Amplified cross-linking efficiency of self-assembled monolayers through targeted dissociative electron attachment for the production of carbon nanomembranes

• Sascha Koch,
• Christopher D. Kaiser,
• Paul Penner,
• Michael Barclay,
• Lena Frommeyer,
• Daniel Emmrich,
• Patrick Stohmann,
• Tarek Abu-Husein,
• Andreas Terfort,
• D. Howard Fairbrother,
• Oddur Ingólfsson and
• Armin Gölzhäuser

Beilstein J. Nanotechnol. 2017, 8, 2562–2571, doi:10.3762/bjnano.8.256

• process in the gas phase (Figure 1) shows that the relative difference between 2-Cl-BPT and 2-Br-BPT is less clear in the SAMs. This is to be expected due to the different conditions in the condensed phase as compared to the gas phase, for example, different temperatures and additional energy dissipation

Material property analytical relations for the case of an AFM probe tapping a viscoelastic surface containing multiple characteristic times

• Enrique A. López-Guerra and
• Santiago D. Solares

Beilstein J. Nanotechnol. 2017, 8, 2230–2244, doi:10.3762/bjnano.8.223

• energy hysteresis). Interestingly, energy dissipation in this case is not exclusively proportional to the loss modulus as in the case of steady-state harmonic applications (e.g., DMA, see Equation 8). It is evident that substantial complexity is generated in the analytical relations derived when the

• system does not achieve steady-state (compare Equation 8 to Equation 30). The above is natural because in the tapping case the force is not harmonic (Equation 29), and therefore, its convolution with velocity (Equation 6) to obtain energy dissipation results in a much more complex solution than in the

• parameters) and Zeq. Fortunately, San Paulo and García [18] have shown that, besides energy dissipation, it is possible to obtain another meaningful energy quantity defined as the convolution of the tip–sample interaction force with the tip deflection [44], as described in Equation 9. This is the virial that

Velocity dependence of sliding friction on a crystalline surface

• Christian Apostoli,
• Giovanni Giusti,
• Jacopo Ciccoianni,
• Gabriele Riva,
• Rosario Capozza,
• Rosalie Laure Woulaché,
• Andrea Vanossi,
• Emanuele Panizon and
• Nicola Manini

Beilstein J. Nanotechnol. 2017, 8, 2186–2199, doi:10.3762/bjnano.8.218

• ; (iv) adopt, rather than a harmonic crystal, a realistic force field modeling a specific substrate, with the target of predicting the frictional dynamic features of a specific interface as was done, e.g., in [49][65]; (v) energy dissipation implemented through suitably remote boundary-atom thermostats

Oxidative stabilization of polyacrylonitrile nanofibers and carbon nanofibers containing graphene oxide (GO): a spectroscopic and electrochemical study

• İlknur Gergin,
• Ezgi Ismar and
• A. Sezai Sarac

Beilstein J. Nanotechnol. 2017, 8, 1616–1628, doi:10.3762/bjnano.8.161

• -independent experimental constants; TCPE relates to the size, thickness, and materials properties, while n relates to the degree of energy dissipation and measures the arc depression, which is frequency-independent. Moreover, n is a parameter describing the deviation from an ideal capacitor and arises from

Miniemulsion copolymerization of (meth)acrylates in the presence of functionalized multiwalled carbon nanotubes for reinforced coating applications

• Bertha T. Pérez-Martínez,
• Lorena Farías-Cepeda,
• Víctor M. Ovando-Medina,
• José M. Asua,
• Lucero Rosales-Marines and
• Radmila Tomovska

Beilstein J. Nanotechnol. 2017, 8, 1328–1337, doi:10.3762/bjnano.8.134

• in an augmentation of the storage modulus (i.e., stiffness) over the entire temperature range. In addition, the loss modulus of the composites was also higher than that of the blank polymer (Figure 4b), namely the energy dissipation as heat was promoted. This may be due to an additional energy

