Multiscale modelling of biomolecular corona formation on metallic surfaces

• Parinaz Mosaddeghi Amini,
• Ian Rouse,
• Julia Subbotina and
• Vladimir Lobaskin

Beilstein J. Nanotechnol. 2024, 15, 215–229, doi:10.3762/bjnano.15.21

• reactivity, sensitivity of NPs, as well as their cellular uptake and systemic transfer [21]. However, in order to develop predictive models, a deeper understanding of the interactions at the bionano interface and their relationship to material and protein properties is necessary. Gathering more information

Ion beam processing of DNA origami nanostructures

• Leo Sala,
• Agnes Zerolová,
• Violaine Vizcaino,
• Alain Mery,
• Alicja Domaracka,
• Hermann Rothard,
• Philippe Boduch,
• Dominik Pinkas and
• Jaroslav Kocišek

Beilstein J. Nanotechnol. 2024, 15, 207–214, doi:10.3762/bjnano.15.20

• , we have observed the stability of DNA origami nanotriangles in dry and aqueous conditions upon exposure to high doses of ionizing radiation in the low linear energy transfer (LET) regime [17]. These results demonstrate DNA origami’s suitability for fundamental studies with ionizing radiation and now

• nanostructure height must be associated with the energy transfer within the DNA nanostructure or highly localized effects, such as thermal and pressure shock waves in the vicinity of the track [40]. We are now preparing experiments to explore this issue. The formation of craters on the nanostructures was

• irradiation in air The higher-energy irradiation 56Fe25+ (60 MeV/u) could only be performed in air and at lower fluences to avoid heating of the sample due to high energy transfer to the substrate as well as to avoid activation of irradiated components. Figure 1B shows AFM images of samples irradiated with

CdSe/ZnS quantum dots as a booster in the active layer of distributed ternary organic photovoltaics

• Gabriela Lewińska,
• Piotr Jeleń,
• Zofia Kucia,
• Maciej Sitarz,
• Łukasz Walczak,
• Bartłomiej Szafraniak,
• Jerzy Sanetra and
• Konstanty W. Marszalek

Beilstein J. Nanotechnol. 2024, 15, 144–156, doi:10.3762/bjnano.15.14

• , the effect of quantum dots in the spectrum is not apparent, indicating that the transitions in the mixture are quenched. This suppression is a result of energy transfer, which necessitates electron clouds of atoms or chemical groups to exhibit overlapping regions. During energy transfer, an electron

• moves from the donor to the acceptor and occupies the acceptor’s least occupied orbital. As a consequence of this energy transfer, the donor returns from an excited state to its ground state, while the acceptor remains in its ground state due to its higher electronegativity. This absence of excited

• equal to or greater than the binding energy of singlet and triplet excitons. The energy levels system of the considered devices with QDs determines the optimal photocurrent of dissociation for most singlet excitons, which require at least 0.07 eV energy [64]. The production of charge-transfer carrier

Enhanced feedback performance in off-resonance AFM modes through pulse train sampling

• Mustafa Kangül,
• Navid Asmari,
• Santiago H. Andany,
• Marcos Penedo and
• Georg E. Fantner

Beilstein J. Nanotechnol. 2024, 15, 134–143, doi:10.3762/bjnano.15.13

• File 1, Figure S1A). In order to investigate the frequency response of the feedback controller, we define the closed-loop transfer function between error, E(s), and disturbance, D(s), in the Laplace domain as in Equation 2, where Tort, Tdelay, Ki denote the ORT period, the delay, and the integral gain

• , respectively (derivation of the formula is provided in Supporting Information File 1). The non-zero delay in the closed-loop system forms a second-order transfer function, which can exhibit a high-amplitude resonance peak in the closed loop, potentially leading to instabilities, depending on Tort, Tdelay, and

In situ optical sub-wavelength thickness control of porous anodic aluminum oxide

• Aleksandrs Dutovs,
• Raimonds Popļausks,
• Oskars Putāns,
• Vladislavs Perkanuks,
• Aušrinė Jurkevičiūtė,
• Tomas Tamulevičius,
• Uldis Malinovskis,
• Iryna Olyshevets,
• Donats Erts and
• Juris Prikulis

