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Search for "metals" in Full Text gives 634 result(s) in Beilstein Journal of Nanotechnology. Showing first 200.
The influence of structure and local structural defects on the magnetic properties of cobalt nanofilms
Beilstein J. Nanotechnol. 2023, 14, 23–33, doi:10.3762/bjnano.14.3
- internal energy and by the symmetry or asymmetry of the crystal structure of ferromagnets. The dipole–dipole interaction does not make a significant contribution to the anisotropy energy and its value is insignificant. Only in a number of rare-earth metals the contribution of the dipole–dipole interaction
Electrical and optical enhancement of ITO/Mo bilayer thin films via laser annealing
Beilstein J. Nanotechnol. 2022, 13, 1589–1595, doi:10.3762/bjnano.13.133
- significantly improve the electrical properties without affecting the optical transmission [9]. Several metals have been used for such thin layers, including silver [10], aluminium [11], copper [12], and gold [13]. Molybdenum thin films are another choice for the application in solar cells because of good
Photoelectrochemical water oxidation over TiO2 nanotubes modified with MoS2 and g-C3N4
Beilstein J. Nanotechnol. 2022, 13, 1541–1550, doi:10.3762/bjnano.13.127
- , the electrode material must be extremely durable and nearly chemically inert to be able to withstand highly acidic or basic environments. Therefore, noble metals such as Pt, Pd, Au and Ag with suitable chemical properties, such as inertness, good resistance against corrosion and good electrical
- conductivity have been widely used in water splitting reactions [10][11]. However, noble metals are still rare and expensive materials, and their application as electrode materials is considered to be not optimal [10]. Therefore, the study of a materials with high-performance in PEC water splitting, which
- could replace noble metals are a research interest. Photocatalytic technology uses semiconductors for effective approaches to the degradation of dyes and antibiotics, the removal of pollutant gases, and water splitting to produce hydrogen using solar energy [12][13][14][15][16][17]. Among such
Non-stoichiometric magnetite as catalyst for the photocatalytic degradation of phenol and 2,6-dibromo-4-methylphenol – a new approach in water treatment
Beilstein J. Nanotechnol. 2022, 13, 1531–1540, doi:10.3762/bjnano.13.126
- igneous and metamorphic rocks [12]. It is also found in sediments and soils. Magnetite has the smallest energy gap, the highest conductivity, and one of the lowest reduction potentials among natural minerals. It is an important reducer of heavy metals and organic pollutants in aquatic environments. Due to
In search of cytotoxic selectivity on cancer cells with biogenically synthesized Ag/AgCl nanoparticles
Beilstein J. Nanotechnol. 2022, 13, 1505–1519, doi:10.3762/bjnano.13.124
- synthesized by green methods and, in some cases, are combined with other metals [2]. AgNPs have potential uses in biomedicine. Several authors have reported the ability of AgNPs to act as antibacterial [3][4] or as cytotoxic agents in certain cancer cell lines [5][6]. This type of application has attracted a
Frequency-dependent nanomechanical profiling for medical diagnosis
Beilstein J. Nanotechnol. 2022, 13, 1483–1489, doi:10.3762/bjnano.13.122
- chemical characterization of surfaces ranging from semiconductors and metals to polymers and biological materials [1][2][3][4][5]. In particular, a variety of mechanical property measurement methods have been developed, although most of them are restricted to relatively simple physical descriptions, such
Structural studies and selected physical investigations of LiCoO2 obtained by combustion synthesis
Beilstein J. Nanotechnol. 2022, 13, 1473–1482, doi:10.3762/bjnano.13.121
- analysis, (ii) morphology (size and distribution of grains) by using SEM, (iii) specific surface area (SSA) by carrying out Brunauer–Emmett–Teller (BET) measurements, (iv) oxidation states of metals by measuring electron paramagnetic resonance (EPR), and (v) electrical parameters (thermal dependencies of
Rapid and sensitive detection of box turtles using an electrochemical DNA biosensor based on a gold/graphene nanocomposite
Beilstein J. Nanotechnol. 2022, 13, 1458–1472, doi:10.3762/bjnano.13.120
- microbes and sources of heavy metals/toxins [6][7], and are prohibited from consumption by Muslims [5]. Therefore, turtle materials in food chains and medicines pose both health and social risks. Aside from that, a rising demand encourages the illicit trafficking of BT [8]. Illegal turtle meat and species
