Heat-induced morphological changes in silver nanowires deposited on a patterned silicon substrate

• Elyad Damerchi,
• Sven Oras,
• Edgars Butanovs,
• Allar Liivlaid,
• Mikk Antsov,
• Boris Polyakov,
• Annamarija Trausa,
• Veronika Zadin,
• Andreas Kyritsakis,
• Loïc Vidal,
• Karine Mougin,
• Siim Pikker and
• Sergei Vlassov

Beilstein J. Nanotechnol. 2024, 15, 435–446, doi:10.3762/bjnano.15.39

• indium tin oxide (ITO), which currently serves as the industry standard for transparent conductive films, the Ag NW network is significantly more mechanically flexible and offers a broader optical transmittance range that extends well beyond the visible region [13][14]. Another related application of Ag

Controllable physicochemical properties of WO_x thin films grown under glancing angle

• Rupam Mandal,
• Aparajita Mandal,
• Alapan Dutta,
• Rengasamy Sivakumar,
• Sanjeev Kumar Srivastava and
• Tapobrata Som

Beilstein J. Nanotechnol. 2024, 15, 350–359, doi:10.3762/bjnano.15.31

• the AFM and SEM analysis, henceforth, the films will be referred to as NS-WOx films. Regarding the optical properties, the transmittance spectra of the as-deposited NS-WOx films on glass show the highest transmittance (more than 90%) over the spectral range of 300 to 1200 nm for 6 nm films, which

• -deposited and (e–h) vacuum-annealed WOx films grown at a fixed glancing angle of 87°. (i, j) Variations in RMS roughness and grain size with WOx films thickness before and after annealing, respectively. (a) Transmittance plots of the as-deposited NS-WOx films and (b) bandgap variation with film thickness

Influence of conductive carbon and MnCo₂O₄ on morphological and electrical properties of hydrogels for electrochemical energy conversion

• Sylwia Pawłowska,
• Karolina Cysewska,
• Yasamin Ziai,
• Jakub Karczewski,
• Piotr Jasiński and
• Sebastian Molin

Beilstein J. Nanotechnol. 2024, 15, 57–70, doi:10.3762/bjnano.15.6

• in Figure 3a. The spectra present the strongest characteristic transmittance peaks of PNIPAAm at 3430, 3284, and 3068 cm−1, which are assigned to the N−H stretching of the secondary amine. Peaks at 1637 and 1535 cm−1 can be ascribed to the stretching of the carbonyl group C=O [42][48]. In the FTIR

• spectrum of MnCo2O4, two transmittance bands at 620 and 478 cm−1, characteristic of M–O stretching and vibrations of the spinel structure, were visible (Figure 3b) [49][50]. In the case of super P Li conductive carbon black, no distinct peaks can be seen in the FTIR spectra. However, it is visible that

• present material functional groups, FTIR spectroscopy in attenuated total reflectance (ATR) mode was used (Bruker Vertex70 FT-IR Spectrometer). The FTIR analysis was carried out in a wavenumber range of 400–4000 cm−1 and with a resolution of 2 cm−1 and eight scans were made for each sample. Transmittance

Fluorescent bioinspired albumin/polydopamine nanoparticles and their interactions with Escherichia coli cells

• Eloïse Equy,
• Jordana Hirtzel,
• Sophie Hellé,
• Béatrice Heurtault,
• Eric Mathieu,
• Morgane Rabineau,
• Vincent Ball and
• Lydie Ploux

Beilstein J. Nanotechnol. 2023, 14, 1208–1224, doi:10.3762/bjnano.14.100

• overnight. The bacterial suspension was then diluted with LB to obtain a transmittance at 600 nm of 0.001 (6 × 106 CFU/mL). 200 µL of fluorescent Ox-, FITC-, or RhBITC-BSA/PDA NPs suspension was added to 800 µL of the bacterial suspension, corresponding to the highest concentration of NPs tested in the

• ) were thus estimated to be 164 and 373 µM for FITC and RhBITC, respectively. The suspensions were all incubated at 37 °C for 24 h. Then, they were diluted in fresh liquid LB to reach a transmittance of 0.5 at 600 nm for suspensions without NPs, or a transmittance of 0.5 increased by the transmittance of

• the control with NPs alone, for samples containing NPs (to take into account the transmittance due to NPs). Afterward, samples were centrifuged at 3000 rpm for 10 min and re-suspended in 1 mL of PBS. This procedure was repeated two times. To allow for the storage of the samples over days, a fixation

