1 article(s) from Murphy, Graham K
Reactions of substituted allenes with HVI reagents.
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Chlorination of p-tolylallene (2a) with (dichloroiodo)benzene (1a).
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Chlorination of various aryl-substituted allenes. General conditions: Allene 2a (0.2 mmol, 1 equiv)...
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Chlorination of various α-substituted phenylallene derivatives. General conditions: Allene 2a (0.2 ...
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Chlorination of methoxy-substituted α-methyl phenylallenes. General conditions: Allene 2a (0.2 mmol...
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Control reactions: (a) chlorination of deuterated biphenylallene [D2]-2b; (b) reaction with TEMPO.
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Proposed reaction mechanism.
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Beilstein J. Org. Chem. 2018, 14, 796–802, doi:10.3762/bjoc.14.67
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