Recent trends in Bi-based nanomaterials: challenges, fabrication, enhancement techniques, and environmental applications
Beilstein J. Nanotechnol. 2022, 13, 1316–1336, doi:10.3762/bjnano.13.109
- and deposition and doping of metals and non-metallic elements are the most common doping methods. Metal ions modify the crystal structure of the Bi-based semiconductor photocatalysts or induce defects. Also, the photocatalytic properties may be altered by doping or deposition of metallic components
- photocatalyst is complex, which is why a h+-capturing substance is frequently added to the system to promote the production of H2 [112]. Pt, Pd, Au, and other precious metals, as well as photocatalysts containing Cd, Pb, and other elements (such as CdS), are some of the costliest and environmentally hazardous
Bending and punching characteristics of aluminum sheets using the quasi-continuum method
Beilstein J. Nanotechnol. 2022, 13, 1303–1315, doi:10.3762/bjnano.13.108
- friction behaviors of different models [52]. Moreover, the QC method based on the embedded-atom method (EAM) potential was adopted to observe the fatigue crack growth and expansion characteristics of single-crystal metals under cyclic loading processes. The results showed that after compressive or shear
Laser-processed antiadhesive bionic combs for handling nanofibers inspired by nanostructures on the legs of cribellate spiders
Beilstein J. Nanotechnol. 2022, 13, 1268–1283, doi:10.3762/bjnano.13.105
- fiber is assumed is still valid in this case. The modulation depth that typically can be achieved for LIPSS (LSFL type [33]) on metals is up to 400 nm. Thus, an antiadhesive effect can be assumed. The peel-off force, that is, the force per unit length of the peeling edge necessary to separate the
- -covered steel samples and, thus, significant lower than for the corresponding polished surfaces (7.69 N/m for Ti alloy and 8.87 N/m for steel). Thus, for both metals (Ti alloy and steel), the LIPSS reduce the adhesion forces by approximately 70–75% compared to the polished surfaces. For the aluminium
- cribellate spiders, we were able to define an upscaled surface nanostructure with reduced adhesion force towards technical electrospun fibers. The biomimetic surface can be produced on metals by means of ultrashort pulse laser processing of self-organized laser-induced periodic surface structures, so-called
Studies of probe tip materials by atomic force microscopy: a review
Beilstein J. Nanotechnol. 2022, 13, 1256–1267, doi:10.3762/bjnano.13.104
- attractive platform, offering more possibilities for sharpening tips in a controlled manner. These metal clusters can be easily generated with various metals (e.g., Ir, Au, Ni, Co, Pb, or Sn), allowing the generation of nano-tips with different functionalities. The good point is that these clusters were
- broad particle size distribution, which was observed to be in the range of 2–80 μm. The polydispersity due to evaporation in the spark helps to select particles of suitable diameter size. The evaporation of sparks is a universal process that can be applied to basically all metals suitable as electrodes
- , such as copper, silver, platinum, etc. Thus, it is also possible to prepare electrochemical colloidal probes (eCPs) with other metals. eCPs under electrochemical control of colloidal probes have potential in various research areas such as adhesion science, tribology or long-range interactions. eCPs
Design of surface nanostructures for chirality sensing based on quartz crystal microbalance
Beilstein J. Nanotechnol. 2022, 13, 1201–1219, doi:10.3762/bjnano.13.100
- sensing layers from inorganic nanostructures In contrast to the abundance of chiral organic molecules, chirality in inorganic materials seems rare. Unlike the well-established theory of chirality for organic molecules, the notion of chirality for metals, semiconductors, and other inorganic nanostructures
- considered to be the most promising platform for enantiospecific sensing and may also be explored for chiral separation and catalysis [111]. Induced chiral metal or inorganic oxides Based on the template strategy, metals or inorganic oxides with chiral channels could be fabricated by using chiral templates
- generated by polypyrrole (PPy) and Trp [127]. Intrinsic chiral metal crystals Until relatively recently, metals were ignored as potential substrates for asymmetric surface chemistry since metals always show highly symmetric and achiral bulk structures with unexposed chiral surfaces [128][129]. Sykes and co
