Influence of conductive carbon and MnCo₂O₄ on morphological and electrical properties of hydrogels for electrochemical energy conversion

• Sylwia Pawłowska,
• Karolina Cysewska,
• Yasamin Ziai,
• Jakub Karczewski,
• Piotr Jasiński and
• Sebastian Molin

Beilstein J. Nanotechnol. 2024, 15, 57–70, doi:10.3762/bjnano.15.6

• appropriate electrical conductivity [22]. Suspension of conductive fillers in the hydrogel structure, such as metallic particles (gold nanoparticles, silver nanoparticles) [23][24][25], carbon-based materials (GO graphene oxide, CNT carbon nanotubes) [26][27][28], and conductive polymers (polyaniline

• /FeTCPP and PPy/FeTCPP/Co samples (74 mV/dec and 65 mV/dec, respectively), they are very similar [55], and much better than the results obtained for NF-NiCo (614 mV/dec) [34]. For transition-metal-functionalised polyaniline-phytic acid hydrogels, Tang et al. obtained Tafel slopes in the range of 78–191 mV

Nanoarchitectonics of photothermal materials to enhance the sensitivity of lateral flow assays

• Elangovan Sarathkumar,
• Rajasekharan S. Anjana and
• Ramapurath S. Jayasree

Beilstein J. Nanotechnol. 2023, 14, 988–1003, doi:10.3762/bjnano.14.82

• , polymers such as polyaniline (PANI), poly(3,4-ethylenedioxythiophene) (PEDOT) and polydopamine (PDA) are used as photothermal agents. After protonation in acidic environments, PANI absorbs photons in the NIR range. PEDOT maintains its photothermal properties even after continuous heating or cooling [24

Metal-organic framework-based nanomaterials as opto-electrochemical sensors for the detection of antibiotics and hormones: A review

• Akeem Adeyemi Oladipo,
• Saba Derakhshan Oskouei and
• Mustafa Gazi

Beilstein J. Nanotechnol. 2023, 14, 631–673, doi:10.3762/bjnano.14.52

Conjugated photothermal materials and structure design for solar steam generation

• Chia-Yang Lin and
• Tsuyoshi Michinobu

Beilstein J. Nanotechnol. 2023, 14, 454–466, doi:10.3762/bjnano.14.36

• (PPy), polyaniline (PANI), and polydopamine (PDA) (Figure 5). Polypyrrole: Polypyrrole (PPy), a conjugated conducting polymer, has a broad optical absorption spectrum and is an excellent solar thermal material. PPy is a promising candidate because of its inexpensive and simple synthetic process

• multilayer PPy nanosheets, and this results in internal light scattering between the layers (Figure 6d). These multilayer nanosheets promote a broadband and wide-angle light absorption across the entire solar spectrum, thus increasing the solar thermal conversion efficiency to 95.33%. Polyaniline

• : Polyaniline (PANI) has proven to be an efficient water evaporation material because it is inexpensive, easy to synthesize, flexible, chemically stable, light absorbing, and adhesive [34][35][36][37][38][39][40][41]. PANI cross-linked to hydrophilic soft polymers makes the material as tough and flexible as an

Structural, optical, and bioimaging characterization of carbon quantum dots solvothermally synthesized from o-phenylenediamine

• Zoran M. Marković,
• Milica D. Budimir,
• Martin Danko,
• Dušan D. Milivojević,
• Pavel Kubat,
• Danica Z. Zmejkoski,
• Vladimir B. Pavlović,
• Marija M. Mojsin,
• Milena J. Stevanović and
• Biljana M. Todorović Marković

Beilstein J. Nanotechnol. 2023, 14, 165–174, doi:10.3762/bjnano.14.17

• CQDs prepared from o-phenylenediamine showed the presence of sp2 domains predominantly in the carbon core structure of the CQDs, which contributed to the formation of polyaniline fluorophores [31]. Figure S2b (Supporting Information File 1) shows a UV–vis spectrum of CQDs. We can observe that the

