High-contrast and reversible scattering switching via hybrid metal-dielectric metasurfaces

• Jonathan Ward,
• Khosro Zangeneh Kamali,
• Lei Xu,
• Guoquan Zhang,
• Andrey E. Miroshnichenko and
• Mohsen Rahmani

Beilstein J. Nanotechnol. 2018, 9, 460–467, doi:10.3762/bjnano.9.44

• optical components that are adjustable, like beam shapers and lenses [29]. Importantly, thermal tuning is only applicable to dielectric metasurfaces, as the low thermo-optical coefficient of most of noble metals, such as gold [38], makes plasmonic metasurfaces insensitive to variation in temperature

Review: Electrostatically actuated nanobeam-based nanoelectromechanical switches – materials solutions and operational conditions

• Liga Jasulaneca,
• Jelena Kosmaca,
• Raimonds Meija,
• Jana Andzane and
• Donats Erts

Beilstein J. Nanotechnol. 2018, 9, 271–300, doi:10.3762/bjnano.9.29

• [112][113], or by the noncrystalline structure of the studied samples [110]. Atomistic simulations for fcc noble metals [113] showed that either a decrease or increase of the Young’s modulus for metallic crystalline nanowires can be achieved by variation of their size and operation temperature. The

Synthesis and characterization of electrospun molybdenum dioxide–carbon nanofibers as sulfur matrix additives for rechargeable lithium–sulfur battery applications

• Ruiyuan Zhuang,
• Shanshan Yao,
• Maoxiang Jing,
• Xiangqian Shen,
• Jun Xiang,
• Tianbao Li,
• Kesong Xiao and
• Shibiao Qin

Beilstein J. Nanotechnol. 2018, 9, 262–270, doi:10.3762/bjnano.9.28

• known to be active in numerous reactions associated with noble metals, such as CO2 hydrogenation, water gas shift, alcohol synthesis and hydrazine decomposition. Here, CH4/H2 atmosphere was not used during calcination, which was much safer and facile when compared to other methods [27]. Raman

Comparative study of post-growth annealing of Cu(hfac)₂, Co₂(CO)₈ and Me₂Au(acac) metal precursors deposited by FEBID

• Marcos V. Puydinger dos Santos,
• Aleksandra Szkudlarek,
• Artur Rydosz,
• Carlos Guerra-Nuñez,
• Fanny Béron,
• Kleber R. Pirota,
• Stanislav Moshkalev,
• José Alexandre Diniz and
• Ivo Utke

Beilstein J. Nanotechnol. 2018, 9, 91–101, doi:10.3762/bjnano.9.11

• , Electronics and Telecommunications, Av. Mickiewicza 30, 30-059 Krakow, Poland 10.3762/bjnano.9.11 Abstract Non-noble metals, such as Cu and Co, as well as noble metals, such as Au, can be used in a number modern technological applications, which include advanced scanning-probe systems, magnetic memory and

• removing the carbon matrix and drastically reducing the electrical resistance of the deposit. Keywords: copper; gold; cobalt; focused-electron-beam-induced deposition; noble metal; non-noble metals; post-growth annealing; Introduction Focused-electron-beam-induced deposition (FEBID) constitutes a well

• methods are not utilized in depositions of non-noble metals in order to avoid oxidation of the metals. For W–C deposits, an electrical conductivity improvement of one order of magnitude was obtained using a genetic algorithm to optimize the deposition parameters [44]. In addition, high-purity W deposits

Gas-sensing behaviour of ZnO/diamond nanostructures

• Marina Davydova,
• Alexandr Laposa,
• Jiri Smarhak,
• Alexander Kromka,
• Neda Neykova,
• Josef Nahlik,
• Jiri Kroutil,
• Jan Drahokoupil and
• Jan Voves

Beilstein J. Nanotechnol. 2018, 9, 22–29, doi:10.3762/bjnano.9.4

• oxides or noble metals [14][15][16][17]. Aside from n-type semiconductors, p-type semiconductor materials have also been extensively used for the detection of toxic gases [3][18][19]. Recently, nanocrystalline diamond (NCD) films have been utilized for advanced electronic devices because of their

The rational design of a Au(I) precursor for focused electron beam induced deposition

• Ali Marashdeh,
• Thiadrik Tiesma,
• Niels J. C. van Velzen,
• Sjoerd Harder,
• Remco W. A. Havenith,
• Jeff T. M. De Hosson and
• Willem F. van Dorp

Beilstein J. Nanotechnol. 2017, 8, 2753–2765, doi:10.3762/bjnano.8.274

• decrease down the periodic table: The calculated CO dissociation energies for complexes of the heavier noble metals Pd and Pt are low. Consequently, Pd(CO)4 and Pt(CO)4 are unstable and only exist in an inert gas matrix at lower temperatures [58]. Similarly, CO complexes of Au(I), a noble metal of high