Beilstein J. Nanotechnol. 2024, 15, 126–133, doi:10.3762/bjnano.15.12

• consistently manufacturing PAAO with the targeted thickness. An electrochemical cell with an optical window was designed for reflectance spectroscopy of PAAO during anodization. Real-time fitting of spectra to a transfer-matrix model enabled continuous monitoring of the thickness growth of the PAAO layer

• the reflectance spectra to a multilayer model of a water–PAAO–aluminum system using the transfer-matrix method (TMM) [22]. Previously, TMM has been employed only for post-production thickness analysis of PAAO-based stratified systems [13][23]. In the present study, it allowed for continuous in situ

• , temperature, voltage, and sample geometry) were found to be less than 1 nm/s. Together with spectrum acquisition, data transfer, and other tasks, it was possible to extract hPAAO values at 0.2 s intervals, which resulted in sub-nanometer sampling resolution of hPAAO. However, it is important to note that

Assessing phytotoxicity and tolerance levels of ZnO nanoparticles on Raphanus sativus: implications for widespread adoptions

• Pathirannahalage Sahan Samuditha,
• Nadeesh Madusanka Adassooriya and
• Nazeera Salim

Beilstein J. Nanotechnol. 2024, 15, 115–125, doi:10.3762/bjnano.15.11

• absorption peak below 400 nm due to the nanometric size effect of the synthesized ZnO and characteristic hexagonal ZnO NPs [32]. A broad band at 362 nm in the UV–vis spectrum was reported, indicating the formation of ZnO NPs, and it could be due to an electron transfer from the valence to the conduction band

Influence of conductive carbon and MnCo₂O₄ on morphological and electrical properties of hydrogels for electrochemical energy conversion

• Sylwia Pawłowska,
• Karolina Cysewska,
• Yasamin Ziai,
• Jakub Karczewski,
• Piotr Jasiński and
• Sebastian Molin

Beilstein J. Nanotechnol. 2024, 15, 57–70, doi:10.3762/bjnano.15.6

• Rs corresponds to solution resistance, Rct is related to charge transfer resistance at the interface of the solution and the electrode material, while CPE is a constant phase element, which represents capacitive performance of the electrode. The circuit parameters and their standard deviations were

• , the results indicate that microporosity, and thus the electroactive surface area of the electrode, increases with a higher content of cCB in the hydrogel-MCO film. A slightly different trend can be observed for the charge transfer resistance Rct at the solution–film interface. The highest Rct is

• particles dispersed inside the structure of the hydrogel (75–90 mV/dec) (Figure 5c). Depending on the potential applied and the process condition, the water oxidation could be a one to four electron transfer process [57][58]. Tafel slope values in the range of 75–90 mV·dec−1 represent a possible mixed

Josephson dynamics and Shapiro steps at high transmissions: current bias regime

• Artem V. Galaktionov and
• Andrei D. Zaikin

Beilstein J. Nanotechnol. 2024, 15, 51–56, doi:10.3762/bjnano.15.5

• T → 0 can flow across the junction. The situation becomes entirely different provided one goes beyond the tunneling limit and considers highly transparent superconducting weak links in which case the charge transfer is essentially controlled by the mechanism of multiple Andreev reflection [2]. This

Curcumin-loaded nanostructured systems for treatment of leishmaniasis: a review

• Douglas Dourado,
• Thayse Silva Medeiros,
• Éverton do Nascimento Alencar,
• Edijane Matos Sales and
• Fábio Rocha Formiga

Beilstein J. Nanotechnol. 2024, 15, 37–50, doi:10.3762/bjnano.15.4

• of nanostructured curc in vivo. Also, clinical studies that prove the efficacy and safety of nanostructured curc must be conducted to encourage the transfer of these formulations to the therapeutic scenario. Based on the findings, polymeric nanoparticles reveal themselves to be a step ahead in the

TEM sample preparation of lithographically patterned permalloy nanostructures on silicon nitride membranes

• Joshua Williams,
• Michael I. Faley,
• Joseph Vimal Vas,
• Peng-Han Lu and
• Rafal E. Dunin-Borkowski

Beilstein J. Nanotechnol. 2024, 15, 1–12, doi:10.3762/bjnano.15.1

• fabrication, stencil lithography employs a separate mask that is later aligned on the substrate and retains its aperture after the pattern transfer. This technique has advantages including simplicity in process, reusable masks, and the absence of resist masks. The latter eliminates common challenges

