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Search for "matrix" in Full Text gives 729 result(s) in Beilstein Journal of Nanotechnology. Showing first 200.
Silver-based SERS substrates fabricated using a 3D printed microfluidic device
Beilstein J. Nanotechnol. 2023, 14, 793–803, doi:10.3762/bjnano.14.65
- formation of a charge-transfer complex between chemisorbed species and matrix material, which yields enhancement when the excitation frequency resonates with a charge-transfer transition [7]. Noble metal nanoparticles (NPs) have gained much popularity in various fields, such as analytical chemistry and
Silver nanoparticles loaded on lactose/alginate: in situ synthesis, catalytic degradation, and pH-dependent antibacterial activity
Beilstein J. Nanotechnol. 2023, 14, 781–792, doi:10.3762/bjnano.14.64
- nanocomposites using saccharides, such as alginate, cyclodextrin, and lactose. This method allows for the loading of metallic ions onto the nanocomposite, followed by their reduction to nanoparticles [36][37]. The nanocomposite matrix can release silver in appropriate environments, exhibiting pH-dependent
In situ magnesiothermic reduction synthesis of a Ge@C composite for high-performance lithium-ion batterie anodes
Beilstein J. Nanotechnol. 2023, 14, 751–761, doi:10.3762/bjnano.14.62
- performance of the electrode (432.3 mAh·g−1 at a specific current of 5000 mA·g−1) are attributed to the enhancement in distribution and chemical contact between Ge nanoparticles and the biomass-based carbon matrix. A comparison with other synthesis routes has been conducted to demonstrate the effectiveness of
- performance of Ge-based anodes, a carbon matrix is the most popular choice to disperse nanoparticles, avoiding their aggregation and reducing the internal stress induced by volume variation, because of its flexible structure and high conductivity [30][31][32]. In our recent study, the combination of Ge
- nanoparticles and a carbon matrix using a hydrothermal route has been reported, and the enhancement in the electrochemical performance of Ge@C electrodes was demonstrated [33]. In this work, a one-pot synthesis route has been followed to prepare a Ge@C composite using an in situ magnesiothermic reduction of
Metal-organic framework-based nanomaterials as opto-electrochemical sensors for the detection of antibiotics and hormones: A review
Beilstein J. Nanotechnol. 2023, 14, 631–673, doi:10.3762/bjnano.14.52
Carbon nanotube-cellulose ink for rapid solvent identification
Beilstein J. Nanotechnol. 2023, 14, 535–543, doi:10.3762/bjnano.14.44
- of lightweight materials comprising a conductive ingredient (e.g., carbon nanotubes (CNTs), graphene, graphene oxide, and metal particles) embedded in a polymer matrix, have been extensively studied as liquid sensors [14][15][16][17][21][22]. The main idea is to combine the responsive electrical
- that the carbon nanotubes tend to twine around the MFC fiber when mixed. Thus, one can visualize that the composite ink is composed of an insulating matrix of MFC fibers intertwined by a conductive CNT network. To analyze the data, principal components analysis (PCA) was performed. PCA is a
- -per-million concentrations with the sensor temperature set to 95 °C. Since glycerin does not evaporate at 95 °C, it leaves residues in the sensor matrix, preventing the same sensor device to be used in successive measurements. Thus, in this case a single (drop) measurement was performed for each
Nanoarchitectonics to entrap living cells in silica-based systems: encapsulations with yolk–shell and sepiolite nanomaterials
Beilstein J. Nanotechnol. 2023, 14, 522–534, doi:10.3762/bjnano.14.43
- sol–gel methods, as well as pre-synthesised yolk–shell bionanohybrids have been studied subsequently. Optical microscopy and SEM confirm that the silica shell microstructures provide a reduced contact between cells. The inorganic matrix increases the survival of the cells and maintains their
- bioactivity. Thus, the encapsulation efficiency is improved compared to the approach using a direct contact of cells in a silica matrix. Encapsulated yeast produced ethanol over a period of several days, pointing out the useful biocatalytic potential of the approach and suggesting further optimization of the
- hand, the use of yolk–silica shell (YS) microstructures formed by soft template synthesis was explored [30] to encapsulate living cells with a highly porous SiO2 network aiming to introduce a small interstitial space between the microorganisms and the silica matrix. The latter strategy intends to