• only a minor role. Furthermore, during the hydrothermal synthesis of CQDs from o-phenylenediamine, the used precursor was able to form slowly a thermodynamically stable polyaniline and further conjugated sp2 domains with NH2 groups. Thus, the formed CQDs do not have reactive centers to generate singlet

A TiO₂@MWCNTs nanocomposite photoanode for solar-driven water splitting

• Anh Quynh Huu Le,
• Ngoc Nhu Thi Nguyen,
• Hai Duy Tran,
• Van-Huy Nguyen and
• Le-Hai Tran

Beilstein J. Nanotechnol. 2022, 13, 1520–1530, doi:10.3762/bjnano.13.125

• water to neutralize. Finally, it is treated at 350 °C within 60 min to form the TiO2@MWCNTs nanocomposite photocatalyst. Photoelectrochemical electrode 1.0 g of the obtained photocatalyst is dispersed in a 25 mL solution containing 0.1 M of polyaniline and 0.3 M of oxalic acid. A plastic bar (15 × 35

Design of surface nanostructures for chirality sensing based on quartz crystal microbalance

• Yinglin Ma,
• Xiangyun Xiao and
• Qingmin Ji

Beilstein J. Nanotechnol. 2022, 13, 1201–1219, doi:10.3762/bjnano.13.100

• recognition of ᴅ/ʟ-phenylalanine in polyaniline (PANI) film using R-camphorsulfonic acid (R-CSA) as the chiral template [51]. The QCM measurements indicated that the CSA-depleted PANI film showed a preference not only for adsorption of ᴅ-phenylalanine but also had similar responses for ᴅ-alanine and ᴅ

Modeling a multiple-chain emeraldine gas sensor for NH₃ and NO₂ detection

• Hana Sustkova and
• Jan Voves

Beilstein J. Nanotechnol. 2022, 13, 721–729, doi:10.3762/bjnano.13.64

• Hana Sustkova Jan Voves Faculty of Electrical Engineering, Czech Technical University in Prague, Technicka 2, Prague 6, Czech Republic 10.3762/bjnano.13.64 Abstract This paper describes atomistic device models of a multiple-chain polyaniline (PANI) gas sensing component, utilizing the non

• good properties for NO2 detection. Keywords: ammonia; gas sensor; nitrogen dioxide; numerical computation; polyaniline; Introduction Polyaniline is a conducting polymer consisting of benzene rings connected by nitrogen units, which can be used in a wide spectrum of applications, for example, dyes for

• base has to be reduced by electrons (Figure 1). Emeraldine base or leucoemeraldine base salts of green color and with conductivity values of up to 400 S/m can be obtained through synthesis [4]. Recently, the polyaniline emeraldine salt has been studied for sensor applications for various gases because

A chemiresistive sensor array based on polyaniline nanocomposites and machine learning classification

• Jiri Kroutil,
• Alexandr Laposa,
• Ali Ahmad,
• Jan Voves,
• Vojtech Povolny,
• Ladislav Klimsa,
• Marina Davydova and
• Miroslav Husak

Beilstein J. Nanotechnol. 2022, 13, 411–423, doi:10.3762/bjnano.13.34

• 1999/2, 182 21 Prague, Czech Republic 10.3762/bjnano.13.34 Abstract The selective detection of ammonia (NH3), nitrogen dioxide (NO2), carbon oxides (CO2 and CO), acetone ((CH3)2CO), and toluene (C6H5CH3) is investigated by means of a gas sensor array based on polyaniline nanocomposites. The array

• between VOCs, supported by a vector machine to distinguish between acetone, nitrogen dioxide, and ammonia, and by a neutral network model to distinguish between ammonia and formaldehyde gas [7][8][9]. In our previous work [10], we demonstrated a combination of organic (polyaniline, PANI) and inorganic

