit measures that indicate how different mathematical models of drug release fit our experimental data. Supporting Information File 54: Supplementary material. Acknowledgements We thank CONICET and Agencia I+D+I (PICT 2017-0643 and PICT

Silver-based SERS substrates fabricated using a 3D printed microfluidic device

• Phommachith Sonexai,
• Minh Van Nguyen,
• Bui The Huy and
• Yong-Ill Lee

Beilstein J. Nanotechnol. 2023, 14, 793–803, doi:10.3762/bjnano.14.65

• formation of a charge-transfer complex between chemisorbed species and matrix material, which yields enhancement when the excitation frequency resonates with a charge-transfer transition [7]. Noble metal nanoparticles (NPs) have gained much popularity in various fields, such as analytical chemistry and

Silver nanoparticles loaded on lactose/alginate: in situ synthesis, catalytic degradation, and pH-dependent antibacterial activity

• Nguyen Thi Thanh Tu,
• T. Lan-Anh Vo,
• T. Thu-Trang Ho,
• Kim-Phuong T. Dang,
• Van-Dung Le,
• Phan Nhat Minh,
• Chi-Hien Dang,
• Vinh-Thien Tran,
• Van-Su Dang,
• Tran Thi Kim Chi,
• Hieu Vu-Quang,
• Radek Fajgar,
• Thi-Lan-Huong Nguyen,
• Van-Dat Doan and
• Thanh-Danh Nguyen

Beilstein J. Nanotechnol. 2023, 14, 781–792, doi:10.3762/bjnano.14.64

• activity. These findings suggest that this nanocomposite has the potential to be tailored for specific applications in environmental and medicinal treatments, making it a highly promising material. Keywords: alginate; bacterial activity; catalysis; lactose; silver nanoparticles; synthesis; Introduction

• release of silver ions or electrostatic interaction between AgNPs and microbial cells, have been proposed [21][22]. The AgNPs might release silver ions capable of binding to nucleic acids, thereby, exhibiting antibacterial activity [23][24]. Consequently, any silver-containing composite material with

• surface properties of silver nanoparticles. The highest bioactivity was observed at pH 6. These findings suggest that the nanocomposite may be customized for specific applications in environmental and medicinal treatments, making it a promising material. Experimental Materials The following chemicals and

Carboxylic acids and light interact to affect nanoceria stability and dissolution in acidic aqueous environments

• Matthew L. Hancock,
• Eric A. Grulke and
• Robert A. Yokel

Beilstein J. Nanotechnol. 2023, 14, 762–780, doi:10.3762/bjnano.14.63

• the experiment the samples were stored in plastic DLS cuvettes, prepared from material that does not significantly absorb UVA radiation [59]. UVA 355 nm radiation at the site of samples exposed to light, at 10 a.m. May 31, 2023, was 6 µW/cm2. Sodium hydroxide and nitric acid were used to adjust

In situ magnesiothermic reduction synthesis of a Ge@C composite for high-performance lithium-ion batterie anodes

• Ha Tran Huu,
• Ngoc Phi Nguyen,
• Vuong Hoang Ngo,
• Huy Hoang Luc,
• Minh Kha Le,
• Minh Thu Nguyen,
• My Loan Phung Le,
• Hye Rim Kim,
• In Young Kim,
• Sung Jin Kim,
• Van Man Tran and
• Vien Vo

Beilstein J. Nanotechnol. 2023, 14, 751–761, doi:10.3762/bjnano.14.62

• report an in situ magnesiothermic reduction to synthesize a composite of Ge@C as an anode material for lithium-ion batteries. The obtained electrode delivered a specific capacity of 454.2 mAh·g−1 after 200 cycles at a specific current of 1000 mA·g−1. The stable electrochemical performance and good rate

• systems have become the most popular energy storage systems, with applications from mobile devices to EVs and grid-scale storage [8][9]. However, the low specific theoretical capacity of graphite limits the energy density of the commercial LIBs [10][11][12][13]. Germanium, as a lithium alloying material

• Fd−3m, JCPDS card No. 04-0545). There is no observable signal related to the GeO2 precursor. The XRD pattern of the BC-800 carbon material exhibits a diffraction signal at 2θ = 26.3° attributed to the (002) plane of disordered graphite-like carbon. The peaks at 2θ = 28.1° and 44.0° correspond to the

Nanoarchitectonics for advanced applications in energy, environment and biology: Method for everything in materials science

