Quantification of lead through rod-shaped silver-doped zinc oxide nanoparticles using an electrochemical approach

• Ravinder Lamba,
• Gaurav Bhanjana,
• Neeraj Dilbaghi,
• Vivek Gupta and
• Sandeep Kumar

Beilstein J. Nanotechnol. 2025, 16, 422–434, doi:10.3762/bjnano.16.33

• different types of oxygen species (one at 528 eV due to lattice oxygen of ZnO and another at 530 eV due to presence of surface hydroxy group) [25][26]. Cyclic voltammetry of modified Ag@ZnO nanorods/gold electrode Figure 8 presents the results of an impedance analysis using a frequency-response analyzer

• (FRA) potentiostat on both fabricated Ag–ZnO/Au electrodes and bare gold electrodes. The modified Ag@ZnO NRs electrode exhibits higher impedance than that of the bare gold electrode. This higher impedance leads to better sensitivity, better electron exchange, and can provide more information about the

• nanorods was generated and coated onto a gold electrode. The modified electrode was then dried to form a chemical sensor specifically designed for the detection of lead. The performance of the sensor, including sensitivity, correlation coefficient, and detection limit, was evaluated using cyclic

Size control of nanoparticles synthesized by pulsed laser ablation in liquids using donut-shaped beams

• Abdel Rahman Altakroury,
• Oleksandr Gatsa,
• Farbod Riahi,
• Zongwen Fu,
• Miroslava Flimelová,
• Andrei Samokhvalov,
• Stephan Barcikowski,
• Carlos Doñate-Buendía,
• Alexander V. Bulgakov and
• Bilal Gökce

Beilstein J. Nanotechnol. 2025, 16, 407–417, doi:10.3762/bjnano.16.31

• laser beam. In experiments on pulsed laser ablation in water of gold, yttrium oxide, and high-entropy alloy targets with both Gaussian and donut-shaped beams, we observed a significant reduction in particle size, narrowing of the size distribution width, and an improvement in sphericity when utilizing

• this pioneering study, further investigation with higher temporal and spatial resolution are warranted. Keywords: beam shaping; cavitation bubble; donut beam; gold nanoparticles; high-entropy alloy nanoparticles; nanoparticle size analysis; yttrium oxide nanoparticles; Introduction The demand for

• the size, requiring a monodisperse or at least monomodal size distribution. As an example, gold NPs with a narrow particle size distribution achieve a higher detection sensitivity in sensing applications [9]. Besides, NP size is critical for biomedical applications, where deviations from the optimum

ReactorAFM/STM – dynamic reactions on surfaces at elevated temperature and atmospheric pressure

• Tycho Roorda,
• Hamed Achour,
• Matthijs A. van Spronsen,
• Marta E. Cañas-Ventura,
• Sander B. Roobol,
• Willem Onderwaater,
• Mirthe Bergman,
• Peter van der Tuijn,
• Gertjan van Baarle,
• Johan W. Bakker,
• Joost W. M. Frenken and
• Irene M. N. Groot

Beilstein J. Nanotechnol. 2025, 16, 397–406, doi:10.3762/bjnano.16.30

• detection method with a laser diode, which is not compatible with the design limitations of a reactor volume of 95 μL. Figure 3a shows a zoomed-in image of a third-generation M5B qPlus sensor (purchased from Nanosurf). The sensor has four gold electrodes of which three are used for AFM drive and readout

• non-conductive epoxy. The metallic sections are then coated with gold to ensure catalytic inertness and slide over tracks that serve as electrical feedthrough. The wiring from the QTF electrodes to the holder is made with 25 μm-diameter gold wire glued with conductive epoxy (EpoTek H20E). The holder

• a CaCl2 electrolytic solution (CaCl2 5 g, H2O 30 mL, acetone 2 mL). An alternating current (AC) voltage (50 Hz, 1–10 V) is applied between the tip and a gold ring electrode with the etching solution in suspension resulting in a sharp tip, which serves as the probe. In a second step, the etched Pt/Ir

Engineered PEG–PCL nanoparticles enable sensitive and selective detection of sodium dodecyl sulfate: a qualitative and quantitative analysis

• Soni Prajapati and
• Ranjana Singh

Beilstein J. Nanotechnol. 2025, 16, 385–396, doi:10.3762/bjnano.16.29

• microscopy (SEM). The nanoparticles obtained from the 10 mg/mL stock solution were diluted 100-fold for the SEM analysis. The slide for SEM imaging was prepared with a sputter coating of gold as a conductive material, followed by the addition of 10 μL of nanoparticles, and air drying. The imaging was