• FERA3 GM), as shown in Figure 1a–h. All nanocomposite active layers, that is, PANI/ZnO, PANI/WO3 (nanopowder), PANI/WO3 (nanowires), PANI/In2O3, PANI/C60, PANI/NCD, and PANI/BaTiO3 have similar morphological features with a uniform distribution of additives in polyaniline. We can observe small ZnO

A comprehensive review on electrospun nanohybrid membranes for wastewater treatment

• Senuri Kumarage,
• Imalka Munaweera and
• Nilwala Kottegoda

Beilstein J. Nanotechnol. 2022, 13, 137–159, doi:10.3762/bjnano.13.10

Tin dioxide nanomaterial-based photocatalysts for nitrogen oxide oxidation: a review

• Viet Van Pham,
• Hong-Huy Tran,
• Thao Kim Truong and
• Thi Minh Cao

Beilstein J. Nanotechnol. 2022, 13, 96–113, doi:10.3762/bjnano.13.7

• TiO2 and BiOBr, recent works reported the successful combination of SnO2 nanomaterials with conjugated polymers such as graphitic carbon nitride (g-C3N4) and polyaniline (PANI), yielding metal-free visible-light-driven photocatalysts for addressing NO gas pollution. Such combinations hold great

• new insights into the underlying mechanism of heterojunction photocatalysts, especially those with Z-shaped interfaces [76]. Polyaniline (PANI) is a conducting polymer and compared to g-C3N4, PANI is inexpensive and easy to synthesize. Bui et al. [35] presented a SnO2/PANI nanocomposite for

Assessment of the optical and electrical properties of light-emitting diodes containing carbon-based nanostructures and plasmonic nanoparticles: a review

• Keshav Nagpal,
• Erwan Rauwel,
• Frédérique Ducroquet and
• Protima Rauwel

Beilstein J. Nanotechnol. 2021, 12, 1078–1092, doi:10.3762/bjnano.12.80

• (Figure 7) present the best results in terms of luminance and EL emission. In addition, the electron conductivity of the device is increased by four orders of magnitude. Concerning graphene–polymer nanocomposites, Choudhary et al. have inserted MoS2 and graphene oxide NP into a polyaniline ETL [72]. The

• conductivity of the nanocomposite was enhanced by 185% as compared to pure polyaniline. Further, the role of carbon quantum dots (CQD) in the ETL has also been examined in the device ITO/PEDOT:PSS/PFO/CQD/LiF/Al [73]. The turn-on voltage with CQD in the device configuration reduced from 8 to 6 V with

Paper-based triboelectric nanogenerators and their applications: a review

• Jing Han,
• Nuo Xu,
• Yuchen Liang,
• Mei Ding,
• Junyi Zhai,
• Qijun Sun and
• Zhong Lin Wang

Beilstein J. Nanotechnol. 2021, 12, 151–171, doi:10.3762/bjnano.12.12

• . TENGs can also be used to harvest mechanical energy and drive electropolymerization processes without an external power source to drive the electrochemical reaction. Shi et al. obtained a P-TENG electrochemical system for electropolymerizing polyaniline (PANI) on a CNT electrode. Figure 10a shows the

ZnO and MXenes as electrode materials for supercapacitor devices

• Ameen Uddin Ammar,
• Ipek Deniz Yildirim,
• Feray Bakan and
• Emre Erdem

Beilstein J. Nanotechnol. 2021, 12, 49–57, doi:10.3762/bjnano.12.4

• applications that offer high power density, stability, and safety. A specific capacitance of 366 F·g−1 was achieved at 2 mVs-1 [18]. In addition, Li et al. designed an asymmetric pseudosupercapacitor of wavy-Ti3C2Tx/reduced graphene oxide (rGO)/CNT/polyaniline(PANI), in which the Ti3C2Tx MXene is used as

High permittivity, breakdown strength, and energy storage density of polythiophene-encapsulated BaTiO₃ nanoparticles