Specific absorption rate of randomly oriented magnetic nanoparticles in a static magnetic field
Beilstein J. Nanotechnol. 2023, 14, 485–493, doi:10.3762/bjnano.14.39
- nanoparticles with uniaxial magnetic anisotropy randomly oriented in a solid matrix. The saturation magnetization of particles and the magnetic anisotropy constant are taken to be Ms = 350 emu/cm3 and K1 = 105 erg/cm3, respectively [27]. The range of nanoparticle diameters studied is D = 18–50 nm, the
- matrix on a dc magnetic field Hdc applied parallel to the ac field Hac. (b) Dynamic hysteresis loops for an assembly of nanoparticles with D = 20 nm at different Hdc values: (1) Hdc = 0, (2) Hdc = 100 Oe, (3) Hdc = 150 Oe, and (4) Hdc = 300 Oe. (a) Dependence of the SAR on the dc magnetic field applied
Mixed oxides with corundum-type structure obtained from recycling can seals as paint pigments: color stability
Beilstein J. Nanotechnol. 2023, 14, 467–477, doi:10.3762/bjnano.14.37
- interests to produce synthetic inorganic pigments [1] using metallic aluminium scrap as precursor to obtain a white matrix that can then be colored by chromophore ions as an approach within the circular economy of aluminium [1]. Aluminium production has one of the most significant energy consumption
- a color change with increasing particle size from brighter yellow-green to darker blue-green [14]. Usually, chromium oxide pigments are synthesized starting from dichromats with chromium in the oxidation state +6, which are toxic [15]. However, using boehmite as a host matrix, the opportunity arises
- and color can be adjusted by the calcination temperature or the combination with other metals as coloring ions [11]. In this context, applying both Cr and Fe ions as coloring ions in a white matrix such as aluminium oxide is interesting. We report on the synthesis of synthetic inorganic pigments using
Conjugated photothermal materials and structure design for solar steam generation
Beilstein J. Nanotechnol. 2023, 14, 454–466, doi:10.3762/bjnano.14.36
- possible to further improve the photothermal conversion efficiency of conjugated molecules by systematically studying structure–property relationships. Optimized structures will be value-added high-performance photothermal materials. Also, they need to be hybridized with mass-produced active matrix
Molecular nanoarchitectonics: unification of nanotechnology and molecular/materials science
Beilstein J. Nanotechnol. 2023, 14, 434–453, doi:10.3762/bjnano.14.35
- and Gong discuss the organization of gels [103]. Specifically, they outline a unique anisotropic hydrogel consisting of uniaxially aligned lamellar bilayers in an amorphous gel matrix. This gel organization exhibits a beautiful structural color that is sensitive to mechanical and chemical stimuli. The
Plasmonic nanotechnology for photothermal applications – an evaluation
Beilstein J. Nanotechnol. 2023, 14, 380–419, doi:10.3762/bjnano.14.33
- engineering, doping, incorporation, and modification of suitable matrix materials. Plasmonic nanomaterials offer an alternative and attractive approach in this regard, through the flexibility in the excitation of surface plasmons. Specific advantages are the considerable improved bandwidth of the absorption
- constant of the surrounding medium and hence the LSPR frequency can be arrived at as [39]: Thus, for any morphology of a plasmonic nanoparticle, the LSPR frequency is intimately tied to the free electron density and the dielectric constant of the surrounding matrix. These factors thus decide the shape
- can be effective [86][87][88][89]. A few governing equations which allow to predict the different aspects of PPT energy conversion are discussed next. They can be of use to explicitly select a material/morphology/matrix based on the application it is being considered for. 3 Calculations in PT heating
Polymer nanoparticles from low-energy nanoemulsions for biomedical applications
Beilstein J. Nanotechnol. 2023, 14, 339–350, doi:10.3762/bjnano.14.29
- , nanocarriers need to be engineered to add functionalities, both in their cores and at their surfaces. This includes therapeutic drugs and genes, targeting moieties, performance enhancers (e.g., for barrier penetration and to avoid opsonization), and imaging agents [2][3]. Core and matrix of the nanoparticles
- should be biocompatible, preferentially biodegradable, and with the capacity for proper encapsulation and release of the drug payload. It is also desired that the matrix surface contains reactive or charged groups that facilitate functionalization by covalent or electrostatic bonding. Herein, we review