SERS performance of GaN/Ag substrates fabricated by Ag coating of GaN platforms

• Magdalena A. Zając,
• Bogusław Budner,
• Malwina Liszewska,
• Bartosz Bartosewicz,
• Łukasz Gutowski,
• Jan L. Weyher and
• Bartłomiej J. Jankiewicz

Beilstein J. Nanotechnol. 2023, 14, 552–564, doi:10.3762/bjnano.14.46

• room temperature in the 250–800 nm spectral range with an increment of 1 nm. The transmittance (%T) and the reflectance (%R) of the GaN/Ag substrates were measured. The absorptance (%A), defined as the fraction of incoming radiant flux absorbed by an object, was calculated via %A = 100% − %T − %R. SERS

Conjugated photothermal materials and structure design for solar steam generation

• Chia-Yang Lin and
• Tsuyoshi Michinobu

Beilstein J. Nanotechnol. 2023, 14, 454–466, doi:10.3762/bjnano.14.36

• the spectral range of terrestrial solar irradiation (Figure 6b and Figure 6c). Single-layer PPy nanosheets transmit 0.2–0.3% of light, while two or more layers of the PPy nanosheets exhibit a very low transmittance over the entire solar spectrum. It is interesting to note that the light absorption

• process of multilayer PPy nanosheets. (b)Transmittance and (c) diffuse reflectance spectra of the air-laid paper substrate coated with different layer numbers of PPy nanosheets. The inset figure in (b) is the enlarged view of the 500–1500 nm wavelength range. The solar spectral irradiance (AM1.5G) is

Polymer nanoparticles from low-energy nanoemulsions for biomedical applications

• Santiago Grijalvo and
• Carlos Rodriguez-Abreu

Beilstein J. Nanotechnol. 2023, 14, 339–350, doi:10.3762/bjnano.14.29

• ethyl acetate. This solvent is less toxic than commonly used aromatic compounds. Kinetically stable O/W nanoemulsions were obtained at oil/surfactant (O/S) mass ratios between 30/70 and 70/30 and water contents above 40 wt %. The light transmittance of the sample increased with water content and

• droplet size does not change much with time in this concentration range, indicating good colloidal stability, although for the highest concentration, the change in transmittance with time is more noticeable. The size of the derived nanoparticles increases with the PLGA concentration in the ethyl acetate

Electrical and optical enhancement of ITO/Mo bilayer thin films via laser annealing

• Abdelbaki Hacini,
• Ahmad Hadi Ali,
• Nurul Nadia Adnan and
• Nafarizal Nayan

Beilstein J. Nanotechnol. 2022, 13, 1589–1595, doi:10.3762/bjnano.13.133

• AFM analysis shows that grain size and RMS roughness increased from 16.02 to 36.19 nm and 0.4 to 2.6 nm, respectively, when the laser energy was increased to 120 mJ. The as-deposited sample has an optical transmittance of nearly 80% in the 300–800 nm range. The laser annealing yielded a higher

• transmittance of 94% and increased the bandgap energy from 2.76 to 2.88 eV at 120 mJ. The annealing treatment decreased the resistivity from 15.63 × 10−4 to 1.73 × 10−4 Ω/cm−1. Additionally, the figure of merit of the ITO/Mo structure improved significantly from 6.63 × 10−4 Ω−1 of the as-deposited sample to

• transmittance spectra of the as-deposited and annealed ITO/Mo bilayer structure thin films. The measurement was taken in the wavelength range of 300–800 nm. The as-deposited sample shows the lowest optical transmittance with an average close to 80% at a wavelength of 550 nm. The annealed samples exhibit an

LED-light-activated photocatalytic performance of metal-free carbon-modified hexagonal boron nitride towards degradation of methylene blue and phenol

• Nirmalendu S. Mishra and
• Pichiah Saravanan

Beilstein J. Nanotechnol. 2022, 13, 1380–1392, doi:10.3762/bjnano.13.114

• ]. Additionally, the photon harvesting ability of the studied photocatalysts was also evaluated by determining the light harvesting efficiency (LHE). The LHE of the material was determined from the following equation and has been demonstrated in Figure 5g [29]. where T and R denote the transmittance and

A super-oscillatory step-zoom metalens for visible light

• Yi Zhou,
• Chao Yan,
• Peng Tian,
• Zhu Li,
• Yu He,
• Bin Fan,
• Zhiyong Wang,
• Yao Deng and
• Dongliang Tang