Refractive index sensing and surface-enhanced Raman spectroscopy using silver–gold layered bimetallic plasmonic crystals

• Somi Kang,
• Sean E. Lehman,
• Matthew V. Schulmerich,
• An-Phong Le,
• Tae-woo Lee,
• Stephen K. Gray,
• Rohit Bhargava and
• Ralph G. Nuzzo

Beilstein J. Nanotechnol. 2017, 8, 2492–2503, doi:10.3762/bjnano.8.249

• imaging-mode and multispectral plasmonic optics [23][24][34][35][36]. This fabrication method yields highly uniform arrays of nanoholes in a dielectric substrate that upon metallization provide a plasmonic platform for SPR sensing and SERS [22][23][24][25][26][37][38]. Noble metals such as Au and Ag are

Evaluating the toxicity of TiO₂-based nanoparticles to Chinese hamster ovary cells and Escherichia coli: a complementary experimental and computational approach

• Alicja Mikolajczyk,
• Natalia Sizochenko,
• Ewa Mulkiewicz,
• Anna Malankowska,
• Michal Nischk,
• Przemyslaw Jurczak,
• Seishiro Hirano,
• Grzegorz Nowaczyk,
• Adriana Zaleska-Medynska,
• Jerzy Leszczynski,
• Agnieszka Gajewicz and
• Tomasz Puzyn

Beilstein J. Nanotechnol. 2017, 8, 2171–2180, doi:10.3762/bjnano.8.216

• (Au > Pd) resulted in the formation of alloy structures. More details about the characterization of Au/Pd-TiO2 structures are reported in our previous study [5]. The relationship between the amount of noble metals (Au, Pd) in the sample and the cytotoxicity to CHO-K1 cells expressed as EC50 values

• and moderate cytotoxicity. Several possible mechanisms of cytotoxic action can be taken into account to explain observed results. First, it is well known that ionic Au and Pd are one of the most toxic forms among the noble metals. The main factor responsible for their toxicity is related to the

Ta₂N₃ nanocrystals grown in Al₂O₃ thin layers

• Krešimir Salamon,
• Maja Buljan,
• Iva Šarić,
• Mladen Petravić and
• Sigrid Bernstorff

Beilstein J. Nanotechnol. 2017, 8, 2162–2170, doi:10.3762/bjnano.8.215

• magnetic recording [6]. Currently, research in these fields is dominated by nanoparticles based on noble metals due to their strong plasmonic resonance in the visible part of the electromagnetic spectrum [7]. However, due to the wide range of parameters for separate applications, such as operation at

Two-dimensional carbon-based nanocomposites for photocatalytic energy generation and environmental remediation applications

• Suneel Kumar,
• Ashish Kumar,
• Ashish Bahuguna,
• Vipul Sharma and
• Venkata Krishnan

Beilstein J. Nanotechnol. 2017, 8, 1571–1600, doi:10.3762/bjnano.8.159

• nanoparticles and accelerate the photocatalytic rate by introducing more reaction sites and promoting charge separation in semiconductors [115]. In water splitting reactions, generally noble metals (e.g., Pt, Rh) and some metal oxides (e.g., NiO) act as the cocatalyst and these are loaded on the surface of

• photocatalysts to produce more reactive sites and to reduce the activation energy for H2 and O2 gas evolution. Cocatalysts also enhances the charge separation in photocatalytic materials because of their high work function. This high work function of noble metals and some metal oxides accelerates the transfer of

• sites for H2 evolution, increasing interfacial charge transfer and reducing the recombination probability of photogenerated electron–hole pairs [116]. However, the high cost of noble metals limits their use as cocatalysts on a large scale. Graphene has been demonstrated to be one of the best

Synthesis of [Fe(L_eq)(L_ax)]_n coordination polymer nanoparticles using blockcopolymer micelles

• Christoph Göbel,
• Ottokar Klimm,
• Florian Puchtler,
• Sabine Rosenfeldt,
• Stephan Förster and
• Birgit Weber

Beilstein J. Nanotechnol. 2017, 8, 1318–1327, doi:10.3762/bjnano.8.133

• procedures for nanoparticles with size control (gold [6][7], metal oxides [8][9]) and/or shape control (gold and silver [10]) are already well known. The reduction of metal salts is very common for noble metals [11], while (fast) precipitation or inverse-micelle technique are often used for metal oxides

Assembly of metallic nanoparticle arrays on glass via nanoimprinting and thin-film dewetting

• Sun-Kyu Lee,
• Sori Hwang,
• Yoon-Kee Kim and
• Yong-Jun Oh

Beilstein J. Nanotechnol. 2017, 8, 1049–1055, doi:10.3762/bjnano.8.106

• temperatures to completely transform them into pure silica by oxidizing and decomposing the CH3 groups in the resist. The maximum annealing temperature was limited to 600 °C, up to which the soda lime glass does not undergo deformation. Noble metals (Au and Ag) were sputter-deposited onto the imprinted resist