Development of a mucoadhesive drug delivery system and its interaction with gastric cells

• Ahmet Baki Sahin,
• Serdar Karakurt and
• Deniz Sezlev Bilecen

Beilstein J. Nanotechnol. 2025, 16, 371–384, doi:10.3762/bjnano.16.28

• with gold (4 nm). STEM micrographs were obtained from one drop of nanoparticle suspension dripped on an ultrathin carbon-coated copper grid. Surface composition of nanoparticles For the analysis of various functional groups on the surface of nanoparticles before and after coating, attenuated total

Pulsed laser in liquid grafting of gold nanoparticle–carbon support composites

• Madeleine K. Wilsey,
• Teona Taseska,
• Qishen Lyu,
• Connor P. Cox and
• Astrid M. Müller

Beilstein J. Nanotechnol. 2025, 16, 349–361, doi:10.3762/bjnano.16.26

• , University of Rochester, Rochester, New York 14627, United States 10.3762/bjnano.16.26 Abstract We developed a novel pulsed laser-assisted process for the fabrication of advanced composites of nonequilibrium gold nanoparticles on carbon fiber paper supports. Our one-step process integrates the generation of

• nanoparticles with their surface attachment and solves longstanding nanoparticle adhesion and electrical contact issues. Irradiation of hydrophilic carbon fiber paper submerged in aqueous HAuCl4 solution by nanosecond laser pulses produced composites with uniform distribution of gold nanoparticles on carbon

• fibers, taking advantage of the high internal surface area of carbon fiber paper. The pulsed laser-grafted composites exhibited zero measurable charge transfer resistance between gold nanoparticles and the carbon support, leading to superior cathode performance over conventionally prepared electrodes for

Preferential enrichment and extraction of laser-synthesized nanoparticles in organic phases

• Theo Fromme,
• Maximilian L. Spiekermann,
• Florian Lehmann,
• Stephan Barcikowski,
• Thomas Seidensticker and
• Sven Reichenberger

Beilstein J. Nanotechnol. 2025, 16, 254–263, doi:10.3762/bjnano.16.20

• ) to determine the preferred phase (1-nonanol or propylene carbonate) of the colloidal nanoparticles (Figure 1a,b). For gold and silver, the nanoparticles remained in the propylene carbonate phase, which is the more polar phase, while the nanoparticles made by LAL of aluminum and titanium were found to

• noble metals accumulating in the propylene carbonate phase, while base metals gather in the alcohol phase. The origin of this behavior is likely linked to the chemical composition of the nanoparticle surface. In earlier studies, nanoparticles of the more noble metals (gold, silver, and copper) formed by

• LAL in alcohols, ketones, or aliphatic hydrocarbons exhibited a carbon shell [7][11][52]. These carbon shells were particularly pronounced for gold and copper nanoparticles synthesized in hydrocarbons without a heteroatom. However, differences were found for the LAL in, for example, acetone. The LAL

Radiosensitizing properties of dual-functionalized carbon nanostructures loaded with temozolomide

• Radmila Milenkovska,
• Nikola Geskovski,
• Dushko Shalabalija,
• Ljubica Mihailova,
• Petre Makreski,
• Dushko Lukarski,
• Igor Stojkovski,
• Maja Simonoska Crcarevska and
• Kristina Mladenovska

Beilstein J. Nanotechnol. 2025, 16, 229–251, doi:10.3762/bjnano.16.18

• chemical modifications and/or coupling with hydrophilic polymers. TMZ was successfully incorporated in magnetic NPs [36], mesoporous silica NPs [37], and NPs made of silver [38], zinc oxide [39], and gold [40], all of them showing high accumulation in tumor cells and cytotoxic activity in vitro and in vivo

Recent advances in photothermal nanomaterials for ophthalmic applications

• Jiayuan Zhuang,
• Linhui Jia,
• Chenghao Li,
• Rui Yang,
• Jiapeng Wang,
• Wen-an Wang,
• Heng Zhou and
• Xiangxia Luo

Beilstein J. Nanotechnol. 2025, 16, 195–215, doi:10.3762/bjnano.16.16

• adjacent healthy cells [109]. After eliminating tumor cells, small gold nanorods can penetrate the blood–brain barrier and be effectively excreted from the body through renal excretion, thereby avoiding the production of VNBs near non-cancerous cells. 3.2 Posterior capsule opacity after cataract surgery

• PAI contrast agents [195][196]. Gold nanorods [197], gold nanostars [198], hollow gold nanocages [199], chains of gold nanoparticles [200], and ultraminiature chain-like gold nanoparticle clusters [201] have been used for the detection of ocular structures such as retinal blood vessels, choroidal