Beilstein J. Nanotechnol. 2022, 13, 1220–1227, doi:10.3762/bjnano.13.101

• field at the subwavelength scale [16][17][18][19][20][21][22]. Compared with metallic metasurfaces, all-dielectric metasurfaces are characterized by high amplitude transmittance, which is important for super-oscillatory lenses with comparatively low focusing efficiency. Generally, for all-dielectric

• , height H = 600 nm, and period P = 250 nm × 250 nm. It is demonstrated in Figure 3b that the transmittance varies only little for different orientation angles and the modulated phase changes almost linearly with a factor of two, which also proves the geometric phase principle and the excellent performance

• is achieved by the metasurface. Nonetheless, due to the shadowing effect and coupling phenomenon among unit cells, the transmittance of the unit cells is affected by the incident angle and the orientation of unit cells. Third, the residual co-polarization component could lead to noticeable stray

Analytical and numerical design of a hybrid Fabry–Perot plano-concave microcavity for hexagonal boron nitride

• Felipe Ortiz-Huerta and
• Karina Garay-Palmett

Beilstein J. Nanotechnol. 2022, 13, 1030–1037, doi:10.3762/bjnano.13.90

• silver (Ag), polymer (pol), air, hBN and DBR layer. The transfer matrices Lpol and Lair are defined as [25]: where G1,2 = arctan(L1,2λ0/n1,2πW01,02) is the Guoy phase shift in the air (n1 = 1) and polymer layer, respectively, where W01 = W02. The transmittance of the microcavity is calculated, from the

• stability range R2 ≈ 2L2. Numerical design Resonant modes of hybrid plano-concave microcavity For the FDTD simulations, we used the Ansys Lumerical FDTD software. The polymer, and DBR stack were treated as lossless and non-dispersive materials [15]. A transmittance T = 8% at 637 nm is measured for our

• (HL)15 configuration. Maximum electric field intensity is found at the surface of the hBN layer. Vertical lines (blue) represent the boundaries between each dielectric layer. Transmittance of plano-concave cavity shows the fundamental TEM modes at 595 nm, 636 nm and 684 nm. Purcell factor of plano

Solar-light-driven LaFe_xNi_1−xO₃ perovskite oxides for photocatalytic Fenton-like reaction to degrade organic pollutants

• Chao-Wei Huang,
• Shu-Yu Hsu,
• Jun-Han Lin,
• Yun Jhou,
• Wei-Yu Chen,
• Kun-Yi Andrew Lin,
• Yu-Tang Lin and
• Van-Huy Nguyen

Beilstein J. Nanotechnol. 2022, 13, 882–895, doi:10.3762/bjnano.13.79

• transmittance and suitable surface area for degrading methylparaben. Although Ti-doped catalyst was expected as a semiconductor to enhance the photocatalytic efficiency, pure LaFeO3 still revealed the better performance of methylparaben photodegradation than LaTi0.15Fe0.85O3 [28]. On the contrary, Garcia-Muñoz

Modeling a multiple-chain emeraldine gas sensor for NH₃ and NO₂ detection

• Hana Sustkova and
• Jan Voves

Beilstein J. Nanotechnol. 2022, 13, 721–729, doi:10.3762/bjnano.13.64

• molecular properties of polyaniline have been studied by quantum mechanical means in [4][8]. The band structure was calculated by Reis et al. [9], together with transmittance, electrical current flow, and charge density. For these calculations, density functional theory (DFT, [10]) based on the generalized

Reliable fabrication of transparent conducting films by cascade centrifugation and Langmuir–Blodgett deposition of electrochemically exfoliated graphene

• Teodora Vićentić,
• Stevan Andrić,
• Vladimir Rajić and
• Marko Spasenović

Beilstein J. Nanotechnol. 2022, 13, 666–674, doi:10.3762/bjnano.13.58

• the Langmuir–Blodgett (LB) method to deposit graphene flakes from solution as uniform thin films. LB has proven to be a method that yields reliable graphene films that have been used as transparent conductors [27][32][33][34] and gas sensors [35][36]. By measuring optical transmittance and electrical

• thickness for a reasonable electrical conductivity. For both, our films made from electrochemically exfoliated graphene and literature-referenced films made from ultrasonic LPE graphene, the percolation limit is reached at an optical transmittance of ca. 83%. This number quantifies the maximum transmittance

• , Madison, USA). A xenon lamp was used as a light source. The glass samples were mounted on a holder and inserted into the light path. Optical transmittance was measured by subtracting the signal from a baseline reference signal obtained when a clean glass substrate without graphene was inserted into the

The role of sulfonate groups and hydrogen bonding in the proton conductivity of two coordination networks

