2 article(s) from Ito, Yukishige
Graphical Abstract
Figure 1: Structure of mycothiol 1.
Scheme 1: Detoxification pathway mediated by MSH.
Scheme 2: Anomerization via endocyclic cleavage.
Scheme 3: Outline of mycothiol synthesis by anomerization.
Scheme 4: Synthesis of a pseudodisaccharide by an anomerization reaction.
Scheme 5: Mycothiol synthesis from pseudo-disaccharide 4.
Graphical Abstract
Scheme 1: Electrochemical conversion of thioglycosides to glycosyl triflates.
Figure 1: 1H NMR spectrum of glycosyl triflate 2a.
Scheme 2: Triflic acid mediated isomerization of β-glycoside.