Continuous parallel ESI-MS analysis of reactions carried out in a bespoke 3D printed device

• Jennifer S. Mathieson,
• Mali H. Rosnes,
• Victor Sans,
• Philip J. Kitson and
• Leroy Cronin

Beilstein J. Nanotechnol. 2013, 4, 285–291, doi:10.3762/bjnano.4.31

• purity. Electrospray ionisation mass spectrometry (ESI-MS) is an excellent analytical tool for flow chemistry due to its high sensitivity, allowing for low sample concentrations and production of structural information that you may not get from other techniques. There are several reports in which ESI-MS

• form the species Cu(C24H24N6)(NO3)]+ (1), m/z 521.1, which can be observed in the mass spectrometry data approximately 5 min after initiation. Analysis of the continuous parallel ESI-MS data collected showed both the species [Ni(C24H24N6)(NO3)]+ (2), m/z 516.1, and [Cu(C24H24N6)(NO3)]+ (1), m/z 521.1

Diamond nanophotonics

• Katja Beha,
• Helmut Fedder,
• Marco Wolfer,
• Merle C. Becker,
• Petr Siyushev,
• Mohammad Jamali,
• Anton Batalov,
• Christopher Hinz,
• Jakob Hees,
• Lutz Kirste,
• Harald Obloh,
• Etienne Gheeraert,
• Boris Naydenov,
• Ingmar Jakobi,
• Florian Dolde,
• Sébastien Pezzagna,
• Daniel Twittchen,
• Matthew Markham,
• Daniel Dregely,
• Harald Giessen,
• Jan Meijer,
• Fedor Jelezko,
• Christoph E. Nebel,
• Rudolf Bratschitsch,
• Alfred Leitenstorfer and
• Jörg Wrachtrup

Beilstein J. Nanotechnol. 2012, 3, 895–908, doi:10.3762/bjnano.3.100

• decrease of the nickel signal after lowering the argon flux at both 40 min and 50 min indicates the absence of unwanted hysteresis effects. 5.3 Verification of nickel incorporation The incorporation of nickel into the as-grown diamond layers was verified by secondary ion mass spectrometry (SIMS). An

Magnetic-Fe/Fe₃O₄-nanoparticle-bound SN38 as carboxylesterase-cleavable prodrug for the delivery to tumors within monocytes/macrophages

• Hongwang Wang,
• Tej B. Shrestha,
• Matthew T. Basel,
• Raj K. Dani,
• Gwi-Moon Seo,
• Sivasai Balivada,
• Marla M. Pyle,
• Heidy Prock,
• Olga B. Koper,
• Prem S. Thapa,
• David Moore,
• Ping Li,
• Viktor Chikan,
• Deryl L. Troyer and
• Stefan H. Bossmann

Beilstein J. Nanotechnol. 2012, 3, 444–455, doi:10.3762/bjnano.3.51

• of the hydroxyl groups by Pd/C-catalyzed hydrogenation, and was used as ligand II to incorporate SN38 to the MNPs. Compound 13 was fully characterized with 1H NMR, 13C NMR, and mass spectrometry. Loading SN38 to Fe/Fe3O4 magnetic nanoparticles (MNPs) Loading of SN38 to core/shell Fe/Fe3O4 magnetic

• -binding SN38 prodrug was achieved in a 10-stage synthesis with overall 32% yield. The final product was fully characterized by 1H NMR, 13C NMR, and mass spectrometry. Characterization of the nanoparticles Figure 1a shows a low-resolution transmission electron microscope (TEM) image of the nanoparticles

Femtosecond time-resolved photodissociation dynamics of methyl halide molecules on ultrathin gold films

• Mihai E. Vaida,
• Robert Tchitnga and
• Thorsten M. Bernhardt

Beilstein J. Nanotechnol. 2011, 2, 618–627, doi:10.3762/bjnano.2.65

• chloride, adsorbed on a metal surface was investigated in real time by means of femtosecond-laser pump–probe mass spectrometry. A weakly interacting gold surface was employed as substrate because the intact adsorption of the methyl halide molecules was desired prior to photoexcitation. The gold surface was

• at all. Keywords: femtosecond laser spectroscopy; gold; methyl halide photodissociation; surface chemistry; time-of-flight mass spectrometry; Introduction The understanding of the mechanisms involved in the light-induced excitation and fragmentation of organic molecules on metal substrates is of

• free molecule [3] cannot be energetically lowered enough to become accessible to the 4.7 eV photons of the 266 nm pump laser beam. Conclusion The present investigation demonstrates that time resolved pump–probe fs-laser time-of-flight mass spectrometry is able to probe the photodissociation dynamics of

Nanostructured, mesoporous Au/TiO₂ model catalysts – structure, stability and catalytic properties

• Matthias Roos,
• Dominique Böcking,
• Kwabena Offeh Gyimah,
• Gabriela Kucerova,
• Joachim Bansmann,
• Johannes Biskupek,
• Ute Kaiser,
• Nicola Hüsing and
• R. Jürgen Behm

Beilstein J. Nanotechnol. 2011, 2, 593–606, doi:10.3762/bjnano.2.63

• room temperature, and in particular on ii) exploring the role of transport effects in these films on the reaction characteristics, both by locally resolved measurements on microstructured samples by means of higher resolution scanning mass spectrometry and by time-resolved measurements, e.g., in a