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1 article(s) from Garrick, Lloyd M

Discovery of practical production processes for arylsulfur pentafluorides and their higher homologues, bis- and tris(sulfur pentafluorides): Beginning of a new era of “super-trifluoromethyl” arene chemistry and its industry

Teruo Umemoto,
Lloyd M. Garrick and
Norimichi Saito

Full Research Paper
Published 29 Mar 2012

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1. Graphical Abstract
2. Scheme 1: Preparation of ArSF₄Cl 2.
  
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3. Scheme 2: Preparation of Ar(SF₄Cl)_n from Ar(SH)_n (n = 2, 3).
  
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4. Scheme 3: Reaction mechanism for the formation of ArSF₄Cl.
  
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5. Scheme 4: Reaction mechanism for the formation of trans and cis-ArSF₄Cl.
  
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6. Scheme 5: Preparation of ArSF₅ with ZnF₂.
  
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7. Scheme 6: Preparation of PhSF₅ with anhydrous HF.
  
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8. Scheme 7: Preparation of 3a with HF–pyridine.
  
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9. Scheme 8: Preparation of polyfluorinated ArSF₅.
  
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10. Scheme 9: Preparation of aryl bis- and tris(sulfur pentafluorides), Ar(SF₅)_n (n = 2,3).
  
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Graphical Abstract

Beilstein J. Org. Chem. 2012, 8, 461–471, doi:10.3762/bjoc.8.53

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