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Beilstein J. Org. Chem. 2026, 22, 213–223, doi:10.3762/bjoc.22.15
Graphical Abstract
Scheme 1: Structure of phytic acid.
Figure 1: Structures of representative phosphate esters.
Figure 2: Synthetic methods for phosphorus compounds bypassing white phosphorus or phosphorus chloride.
Figure 3: Conditions for the syntheses of diaryl phosphates using phytic acid as a phosphorus source and scop...
Scheme 2: Phosphoric acid diesterification reaction conducted in a previous study.
Scheme 3: Scale-up reaction conducted for the time-course analysis of phosphate esterification. The reaction ...
Figure 4: Time-course analysis plots of the diphenylphosphate formation from phytic acid and 1a. The beginnin...
Figure 5: A possible reaction pathway for the formation of phosphate ester using phytic acid as the phosphoru...
Figure 6: 31P NMR spectrum of phytic acid extracted from rice bran.
Scheme 4: Esterification reaction conditions using the extracted phytic acid. The yield refers to the isolate...
Beilstein J. Org. Chem. 2021, 17, 866–872, doi:10.3762/bjoc.17.72
Scheme 1: Radical addition of Ph2PPPh2 and Ph2P(X)PPh2 to unsaturated C–C bonds.
Scheme 2: The addition of Ph2P(O)PPh2 (1) to 1-octyne (2a).
Scheme 3: Phosphinylphosphination of various terminal alkynes 2 with 1. aIsolated yields. V-40 = 1,1’-azobis(...
Scheme 4: Attempted radical addition to internal alkynes and insight into the addition to 2n.
Scheme 5: A plausible reaction pathway for the radical addition of Ph2P(O)PPh2 to terminal alkynes.
Beilstein J. Org. Chem. 2013, 9, 1141–1147, doi:10.3762/bjoc.9.127
Scheme 1: Photoinduced radical reaction of diaryl diselenide with triphenylbismuthine.
Scheme 2: Photoinduced reaction of diphenyl disulfide with triphenylbismuthine.
Scheme 3: A plausible reaction pathway for the photoinduced reaction of diaryl diselenide with triarylbismuth...