2 article(s) from Krylov, Igor B
Difunctionalization of double C=C bond with the formation of C–O and C–I bonds.
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Iodo-oxyimidation of styrenes 1a–k with preparation of products 3aa–ka, 3ab–db, 3fb, 3hb, and 3kb.
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Scope of the iodo-oxyimidation of vinylarenes with I2/PhI(OAc)2 system. Reaction conditions: vinyla...
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Molecular structure of 3ca. Atoms are presented as anisotropic displacement parameters (ADP) ellips...
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The proposed mechanism of iodo-oxyimidation of styrene (1a) using the NHPI/I2/PhI(OAc)2 system with...
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CV curves of styrene (1a, purple), NHPI (2a, red), I2 (blue) and PhI(OAc)2 (green) in 0.1 M n-Bu4NBF...
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Gram-scale synthesis of compound 3aa.
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Synthetic utility of the iodo-oxyimides 3aa and 3ab.
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Beilstein J. Org. Chem. 2018, 14, 2146–2155, doi:10.3762/bjoc.14.188
Cross-dehydrogenative C–O coupling.
Regioselective ortho-acetoxylation of meta-substituted arylpyridines and N-arylamides.
ortho-Acyloxylation and alkoxylation of arenes directed by pyrimidine, benzoxazole, benzimidazole a...
Cu(OAc)2/AgOTf/O2 oxidative system in the ortho-alkoxylation of arenes.
Pd(OAc)2/persulfate oxidative system in the ortho-alkoxylation and acetoxylation of arenes with nit...
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ortho-Acetoxylation and methoxylation of O-methyl aryl oximes, N-phenylpyrrolidin-2-one, and (3-ben...
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Ruthenium-catalyzed ortho-acyloxylation of acetanilides.
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Acetoxylation and alkoxylation of arenes with amide directing group using Pd(OAc)2/PhI(OAc)2 oxidat...
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Alkoxylation of azoarenes, 2-aryloxypyridines, picolinamides, and N-(1-methyl-1-(pyridin-2-yl)ethyl...
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Acetoxylation of compounds containing picolinamide and quinoline-8-amine moieties using the Pd(OAc)2...
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(CuOH)2CO3 catalyzed oxidative ortho-etherification using air as oxidant.
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Copper-catalyzed aerobic alkoxylation and aryloxylation of arenes containing pyridine-N-oxide moiet...
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Cobalt-catalyzed aerobic alkoxylation of arenes and alkenes containing pyridine N-oxide moiety.
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Non-symmetric double-fold C–H ortho-acyloxylation.
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N-nitroso directed ortho-alkoxylation of arenes.
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Selective alkoxylation and acetoxylation of alkyl groups.
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Acetoxylation of 2-alkylpyridines and related compounds.
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Acyloxylation and alkoxylation of alkyl fragments of substrates containing amide or sulfoximine dir...
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Palladium-catalyzed double sp3 C–H alkoxylation of N-(quinolin-8-yl)amides for the synthesis of sym...
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Copper-catalyzed acyloxylation of methyl groups of N-(quinolin-8-yl)amides.
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One-pot acylation and sp3 C–H acetoxylation of oximes.
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Possible mechanism of oxidative esterification catalyzed by N-heterocyclic nucleophilic carbene.
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Oxidative esterification employing stoichiometric amounts of aldehydes and alcohols.
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Selective oxidative coupling of aldehydes with alcohols in the presence of amines.
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Iodine mediated oxidative esterification.
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Oxidative C–O coupling of benzyl alcohols with methylarenes under the action of Bu4NI/t-BuOOH syste...
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Oxidative coupling of methyl- and ethylarenes with aromatic aldehydes under the action of Bu4NI/t-B...
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Cross-dehydrogenative C–O coupling of aldehydes with t-BuOOH in the presence of Bu4NI.
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Bu4NI-catalyzed α-acyloxylation reaction of ethers and ketones with aldehydes and t-BuOOH.
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Oxidative coupling of aldehydes with N-hydroxyimides and hexafluoroisopropanol.
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Oxidative coupling of alcohols with N-hydroxyimides.
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Oxidative coupling of aldehydes and primary alcohols with N-hydroxyimides using (diacetoxyiodo)benz...
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Proposed mechanism of the oxidative coupling of aldehydes and N-hydroxysuccinimide under action of ...
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Oxidative coupling of aldehydes with pivalic acid (172).
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Oxidative C–O coupling of aldehydes with alkylarenes using the Cu(OAc)2/t-BuOOH system.
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Copper-catalyzed acyloxylation of C(sp3)-H bond adjacent to oxygen in ethers using benzyl alcohols.
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Oxidative C–O coupling of aromatic aldehydes with cycloalkanes.
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Ruthenium catalyzed cross-dehydrogenative coupling of primary and secondary alcohols.
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Cross-dehydrogenative C–O coupling reactions of β-dicarbonyl compounds with sulfonic acids, acetic ...
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Acyloxylation of ketones, aldehydes and β-dicarbonyl compounds using carboxylic acids and Bu4NI/t-B...
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Acyloxylation of ketones using Bu4NI/t-BuOOH system.
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Cross-dehydrogenative C–O coupling of β-dicarbonyl compounds and their heteroanalogues with N-hydro...
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Cross-dehydrogenative C–O coupling of β-dicarbonyl compounds and their heteroanalogues with t-BuOOH....