Bismuth-based nanostructured photocatalysts for the remediation of antibiotics and organic dyes
Beilstein J. Nanotechnol. 2023, 14, 291–321, doi:10.3762/bjnano.14.26
- allow for the integration of multiple functions derived from various types of nanocatalysts, such as semiconductor nanoparticles, plasmonic metals, and carbon-based and magnetic oxides, into the same host matrix. This enables effective tuning of the photocatalytic characteristics of the final
Nanotechnology – a robust tool for fighting the challenges of drug resistance in non-small cell lung cancer
Beilstein J. Nanotechnol. 2023, 14, 240–261, doi:10.3762/bjnano.14.23
- targeting efficacy of nanomedicines. Various solutions have been proposed to improve mononuclear phagocytic system (MPS) evasion, extravasation at the tumor site, and diffusion through the dense collagen matrix of the solid tumors. Biomimetic, multifunctional, and multistage targeted nanoscale delivery
Spin dynamics in superconductor/ferromagnetic insulator hybrid structures with precessing magnetization
Beilstein J. Nanotechnol. 2023, 14, 233–239, doi:10.3762/bjnano.14.22
- superconducting condensate in the weak proximity effect regime can be described via the nonstationary Usadel equation [18][19][30]: where is the stationary BCS superconducting order parameter matrix [28], D is the diffusion constant, is the auxiliary matrix in Nambu–spin-Keldysh space, is the time convolution
- spin current takes the following form [29]: where K is the Keldysh component. Using the normalization condition, Keldysh Green’s function can be written through the distribution function : . In thermal equilibrium, the distribution matrix reduces to a function tanh(βℏω/2), β = 1/kT, which corresponds
- of spin current inside the superconducting layer completely agrees with the boundary condition of the zero matrix current at the interface between the free space and superconducting layer at z = 0. Now let us consider the Fourier coefficients for the induced magnetization. Earlier, we have shown that
Structural, optical, and bioimaging characterization of carbon quantum dots solvothermally synthesized from o-phenylenediamine
Beilstein J. Nanotechnol. 2023, 14, 165–174, doi:10.3762/bjnano.14.17
- as polymer-like nanoparticles of amorphous carbon with embedded partially sp2-hybridized atomic domains [8]. In this structure, electrons are partially delocalized over the domain area, but a strong coupling of the amorphous host matrix is maintained continuously. CQDs are well known as chemically
- surface states, precursors, preparation methods, and heteroatom doping [9]. Previous investigations showed that possible mechanisms of the CQD photoluminescence are radiative recombination of electron–hole pairs in the sp2 domains inside the sp3 matrix as well as the effect of zig-zag edges [6][18]. Apart
- n–π* transition of C=O whereas a very wide band at 585 nm stems from surface states of the CQDs. All of these peaks can be identified also in the UV–vis spectrum of pure CQDs as well, but when the CQDs are encapsulated inside the polymer matrix, these peaks are redshifted because of the crosslinking
Intermodal coupling spectroscopy of mechanical modes in microcantilevers
Beilstein J. Nanotechnol. 2023, 14, 123–132, doi:10.3762/bjnano.14.13
- on a finite number of eigenmodes due to our equipment limitations. The full Hamiltonian is given by If this coupling is a direct analogue to optomechanics, the coupling matrix should be symmetric, that is, . Expanding the experiment to multiple eigenmodes will elucidate if this symmetry is respected
- mode. The regime changes at this point as detailed before. Figure 5b presents the coupling matrix and a colormap containing the directional coupling strength between two modes normalised to pump amplitude in nanometers. The highest measured coupling rate between flexural modes is 5.15 × 102 Hz/nm
- –T3, which has a regime transition. Inset: Coupling rates determined from linewidth changes or eigenmode separation against half the linewidth of cavity mode T3. (b) Matrix showing the coupling rates of all mode combinations. Contoured squares represent combinations between flexural modes only. (c
Antimicrobial and mechanical properties of functionalized textile by nanoarchitectured photoinduced Ag@polymer coating
Beilstein J. Nanotechnol. 2023, 14, 95–109, doi:10.3762/bjnano.14.11
