Velocity dependence of sliding friction on a crystalline surface

• Christian Apostoli,
• Giovanni Giusti,
• Jacopo Ciccoianni,
• Gabriele Riva,
• Rosario Capozza,
• Rosalie Laure Woulaché,
• Andrea Vanossi,
• Emanuele Panizon and
• Nicola Manini

Beilstein J. Nanotechnol. 2017, 8, 2186–2199, doi:10.3762/bjnano.8.218

• conservative simulations, for example, can describe the energy transfer into internal vibrational energy omitting all unphysical damping terms altogether [20][21][22][23][24][25]. The disadvantage of this approach is that, due to the finite and relatively small number of degrees of freedom available in a

• reason we do include a weak viscous damping term, but this term acts on the elastic substrate only. We make sure that the effect of this term is negligible for the target of this research: the energy transfer from the slider to the substrate. This model virtually allows us to dispose of the arbitrary

• one of Figure 2, which of course allows for no energy transfer, and no dissipation. As damping is decreased to the physically relevant underdamped region γ < (mK)1/2, friction stabilizes to a physically significant γ-independent value. However, when γ is further decreased below approximately 10−2 (mK

Ester formation at the liquid–solid interface

• Nguyen T. N. Ha,
• Thiruvancheril G. Gopakumar,
• Nguyen D. C. Yen,
• Carola Mende,
• Lars Smykalla,
• Maik Schlesinger,
• Roy Buschbeck,
• Tobias Rüffer,
• Heinrich Lang,
• Michael Mehring and
• Michael Hietschold

Beilstein J. Nanotechnol. 2017, 8, 2139–2150, doi:10.3762/bjnano.8.213

• thoroughly investigated. In addition to the imaging, the tunnel tip was active in promoting the reaction by local energy transfer to and local transport of the reactants. Endothermal on-surface reactions of a whole molecular monolayer can be initiated by a corresponding heating process after deposition. STM

Synthesis and characterization of noble metal–titania core–shell nanostructures with tunable shell thickness

• Bartosz Bartosewicz,
• Marta Michalska-Domańska,
• Malwina Liszewska,
• Dariusz Zasada and
• Bartłomiej J. Jankiewicz

Beilstein J. Nanotechnol. 2017, 8, 2083–2093, doi:10.3762/bjnano.8.208

• electromagnetic fields increased the efficiency of light interaction with sensitizers (dyes). On the other hand, plasmon resonance energy transfer (PRET) and “hot” electron transfer led to an increased e−/h+ pair generation and amplified number of carriers available for photocurrent generation. An increased

Three-in-one approach towards efficient organic dye-sensitized solar cells: aggregation suppression, panchromatic absorption and resonance energy transfer

• Jayita Patwari,
• Samim Sardar,
• Bo Liu,
• Peter Lemmens and
• Samir Kumar Pal

Beilstein J. Nanotechnol. 2017, 8, 1705–1713, doi:10.3762/bjnano.8.171

• absorption coefficients in the visible and NIR region of the solar spectrum and to probe the possibility of Förster resonance energy transfer (FRET) between the two dyes. FRET from the donor PPIX to acceptor SQ2 was observed from detailed investigation of the excited-state photophysics of the dye mixture

• . Keywords: anti-aggregation; co-sensitization; dye-sensitized solar cells (DSSC); Förster resonance energy transfer (FRET); NIR harvesting; panchromatic absorption; Introduction The increasing demand for fossil-fuel energy sources and the intensifying environmental pollution have promoted an extensive

• using a sensitizer solution cocktail mixing one dye absorbing in the visible region with another dye absorbing in the NIR region or incorporating Förster resonance energy transfer (FRET) between two co-sensitizers [9][15][16][17][18][19]. However, co-sensitization brings some additional complexity to

Two-dimensional carbon-based nanocomposites for photocatalytic energy generation and environmental remediation applications

• Suneel Kumar,
• Ashish Kumar,
• Ashish Bahuguna,
• Vipul Sharma and
• Venkata Krishnan

Beilstein J. Nanotechnol. 2017, 8, 1571–1600, doi:10.3762/bjnano.8.159

Bright fluorescent silica-nanoparticle probes for high-resolution STED and confocal microscopy