Probing the potential of rare earth elements in the development of new anticancer drugs: single molecule studies

• Josiane A. D. Batista,
• Rayane M. de Oliveira,
• Carlos H. M. Lima,
• Milton L. Lana Júnior,
• Virgílio C. dos Anjos,
• Maria J. V. Bell and
• Márcio S. Rocha

Beilstein J. Nanotechnol. 2025, 16, 187–194, doi:10.3762/bjnano.16.15

• fact that some metals have been successfully used, or are being investigated, as components of chemotherapeutic drugs [9][10], especially platinum [11][12][13][14][15][16] or, alternatively, ruthenium [17], titanium [18], gold, and copper. Here we report the high potential of three rare earth elements

Nanocarriers and macrophage interaction: from a potential hurdle to an alternative therapeutic strategy

• Naths Grazia Sukubo,
• Paolo Bigini and
• Annalisa Morelli

Beilstein J. Nanotechnol. 2025, 16, 97–118, doi:10.3762/bjnano.16.10

• such as iron and gold [4][5]. Each material is chosen for its unique properties, such as size, hydrophilicity, and charge, that make it suitable for acting as a drug carrier. NCs can be functionalized on their surface to improve the stability and solubility of high-payload encapsulated cargos, promote

• normal liver tissue [98]. This targeted approach allows for the selective delivery of therapeutic agents to cancer cells, sparing healthy cells and reducing systemic toxicity. For example, gold NPs functionalized with antibodies against GPC3 have been used in photothermal therapy to selectively kill

• ultrastructural changes in macrophages, providing nanoscale insights into inflammation. The efficiency of gold NP (AuNP)-loaded macrophages as a targeted delivery system was tested in an ovalbumin-induced asthma mouse model. Findings showed significant macrophage–NP interactions, highlighting the potential of

Advanced atomic force microscopy techniques V

• Philipp Rahe,
• Ilko Bald,
• Nadine Hauptmann,
• Regina Hoffmann-Vogel,
• Harry Mönig and
• Michael Reichling

Beilstein J. Nanotechnol. 2025, 16, 54–56, doi:10.3762/bjnano.16.6

• carry out a more detailed characterization of the optoelectronic properties. Rothhardt et al. map the local work function on graphene nanoribbons [7]. They experimentally investigate the charge transfer between a gold substrate and graphene nanoribbons and compare that to DFT calculations. Indeed, the

Precursor sticking coefficient determination from indented deposits fabricated by electron beam induced deposition

• Alexander Kuprava and
• Michael Huth

Beilstein J. Nanotechnol. 2025, 16, 35–43, doi:10.3762/bjnano.16.4

• growth regime has to be assessed. Using the parameters reported in [10][11], an estimation of the secondary electron (SE) surface flux of 5.4 × 105 nm−2·s−1 at the BIR center with a 1400 nm wide beam at 5 keV and 400 nA on a gold-covered substrate and precursor flux estimation of 1900 nm−2·s−1, the

Orientation-dependent photonic bandgaps in gold-dust weevil scales and their titania bioreplicates

• Norma Salvadores Farran,
• Limin Wang,
• Primoz Pirih and
• Bodo D. Wilts

Beilstein J. Nanotechnol. 2025, 16, 1–10, doi:10.3762/bjnano.16.1

• 10.3762/bjnano.16.1 Abstract The scales of the gold-dust weevil Hypomeces squamosus are green because of three-dimensional diamond-type chitin–air photonic crystals with an average periodicity of about 430 nm and a chitin fill fraction of about 0.44. A single scale usually contains one to three

• complex biological structures and obtaining photonic crystals with desired optical properties [23][24]. In this work, we characterized natural photonic crystals found in the scales of the gold-dust weevil, Hypomeces squamosus (Coleoptera: Curculionidae; Herbst 1795), a pest of several crops [25][26][27

• orientations, we obtained a uniform diffuse green scatterogram, confirming the mechanism producing the dull, unsaturated overall coloration found on the gold-dust weevil and several other weevils [19][21][28]. Subsequently, using plasma etching, we removed the scale cortex and made negative titania replicas of

Attempts to preserve and visualize protein corona on the surface of biological nanoparticles in blood serum using photomodification

• Julia E. Poletaeva,
• Anastasiya V. Tupitsyna,
• Alina E. Grigor’eva,
• Ilya S. Dovydenko and
• Elena I. Ryabchikova