• Adnanullah Khan,
• Amir Habib and
• Adeel Afzal

Beilstein J. Nanotechnol. 2020, 11, 1190–1197, doi:10.3762/bjnano.11.103

• ][10], which are largely attributed to the interphase inhomogeneity, poor distribution, and agglomeration of BTO nanoparticles in the polymer matrix. You et al. [10] observed an increase in the permittivity (from 4 to 14) of poly(arylene ether nitrile) filled with 40 wt % polyaniline-functional-BTO

Silver-decorated gel-shell nanobeads: physicochemical characterization and evaluation of antibacterial properties

• Marta Bartel,
• Katarzyna Markowska,
• Marcin Strawski,
• Krystyna Wolska and
• Maciej Mazur

Beilstein J. Nanotechnol. 2020, 11, 620–630, doi:10.3762/bjnano.11.49

• sulfonate beads modified with polyaniline followed by decoration with silver nanoparticles and demonstrated the considerable antibacterial activity of this material [24]. While the number of works on hybrid polymer/nanoparticle structures and their antibacterial activity is relatively limited, a great

Adsorptive removal of bulky dye molecules from water with mesoporous polyaniline-derived carbon

• Hyung Jun An,
• Jong Min Park,
• Nazmul Abedin Khan and
• Sung Hwa Jhung

Beilstein J. Nanotechnol. 2020, 11, 597–605, doi:10.3762/bjnano.11.47

• Hyung Jun An Jong Min Park Nazmul Abedin Khan Sung Hwa Jhung Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University, Daegu 41566, Republic of Korea 10.3762/bjnano.11.47 Abstract Polyaniline-derived carbon (PDC) was obtained via pyrolysis of polyaniline

• ; polyaniline-derived carbon; water purification; Introduction Dyes have been widely used in a wide range of industries including textile, leather and paper, causing serious concern worldwide mainly because of the contamination of water resources. For example, around 700,000 tons of textile dyes are produced

• ]. Moreover, highly porous carbon materials, especially with high nitrogen content, have been produced from various precursors including organic polymers [29][30][31][32][33] and MOFs [34][35][36][37][38]. Polyaniline (PANI), prepared from aniline, is a useful polymer in various fields because of its facile

Synthesis of amorphous and graphitized porous nitrogen-doped carbon spheres as oxygen reduction reaction catalysts

• Maximilian Wassner,
• Markus Eckardt,
• Andreas Reyer,
• Thomas Diemant,
• Michael S. Elsaesser,
• R. Jürgen Behm and
• Nicola Hüsing

Beilstein J. Nanotechnol. 2020, 11, 1–15, doi:10.3762/bjnano.11.1

• . Annealing graphene oxide (GO) in an ammonia atmosphere at 550 °C led to pyridinic N-doped graphene, while at a temperature of 850 °C graphitic nitrogen coexisted with pyridinic nitrogen, and for higher temperatures the amount of graphitic N increased. Annealing GO at 850 °C in the presence of polyaniline or

Advanced hybrid nanomaterials

• Andreas Taubert,
• Fabrice Leroux,
• Pierre Rabu and
• Verónica de Zea Bermudez

Beilstein J. Nanotechnol. 2019, 10, 2563–2567, doi:10.3762/bjnano.10.247

• , polyaniline and hexaniobate: hierarchical architecture and high polaron formation” were explored for the promotion of synergistic effects expected at the nanoscale [23]. The resulting mixture between polyaniline chains with reduced graphene flakes and hexaniobate nanoscrolls may find application as coatings

Widening of the electroactivity potential range by composite formation – capacitive properties of TiO₂/BiVO₄/PEDOT:PSS electrodes in contact with an aqueous electrolyte

• Konrad Trzciński,
• Mariusz Szkoda,
• Andrzej P. Nowak,
• Marcin Łapiński and
• Anna Lisowska-Oleksiak

Beilstein J. Nanotechnol. 2019, 10, 483–493, doi:10.3762/bjnano.10.49

• work (not exceeding 1 V) [74][75][76]. Recently, it was reported that titania nanotubes/polyaniline composites in contact with aqueous electrolyte can be polarized in a range between −0.2 to 1.8 V vs SCE with very good capacitance retention [77], but the achieved areal capacitance (ca. 6 mF·cm−2) seems