• Isabella Tavernaro,
• Christian Cavelius,
• Henrike Peuschel and
• Annette Kraegeloh

Beilstein J. Nanotechnol. 2017, 8, 1283–1296, doi:10.3762/bjnano.8.130

• multicolour silica particles with or without Förster resonance energy transfer (FRET). These different approaches are currently under investigation. Experimental Materials All syntheses and purification steps in aqueous solution were conducted in ultrapure water (18.2 MΩ·cm, MilliQ water purification system

ZnO nanoparticles sensitized by CuInZn_xS_2+x quantum dots as highly efficient solar light driven photocatalysts

• Florian Donat,
• Serge Corbel,
• Halima Alem,
• Steve Pontvianne,
• Lavinia Balan,
• Ghouti Medjahdi and
• Raphaël Schneider

Beilstein J. Nanotechnol. 2017, 8, 1080–1093, doi:10.3762/bjnano.8.110

• oxygen 1O2 generation has scarcely been reported for photocatalysts and may originate from the oxidation of O2•− into 1O2 and triplet oxygen 3O2 or from the energy transfer of the photo-excited catalyst to 3O2 [50][51][52][53]. 1O2 has been demonstrated to play a key role in some TiO2-catalyzed

• are formed by the ZnO/ZCIS catalyst, we suppose that 1O2 is preferentially generated by the oxidation of O2•− by holes rather than by an energy transfer of the photo-excited catalyst to 3O2. Conclusion In summary, we have successfully prepared ZnO/ZCIS composites via a facile thermal treatment at 400

Synthesis of graphene–transition metal oxide hybrid nanoparticles and their application in various fields

• Arpita Jana,
• Elke Scheer and
• Sebastian Polarz

Beilstein J. Nanotechnol. 2017, 8, 688–714, doi:10.3762/bjnano.8.74

Photo-ignition process of multiwall carbon nanotubes and ferrocene by continuous wave Xe lamp illumination

• Paolo Visconti,
• Patrizio Primiceri,
• Daniele Longo,
• Luciano Strafella,
• Paolo Carlucci,
• Mauro Lomascolo,
• Arianna Cretì and
• Giuseppe Mele

Beilstein J. Nanotechnol. 2017, 8, 134–144, doi:10.3762/bjnano.8.14

• process (b). Chemical reactions relative to photo-induced electron and energy transfer in MWNTs–FeCp2 nanocomposites occurring during the photo-induced ignition process. Solvent type and amount of ferrocene used in this work.

Grazing-incidence optical magnetic recording with super-resolution

• Gunther Scheunert,
• Sidney. R. Cohen,
• René Kullock,
• Ryan McCarron,
• Katya Rechev,
• Ifat Kaplan-Ashiri,
• Ora Bitton,
• Paul Dawson,
• Bert Hecht and
• Dan Oron

Beilstein J. Nanotechnol. 2017, 8, 28–37, doi:10.3762/bjnano.8.4

• (~70%). The Co layer is the single greatest absorber in the stack by a factor of 2 (Figure 7, inset), which is ideal for energy transfer to the desired magnetic layer only. The inset further shows the ideal wavelength within the visible regime to be as short as possible for maximal coupling efficiency

A dioxaborine cyanine dye as a photoluminescence probe for sensing carbon nanotubes

• Mohammed Al Araimi,
• Petro Lutsyk,
• Anatoly Verbitsky,
• Yuri Piryatinski,
• Mykola Shandura and
• Aleksey Rozhin

Beilstein J. Nanotechnol. 2016, 7, 1991–1999, doi:10.3762/bjnano.7.190

• we have revealed new optical features in the spectral range of the intrinsic excitation of the dye due to resonance energy transfer from DOB-719 to SWNTs. Specifically, we have observed an emergence of new PL peaks at the excitation wavelength of 735 nm and a redshift of the intrinsic PL peaks of

• . Keywords: dioxaborine cyanine dye; photoluminescence; resonant energy transfer; sensor; single-walled carbon nanotubes (SWNTs); Introduction Carbon nanotubes exhibit unique physical and chemical properties distinctive from other materials because of their extreme aspect ratio offering a number of exciting