• dissipation mechanism when the MWCNTs slide at the interface with polymer in presence of PVP, as previously reported in case of organic/inorganic hybrids [43]. The strong polymer–MWCNT interaction substantially improves the mechanical properties of the in situ composites, particularly at high temperatures

Impact of surface wettability on S-layer recrystallization: a real-time characterization by QCM-D

• Jagoba Iturri,
• Ana C. Vianna,
• Alberto Moreno-Cencerrado,
• Dietmar Pum,
• Uwe B. Sleytr and
• José Luis Toca-Herrera

Beilstein J. Nanotechnol. 2017, 8, 91–98, doi:10.3762/bjnano.8.10

• -layers on different supports [17][18]. The QCM-D responses, i.e., the resonance frequency f and the energy dissipation D of the shear oscillatory motion of a piezoelectric quartz crystal sensor, change upon adsorption or desorption of material on the surface of that sensor. The measured parameters are

Structural and tribometric characterization of biomimetically inspired synthetic "insect adhesives"

• Matthias W. Speidel,
• Malte Kleemeier,
• Andreas Hartwig,
• Klaus Rischka,
• Angelika Ellermann,
• Rolf Daniels and
• Oliver Betz

Beilstein J. Nanotechnol. 2017, 8, 45–63, doi:10.3762/bjnano.8.6

• influence of the energy dissipation in the viscoelastic cuticle, which provides additional resistance towards separation. This suggests that natural insect tarsal adhesives actually show only low adhesive strengths that are in the range of a few kilopascal. Such properties have been produced especially in

Influence of ambient humidity on the attachment ability of ladybird beetles (Coccinella septempunctata)

• Lars Heepe,
• Jonas O. Wolff and
• Stanislav N. Gorb

Beilstein J. Nanotechnol. 2016, 7, 1322–1329, doi:10.3762/bjnano.7.123

• ) humidity-dependent material properties of insect cuticle and β-keratin (main constituent of gecko setae) [41][42][43][44]. In geckos, the effect of a RH on viscoelastic properties of the setal shaft was shown [13]. It was argued that with an increasing humidity the viscoelastic bulk energy dissipation

• about where tarsal liquids are actually secreted and delivered in hairy attachment pads of beetles. Moreover, assuming capillarity to be responsible for the generated traction forces, it is not clear how the proposed increase in the viscoelastic bulk energy dissipation with increasing humidity should

Advanced atomic force microscopy techniques III

• Thilo Glatzel and
• Thomas Schimmel

Beilstein J. Nanotechnol. 2016, 7, 1052–1054, doi:10.3762/bjnano.7.98

• . Combined AFM and STM measurements reveal related force and electronic properties [9], energy dissipation in manipulation processes can be examined via the excitation voltage needed to keep a constant amplitude of the probe oscillation [10][11], pulling forces of atomic or molecular wires can be determined

The influence of phthalocyanine aggregation in complexes with CdSe/ZnS quantum dots on the photophysical properties of the complexes

• Irina V. Martynenko,
• Anna O. Orlova,
• Vladimir G. Maslov,
• Anatoly V. Fedorov,
• Kevin Berwick and
• Alexander V. Baranov

Beilstein J. Nanotechnol. 2016, 7, 1018–1027, doi:10.3762/bjnano.7.94

• PL of tetrapyrrole molecules [26]. In nonconjugated complexes of cysteamine-capped QDs and chlorin e6 additional channels of nonradiative energy dissipation in QDs and/or in chlorin e6 took place when the relative chlorin e6 concentration in the mixture was increased [19][27]. Aggregation of acceptor

Thermo-voltage measurements of atomic contacts at low temperature

• Ayelet Ofarim,
• Bastian Kopp,
• Thomas Möller,
• León Martin,
• Johannes Boneberg,
• Paul Leiderer and
• Elke Scheer

Beilstein J. Nanotechnol. 2016, 7, 767–775, doi:10.3762/bjnano.7.68

• temperature gradients into electrical energy and for the local energy dissipation. More fundamentally, the study of thermoelectric effects in atomic-scale nanostructures and in molecular junctions gives important additional information of charge transport [2][3][4]. The thermopower is quantified by the