Wet chemistry route for the decoration of carbon nanotubes with iron oxide nanoparticles for gas sensing

• Hussam M. Elnabawy,
• Juan Casanova-Chafer,
• Badawi Anis,
• Mostafa Fedawy,
• Mattia Scardamaglia,
• Carla Bittencourt,
• Ahmed S. G. Khalil,
• Eduard Llobet and
• Xavier Vilanova

Beilstein J. Nanotechnol. 2019, 10, 105–118, doi:10.3762/bjnano.10.10

• composites with other materials such as graphene oxide or polyaniline has been reported to detect NO2 [17][18]. The decoration of CNTs with iron oxide has been reported for sensing different species in air such as acetone, CO2 and some volatile organic compounds [19][20][21]. Moreover, composites made of

Ternary nanocomposites of reduced graphene oxide, polyaniline and hexaniobate: hierarchical architecture and high polaron formation

• Claudio H. B. Silva,
• Maria Iliut,
• Christopher Muryn,
• Christian Berger,
• Zachary Coldrick,
• Vera R. L. Constantino,
• Marcia L. A. Temperini and
• Aravind Vijayaraghavan

Beilstein J. Nanotechnol. 2018, 9, 2936–2946, doi:10.3762/bjnano.9.272

• nanocomposite composed of polyaniline (PANI), reduced graphene oxide (rGO) and hexaniobate (hexNb) nanoscrolls. Atomic force microscopy images show an interesting architecture of rGO flakes coated with PANI and decorated by hexNb. Such features are attributed to the high stability of the rGO flakes prepared at

• morphological aspects. Therefore, the new nanocomposite presents promising properties for development of new materials in the film form on substrates for sensing or corrosion protection for example. Keywords: graphene oxide; hexaniobate; polyaniline; Raman spectroscopy; secondary doping; Introduction

• electrocatalytic activity in the quantification of chemical species compared to the isolated components [5]. In earlier studies, some of us reported the preparation of binary nanocomposites of polyaniline (PANI) and hexaniobate (hexNb) nanoscrolls by layer-by-layer assembly and the characterisation by

Electrospun one-dimensional nanostructures: a new horizon for gas sensing materials

• Muhammad Imran,
• Nunzio Motta and
• Mahnaz Shafiei

Beilstein J. Nanotechnol. 2018, 9, 2128–2170, doi:10.3762/bjnano.9.202

• (e.g., polypyrrole (PPy), polyaniline (PANI), polythiophene (PTh) and their derivatives) [32][87][88][90], MOx nanofibers surface functionalized by metal nanoparticles [75] and graphene sheets incorporated with MOx nanofibers [89]. 4.1 Conductometric gas sensors Nanostructure-based conductometric

Metal-free catalysis based on nitrogen-doped carbon nanomaterials: a photoelectron spectroscopy point of view

• Mattia Scardamaglia and
• Carla Bittencourt

Beilstein J. Nanotechnol. 2018, 9, 2015–2031, doi:10.3762/bjnano.9.191

• underwent different temperature treatments, yielding different surface compositions of nitrogen functionalities, as observed by XPS [114]. They produced N-graphene either by the annealing of graphene oxide (GO) in NH3 or by annealing a composite of N-containing polymer (polyaniline or polypyrrole) and rGO

Cr(VI) remediation from aqueous environment through modified-TiO₂-mediated photocatalytic reduction

• Rashmi Acharya,
• Brundabana Naik and
• Kulamani Parida

Beilstein J. Nanotechnol. 2018, 9, 1448–1470, doi:10.3762/bjnano.9.137

• superior synergetic performance of adsorption and photocatalysis by removing 100% Cr(VI) from a solution containing 5 mg L−1 of Cr(VI) within 30 minutes. Under continuous flow conditions, the percentage removal was maintained at 100% till the breakthrough point was achieved [132]. Halloysite–polyaniline