Beilstein J. Nanotechnol. 2024, 15, 1654–1666, doi:10.3762/bjnano.15.130

• regarding the presence of a protein corona in TEM. Isolation of bio-NPs using ultracentrifugation UC is still a gold standard for the isolation of EVs from biological fluids [11][25], and we started the isolation of corona-bearing bio-NPs using this method (Figure 2d1). The same procedure was used to

Biomimetic nanocarriers: integrating natural functions for advanced therapeutic applications

• Hugo Felix Perini,
• Beatriz Sodré Matos,
• Carlo José Freire de Oliveira and
• Marcos Vinicius da Silva

Beilstein J. Nanotechnol. 2024, 15, 1619–1626, doi:10.3762/bjnano.15.127

• nanotechnology, introduced by Richard Feynman in 1959 during an American Physical Society meeting [1][2], involves the manipulation of matter at the atomic level. The term "nanometer" was initially proposed by Richard Zsigmondy in the context of measuring gold colloids. Nanotechnology is generally defined as the

• neuronal mitochondria, as evidenced by fluorescence intensities identified in brain homogenates, and reduced Aβ1 deposition, demonstrating the ability of the nanocomposite to cross the BBB [71]. Inorganic nanoparticles exhibit unique optical, magnetic, and chemical properties and stability. Gold

Facile synthesis of size-tunable L-carnosine-capped silver nanoparticles and their role in metal ion sensing and catalytic degradation of p-nitrophenol

• Akash Kumar,
• Ridhima Chadha,
• Abhishek Das,
• Nandita Maiti and
• Rayavarapu Raja Gopal

Beilstein J. Nanotechnol. 2024, 15, 1576–1592, doi:10.3762/bjnano.15.124

• al., where different shapes of gold nanoparticles had varying efficiencies in the catalytic degradation of nitrophenol compounds, with spherical nanoparticles being highly effective [48]. Kinetic analysis was performed based on pseudo-first-order reaction kinetics for the concentration of 0.25 mM P

Ultrablack color in velvet ant cuticle

• Vinicius Marques Lopez,
• Wencke Krings,
• Juliana Reis Machado,
• Stanislav Gorb and
• Rhainer Guillermo-Ferreira

Beilstein J. Nanotechnol. 2024, 15, 1554–1565, doi:10.3762/bjnano.15.122

• characteristics of cuticle cross sections, we prepared the samples by sectioning, allowing for the visualization of the underlying structures. Prior to SEM imaging, a thin layer of gold–palladium, 10 nm thick, was applied to the samples. We utilized a Hitachi S-4800 SEM, operating at 3 kV. Images were captured at

Effect of radiation-induced vacancy saturation on the first-order phase transformation in nanoparticles: insights from a model

• Aram Shirinyan and
• Yuriy Bilogorodskyy

Beilstein J. Nanotechnol. 2024, 15, 1453–1472, doi:10.3762/bjnano.15.117

• film through in situ ion irradiation, observed using atomic-resolution transmission electron microscopy [16]. The gold sample was irradiated with 2.8 MeV Au4+ ions at 200 °C with a fluence of approximately 1014 ions·cm−2 (equivalent to a dose of 10 dpa). A combination of surface- and radiation-induced

A biomimetic approach towards a universal slippery liquid infused surface coating

• Ryan A. Faase,
• Madeleine H. Hummel,
• AnneMarie V. Hasbrook,
• Andrew P. Carpenter and
• Joe E. Baio

Beilstein J. Nanotechnol. 2024, 15, 1376–1389, doi:10.3762/bjnano.15.111

• Microscopy Sciences). Samples were sputter-coated with gold/palladium (Cressington 108A) and imaged on a scanning electron microscope (SEM) (FEI Quanta 600F). ImageJ was used to measure fiber diameter and clot density. Clot density was determined by drawing a line through the image and counting the number of

Green synthesis of carbon dot structures from Rheum Ribes and Schottky diode fabrication

• Muhammed Taha Durmus and
• Ebru Bozkurt

Beilstein J. Nanotechnol. 2024, 15, 1369–1375, doi:10.3762/bjnano.15.110

• steady-state fluorescence measurements. In the second part of the study, CDs were dripped onto silicon substrates, and a CDs thin film was formed by evaporation. A diode structure was obtained by evaporating gold with the shadow mask technique on the CDs film, and the current–voltage characteristics of

• dried to synthesize CDs. Acetone, methanol, silicon, gold powder, and aluminum were purchased from Sigma-Aldrich, Merck, and Alfa Aesar. All studies were carried out at room temperature. Instruments Various devices were used for the structural, morphological, and optical characterization of the CDs. FEI

