2 article(s) from Yoshikai, Naohiko
Cobalt–NHC-catalyzed C–H alkenylation reactions with alkenyl electrophiles.
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Reaction of substituted pivalophenone N–H imines with 2a. aThe major regioisomer is shown (rr = reg...
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Reaction of 1a with various alkenyl phosphates. aA mixture of E- and Z-alkenyl phosphate (ca. 1:1) ...
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The cyclization of o-alkenylpivalophenone N–H imine.
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Proposed catalytic cycle (R = t-BuCH2, R' = P(O)(OEt)2).
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Beilstein J. Org. Chem. 2018, 14, 709–715, doi:10.3762/bjoc.14.60
(a) Cobalt-catalyzed C2-alkenylation of N-pyrimidylindole, (b) ortho-alkylation of aryl imine, and ...
Addition of N-pyrimidylindoles to vinylsilanes.
Addition of N-pyrimidylindole to norbornene (a) and 1-octene (b).
Gram-scale reaction and deprotection of N-pyrimidyl group.
Beilstein J. Org. Chem. 2012, 8, 1536–1542, doi:10.3762/bjoc.8.174
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