Coupled molecular and cantilever dynamics model for frequency-modulated atomic force microscopy

• Michael Klocke and
• Dietrich E. Wolf

Beilstein J. Nanotechnol. 2016, 7, 708–720, doi:10.3762/bjnano.7.63

• . It is shown how this may lead to a systematic shift between the periodic patterns obtained from the frequency and from the damping signal, respectively. Keywords: atomic force microscopy; frequency-modulated atomic force microscopy (FM-AFM); energy dissipation; Introduction The physical background

• ). Energy dissipation sets in abruptly as soon as the nominal distance drops below d < 1.2 and is basically constant for smaller distances. This is a typical sign for adhesion hysteresis: The sudden configurational change happens only if the tip comes close enough to the surface. Once it happened, the

• oppositely charged. The results, Figure 8, are clear indication of adhesion hysteresis: energy dissipation sets in abruptly as soon as the tip approaches the substrate closer than (nominally) 5.4 Å. At that point, also the reduced frequency shift γ = (Δf/fz)kzA3/2 changes abruptly. (The reduced frequency

Controlled graphene oxide assembly on silver nanocube monolayers for SERS detection: dependence on nanocube packing procedure

• Martina Banchelli,
• Bruno Tiribilli,
• Roberto Pini,
• Luigi Dei,
• Paolo Matteini and
• Gabriella Caminati

Beilstein J. Nanotechnol. 2016, 7, 9–21, doi:10.3762/bjnano.7.2

• energy dissipation of a SiO2-coated AT-cut 5 MHz quartz microcrystal were simultaneously measured at its resonant frequency and at the third, fifth, seventh, ninth and eleventh overtones. The temperature of the measuring cell was kept constant at 20 °C with a Peltier element connected to the TE module

Optimization of phase contrast in bimodal amplitude modulation AFM

• Mehrnoosh Damircheli,
• Amir F. Payam and
• Ricardo Garcia

Beilstein J. Nanotechnol. 2015, 6, 1072–1081, doi:10.3762/bjnano.6.108

• map compositional variations under the influence of conservative forces is a main advantage with respect to AFM phase imaging (tapping mode AFM), where the phase contrast is related to variations in energy dissipation [33]. In AM-AFM there are two interacting regimes, attractive and repulsive [2]. The

• function of the amplitude ratio, the amplitude values of the second mode and the kinetic energy ratios of the excited modes. We also study the phase contrast between different materials by including energy dissipation in the tip–sample interaction, by inverting the roles of the excited modes (indirect

• effect of energy dissipation in the bimodal phase contrast, in addition the above conservative force, we introduce the following non-conservative interaction [47]: The power dissipated in the sample for each mode is calculated by [47] Figure 3a,b show the dependence of versus A1/A01 when the tip–sample

Stick–slip behaviour on Au(111) with adsorption of copper and sulfate

• Nikolay Podgaynyy,
• Sabine Wezisla,
• Christoph Molls,
• Shahid Iqbal and
• Helmut Baltruschat

Beilstein J. Nanotechnol. 2015, 6, 820–830, doi:10.3762/bjnano.6.85

• of stick–slip behaviour at normal loads of less than 15 nN. In spite of non-stick–slip resolution the contact between tip and surface is preserved and energy dissipation is still observed. A transition to superlubricity would involve disappearing friction [35][36]. Since this is not the case here one

• investigated. Friction is minimal at the potential of zero charge, suggesting again the role of adsorbates for frictional energy dissipation. On the other hand, friction is particularly large when the adlayer is disordered at the potential of a phase transition, as shown here for the formation of the √3 × √3

Capillary and van der Waals interactions on CaF₂ crystals from amplitude modulation AFM force reconstruction profiles under ambient conditions

