Beilstein J. Org. Chem.2013,9, 2470–2475, doi:10.3762/bjoc.9.286
yields. Unsymmetrical di-coupled products 4 were obtained in high yields from the reactions of 3 with 2 equiv of boronic acids in the presence of catalytic amounts of Pd(OAc)2 and Na2CO3.
Keywords: boronic acids; cross-coupling reaction; 1,1-diaryl-2,2-difluoroethene; 1,1-difluoro-1,3-dienes; 2,2
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Graphical Abstract
Scheme 1:
Preparation of 2,2-difluoro-1-iodoethenyl tosylate (2).