- , and textiles need to be cleaned on a daily basis. Silver nanoparticles (AgNPs) possess well-documented antimicrobial properties and by combining them with a physical matrix, they can be applied to various surfaces to limit microbial contamination. With this in mind, a rapid and easy way to implement a
- antimicrobial agents can be further explored by combining them with a physical matrix. Textiles are a prime breeding ground for bacteria and fungi, given the right temperature, nutrient-available and humidity conditions. With this in mind, antimicrobial nanoparticles-functionalized textiles are being actively
- nanocomposites are prepared via ex situ or in situ approaches, in which MNPs are either synthesized beforehand and subsequently added to a polymer matrix or directly generated inside the polymer film. Ex situ methods include grafting [34], electrostatic [35] or polyol processes [36], but remain relatively
Cooper pair splitting controlled by a temperature gradient
Beilstein J. Nanotechnol. 2023, 14, 61–67, doi:10.3762/bjnano.14.7
- with the aid of the path integral technique [22][25], which yields where is the Keldysh Green function of our system the 4 × 4 matrices represent the inverse Keldysh Green functions of isolated normal and superconducting leads and is the diagonal 4 × 4 matrix in the Nambu–Keldysh space describing
Gap-directed chemical lift-off lithographic nanoarchitectonics for arbitrary sub-micrometer patterning
Beilstein J. Nanotechnol. 2023, 14, 34–44, doi:10.3762/bjnano.14.4
- . Increasing W or utilizing stamps with greater Young’s modulus (stiffer) while fixing other parameters would decrease the tendency for roof to collapse, thus increasing line width and decreasing gap size. In addition to acting as the matrix for biorecognition arrays, the molecular pattern created on a post
Two-step single-reactor synthesis of oleic acid- or undecylenic acid-stabilized magnetic nanoparticles by thermal decomposition
Beilstein J. Nanotechnol. 2023, 14, 11–22, doi:10.3762/bjnano.14.2
- investigated using a conventional transmission device with a Co source diffused into a Rh matrix. The hyperfine parameters were refined by using quadrupolar doublets and magnetic sextets with Lorentzian lines. The values of the isomer shift are quoted to that of α-Fe at room temperature (RT). Indeed, this
In search of cytotoxic selectivity on cancer cells with biogenically synthesized Ag/AgCl nanoparticles
Beilstein J. Nanotechnol. 2022, 13, 1505–1519, doi:10.3762/bjnano.13.124
- indicated with asterisks. In an earlier work, the same combination of Ag and AgCl signals was obtained using extracts of Stevia rebaudiana [21]. In that report, the effect of the ratio between metallic AgNPs and AgClNPs on the morphology and dispersion in a thermoplastic starch matrix was demonstrated. At
- % for AgNPs-T80. In other words, at concentrations close to 50 µg/mL, the cytotoxic action of the nanoparticles becomes selective. This result is possibly due to the fact that a higher content of nanoparticles prevents cell proliferation in neoplastic cells. MCF-7 cells are known to overexpress matrix
Hydroxyapatite–bioglass nanocomposites: Structural, mechanical, and biological aspects
Beilstein J. Nanotechnol. 2022, 13, 1490–1504, doi:10.3762/bjnano.13.123
- fraction of the pores with respect to the dense matrix, the probability of pores falling into the indentation zone is reduced with decreasing load. Hence, less volume of pores and more volume of dense matrix is involved in the deformation process with decreasing load, resulting in the increase of hardness
Frequency-dependent nanomechanical profiling for medical diagnosis
Beilstein J. Nanotechnol. 2022, 13, 1483–1489, doi:10.3762/bjnano.13.122
- diseases that are linked to mechanical changes in cells and/or the extracellular matrix. Existing micro-robotics technology could be harnessed to develop the specific types of sensors needed in each case. For example, in the case of gastrointestinal cancer screening, one could envision the integration of a
Rapid and sensitive detection of box turtles using an electrochemical DNA biosensor based on a gold/graphene nanocomposite
Beilstein J. Nanotechnol. 2022, 13, 1458–1472, doi:10.3762/bjnano.13.120
- composite. The weight and atomic contribution of each of these elements in the nanocomposite were given with their corresponding EDX spectrum. The use of AuNPs–Gr as a DNA immobilisation matrix enhances the active surface area of the modified SPCE, allowing for a stronger DNA hybridisation detection signal
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