Thiocarbonyl-enabled ferrocene C–H nitrogenation by cobalt(III) catalysis: thermal and mechanochemical

Santhivardhana Reddy Yetra, Zhigao Shen, Hui Wang and Lutz Ackermann
Beilstein J. Org. Chem. 2018, 14, 1546–1553. https://doi.org/10.3762/bjoc.14.131

Supporting Information

Supporting Information File 1: Experimental procedures, characterization data, and NMR spectra for new compounds.
Format: PDF Size: 2.8 MB Download

Cite the Following Article

Thiocarbonyl-enabled ferrocene C–H nitrogenation by cobalt(III) catalysis: thermal and mechanochemical
Santhivardhana Reddy Yetra, Zhigao Shen, Hui Wang and Lutz Ackermann
Beilstein J. Org. Chem. 2018, 14, 1546–1553. https://doi.org/10.3762/bjoc.14.131

How to Cite

Yetra, S. R.; Shen, Z.; Wang, H.; Ackermann, L. Beilstein J. Org. Chem. 2018, 14, 1546–1553. doi:10.3762/bjoc.14.131

Download Citation

Citation data can be downloaded as file using the "Download" button or used for copy/paste from the text window below.
Citation data in RIS format can be imported by all major citation management software, including EndNote, ProCite, RefWorks, and Zotero.

Presentation Graphic

Picture with graphical abstract, title and authors for social media postings and presentations.
Format: PNG Size: 136.5 KB Download

Citations to This Article

Up to 20 of the most recent references are displayed here.

Scholarly Works

  • Hribersek, M.; Méndez-Gálvez, C.; Huber, M.; Gates, P. J.; Shakari, P.; Samanta, A.; Pilarski, L. T. Solvent-free and ball mill-free catalytic C–H methylation. Green Chemistry 2023, 25, 9138–9145. doi:10.1039/d3gc02411c
  • Park, J.; Krishnapriya, A. U.; Park, Y.; Kim, M.; Reidl, T. W.; Kuniyil, R.; Son, J. Copper(I)‐Catalyzed Decarboxylative N‐Phosphorylation: Modular Preparation of N‐Acyl Iminophosphoranes Using Dioxazolones and Phosphines. Advanced Synthesis & Catalysis 2023, 365, 4495–4501. doi:10.1002/adsc.202300693
  • Bao, R.; Shao, N.; Wang, F.; Wang, D. doi:10.1002/9783527834242.chf0188
  • Jin, Z. doi:10.1002/9783527834242.chf0132
  • Dolui, P.; Verma, A.; Elias, A. J. doi:10.1002/9783527834242.chf0074
  • Mou, Q.; Zhao, R.; Sun, B. Recent Advances in Transition-Metal-Catalyzed C-H Functionalization of Ferrocene Amides. Chemistry, an Asian journal 2022, 17, e202200818. doi:10.1002/asia.202200818
  • Ban, Y.; Wang, Y.; Li, H.; Wang, Y.; Li, D.; Yang, J. Thioamide directed iridium(I)-catalyzed C-H arylation of ferrocenes with aryl boronic acids. Organic & biomolecular chemistry 2022, 20, 5759–5763. doi:10.1039/d2ob00863g
  • Zhang, Z.-Z.; Huang, D.-Y.; Shi, B.-F. Recent advances in the synthesis of ferrocene derivatives via 3d transition metal-catalyzed C-H functionalization. Organic & biomolecular chemistry 2022, 20, 4061–4073. doi:10.1039/d2ob00558a
  • Begam, H. M.; Nandi, S.; Jana, R. A directing group switch in copper-catalyzed electrophilic C-H amination/migratory annulation cascade: divergent access to benzimidazolone/benzimidazole. Chemical science 2022, 13, 5726–5733. doi:10.1039/d2sc01420c
  • Ardila-Fierro, K. J.; Rubčić, M.; Hernández, J. G. Cocrystal Formation Precedes the Mechanochemically Acetate-Assisted C-H Activation with [Cp*RhCl2 ]2. Chemistry (Weinheim an der Bergstrasse, Germany) 2022, 28, e202200737. doi:10.1002/chem.202200737
  • Xie, H.; Song, J.-L.; Jiang, C.-Y.; Huang, Y.-X.; Zeng, J.-Y.; Liu, X.-G.; Zhang, S.-S.; Yang, F. Thioether-directed Rh(III)-catalyzed peri-selective acyloxylation of arenes. Organic & biomolecular chemistry 2022, 20, 565–569. doi:10.1039/d1ob02236a
  • Yoshikai, N. doi:10.1002/9780470682531.pat0985
  • Yoshikai, N. Organocobalt Complexes in C–H Bond Activation. Comprehensive Organometallic Chemistry IV; Elsevier, 2022; pp 759–815. doi:10.1016/b978-0-12-820206-7.00140-2
  • Casado, C. M.; Alonso, B.; García-Armada, M. P. Reference Module in Chemistry, Molecular Sciences and Chemical Engineering - Ferrocenes and Other Sandwich Complexes of Iron. Comprehensive Organometallic Chemistry IV; Elsevier, 2022; pp 3–45. doi:10.1016/b978-0-12-820206-7.00083-4
  • Pengpeng, G.; Xiaohui, Z.; Zheng, Q.-Z. Cobalt(III)-catalyzed C-H amidation of N,N-dialkyl thiobenzamides by sulfur coordination. Organic & biomolecular chemistry 2021, 19, 10332–10336. doi:10.1039/d1ob02034j
  • Singh, R.; Sathish, E.; Gupta, A. K.; Goyal, S. 3d-transition metal catalyzed C–H to C–N bond formation: An update. Tetrahedron 2021, 100, 132474. doi:10.1016/j.tet.2021.132474
  • Jia, Z.-S.; Yue, Q.; Li, Y.; Xu, X.-T.; Zhang, K.; Shi, B.-F. Copper-catalyzed monoselective C–H amination of ferrocenes with alkylamines. Beilstein journal of organic chemistry 2021, 17, 2488–2495. doi:10.3762/bjoc.17.165
  • Sunny, S.; Karvembu, R. Recent Advances in Cobalt-Catalyzed, Directing-Group-Assisted C−H Bond Amidation Reactions. Advanced Synthesis & Catalysis 2021, 363, 4309–4331. doi:10.1002/adsc.202100558
  • Gonzalez-Gomez, J. C.; Alonso, F. Organic Reaction Mechanisms Series; Wiley, 2021; pp 513–551. doi:10.1002/9781119531975.ch13
  • Zhang, Z.-Z.; Cheng, J.; Yao, Q.-J.; Yue, Q.; Zhou, G. Cobalt-Catalyzed C−H Alkoxylation of Ferrocenes with Alcohols under Mild Conditions. Advanced Synthesis & Catalysis 2021, 363, 3946–3951. doi:10.1002/adsc.202100423
Other Beilstein-Institut Open Science Activities