3 article(s) from Medvedev, Jury J
The structures of carbocyclic diazodiketones 1a–g and C–H-donating tetrahydrofuran used in the proj...
Jump to Figure 1
Molecular structure of hydrazone 2b as determined by X-ray analysis data (Olex2 plot with 50% proba...
Jump to Figure 2
Photochemical cycloelimination of furans from hydrazones 2d,e.
Jump to Scheme 1
Different pathways of diazodiketones 1 light-induced reactions in the singlet (reaction I) and trip...
Jump to Scheme 2
Beilstein J. Org. Chem. 2018, 14, 2250–2258, doi:10.3762/bjoc.14.200
General scheme for intramolecular heterocylization of intermediate X-ylides.
Thioamides 1a–e, diazoesters 2a–d and Rh(II)-catalysts used in the project.
The structures of compounds 4a and 3b according to the data of X-ray analysis (Olex2 plot with 50% ...
Rh(II)-Catalyzed reactions of α-diazocyanoacetic ester 2d with α-cyanothioacetamides 1a–e.
The structure of thiophene 5c according to the data of X-ray analysis (Olex2 plot with 50% probabil...
Jump to Figure 3
Interaction of thioacetamide 1e with dirhodium pivalate to produce complex 6e.
Jump to Scheme 3
The structure of the complex 6e according to the data of X-ray analysis (Olex2 plot with 50% probab...
Jump to Figure 4
The assumed mechanism for the formation of thiophenes 3, 5.
Jump to Scheme 4
The plausible mechanism for the formation of thiophenes 4.
Jump to Scheme 5
Beilstein J. Org. Chem. 2017, 13, 2569–2576, doi:10.3762/bjoc.13.253
Catalytic reactions of diazocarbonyl compounds with unsaturated δ-amino esters.
The structures of the starting compounds 1–3 and catalysts used in this study.
The assumed pathway for the occurance of amides 6a–c by way of the catalytic Wolff rearrangement.
The assumed mechanism for the formation of the amides 4 and 7 during oxidative cleavage of the N–H-...
Beilstein J. Org. Chem. 2016, 12, 1904–1910, doi:10.3762/bjoc.12.180
Subscribe to our Latest Articles RSS Feed.
Register and get informed about new articles.
Follow the Beilstein-Institut