Spatial variations of conductivity of self-assembled monolayers of dodecanethiol on Au/mica and Au/Si substrates

• Julian Skolaut,
• Jędrzej Tepper,
• Federica Galli,
• Wulf Wulfhekel and
• Jan M. van Ruitenbeek

Beilstein J. Nanotechnol. 2023, 14, 1169–1177, doi:10.3762/bjnano.14.97

• warm ethanol. DDT SAMs were deposited onto these substrates by immersing them in a 10 mM solution of DDT in ethanol with subsequent incubation for 24 h. After transfer into a glovebox, the samples were rinsed with ethanol and dried. To improve the order of the SAMs, they were again immersed in 10 mM

A bifunctional superconducting cell as flux qubit and neuron

• Dmitrii S. Pashin,
• Pavel V. Pikunov,
• Marina V. Bastrakova,
• Andrey E. Schegolev,
• Nikolay V. Klenov and
• Igor I. Soloviev

Beilstein J. Nanotechnol. 2023, 14, 1116–1126, doi:10.3762/bjnano.14.92

• transfer characteristic should be such that small fluctuations at the input do not produce a noticeable response, but above a certain threshold, any signal at the input produces a fixed magnetic flux at the output. Also, if it were possible to adapt the ASL cell in a perceptron to process the signal from a

• l). Here and further, we use magnetic fluxes normalised by the quantum value, Φ0. To investigate the flux-to-flux transfer characteristics of such a system, it is convenient to interpret its evolution as the movement of a particle with “mass” M = and “momentum” p = in the potential profile defined

• affect the flux-to-flux transfer characteristics of such systems. In [30], we demonstrated that increasing the coupling coefficient of the interferometer with the reservoir suppresses oscillations of the mean flux value (generalised coordinate) caused by nonadiabatic interference effects. However

Density functional theory study of Au-fcc/Ge and Au-hcp/Ge interfaces

• Olga Sikora,
• Małgorzata Sternik,
• Benedykt R. Jany,
• Franciszek Krok,
• Przemysław Piekarz and
• Andrzej M. Oleś

Beilstein J. Nanotechnol. 2023, 14, 1093–1105, doi:10.3762/bjnano.14.90

• atom forms two bonds with Au atoms in the Au-fcc/Ge structure and only one at the Au-hcp/Ge interface. The maps of charge density differences show charge transfer occurs both at the interface and in the adjacent germanium layer. Appendix A Surface energies The surface energies calculated for several

•  13 with yellow regions representing charge accumulation and light blue regions indicating charge depletion. For all heterostructures, the charge transfer from Au and Ge interfacial atoms leads to the electron accumulation at approximately half of their distance. At the presented isocharge surface

Dual-heterodyne Kelvin probe force microscopy

• Benjamin Grévin,
• Fatima Husainy,
• Dmitry Aldakov and
• Cyril Aumaître

Beilstein J. Nanotechnol. 2023, 14, 1068–1084, doi:10.3762/bjnano.14.88

• cantilever eigenmode. This transfer or rejection (i.e., a measurement of a Fourier harmonic at the pump frequency through a demodulation at the second eigenmode frequency) is achieved by using two numerical lock-in amplifiers in cascade, which allows the generation of proper phase-coherent combination of

• components (modulus and phase) onto a 2D grid. The validity of DHe-KPFM implementation is first demonstrated by carrying out measurements on a conducting reference substrate under electrical pumping. The results confirm that – thanks to the constant transfer function over the entire spectrum provided by the

• time window. However, it offers interesting advantages. First, the sideband rejection at the second eigenmode ensures that the transfer function remains exactly the same regardless of the measured harmonic. This allows a quantitative measurement of the Fourier components without the need for cantilever

Experimental investigation of usage of POE lubricants with Al₂O₃, graphene or CNT nanoparticles in a refrigeration compressor

• Kayhan Dağıdır and
• Kemal Bilen

Beilstein J. Nanotechnol. 2023, 14, 1041–1058, doi:10.3762/bjnano.14.86

• nanoparticles at different concentrations. They found that the addition of nanoparticles enhanced the thermophysical properties and heat transfer characteristics of the lubricant. The researchers specified that nanolubricants typically provide greater thermal conductivity and viscosity in comparison to pure

• that the thermal conductivity and viscosity of the nanolubricant increased with the increase in mass fraction at a constant temperature. This capability in thermal conductivity enhancement can aid in addressing heat transfer issues within systems. Due to the fact that heat transfer takes place at the