• sidewall with π-conjugated organic compounds [9][10][11][12]. Considering sensors, particular attention has to be paid to the PL enhancement in aqueous media, like the complexation and resonant energy transfer (RET) from cyanine dyes to the SWNTs covered by anionic surfactants in water [12]. However, a

Dynamic of cold-atom tips in anharmonic potentials

• Tobias Menold,
• Peter Federsel,
• Carola Rogulj,
• Hendrik Hölscher,
• József Fortágh and
• Andreas Günther

Beilstein J. Nanotechnol. 2016, 7, 1543–1555, doi:10.3762/bjnano.7.148

• -atom tip. Assuming certain symmetries, the complete phase-space distribution function can then be obtained from a time-of-flight image series. Unfortunately, absorption imaging is a fully destructive process, such that the cold-atom tip is destroyed due to energy transfer from absorbed photons. At

High performance Ce-doped ZnO nanorods for sunlight-driven photocatalysis

• Bilel Chouchene,
• Tahar Ben Chaabane,
• Lavinia Balan,
• Emilien Girot,
• Kevin Mozet,
• Ghouti Medjahdi and
• Raphaël Schneider

Beilstein J. Nanotechnol. 2016, 7, 1338–1349, doi:10.3762/bjnano.7.125

• efficiency by energy transfer processes and this topic is becoming an exciting area of research for developing electronic and optical applications like sensors, light-emitting phosphors or flat panel displays [14][15][16][17][18][19][20][21][22][23][24][25][26][27]. Due to the defects induced in the ZnO

Photocurrent generation in carbon nanotube/cubic-phase HfO₂ nanoparticle hybrid nanocomposites

• Protima Rauwel,
• Augustinas Galeckas,
• Martin Salumaa,
• Frédérique Ducroquet and
• Erwan Rauwel

Beilstein J. Nanotechnol. 2016, 7, 1075–1085, doi:10.3762/bjnano.7.101

• optical quenching was attributed to a nonradiative energy transfer from the quantum dot to the SWCNT in the ground state [53]. In the present study, we observe an overall decrease in the PL intensity when the HfO2 nanoparticles are attached to the CNT compared to the PL emission of the free-standing

The influence of phthalocyanine aggregation in complexes with CdSe/ZnS quantum dots on the photophysical properties of the complexes

• Irina V. Martynenko,
• Anna O. Orlova,
• Vladimir G. Maslov,
• Anatoly V. Fedorov,
• Kevin Berwick and
• Alexander V. Baranov

Beilstein J. Nanotechnol. 2016, 7, 1018–1027, doi:10.3762/bjnano.7.94

• Technology, Dublin 8, Ireland 10.3762/bjnano.7.94 Abstract The formation of nonluminescent aggregates of aluminium sulfonated phthalocyanine in complexes with CdSe/ZnS quantum dots causes a decrease of the intracomplex energy transfer efficiency with increasing phthalocyanine concentration. This was

• ; Förster resonance energy transfer; photosensitizer; semiconductor nanocrystals; tetrapyrroles; Introduction Semiconductor quantum dots (QDs) and their complexes with organic molecules have been a subject of extensive research during the last couple of decades. In particular, complexes of QDs and

• , photoexcited tetrapyrrole molecules undergo intersystem crossing from a singlet state to a triplet state. Energy is then transferred from the triplet state to the surrounding oxygen molecules. This energy transfer converts oxygen to the extremely reactive singlet oxygen, which can destroy diseased cells [11

Highly compact refractive index sensor based on stripe waveguides for lab-on-a-chip sensing applications

• Chamanei Perera,
• Kristy Vernon,
• Elliot Cheng,
• Juna Sathian,
• Esa Jaatinen and
• Timothy Davis

Beilstein J. Nanotechnol. 2016, 7, 751–757, doi:10.3762/bjnano.7.66

• input end to increase the energy transfer of incoming light into the input waveguide [22]. The gratings were excited through an inverted microscope set-up using a 633 nm wavelength laser, further details are provided in [22]. The plasmon propagation and coupling in the RI sensor was imaged using CdSe

