2 article(s) from Adonin, Nicolay Yu
Preparation of polyfluoroorganotrifluoroborates.
Jump to Scheme 1
Interaction of K[C6F5BF3] (1-K) with methyllithium (byproducts of hydrodeboration are not depicted)....
Jump to Scheme 2
Interaction of M[C6F5BF3] (1-M) with butyllithium (byproducts of hydrodeboration are not depicted).
Jump to Scheme 3
Interaction of K[C6F5BF3] (1-K) with phenyllithium (byproducts of hydrodeboration are not depicted)....
Jump to Scheme 4
Hydrodeboration of 6-K, 7-K, 8-K and 9-K in MeOH.
Jump to Scheme 5
Hydrodeboration of 1-K, 10-K and 11-K in methyl cellosolve.
Jump to Scheme 6
Hydrodeboration of 10-K, 11-K, 12-K and 13-K in MeOH.
Jump to Scheme 7
Preparation of 1-Li and 1-N.
Jump to Scheme 8
Formation of 2-R-tetrafluorophenyltrifluoroborates.
Jump to Scheme 9
Interaction between C6F5BF3− and PhLi.
Jump to Scheme 10
Interaction of 1-K with MeONa.
Jump to Scheme 11
Interaction of M[RC6F5BF3] with lithium halides.
Jump to Scheme 12
Assumed role of lithium halides.
Jump to Scheme 13
Beilstein J. Org. Chem. 2017, 13, 703–713, doi:10.3762/bjoc.13.69
The assumed silver(I) oxide assisted transmetallation with organoboronic acids.
Cross-coupling of K[4-RC6F4BF3] (1a–r) with 3-IC6H4F (2) and 4-IC6H4F (3).
Attempted synthesis of 7 (3’-F) and 8 (4’-F) by cross-coupling reaction.
Synthesis of biphenyls 10a,c–f,h–p.
Pd-catalyzed cross-coupling of 1a and salts 1b–p (1:1) with 11 (the results are presented in Table 3 and o...
The cross-coupling of 1a with 11 in the presence of different silver(I) compounds.
General concept of Pd-catalyzed Suzuki–Miyaura reaction.
Assumed silver(I)-assisted transmetallation of weakly nucleophilic aryitrifluoroborates.
Beilstein J. Org. Chem. 2015, 11, 608–616, doi:10.3762/bjoc.11.68
Subscribe to our Latest Articles RSS Feed.
Register and get informed about new articles.
Follow the Beilstein-Institut