• to the fact that heat transfer is fundamentally a surface-related process [5]. Nanolubricants have been widely used in recent years to improve the performance of refrigeration compressors [6][7][8]. Singh et al. [9] experimentally verified the effect of addition of multiwalled carbon nanotube (MWCNT

A visible-light photodetector based on heterojunctions between CuO nanoparticles and ZnO nanorods

• Doan Nhat Giang,
• Nhat Minh Nguyen,
• Duc Anh Ngo,
• Thanh Trang Tran,
• Le Thai Duy,
• Cong Khanh Tran,
• Thi Thanh Van Tran,
• Phan Phuong Ha La and
• Vinh Quang Dang

Beilstein J. Nanotechnol. 2023, 14, 1018–1027, doi:10.3762/bjnano.14.84

• properties of ZnO nanostructures, such as bandgap or conductivity [26]. Decorating ZnO with metals such as Ag, Au, Pd, Pt, and Al [27][28] can provide surface plasmonic effects that assist the electron transfer process in materials and extend the light absorption range of a photodetector [29][30]. However

• , increasing the visible-light intensity promotes more excited electrons in the conduction band (CB) of CuO NPs. These electrons transfer to the CB of ZnO NRs and increase the photocurrent collected by the Ag electrodes. Response time and recovery are essential when evaluating a photodetector’s performance

• generation can occur easily inside CuO NPs as this material has a suitable value of Eg (ca. 1.7 eV): Since the CB of CuO NPs is higher (more negative) than that of ZnO NRs, photoexcited electrons in CuO easily transfer into ZnO NRs, while holes stay in the VB of CuO NPs: Besides the internal electric field

Exploring internal structures and properties of terpolymer fibers via real-space characterizations

• Michael R. Roenbeck and
• Kenneth E. Strawhecker

Beilstein J. Nanotechnol. 2023, 14, 1004–1017, doi:10.3762/bjnano.14.83

• . Nevertheless, Ozawa hypothesized that well-aligned, extended chain molecules consisting of 50% PPTA concentration could still effectively transfer applied loads between adjacent chains [1]. These previous characterizations of the molecular chemistry of Technora® appear to explain the branched network of

• chemistry of Kevlar® (Figure 1) leads to a well-ordered molecular structure (i.e., ‘ACACAC…’ in Figure 9), which should enhance load transfer at this scale compared to Technora®. Together, the more uniform molecular sequencing and the resulting microstructure in Kevlar® appear to explain why K29 has higher

Nanoarchitectonics of photothermal materials to enhance the sensitivity of lateral flow assays

• Elangovan Sarathkumar,
• Rajasekharan S. Anjana and
• Ramapurath S. Jayasree

Beilstein J. Nanotechnol. 2023, 14, 988–1003, doi:10.3762/bjnano.14.82

• results again verified that smaller nanorods have better heat transfer characteristics than larger nanorods because of their high cross-sectional area [48] (Figure 5C,D). Though the application of photothermal nanomaterials is not explored much in LFAs, it is expected that enhanced plasmon resonance could

Fragmentation of metal(II) bis(acetylacetonate) complexes induced by slow electrons

• Janina Kopyra and
• Hassan Abdoul-Carime

Beilstein J. Nanotechnol. 2023, 14, 980–987, doi:10.3762/bjnano.14.81

• scale was calibrated using a flow of SF6 gas through the oven that produced the well-known SF6− resonance near 0 eV. The measurements were performed without the presence of the calibration gas, avoiding potentially unwanted reactions such as dissociative electron transfer with the investigated molecules

Upscaling the urea method synthesis of CoAl layered double hydroxides

• Camilo Jaramillo-Hernández,
• Víctor Oestreicher,
• Martín Mizrahi and
• Gonzalo Abellán

Beilstein J. Nanotechnol. 2023, 14, 927–938, doi:10.3762/bjnano.14.76

• , evidencing differences in heat transfer. Hence, considering that the precipitation kinetics is controlled by the alkalization process (i.e., the hydrolysis of urea, which depends on the temperature [35]), modifications in the heating process can affect the final size and shape of the particles [69]. This

• size is observed as the volume increases. This feature is related to changes in the heating process (heat transfer) modifying the alkalinization kinetics and the concomitant precipitation process, even after 48 h of recrystallization. These results suggest that the final LDH morphology (size and