Microneedle-based ocular drug delivery systems – recent advances and challenges
Beilstein J. Nanotechnol. 2022, 13, 1167–1184, doi:10.3762/bjnano.13.98
- if the needles break and are deposited in the tissue [117][118]. Other non-degradable materials utilized to fabricate microneedles, include metals such as stainless steel [119] and titanium [120], ceramics, such as aluminum oxide [121], or synthetic polymers comprising polyvinylpyrrolidone (PVP) [122
- of the microneedle system and the material from which it is to be made. In addition, the technique must be adapted to the properties of the drug. The most common materials used in the production of microneedles are silicon, ceramics, and metals, such as stainless steel and titanium. Also
- cutting technique can be used to produce microneedles from metals or polymers. The main part of the process is cutting microneedles out of a plate with a laser and then bending them. The alignment of the tips can be achieved by electropolishing [149]. A similar technique is laser ablation. In this case
Biomimetic chitosan with biocomposite nanomaterials for bone tissue repair and regeneration
Beilstein J. Nanotechnol. 2022, 13, 1051–1067, doi:10.3762/bjnano.13.92
- wettability and protein adsorption which can facilitate osteogenesis [129]. Biomaterials such as chitosan and its composites containing bioactive metals draw much attention in tissue engineering and regenerative applications. Chitosan-based composites are now being studied in wound healing, bone and cartilage
- mechanical characteristics. Nanocomposites formed by chitosan and metals, such as silver, gold, copper, titanium oxide, and zinc oxide were studied in the treatment of bone tissue defects and have proven to be effective in bone tissue repairing processes. Also, chitosan combined with carbon nanomaterials
Electrocatalytic oxygen reduction activity of AgCoCu oxides on reduced graphene oxide in alkaline media
Beilstein J. Nanotechnol. 2022, 13, 1020–1029, doi:10.3762/bjnano.13.89
- . Electrocatalytic enhancement of the Ag nanoarchitectonics can be obtained via support structures and amalgamating Ag with one or two additional metals. The work presented here deals with a facile microwave-assisted synthesis to produce bimetallic Ag-Cu and Ag-Co (1:1) oxide nanoparticles (NPs) and trimetallic
- electrocatalysts [14][18][19]. Oxophilicity, agglomeration, and poor chemical stability of Ag require the amalgamation of Ag with other metals for a better optical and catalytic activity [20]. Chen et al. synthesised Ag nanoscale alloys containing metals such as copper, cobalt, iron, and indium via pulse film
Effects of focused electron beam irradiation parameters on direct nanostructure formation on Ag surfaces
Beilstein J. Nanotechnol. 2022, 13, 1004–1010, doi:10.3762/bjnano.13.87
- on the growth rate of the nanodots was observed. Metals with lower melting points (implying lower interatomic bond energy) produced higher nanodots at similar irradiation parameters. Conversely, metals with higher volume magnetic susceptibility produced much wider nanodots with a higher volume. A
Theoretical investigations of oxygen vacancy effects in nickel-doped zirconia from ab initio XANES spectroscopy at the oxygen K-edge
Beilstein J. Nanotechnol. 2022, 13, 975–985, doi:10.3762/bjnano.13.85
- large set of DMO. It is thus important to investigate other types of dopants in DMO or other types of oxide matrices doped with transition metals. Oxygen vacancies play a fundamental role in the aforementioned microscopic mechanisms since an excess or lack of oxygen vacancies with respect to their
- stoichiometric concentration required to ensure overall charge neutrality can modify the presence of defect states in the electron bandgap [4][26][27]. In diluted magnetic semiconductors (DMS), magnetic impurities such as the transition metals (TM) Fe or Ni are introduced to produce a magnetic ground state. The
- , the covalency of the metal–ligand bonds, and the change in the metal oxidation state. The latter may lead to distinct changes in the spectral shape and incident energy [30][31]. For high-spin transition metals, for instance, it has been established that the L2,3-edge spectrum shifts to higher energies
Ultrafast signatures of magnetic inhomogeneity in Pd1−xFex (x ≤ 0.08) epitaxial thin films
Beilstein J. Nanotechnol. 2022, 13, 836–844, doi:10.3762/bjnano.13.74
- ferromagnetic metals was a subject of interest in magnetic nanostructures [50][51][52] and had a value of about 3 × 105 m/s. Being stronger localized in the narrower 4d bands [44], the itinerant 4d electrons must have a lower velocity, say 105 m/s. Then, with the transport time τ ≈ 10−14 s and the electron-spin