• Annalisa Calò,
• Oriol Vidal Robles,
• Sergio Santos and
• Albert Verdaguer

Beilstein J. Nanotechnol. 2015, 6, 809–819, doi:10.3762/bjnano.6.84

• contributions to the net energy dissipation by their physical origin and/or distance-dependence [34] has been the object of recent efforts in the direction of performing quantitative measurements with the AFM [35][36]. For example, Gadelrab and coauthors showed that the difference in the phase signal compared

• follows that if there is no energy dissipation, ΔΦ = 0. Numerical integration method The standard (single mode) equation of motion [27][51] of the cantilever has been implemented in the programming language C and solved with the use of a standard Euler algorithm, where ω is the angular drive frequency

• position. The reconstruction of the conservative force and the determination of the energy dissipation have been carried out by implementing the expressions in Equation 2 and Equation 4 in Matlab [53]. The raw amplitude and phase data have been processed both when dealing with the experimental data and

Entropy effects in the collective dynamic behavior of alkyl monolayers tethered to Si(111)

• Christian Godet

Beilstein J. Nanotechnol. 2015, 6, 583–594, doi:10.3762/bjnano.6.60

• chain segments located away from the head towards the molecular tail. The strain-induced formation of gauche defects, initiating at outer bonds (end-gauche) and proceeding inward (kinks and gauche–gauche conformers) [3][17][22] results into a disorder gradient. Another important issue related to energy

• dissipation mechanisms is the behavior of tethered OML under compressive and shear forces, as found in nano-tribology experiments, where external forces can cause conformational changes. Again, a disorder gradient results from the formation of gauche defects which can be reverted when the atomic force

A scanning probe microscope for magnetoresistive cantilevers utilizing a nested scanner design for large-area scans

• Tobias Meier,
• Alexander Förste,
• Ali Tavassolizadeh,
• Karsten Rott,
• Dirk Meyners,
• Roland Gröger,
• Günter Reiss,
• Eckhard Quandt,
• Thomas Schimmel and
• Hendrik Hölscher

Beilstein J. Nanotechnol. 2015, 6, 451–461, doi:10.3762/bjnano.6.46

• , atomic step edges of 2.54 Å height are resolved. For dynamic-mode experiments, the phase-shift signal is of high interest as it provides information about energy dissipation between tip and sample [60][61] and visualizes chemical contrasts [62]. To demonstrate this kind of measurement also with our TMR

• topography contrast in ambient conditions is most likely caused by the thin water films present on hydrophilic SiOx under ambient conditions [65]. This effect obscures the height difference between the FDTS and SiOx. However, as shown in Figure 7a, the difference of the energy dissipation between the two

• sample system, dissipative tip–sample forces are dominant. Therefore, a high phase-signal contrast can be observed and reveals the different materials of the sample due to different energy dissipation between tip and sample while the amplitude-signal feedback reveals no topographic features. b) On such

Dynamic force microscopy simulator (dForce): A tool for planning and understanding tapping and bimodal AFM experiments

• Horacio V. Guzman,
• Pablo D. Garcia and
• Ricardo Garcia

Beilstein J. Nanotechnol. 2015, 6, 369–379, doi:10.3762/bjnano.6.36

• ]. They explained the origin of the phase contrast observed on heterogeneous samples by tapping mode AFM in air [3] and liquid [4][5]. In the process, simulations validated the theory of AFM phase imaging in air [6][7], its use to identify energy dissipation processes [7] or to measure the energy

High-frequency multimodal atomic force microscopy

• Adrian P. Nievergelt,
• Jonathan D. Adams,
• Pascal D. Odermatt and
• Georg E. Fantner

Beilstein J. Nanotechnol. 2014, 5, 2459–2467, doi:10.3762/bjnano.5.255

• resonance. Panels b and e show the resonance frequency shift of the first higher resonant mode, and panels c and f show the drive amplitude needed to keep the first higher resonant mode at constant amplitude, related to the energy dissipation in the tip–sample interaction. a) Schematic of the drive

Modeling viscoelasticity through spring–dashpot models in intermittent-contact atomic force microscopy

