2 article(s) from Daniliuc, Constantin G
- Full Research Paper
- Published 10 Jul 2020
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Figure 1: (A) Synthetic routes to α-fluoroketones from silyl enol ethers or acetophenone derivatives. (B) Sel...
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Scheme 1: Substrate scope with standard reaction conditions: alkyne (0.2 mmol), p-TolI (20 mol %), Selectfluor...
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Figure 2: X-ray molecular structure of compound 2. Conformation of the carbonyl group and the fluoride with a...
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Figure 3: (A) Structure activity relationship of the core scaffold. (B) Exploring the effect of methyl benzoa...
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Figure 4: (A) Hammett plot varying the para-substitution on the alkyne (ρ ≈ 0). (B) Hammett plot varying the ...
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Figure 5: An overview of the I(I)/I(III)-catalysed fluorohydration of alkynes.
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- Full Research Paper
- Published 09 May 2018
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Figure 1: Selected examples of bioactive compounds containing the 2-oxazoline motif.
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Figure 2: The catalytic difluorination of alkenes (top) and the proposed fluorocyclisation via the same I(I)/...
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Figure 3: Substrate scope. aReaction conducted on 1 mmol scale. bReaction time increased to 40 hours. cReacti...
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Scheme 1: Exploring diastereocontrol and the synthesis of the fluorohydrin 3. Yields in parentheses were dete...
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Figure 4: X-ray molecular structure of compound 2c. Thermal ellipsoids shown at the 50% propability level. To...
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