• and diluted with 5 mL of pure water; 100 μL of this solution was dripped onto the silicon substrate and evaporated at room temperature. In the last stage, the diode structure was obtained by evaporating gold onto the created CDs film using the shadow mask technique (Figure 1). The size of the diode

Investigation of Hf/Ti bilayers for the development of transition-edge sensor microcalorimeters

• Victoria Y. Safonova,
• Anna V. Gordeeva,
• Anton V. Blagodatkin,
• Dmitry A. Pimanov,
• Anton A. Yablokov and
• Andrey L. Pankratov

Beilstein J. Nanotechnol. 2024, 15, 1353–1361, doi:10.3762/bjnano.15.108

• temperature to the required values because of the proximity effect. One of the most common pairs is titanium with gold [1][8]. Moreover, there are at least two materials that in pure form already possess TC close to the required value, iridium with a critical temperature of 112 mK [9] and hafnium with one of

• in different transition temperatures at heating and cooling. The presumed reason is the heating of the film sample C1 through the measuring pogo pin contacts made of gold-coated brass and the contact resistance between the contacts and the film. Samples A1–A4 and B1 were measured through the same

Nanoarchitectonics with cetrimonium bromide on metal nanoparticles for linker-free detection of toxic metal ions and catalytic degradation of 4-nitrophenol

• Akash Kumar and
• Raja Gopal Rayavarapu

Beilstein J. Nanotechnol. 2024, 15, 1312–1332, doi:10.3762/bjnano.15.106

• metals and efficient degradation of 4-NP. For enabling linker-free/ligand-free detection of heavy metal ions and catalytic degradation of 4-NP, CTAB was engineered as a versatile capping agent on gold and silver nanoparticles. Various factors, including nanoparticle characteristics such as shape, size

• degrading 94.37% of 4-NP within 1 min. In contrast, silver nanospheres effectively detected Hg2+, Cu2+, and Fe3+ at concentrations as low as 1 ppm and degraded 90.78% of 4-NP within 30 min. Moreover, anisotropic gold nanorods (CTAB-AuNR1 and CTAB-AuNR2) showed promising sensing capabilities towards Cu2

• protection. Keywords: catalysis; CTAB; heavy metal; nanoparticles; 4-nitrophenol; sensing; Introduction Metal nanoparticles are widely used for a great number of applications owing to their excellent optochemical properties and high surface-to-volume ratio in comparison to bulk materials. Noble metal (gold

Functional morphology of cleaning devices in the damselfly Ischnura elegans (Odonata, Coenagrionidae)

• Silvana Piersanti,
• Gianandrea Salerno,
• Wencke Krings,
• Stanislav Gorb and
• Manuela Rebora

Beilstein J. Nanotechnol. 2024, 15, 1260–1272, doi:10.3762/bjnano.15.102

• on the grooming structures. The specimens were deposited on aluminum stubs using double-sided adhesive tape. Before the analysis, the samples were sputter-coated with a thin layer of gold (8 nm) using a Q150 T ES (Quorum, Laughton, UK) for 30 s. The samples were then analyzed in a field-emission

Enhanced catalytic reduction through in situ synthesized gold nanoparticles embedded in glucosamine/alginate nanocomposites

• Chi-Hien Dang,
• Le-Kim-Thuy Nguyen,
• Minh-Trong Tran,
• Van-Dung Le,
• Nguyen Minh Ty,
• T. Ngoc Han Pham,
• Hieu Vu-Quang,
• Tran Thi Kim Chi,
• Tran Thi Huong Giang,
• Nguyen Thi Thanh Tu and
• Thanh-Danh Nguyen

Beilstein J. Nanotechnol. 2024, 15, 1227–1237, doi:10.3762/bjnano.15.99

• synthesizing gold nanoparticles (AuNPs) within a glucosamine/alginate (GluN/Alg) nanocomposite via an ionotropic gelation mechanism in aqueous environment. The resulting nanocomposite, AuNPs@GluN/Alg, underwent thorough characterization using UV–vis, EDX, FTIR, SEM, TEM, SAED, and XRD analyses. The spherical

• nanocomposite as a versatile catalyst with promising applications across various industrial sectors. Keywords: catalysis; gold nanoparticles; organic dyes; organometallic nanocomposites; reduction; Introduction Gold nanoparticles (AuNPs) have garnered significant attention because of their exceptional

• Materials The study utilized reagents and chemicals without additional purification. Glucosamine, gold(III) chloride, calcium acetate hydrate, sodium alginate, sodium tetrahydroborate, 2-nitrophenol, 4-nitrophenol, and methyl orange were procured from Acros Scientific (Belgium). Distilled water was used