Temperature and chemical effects on the interfacial energy between a Ga–In–Sn eutectic liquid alloy and nanoscopic asperities
Beilstein J. Nanotechnol. 2022, 13, 817–827, doi:10.3762/bjnano.13.72
- liquid metals strongly depend on their surface and interfacial properties. The surface tension of room-temperature-liquid Ga-based alloys has been reported to be lowered by a thin surface oxide layer [8]. In [9], the authors electrochemically controlled the growth and removal of gallium oxide to tune the
- surface tension of liquid gallium. Oxygen is a surface-active substance whose effect on surface tension has been investigated for various liquid metals [10]. In metallic alloys, surface segregation has also been observed, where an element with a higher oxygen affinity enriches at the surface to form an
Hierarchical Bi2WO6/TiO2-nanotube composites derived from natural cellulose for visible-light photocatalytic treatment of pollutants
Beilstein J. Nanotechnol. 2022, 13, 745–762, doi:10.3762/bjnano.13.66
- pollutants including dyes, organic matter, and heavy metals has caused disastrous consequences to the ecosystem [1]. Cr(VI) is one of the unmanageable pollutants in industrial effluents. It is highly toxic, carcinogenic, and harmful to the lungs, liver, and other organs [2][3]. Photocatalysis is a promising
Zinc oxide nanostructures for fluorescence and Raman signal enhancement: a review
Beilstein J. Nanotechnol. 2022, 13, 472–490, doi:10.3762/bjnano.13.40
- , enhanced Raman scattering for periodic ZnO-elevated Au dimer nanostructures [12] and enhanced fluorescence emission signals from Al-doped ZnO films [13] were obtained. The development of hybrid nanocomposites based on ZnO and noble metals for fluorescence and Raman signal enhancement has recently attracted
- nanostructures, however, are significantly inferior to those on noble metals since the LSPR is centred in the near-infrared in the case of the conduction band (CB) and in the UV region in the case of the valence band (VB) [14]. Therefore, concrete solutions have been proposed to improve the EM enhancement in ZnO
- as SEF, SERS [16][17], infrared absorption, and even second harmonic generation [18], which can improve the performance of optical sensors and optoelectronic devices. ZnO alone and in combination with noble metals has been recently used for the development of SERS substrates [15][19] due to several
Electrostatic pull-in application in flexible devices: A review
Beilstein J. Nanotechnol. 2022, 13, 390–403, doi:10.3762/bjnano.13.32
- nonvolatile storage memory. However, vertically aligned switches require a pull-in voltage of more than 20 V, higher than the usual horizontally distributed switches. CNT-NEM switches have great potential in nonvolatile memory devices. In addition, CNTs used with metals in composite electrodes, as a bottom
Micro- and nanotechnology in biomedical engineering for cartilage tissue regeneration in osteoarthritis
Beilstein J. Nanotechnol. 2022, 13, 363–389, doi:10.3762/bjnano.13.31
- . Nanomaterials are defined by the National Nanotechnology Initiative as manufactured or natural materials that have at least one dimension between 1 and 100 nm [33][34][35][36][37][38][39][40][41][42][43][44][45][46]. Nanomaterials are classified as metals, polymers, or ceramics according to their structure and
Relationship between corrosion and nanoscale friction on a metallic glass
Beilstein J. Nanotechnol. 2022, 13, 236–244, doi:10.3762/bjnano.13.18
- ]. Tao et al. [3] found that Zr-based MGs present a much smaller friction coefficient than other metals under dry-sliding conditions. W-based MGs were developed whose wear resistance was demonstrated to be comparable to classical tribological ceramics [6]. Hofmann et al. [7] reported that the wear
- nanoscale is crucially important. Microscale bearings made of Ni-based MGs lasted four times longer than those machined from sintered alloy [12]. Corrosive degradation, as one of the major failure mechanisms of metals and alloys, is an important issue in engineering applications of MGs. Protective oxide
- electrochemical methods, often combined with surface analytical techniques [13][14][15]. Wang et al. [13] reported that the passive oxide films are grown as a double layer structure on MGs with a corrosion product layer underlying an inner barrier layer in NaCl and Na2SO4 solutions. Since most metals and alloys
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