Ni, Co, Zn, and Cu metal-organic framework-based nanomaterials for electrochemical reduction of CO₂: A review

• Ha Huu Do and
• Hai Bang Truong

Beilstein J. Nanotechnol. 2023, 14, 904–911, doi:10.3762/bjnano.14.74

• transfer processes take place to create intermediates such as *CHO, *CO, and *COO. The process could include many electrons attending in the electrochemical reaction, and orientate the formed products. Finally, these species are desorbed from the active sites of electrocatalysts to generate various

Industrial perspectives for personalized microneedles

• Remmi Danae Baker-Sediako,
• Benjamin Richter,
• Matthias Blaicher,
• Michael Thiel and
• Martin Hermatschweiler

Beilstein J. Nanotechnol. 2023, 14, 857–864, doi:10.3762/bjnano.14.70

• production is advantageous for reducing design transfer and going to market faster. Microneedle fabrication is a rapidly evolving field that is overcoming traditional fabrication challenges and opening the door for personalized medicine. Methods All microneedle arrays in the presented images were 3D printed

Biomimetics on the micro- and nanoscale – The 25th anniversary of the lotus effect

• Matthias Mail,
• Kerstin Koch,
• Thomas Speck,
• William M. Megill and
• Stanislav N. Gorb

Beilstein J. Nanotechnol. 2023, 14, 850–856, doi:10.3762/bjnano.14.69

• concept of “copying” nature or learning from it arose (e.g., the story of Daedalus and Icarus [4]). This and other examples show that often physical phenomena in animals and plants can be described; however, it is not possible to immediately understand the mechanisms behind them and to transfer those to

• new research techniques and methodologies that enabled detailed investigation of biological archetypes. High-detail microscopy, analysis systems, and novel simulation tools helped to decode the secrets of nature, while new fabrication techniques helped to transfer these findings into technical

• applications. In the last decades, production methods have enabled the transfer of many outstanding properties of the biological archetypes into innovative biomimetic products at reasonable cost. These developments helped to bring the field of biomimetics forward, initially by fostering interest in biomimetic

Nanostructured lipid carriers containing benznidazole: physicochemical, biopharmaceutical and cellular in vitro studies

• Giuliana Muraca,
• María Esperanza Ruiz,
• Rocío C. Gambaro,
• Sebastián Scioli-Montoto,
• María Laura Sbaraglini,
• Gisel Padula,
• José Sebastián Cisneros,
• Cecilia Yamil Chain,
• Vera A. Álvarez,
• Cristián Huck-Iriart,
• Guillermo R. Castro,
• María Belén Piñero,
• Matias Ildebrando Marchetto,
• Catalina Alba Soto,
• Germán A. Islan and
• Alan Talevi

Beilstein J. Nanotechnol. 2023, 14, 804–818, doi:10.3762/bjnano.14.66

• intensity, I(q), was recorded by means of the scattering momentum transfer q, where q = 4π/λ sin(θ), 2θ is the scattering angle and λ = 0.15419 nm is the weighted average of the X-ray wavelength of the Cu Kα1,2 emission lines. Owing to the small beam size pointed at the sample (< 1 mm × 1 mm) smearing

Silver-based SERS substrates fabricated using a 3D printed microfluidic device

• Phommachith Sonexai,
• Minh Van Nguyen,
• Bui The Huy and
• Yong-Ill Lee

Beilstein J. Nanotechnol. 2023, 14, 793–803, doi:10.3762/bjnano.14.65

• formation of a charge-transfer complex between chemisorbed species and matrix material, which yields enhancement when the excitation frequency resonates with a charge-transfer transition [7]. Noble metal nanoparticles (NPs) have gained much popularity in various fields, such as analytical chemistry and

• reactants in segmented flow and oil in continuous flow. They can control the reaction rates by mass transfer through convection and diffusion [20][21]. Furthermore, droplet-based microfluidic devices are frequently utilized to synthesize complex materials of uniform size, as each droplet can function as a

• moved from water to hexane with the aid of acetone. The porous silicon (PS) template substrate was placed at the bottom of a beaker containing methanol. A pipette was then used to gradually transfer the Ag NPs suspension in hexane to the surface of methanol. After the hexane evaporated, a tightly packed