• converted silica and the substrate glass, which was heated above its glass transition temperature (564 °C) during annealing. Indeed, some glass substrates were observed to be slightly deformed after annealing at 600 °C. Thin films of noble metals were deposited on imprinted resists that were converted to

Gas sensing properties of MWCNT layers electrochemically decorated with Au and Pd nanoparticles

• Elena Dilonardo,
• Michele Penza,
• Marco Alvisi,
• Riccardo Rossi,
• Gennaro Cassano,
• Cinzia Di Franco,
• Francesco Palmisano,
• Luisa Torsi and
• Nicola Cioffi

Beilstein J. Nanotechnol. 2017, 8, 592–603, doi:10.3762/bjnano.8.64

• of CNT-based sensors, due to an increase in the number of the adsorption sites for the targeted gases [18]. CNT sidewalls can be decorated with various noble metals such as Au, Pt, Pd, Rh, and Ag [19][20][21][22][23][24]. Different methods have been used to decorate CNTs, including electrodeposition

Photocatalysis applications of some hybrid polymeric composites incorporating TiO₂ nanoparticles and their combinations with SiO₂/Fe₂O₃

• Andreea Laura Chibac,
• Tinca Buruiana,
• Violeta Melinte and
• Emil C. Buruiana

Beilstein J. Nanotechnol. 2017, 8, 272–286, doi:10.3762/bjnano.8.30

• the catalytic activity of titanium(IV) oxide in the range of visible light (λ > 430 nm) can be attained by doping the TiO2 network with non-metals [16][17][18], lanthanide ions [19][20], transitional metal ions [21][22][23], noble metals [24][25] or metallic oxides [26]. Other strategies can be

Nanocrystalline ZrO₂ and Pt-doped ZrO₂ catalysts for low-temperature CO oxidation

• Amit Singhania and
• Shipra Mital Gupta

Beilstein J. Nanotechnol. 2017, 8, 264–271, doi:10.3762/bjnano.8.29

• anthropogenic activities. The catalytic CO oxidation is a very well established and exploited process. So far, noble metals such as Pt, Pd, Rh and Au dominated as catalysts for CO oxidation [10][11][12]. Various supports such as Al2O3, TiO2, SiO2, CeO2, Fe2O3 and carbon nanotubes (CNTs) have also been used for

Sensitive detection of hydrocarbon gases using electrochemically Pd-modified ZnO chemiresistors

• Elena Dilonardo,
• Michele Penza,
• Marco Alvisi,
• Gennaro Cassano,
• Cinzia Di Franco,
• Francesco Palmisano,
• Luisa Torsi and
• Nicola Cioffi

Beilstein J. Nanotechnol. 2017, 8, 82–90, doi:10.3762/bjnano.8.9

• but lower the activation energy. The sensing response of ZnO towards most of the toxic gases in general, and towards HC gases in particular, can be improved by surface deposition of noble metals. Sivapunniyam et al. [39] have reported the improvement of ZnO-nanorod-based HC gas sensing by doping the

• NPs on the surface of ZnO NRs improves the sensitivity and selectivity towards the detection of HCs gases at an operating temperature of 300 °C. Future work will be addressed to evaluate the sensing properties of electrochemically functionalize ZnO NRs with noble metals (e.g. Au and Pd), used as

Surface-enhanced Raman scattering of self-assembled thiol monolayers and supported lipid membranes on thin anodic porous alumina

• Marco Salerno,
• Amirreza Shayganpour,
• Barbara Salis and
• Silvia Dante

Beilstein J. Nanotechnol. 2017, 8, 74–81, doi:10.3762/bjnano.8.8

• surface roughness [3][4], the latter of which can play an important role in the adhesion and proliferation of cells [5][6][7]. The self-ordered nano-structured APA, also demonstrated recently as a possible nanolithographic mask [8][9] and for chemical sensors and biosensors [10], after coating with noble

• metals can be used for plasmonics-based enhanced spectroscopy such as in surface-enhanced Raman spectroscopy (SERS) [11][12][13][14]. In recent years, the thin form of APA (tAPA), resulting from anodization of Al films of less than 1 µm thickness, has been increasingly used because it can be better

Fundamental properties of high-quality carbon nanofoam: from low to high density

• Natalie Frese,
• Shelby Taylor Mitchell,
• Christof Neumann,
• Amanda Bowers,
• Armin Gölzhäuser and
• Klaus Sattler

Beilstein J. Nanotechnol. 2016, 7, 2065–2073, doi:10.3762/bjnano.7.197

• various chemical elements have been investigated. In particular, foams from transition metals and noble metals have attracted attention, and interesting applications have been developed. Nickel nanofoam has been used for glucose sensing [1] and also been suggested for high-performance supercapacitor

