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1 article(s) from Markos, Athanasios

Ligand-dependent stereoselective Suzuki–Miyaura cross-coupling reactions of β-enamido triflates

Tomáš Chvojka,
Athanasios Markos,
Svatava Voltrová,
Radek Pohl and
Petr Beier

Letter
Published 29 Oct 2021

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1. Graphical Abstract
2. Scheme 1: A: Synthesis of (Z)-β-enamido triflates and subsequent stereoselective cross-coupling reactions. B:...
  
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3. Scheme 2: Substrate scope of the Suzuki coupling leading to enamides 2 and 3. ^aRatio determined by ¹⁹F NMR; ^b...
  
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4. Scheme 3: Proposed mechanisms for the formed Suzuki coupling retention products 2 and inversion products 3.
  
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Graphical Abstract

Beilstein J. Org. Chem. 2021, 17, 2657–2662, doi:10.3762/bjoc.17.179

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