• Enrique A. López-Guerra and
• Santiago D. Solares

Beilstein J. Nanotechnol. 2014, 5, 2149–2163, doi:10.3762/bjnano.5.224

• quantitative information about the dissipative and conservative tip–sample interactions by converting them to energy-based quantities, namely the dissipated power (Pts) and virial (Vts) [9][11]. Although several authors have achieved quantification of energy dissipation processes [12][13][14][15], the further

• Figure 4. Results of energy dissipation when a numerically simulated tip trajectory in intermittent contact AFM interacts with a Nafion model. (a) shows force–distance curves for tips driven at different eigenfrequencies (color coded). The inset in (a) shows the behavior of the dissipation as the

• use were: ke = 20 N/m, k1 = 10 N/m, k2 = 5 N/m, and c1 = c2 = 1.0 × 10−5 N·s/m. Time normalization has been carried out in (c) with respect to the fundamental period for ease of comparison. Results of energy dissipation when a tip interacts with a Nafion model under a numerically simulated trajectory

Dissipation signals due to lateral tip oscillations in FM-AFM

• Michael Klocke and
• Dietrich E. Wolf

Beilstein J. Nanotechnol. 2014, 5, 2048–2057, doi:10.3762/bjnano.5.213

• force microscopy (AFM); frequency-modulated atomic force microscopy (FM-AFM); energy dissipation; Introduction The usage of scanning probe microscopes requires an understanding of the physical processes during the scan, otherwise images can be misinterpreted. Due to the importance of frequency

• -modulated atomic force microscopy (FM-AFM), the physical processes involved have been studied intensively in the past [1]. This includes the relation between tip–surface interaction and frequency-shift [2], as well as features such as the energy dissipation during the scan [3], which is an interesting side

• for the understanding and correction of certain distortions seen in the actual images. Here, we enhance these studies by taking lateral dynamics of the tip into account and study the effect on the topography as well as on the energy dissipation signal. It is necessary to distinguish between the terms

Controlling the optical and structural properties of ZnS–AgInS₂ nanocrystals by using a photo-induced process

• Takashi Yatsui,
• Fumihiro Morigaki and
• Tadashi Kawazoe

Beilstein J. Nanotechnol. 2014, 5, 1767–1773, doi:10.3762/bjnano.5.187

• -radiative energy dissipation, and resulted in the increase of the emission intensity of the band edge. Using the emission spectra to control the nanocrystal size For the investigation of ways to control the size of ZAIS nanocrystals, we synthesized ZAIS nanocrystals with 532 nm irradiation (λ2) during the

Probing viscoelastic surfaces with bimodal tapping-mode atomic force microscopy: Underlying physics and observables for a standard linear solid model

• Santiago D. Solares

Beilstein J. Nanotechnol. 2014, 5, 1649–1663, doi:10.3762/bjnano.5.176

• ] and Garcia et al. [31] proved mathematically that when tip–sample energy dissipation is absent, the phase shift remains unchanged even if the elastic properties of the sample are non-uniform across the surface. This enables the user to directly map variations in energy dissipation based on the phase

• to obtain images of the sample topography, energy dissipation and elasticity of polymer surfaces immersed in a liquid environment [16]. We have also reported experiments in which images of Vts and Pts were compared for different control schemes applied to the higher mode, including open loop

Probing the electronic transport on the reconstructed Au/Ge(001) surface

• Franciszek Krok,
• Mark R. Kaspers,
• Alexander M. Bernhart,
• Marek Nikiel,
• Benedykt R. Jany,
• Paulina Indyka,
• Mateusz Wojtaszek,
• Rolf Möller and
• Christian A. Bobisch

Beilstein J. Nanotechnol. 2014, 5, 1463–1471, doi:10.3762/bjnano.5.159

• financial support from the Deutsche Forschungsgemeinschaft under the program “SFB616: Energy Dissipation at Surfaces” and the Polish National Science Center, grant no. DEC-2012/07/B/ST5/00906. Part of the research was carried out with equipment purchased with financial support from the European Regional