In situ formation of reduced graphene oxide structures in ceria by combined sol–gel and solvothermal processing

• Jingxia Yang,
• Johannes Ofner,
• Bernhard Lendl and
• Ulrich Schubert

Beilstein J. Nanotechnol. 2016, 7, 1815–1821, doi:10.3762/bjnano.7.174

• capacity. It is mostly used together with other components, such as noble metals or transition metal oxides, such as NiO or Co3O4, because synergistic effects improve the catalytic properties. Graphene-modified CeO2 greatly enhances the performance in electrochemical devices (supercapacitors, fuel cells or

Sandwich-like layer-by-layer assembly of gold nanoparticles with tunable SERS properties

• Zhicheng Liu,
• Lu Bai,
• Guizhe Zhao and
• Yaqing Liu

Beilstein J. Nanotechnol. 2016, 7, 1028–1032, doi:10.3762/bjnano.7.95

• ; polyelectrolyte; Introduction Surface-enhanced Raman scattering (SERS) spectroscopy, which relies on metal nanostructures made of noble metals (Au, Ag and Cu) that sustain localized surface plasmon resonance (LSPR), is applied as a promising analytical tool for detecting and identifying trace amounts of

Linear and nonlinear optical properties of hybrid metallic–dielectric plasmonic nanoantennas

• Mario Hentschel,
• Bernd Metzger,
• Bastian Knabe,
• Karsten Buse and
• Harald Giessen

Beilstein J. Nanotechnol. 2016, 7, 111–120, doi:10.3762/bjnano.7.13

• triangles [58]. Here, the monolayers are the source of the signal, rather than the silver triangles themselves. The main hurdle, however, is the weak nonlinearity of dielectrics when compared with noble metals, such as gold or silver. Nonlinear waveguides are thus a doubly smart choice, as the waveguide

Evaluation of gas-sensing properties of ZnO nanostructures electrochemically doped with Au nanophases

• Elena Dilonardo,
• Michele Penza,
• Marco Alvisi,
• Cinzia Di Franco,
• Francesco Palmisano,
• Luisa Torsi and
• Nicola Cioffi

Beilstein J. Nanotechnol. 2016, 7, 22–31, doi:10.3762/bjnano.7.3

• operating temperature of the sensors [32], cycled temperature operation, and the use of nanotechnology. Among these, the use of dopants and/or catalytic elements has been considered an effective way to improve the sensor performance [33]. Specifically, the loading of MOS with noble metals (e.g., Au, Pt, and

• Pd) that act as sensitizers or promoters, is an effective method to catalyze the gas-sensing reactions [34]. Until now, many strategies have been developed to deposit noble metals onto MOS matrices [35][36][37][38][39][40], and, although most of them are unique and effective, they are also complex

• 300 °C, the spherical structures and the residual presence of electrolyte on Au NPs surfaces influence the gas-sensing response, yielding the worst sensor response towards NO2. Future work will be addressed to electrochemically functionalize ZnO nanocomposites with other noble metals, such as Pd, to

Synthesis, characterization and in vitro biocompatibility study of Au/TMC/Fe₃O₄ nanocomposites as a promising, nontoxic system for biomedical applications

• Hanieh Shirazi,
• Maryam Daneshpour,
• Soheila Kashanian and
• Kobra Omidfar

Beilstein J. Nanotechnol. 2015, 6, 1677–1689, doi:10.3762/bjnano.6.170

• , noble metals such as gold, or oxide layers such as silica or alumina) not only prevents their aggregation due to the change in surface charge, but also protects them from oxidation [12][20][21]. Additionally, proper surface coverage increases the stability and half-life of the magnetic nanoparticles

Materials for sustainable energy production, storage, and conversion

• Maximilian Fichtner

Beilstein J. Nanotechnol. 2015, 6, 1601–1602, doi:10.3762/bjnano.6.163

• -noble metals with a long lifetime and a low kinetic barrier for conversion. For electrochemical storage, batteries based on new ionic shuttles such as sodium or magnesium are being explored. Moreover, oxygen from air could serve as an active cathode material, which does not need to be intrinsically

Growth and morphological analysis of segmented AuAg alloy nanowires created by pulsed electrodeposition in ion-track etched membranes

• Ina Schubert,
• Loic Burr,
• Christina Trautmann and
• Maria Eugenia Toimil-Molares

Beilstein J. Nanotechnol. 2015, 6, 1272–1280, doi:10.3762/bjnano.6.131

• different noble metals [38]. In these cases, segmented nanowires were created by using different electrolytes for Au and Ag and by exchanging the electrolyte after the deposition of each segment. Our nanowires, in turn, are deposited from a single-bath electrolyte, which could influence the dissolution