Coupled molecular and cantilever dynamics model for frequency-modulated atomic force microscopy

• Michael Klocke and
• Dietrich E. Wolf

Beilstein J. Nanotechnol. 2016, 7, 708–720, doi:10.3762/bjnano.7.63

• integrals of the three cartesian components add up to zero (corresponding to energy transfer into lateral degrees of freedom) or not (corresponding to adhesion hysteresis). This is more elaborate and likely more error-prone than monitoring the energies directly. Simulation method It is not feasible to

• -values). It is due to an energy transfer into the lateral degree of freedom. A signature of this effect is that it is nearly equally strong on both sides of the points of strongest attraction between tip and substrate, so that the scan has two dissipation maxima per lattice constant, but only one

• soon as d becomes small enough and remains roughly constant below. At the same time, the frequency of the cantilever oscillation changes discontinuously. If the normal cantilever oscillation is damped, for lateral oscillations get excited, the energy transfer increases smoothly with decreasing d, due

Hierarchical coassembly of DNA–triptycene hybrid molecular building blocks and zinc protoporphyrin IX

• Rina Kumari,
• Sumit Singh,
• Mohan Monisha,
• Sourav Bhowmick,
• Anindya Roy,
• Neeladri Das and
• Prolay Das

Beilstein J. Nanotechnol. 2016, 7, 697–707, doi:10.3762/bjnano.7.62

• was chosen as a prototype where ROS generation is proportional to the extent of oxidation of DHR 123. The ROS generation was attributed to energy transfer from the PpIX molecules to neighboring oxygen atoms upon irradiation at 330 nm. The formation of R 123 from DHR 123 was quantified by steady-state

Fabrication and properties of luminescence polymer composites with erbium/ytterbium oxides and gold nanoparticles

• Julia A. Burunkova,
• Ihor Yu. Denisiuk,
• Dmitri I. Zhuk,
• Lajos Daroczi,
• Attila Csik,
• István Csarnovics and
• Sándor Kokenyesi

Beilstein J. Nanotechnol. 2016, 7, 630–636, doi:10.3762/bjnano.7.55

• nanoparticles is not always a good solution to the problem because of the possible decrease of luminescence intensity due to the counterproductive introduction of energy-transfer processes at high concentrations of rare earth ions. For example, as it was shown in [5] for Er-doped silicon materials, a practical

Organized films

• Maurizio Canepa and
• Helmuth Möhwald

Beilstein J. Nanotechnol. 2016, 7, 406–408, doi:10.3762/bjnano.7.35

• ]. Their impact on interface science over the last four decades was undoubtedly based on pioneering works such as the beautiful studies of Kuhn and Möbius on energy transfer between molecules arranged with angstrom precision [2], or the stimulating works of Roberts and Petty [3], which envisaged many

Early breast cancer screening using iron/iron oxide-based nanoplatforms with sub-femtomolar limits of detection

• Dinusha N. Udukala,
• Hongwang Wang,
• Sebastian O. Wendel,
• Aruni P. Malalasekera,
• Thilani N. Samarakoon,
• Asanka S. Yapa,
• Gayani Abayaweera,
• Matthew T. Basel,
• Pamela Maynez,
• Raquel Ortega,
• Yubisela Toledo,
• Leonie Bossmann,
• Colette Robinson,
• Katharine E. Janik,
• Olga B. Koper,
• Ping Li,
• Massoud Motamedi,
• Daniel A. Higgins,
• Gary Gadbury,
• Gaohong Zhu,
• Deryl L. Troyer and
• Stefan H. Bossmann

Beilstein J. Nanotechnol. 2016, 7, 364–373, doi:10.3762/bjnano.7.33

• sequence. A second dye (cyanine 5.5) is permanently linked to the dopamine coating (Figure 1). This design enables both, plasmon-resonance quenching (SET) [20][21] and Förster resonance energy transfer (FRET) quenching [20][22] of the tethered TCPP units. Once TCPP is released via proteolytic cleavage of