• Ali Javed,
• Felix Steinke,
• Stephan Wöhlbrandt,
• Hana Bunzen,
• Norbert Stock and
• Michael Tiemann

Beilstein J. Nanotechnol. 2022, 13, 437–443, doi:10.3762/bjnano.13.36

• % were recorded on a Panalytical Empyrean diffractometer equipped with a CHC plus+ chamber in a transmittance Bragg–Brentano geometry employing Cu radiation. The patterns were recorded at a temperature of 25 °C before and after the activation of sample at 80 °C and 10% relative humidity. For impedance

Selected properties of Al_xZn_yO thin films prepared by reactive pulsed magnetron sputtering using a two-element Zn/Al target

• Witold Posadowski,
• Artur Wiatrowski,
• Jarosław Domaradzki and
• Michał Mazur

Beilstein J. Nanotechnol. 2022, 13, 344–354, doi:10.3762/bjnano.13.29

• manufacturing transparent electrodes, the TCO films should have relatively low resistivity, ρTCO ≤ 10−3 Ω·cm, and optical transmittance, preferably over 80%, for films with thicknesses not exceeding 200 nm. In addition, parameters such as high resistance to mechanical exposure and good adhesion to the substrate

• heated to 500 °C. The lowest measured resistivity of the investigated thin films was in the range from 1 × 10−4 to 1 × 10−3 Ω·cm. Furthermore, the prepared films were characterized by a light transmittance greater than 80%. Post-process annealing was also found to result in reduced resistivity and

Sputtering onto liquids: a critical review

• Anastasiya Sergievskaya,
• Adrien Chauvin and
• Stephanos Konstantinidis

Beilstein J. Nanotechnol. 2022, 13, 10–53, doi:10.3762/bjnano.13.2

Plasmon-enhanced photoluminescence from TiO₂ and TeO₂ thin films doped by Eu³⁺ for optoelectronic applications

• Marcin Łapiński,
• Jakub Czubek,
• Katarzyna Drozdowska,
• Anna Synak,
• Wojciech Sadowski and
• Barbara Kościelska

Beilstein J. Nanotechnol. 2021, 12, 1271–1278, doi:10.3762/bjnano.12.94

• composition, layers were etched for 2, 6, and 8 min. Optical transmittance spectra of all prepared structures were measured using an Evolution 220 UV–visible spectrophotometer in the range of 200–1000 nm. Luminescence excitation and emission spectra were recorded using a Scinco FluoroMate FS-2 fluorescence

• nanostructure with a diameter of ca. 50 nm is not perfectly spherical, but flattened on the substrate side. An exemplary transmittance spectrum recorded for the plasmonic platform is presented in Figure 3. A strong transmittance minimum, corresponding to plasmon resonance is observed at about 530 nm. The rapid

• decrease of transmittance at 350 nm is caused by absorption of glass substrate and can be noticed for other samples as well. TiO2:Eu-based structures The chemical composition of the luminescent titanium dioxide doped with europium was examined using XPS. The spectra of Ti 2p and Eu 4d core level electrons

pH-driven enhancement of anti-tubercular drug loading on iron oxide nanoparticles for drug delivery in macrophages

• Karishma Berta Cotta,
• Sarika Mehra and
• Rajdip Bandyopadhyaya

Beilstein J. Nanotechnol. 2021, 12, 1127–1139, doi:10.3762/bjnano.12.84

• for crystalline iron oxide. (d) FTIR spectrum of transmittance v/s wavenumber, depicting major functional groups of iron oxide and NOR. Characterization of NOR@IONPpH10 nanoparticles. (a) Dynamic light scattering plot of number (%) v/s size (nm) of the nanoparticles in solution at the completion of

• synthesis (n = 3). (b) Transmission electron microscopy image with a 50 nm scale bar. (c) X-ray diffraction pattern indicating the Bragg’s angle corresponding to those observed in iron oxide. (d) FTIR plot of transmittance v/s wavenumber depicting functional groups of iron oxide. Drug release profile over

Assessment of the optical and electrical properties of light-emitting diodes containing carbon-based nanostructures and plasmonic nanoparticles: a review

• Keshav Nagpal,
• Erwan Rauwel,
• Frédérique Ducroquet and
• Protima Rauwel

Beilstein J. Nanotechnol. 2021, 12, 1078–1092, doi:10.3762/bjnano.12.80

• transmittance (>80% in the visible region) and low sheet resistance (≈20 Ω/sq). Typically, ITO consists of 90% In2O3 and 10% SnO2 by weight. Kim et al. have grown ITO on glass substrates with varying Sn concentrations [35]. Although ITO is a conventional favorite current-spreading layer, it nevertheless suffers