• Katsuhiko Ariga

Beilstein J. Nanotechnol. 2023, 14, 738–740, doi:10.3762/bjnano.14.60

• parallel and is due to the development of functional materials. In the beginning of the civilization, humans used to extract materials directly from nature and process them for personal use. Later, we learned how to create materials not found in nature through various chemical reactions. Such material

• the creation of functional materials that improved human life. In the course of their development, we have learned that the function of a material depends not only on the material itself but also on the precision of its internal structure. This is where nanotechnology has brought about a revolution

• the 20th century [4][5] whereas nanoarchitectonics was proposed by Masakazu Aono in the early 21st century [6]. Nanoarchitectonics is a methodology for architecting functional material systems from components at the nanoscale (i.e., atoms, molecules, and nanomaterials) following the footsteps of

Cross-sectional Kelvin probe force microscopy on III–V epitaxial multilayer stacks: challenges and perspectives

• Mattia da Lisca,
• José Alvarez,
• James P. Connolly,
• Nicolas Vaissiere,
• Karim Mekhazni,
• Jean Decobert and
• Jean-Paul Kleider

Beilstein J. Nanotechnol. 2023, 14, 725–737, doi:10.3762/bjnano.14.59

• ; surface photovoltage; Introduction The development of photovoltaic (PV) technologies has progressed significantly over the past twenty years as a result of considerable advancements in solar cell device engineering and material science. As a consequence, solar cells have turned into complex structures

• surface of a photoactive material [20]. Since the surface potential of the tip is assumed to be unaffected by illumination, the difference between VCPD/light and VCPD/dark is equal to the change in surface potential of the sample between illumination and dark, which defines the surface photovoltage: It is

• potential is modified by the presence of surface states induced by surface defects since we know that KPFM is a surface technique and that the simulated VCPD variation at this stage is based solely on bulk material properties and is not affected by any surface defects. Therefore, the experimental surface

Nanomaterials for photocatalysis and applications in environmental remediation and renewable energy

• Viet Van Pham and
• Wee-Jun Ong

Beilstein J. Nanotechnol. 2023, 14, 722–724, doi:10.3762/bjnano.14.58

• nanomaterials for environmental remediation and sustainable applications; for instance, dye solar cells, solar-driven water splitting, NOx removal, and contaminant degradation. This Thematic Issue will make a good reference material and be of great use for scientists in nanomaterials fields. Viet Van Pham and

A graphene quantum dots–glassy carbon electrode-based electrochemical sensor for monitoring malathion

• Sanju Tanwar,
• Aditi Sharma and
• Dhirendra Mathur

Beilstein J. Nanotechnol. 2023, 14, 701–710, doi:10.3762/bjnano.14.56

• were taken from Fisher Scientific. For all experimental work and the preparation of stock solutions, deionized (DI) water was used. Synthesis of graphene quantum dots Graphene quantum dots (GQDs) were synthesized using glucose as a precursor material via a hydrothermal route [29] with some

The microstrain-accompanied structural phase transition from h-MoO₃ to α-MoO₃ investigated by in situ X-ray diffraction

• Zeqian Zhang,
• Honglong Shi,
• Boxiang Zhuang,
• Minting Luo and
• Zhenfei Hu

Beilstein J. Nanotechnol. 2023, 14, 692–700, doi:10.3762/bjnano.14.55

• increase of microstrain during the h-MoO3→α-MoO3 transition. Note that since the thermal shock properties of a material are proportional to the CTEs, large values of CTE and the anisotropy of the hexagonal phase h-MoO3 may increase thermal shock, leading to fatigue or damage to devices. Microscopic view on

Humidity-dependent electrical performance of CuO nanowire networks studied by electrochemical impedance spectroscopy

• Jelena Kosmaca,
• Juris Katkevics,
• Jana Andzane,
• Raitis Sondors,
• Liga Jasulaneca,
• Raimonds Meija,
• Kiryl Niherysh,
• Yelyzaveta Rublova and
• Donats Erts

Beilstein J. Nanotechnol. 2023, 14, 683–691, doi:10.3762/bjnano.14.54

• , a decrease of conductivity in humid environments was observed, as expected for a p-type semiconductor material [6][13][18][19], other reports described a conductivity increase [20][21][22][23][24]. For example, arrays of free-standing nanowires showed an impedance increase upon exposure to humidity

• explained by parallel contributions to the net electrical signal from different conduction paths, for example, electronic and ionic transport inside the material and on the surface [29]. First, the conduction at very low RH is presumed to be primarily due to electronic transport inside the material. The CuO