• -resonance quenching (dipole–surface energy transfer (SET) [20][21]) from TCPP to Fe/Fe3O4 and Förster resonance energy transfer (FRET [20][22]) from TCPP to cyanine 5.5. The latter is permanently tethered to the inorganic nanoparticle. For all of the employed consensus sequences, with the exceptions of

• effect” upon proteolytic cleavage: the fluorophore is switched on due to the increase in distance between the Fe/Fe3O4 core/shell nanoparticle, leading to decreased Förster resonance energy transfer (FRET) [21][24], k1, and dipole–surface energy transfer (SET) [20][22], k2. Further explanations are

Green and energy-efficient methods for the production of metallic nanoparticles

• Mitra Naghdi,
• Mehrdad Taheran,
• Satinder K. Brar,
• M. Verma,
• R. Y. Surampalli and
• J. R. Valero

Beilstein J. Nanotechnol. 2015, 6, 2354–2376, doi:10.3762/bjnano.6.243

• , researchers had the opportunity to investigate eco-friendly reagents and new energy transfer techniques. In order to substitute the harmful reagents with green ones, researchers worked on different types of saccharides, polyols, carboxylic acids, polyoxometalates and extracts of various plants that can play

• the role of reducers, stabilizers or solvents. Also, there are some reports on using ultraviolet (UV), gamma and microwave irradiation that are capable of reducing and provide uniform heating. According to the literature, it is possible to use green reagents and novel energy transfer techniques for

• production of NPs. However, these new synthesis routes should be optimized in terms of performance, cost, product quality (shape and size distribution) and scale-up capability. This paper presents a review on most of the employed green reagents and new energy transfer techniques for the production of

Silica-coated upconversion lanthanide nanoparticles: The effect of crystal design on morphology, structure and optical properties

• Uliana Kostiv,
• Miroslav Šlouf,
• Hana Macková,
• Alexander Zhigunov,
• Hana Engstová,
• Katarína Smolková,
• Petr Ježek and
• Daniel Horák

Beilstein J. Nanotechnol. 2015, 6, 2290–2299, doi:10.3762/bjnano.6.235

• nm) [14]. Upconversion proceeds by different mechanisms, such as energy transfer and excited-state absorption and photon avalanche. These three mechanisms are based on the sequential absorption of two or more photons. Upconversion emission proceeds by sequential absorption of two photons and leads to

• inorganic compounds at high temperatures. To investigate the optical properties of the OM–NaYF4:Yb3+/Er3+ nanoparticles prepared at different reaction temperatures, the upconversion emission spectra were recorded at 980 nm excitation (Figure 7a). The energy transfer upconversion started after sequential

• insufficient energy transfer to Er3+ and energy losses between the ions. When the particles were prepared at temperatures above 300 °C, luminescence intensities were slightly higher, indicating that maximum luminescence efficiency was achieved by optimizing the interatomic distance between the absorbers and

Nonconservative current-driven dynamics: beyond the nanoscale

• Brian Cunningham,
• Tchavdar N. Todorov and
• Daniel Dundas

Beilstein J. Nanotechnol. 2015, 6, 2140–2147, doi:10.3762/bjnano.6.219

• transport; failure mechanisms; nanoelectronic devices; nanomotors; Introduction The development of electronic devices at the nanoscale is a challenging avenue of research with the aim of improving their efficiency and performance. This requires an understanding of the mechanisms for energy transfer from

Thermoelectricity in molecular junctions with harmonic and anharmonic modes

• Bijay Kumar Agarwalla,
• Jian-Hua Jiang and
• Dvira Segal

Beilstein J. Nanotechnol. 2015, 6, 2129–2139, doi:10.3762/bjnano.6.218

• , Suzhou 215006, China 10.3762/bjnano.6.218 Abstract We study charge and energy transfer in two-site molecular electronic junctions in which electron transport is assisted by a vibrational mode. To understand the role of mode harmonicity/anharmonicity in transport behavior, we consider two limiting

• is notable that the only difference between the HO and AH models is the sign in the denominator. Note that we did not simplify the expression for the energy current above; the derivatives return energy transfer rates analogous to Equation 10, only with an additional energy variable in the integrand