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Oxidative C–O coupling of 2,6-dialkylphenyl-β-keto esters and thioesters with tert-butyl hydroxycar...
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α’-Acyloxylation of α,β-unsaturated ketones using KMnO4.
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Possible mechanisms of the acetoxylation at the allylic position of alkenes by Pd(OAc)2.
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Products of the oxidation of terminal alkenes by Pd(II)/AcOH/oxidant system.
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Acyloxylation of terminal alkenes with carboxylic acids.
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Synthesis of linear E-allyl esters by cross-dehydrogenative coupling of terminal alkenes wih carbox...
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Pd(OAc)2-catalyzed acetoxylation of Z-vinyl(triethylsilanes).
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α’-Acetoxylation of α-acetoxyalkenes with copper(II) chloride in acetic acid.
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Oxidative acyloxylation at the allylic position of alkenes and at the benzylic position of alkylare...
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Copper-catalyzed alkoxylation of methylheterocyclic compounds using di-tert-butylperoxide as oxidan...
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Oxidative C–O coupling of methylarenes with β-dicarbonyl compounds or phenols.
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Copper-catalyzed esterification of methylbenzenes with cyclic ethers and cycloalkanes.
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Oxidative C–O coupling of carboxylic acids with toluene catalyzed by Pd(OAc)2.
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Oxidative acyloxylation at the allylic position of alkenes with carboxylic acids using the Bu4NI/t-...
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Cross-dehydrogenative C–O coupling of carboxylic acids with alkylarenes using the Bu4NI/t-BuOOH sys...
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Oxidative C–O cross-coupling of methylarenes with ethyl or isopropylarenes.
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Phosphorylation of benzyl C–H bonds using the Bu4NI/t-BuOOH oxidative system.
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Selective C–H acetoxylation of 2,3-disubstituted indoles.
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Acetoxylation of benzylic position of alkylarenes using DDQ as oxidant.
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C–H acyloxylation of diarylmethanes, 3-phenyl-2-propen-1-yl acetate and dimethoxyarene using DDQ.
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Cross-dehydrogenative C–O coupling of 1,3-diarylpropylenes and 1,3-diarylpropynes with alcohols.
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One-pot azidation and C–H acyloxylation of 3-chloro-1-arylpropynes.
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Cross-dehydrogenative C–O coupling of 1,3-diarylpropylenes, (E)-1-phenyl-2-isopropylethylene and is...
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Cross-dehydrogenative C–O coupling of alkylarenes and related compounds with N-hydroxyphthalimide.
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Acetoxylation at the benzylic position of alkylarenes mediated by N-hydroxyphthalimide.
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C–O coupling of methylarenes with aromatic carboxylic acids employing the NaBrO3/NaHSO3 system.
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tert-Butyl peroxidation of allyl, propargyl and benzyl ethers catalyzed by Fe(acac)3.
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Cross-dehydrogenative C–O coupling of ethers with carboxylic acids mediated by Bu4NI/t-BuOOH system....
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Oxidative acyloxylation of dimethylamides and dioxane with 2-aryl-2-oxoacetic acids accompanied by ...
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tert-Butyl peroxidation of N-benzylamides and N-allylbenzamide using the Bu4NI/t-BuOOH system.
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Cross-dehydrogenative C–O coupling of aromatic carboxylic acids with ethers using Fe(acac)3 as cata...
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Cross-dehydrogenative C–O coupling of cyclic ethers with 2-hydroxybenzaldehydes using iron carbonyl...
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Cross-dehydrogenative C–O coupling of ethers with β-dicarbonyl compounds and phenols using copper c...
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Cross-dehydrogenative C–O coupling of 2-hydroxybenzaldehyde with dioxane catalyzed by Cu2(BPDC)2(BP...
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Ruthenium chloride-catalyzed acyloxylation of β-lactams.
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Ruthenium-catalyzed tert-butyl peroxydation amides and acetoxylation of β-lactams.
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PhI(OAc)2-mediated α,β-diacetoxylation of tertiary amines.
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Electrochemical oxidative methoxylation of tertiary amines.
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Cross-dehydrogenative C–O coupling of ketene dithioacetals with carboxylic acids in the presence of...
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Cross-dehydrogenative C–O coupling of enamides with carboxylic acids using iodosobenzene as oxidant....
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Oxidative alkoxylation, acetoxylation, and tosyloxylation of acylanilides using PhI(O(O)CCF3)2 in t...
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Proposed mechanism of the oxidative C–O coupling of actetanilide with O-nucleophiles in the presenc...
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Three-component coupling of aldehydes, anilines and alcohols involving oxidative intermolecular C–O...
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Oxidative coupling of phenols with alcohols.
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2-Acyloxylation of quinoline N-oxides with arylaldehydes in the presence of the CuOTf/t-BuOOH syste...
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Cross-dehydrogenative C–O coupling of azoles with primary alcohols.
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Oxidation of dipyrroles to dipyrrins and subsequent oxidative alkoxylation in the presence of Na3Co...
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Oxidative dehydrogenative carboxylation of alkanes and cycloalkanes to allylic esters.
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Pd-catalyzed acetoxylation of benzene.
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Beilstein J. Org. Chem. 2015, 11, 92–146, doi:10.3762/bjoc.11.13
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