• thermal resistance between the device layers [37][38]. Furthermore, the transmittance of large-area few-layer graphene used as a current-spreading layer in InGaN-based UV LED is similar to the transmittance of ITO in the blue region (Figure 1a) [39]. Furthermore, the I–V results in Figure 1b show an

• -based devices are 2800 cd/m2 and 1.4 cd/A, respectively, at a turn-on voltage of 6.6 V. These values are however not as satisfactory as the ITO-based device: 6000 cd/m2 and 1.9 cd/A at a turn-on voltage of 6.2 V. One reason for lower SWNT device performance is associated with its lower transmittance of

High-yield synthesis of silver nanowires for transparent conducting PET films

• Gul Naz,
• Hafsa Asghar,
• Muhammad Ramzan,
• Muhammad Arshad,
• Rashid Ahmed,
• Muhammad Bilal Tahir,
• Bakhtiar Ul Haq,
• Nadeem Baig and
• Junaid Jalil

Beilstein J. Nanotechnol. 2021, 12, 624–632, doi:10.3762/bjnano.12.51

• flexibility after the ink coating. The maximum transmittance value of as-prepared PET films in the visible region was estimated to be about 92.5% with a sheet resistance value of ca. 20 Ω/sq. This makes the films a potential substitute to commonly used expensive indium tin oxide (ITO) in the field of flexible

• optoelectronics. Keywords: silver nanowires; high yield; visible luminescence; PET film; transmittance; sheet resistance; Introduction Several optoelectronic devices, such as solar cells, touch screens, LC displays, organic EL panels, light-emitting diodes, and organic light emitting diodes, use transparent

• electrodes made of sputtered indium tin oxide (ITO) films [1][2][3]. These films are widely used because of their high transmittance, low sheet resistance, and high electrical conductivity. Yet, they still have some major drawbacks such as high cost, intrinsic brittleness due to the ceramic nature [4], and

Surface-enhanced Raman scattering of water in aqueous dispersions of silver nanoparticles

• Paulina Filipczak,
• Krzysztof Hałagan,
• Jacek Ulański and
• Marcin Kozanecki

Beilstein J. Nanotechnol. 2021, 12, 497–506, doi:10.3762/bjnano.12.40

• transmittance values of AgNPs in the OH stretching vibration spectral region. Also, the transmittance value at the excitation wavelength used in the Raman experiments (514.5 nm) was taken into account. After this correction, the spectra were then treated with a baseline correction. Only the non-polarised Raman

A review on the green and sustainable synthesis of silver nanoparticles and one-dimensional silver nanostructures

• Sina Kaabipour and
• Shohreh Hemmati

Beilstein J. Nanotechnol. 2021, 12, 102–136, doi:10.3762/bjnano.12.9

• direction [89], and can form networks of wires that facilitate the passage of electrical current. They can also improve transmittance characteristics due to their high aspect ratio [90]. Novel applications can be seen in transparent conductive films (TCFs) [91], wireless technology [92][93], touchscreen

High-responsivity hybrid α-Ag₂S/Si photodetector prepared by pulsed laser ablation in liquid

• Raid A. Ismail,
• Hanan A. Rawdhan and
• Duha S. Ahmed

Beilstein J. Nanotechnol. 2020, 11, 1596–1607, doi:10.3762/bjnano.11.142

• taking into account the transmittance of the ablation liquid at 1064 nm. The ablation time for each sample was set to 20 min. Figure 1 shows a schematic of the pulsed laser ablation system used in this work. A rotating motor was used to help prevent the aggregation and agglomeration of particles during

Structural and electronic properties of SnO₂ doped with non-metal elements

• Jianyuan Yu,
• Yingeng Wang,
• Yan Huang,
• Xiuwen Wang,
• Jing Guo,
• Jingkai Yang and
• Hongli Zhao

Beilstein J. Nanotechnol. 2020, 11, 1321–1328, doi:10.3762/bjnano.11.116

• SnO2; electronic structure; optical properties; Introduction Thin film solar cells are devices that convert solar energy into electrical energy. Transparent conductive films (TCFs) are a thin film material with both conductive capabilities and high transmittance in the visible light range (300–800 nm

• , high transmittance of visible light, good thermal stability, acid–base corrosion resistance, high material hardness, and easiness of preparation processes [5]. Non-metal atoms, such as fluorine (F) and nitrogen (N), were proved to be proper elements for doping. After doping with heteroatoms, the