• nanowires synthesized by thermal annealing of copper are a p-type semiconductor material [9][12][14]; its majority charge carriers are positive holes (h+) related to the presence of Cu vacancies or impurities. Under dry conditions, possible ionosorption of oxygen species from air on the nanowire surface

Investigations on the optical forces from three mainstream optical resonances in all-dielectric nanostructure arrays

• Guangdong Wang and
• Zhanghua Han

Beilstein J. Nanotechnol. 2023, 14, 674–682, doi:10.3762/bjnano.14.53

• nanoscale polystyrene (PS) spheres in the slot of the all-dielectric nanostructures. All these spheres have their own response to the incident radiations (e.g., Mie resonances). However, we noted that due to the small size of the spheres and the relatively lower refractive index of the polymeric material

Metal-organic framework-based nanomaterials as opto-electrochemical sensors for the detection of antibiotics and hormones: A review

• Akeem Adeyemi Oladipo,
• Saba Derakhshan Oskouei and
• Mustafa Gazi

Beilstein J. Nanotechnol. 2023, 14, 631–673, doi:10.3762/bjnano.14.52

• in different matrices. The choice of the sensor material is crucial to achieving efficient sensing of the target analyte for luminescence-based sensors. Although luminescent sensors have been made using a variety of organic fluorophores and phosphors, the drawbacks of conventional organic dyes for

• lanthanides, have been thoroughly researched to address these drawbacks. In recent years, theoretical and applied research has focused heavily on luminescent MOFs as an alternative sensing material for fluorescent sensors. These MOFs have an easy-to-functionalize surface, a tunable pore size, intrinsic

• that MOFs exhibit not just fluorescence but also phosphorescence and scintillation has drawn attention to their optical capabilities for some time. Due to their hybrid composition, MOF materials are capable of a variety of emission phenomena (Figure 12) that are uncommon in other material classes. For

Titania nanoparticles for photocatalytic degradation of ethanol under simulated solar light

• Evghenii Goncearenco,
• Iuliana P. Morjan,
• Claudiu Teodor Fleaca,
• Florian Dumitrache,
• Elena Dutu,
• Monica Scarisoreanu,
• Valentin Serban Teodorescu,
• Alexandra Sandulescu,
• Crina Anastasescu and
• Ioan Balint

Beilstein J. Nanotechnol. 2023, 14, 616–630, doi:10.3762/bjnano.14.51

• components to substances that catalyze decomposition processes. They have a bandgap that varies from one material to another. Titanium dioxide is a semiconductor material and has been investigated, at first, for solar cells [1][2][3][4] and as optoelectronic component [5][6][7]. In recent years, it has been

• ][18]. Moreover, investigations have shown the possibility for applying TiO2 in hydrogen production by water decomposition [19][20][21][22][23]. Given the TiO2 bandgap, it is considered a low-efficiency material in photodriven water splitting, because only 3% of the solar light can be used. Different

• recombination between free electrons and holes. The optical properties of the TiO2 powders has been investigated by absorbance measurements. Figure 5 presents an example of these measurements of both sample series. In the case of the TiO2 material, it is known that it can have two types of transitions, namely

Suspension feeding in Copepoda (Crustacea) – a numerical model of setae acting in concert

• Alexander E. Filippov,
• Wencke Krings and
• Stanislav N. Gorb

Beilstein J. Nanotechnol. 2023, 14, 603–615, doi:10.3762/bjnano.14.50

• adhesive forces to retain particles. In contrast to organisms, which collect particles at the nano- to millimeter scale, most industrial cross-flow filtration systems can capture material only in more limited size ranges, highlighting the necessity to investigate particle retention in biological systems

Thermal transport in kinked nanowires through simulation

• Alexander N. Robillard,
• Graham W. Gibson and
• Ralf Meyer

Beilstein J. Nanotechnol. 2023, 14, 586–602, doi:10.3762/bjnano.14.49

• simulations usually treat the simulated material as isotropic. While this is typically seen as a missing component in PMC, in our case it provides a significant advantage: We can examine the thermal transport of phonons without including the effects of the lattice orientation. This is particularly useful for

• quantitative data for a specific material, we do not expect the limitation to acoustic phonons to be problematic. For the scattering rates of the phonons, Jean et al. [28] use a parametrization based on the formulas developed by Holland [53]. The values given in [28] correspond to the 1× scattering rate used