2 article(s) from Gade, Lutz H.
- Full Research Paper
- Published 29 Apr 2016
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Graphical Abstract
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Figure 1: P,N-ligand frameworks studied in this work.
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Scheme 1: Synthesis of N-phosphanylformamidines 2 and 3. Reaction conditions: (i) t-BuLi, THF, −78 °C to rt, ...
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Scheme 2: Synthesis of phosphanylformamidines 5 and 7. Reaction conditions: (i) t-BuLi, THF, −78 °C to rt, 1 ...
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Scheme 3: Synthesis of complexes [2-M(cod)]X, [3-M(cod)]X, [5-M(cod)]X and [7-M(cod)]X. M = Rh, Ir; X = BF4− ...
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Figure 2: Molecular structures of [2a-Rh(cod)]+ (A), [5-Ir(cod)]+ (B), and [7-Rh(cod)]+ (C,D). Anisotropic di...
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Figure 3: Coordination of ligands 2a and 5 to Rh(III) and Ir(III) precursors. Yields: [2a-Cp*RhCl]BF4 = 87%, [...
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Figure 4: Molecular structures of [2a-Cp*IrI]+ (left) and [5-Cp*IrI]+ (right). Anisotropic displacement ellip...
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Figure 5: Formation of palladium complexes of ligands 2a, 5 and 7. (A) Formation of [2a-PdCl2] and [2a-PdCl]2...
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Figure 6: Molecular structures of [2a-PdCl2] (left) and [5-Pd(2-Me-allyl)]+ (right). Anisotropic displacement...
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