Nanostructured carbon materials decorated with organophosphorus moieties: synthesis and application

• Giacomo Biagiotti,
• Vittoria Langè,
• Cristina Ligi,
• Stefano Caporali,
• Maurizio Muniz-Miranda,
• Anna Flis,
• K. Michał Pietrusiewicz,
• Giacomo Ghini,
• Alberto Brandi and
• Stefano Cicchi

Beilstein J. Nanotechnol. 2017, 8, 485–493, doi:10.3762/bjnano.8.52

• 11 and 12 (Scheme 3) [33]. The successful decoration of NMs 11 and 12 was confirmed by elemental analysis and IR spectroscopy (see Supporting Information File 1, Figures S9 and S10) and, finally, they were reacted with compound 3 to afford the functionalized compounds 13 and 14 (Scheme 3). The

Methods for preparing polymer-decorated single exchange-biased magnetic nanoparticles for application in flexible polymer-based films

• Laurence Ourry,
• Delphine Toulemon,
• Souad Ammar and
• Fayna Mammeri

Beilstein J. Nanotechnol. 2017, 8, 408–417, doi:10.3762/bjnano.8.43

• polystyrene (PS), using radical-controlled polymerization under various processing conditions. We evidenced through TGA, IR spectroscopy and XPS measurements that polymer chains were efficiently grafted onto the nanoparticles using either the direct grafting or the “all in solution” process. In the TEM images

Tailoring bifunctional hybrid organic–inorganic nanoadsorbents by the choice of functional layer composition probed by adsorption of Cu²⁺ ions

• Veronika V. Tomina,
• Inna V. Melnyk,
• Yuriy L. Zub,
• Aivaras Kareiva,
• Miroslava Vaclavikova,
• Gulaim A. Seisenbaeva and
• Vadim G. Kessler

Beilstein J. Nanotechnol. 2017, 8, 334–347, doi:10.3762/bjnano.8.36

• particles was confirmed by IR spectroscopy (diffuse reflectance infrared Fourier transform, DRIFT, for details see Figure S6, Supporting Information File 1) and their structure was analyzed by solid-state NMR. All the 13C CP/MAS NMR spectra (Figure 3, Figure S2 and assignment in Tables S2 and S3, Supporting

• Information File 1). It can be deduced that the introduction of a silane bearing a hydrophobic group possibly favors nucleation over growth and results in relatively smaller particles. Molecular structure of the functional layers from IR and NMR data IR spectroscopy was used to identify the presence of

• functional groups in the surface layers of nanoparticles. Consequently, IR spectroscopy confirmed the presence of a polysiloxane network containing 3-aminopropyl and methyl or fluorinated functional groups, as well as silanol groups, and alkyl radicals in the synthesized particles. Furthermore, all samples

From iron coordination compounds to metal oxide nanoparticles

• Mihail Iacob,
• Carmen Racles,
• Codrin Tugui,
• George Stiubianu,
• Adrian Bele,
• Liviu Sacarescu,
• Daniel Timpu and
• Maria Cazacu

Beilstein J. Nanotechnol. 2016, 7, 2074–2087, doi:10.3762/bjnano.7.198

• structures protruding from the surface at various angles, but generally in a radial direction from the sphere center. The diameter of the spheres is 80 ± 60 nm, and the hairs are of 20 ± 5 nm length and 2 ± 0.5 nm width. The analysis of the samples by IR spectroscopy (Supporting Information File 1, Figure S6

• carboxyl groups at 1649–1641 cm−1 and 1439 cm−1. The bands at 2853–2851 cm−1 and 2922 cm−1 are attributed to CH2 groups, which are characteristic of fatty acids [26]. Absorption bands characteristic for CH3 groups were identified at 2955 cm−1 in the spectra of all the samples. From the data obtained by IR

• spectroscopy it can be deduced that nanoparticle samples NPS1–NPS3 are coated with organic material (stabilizing agents). The presence of iron in the samples NPS1–NPS3 was confirmed by XRF spectroscopy (Supporting Information File 1, Figure S11b). The residual mass at the end of the temperature range

Localized surface plasmons in structures with linear Au nanoantennas on a SiO₂/Si surface

• Ilya A. Milekhin,
• Sergei A. Kuznetsov,
• Ekaterina E. Rodyakina,
• Alexander G. Milekhin,
• Alexander V. Latyshev and
• Dietrich R. T. Zahn

Beilstein J. Nanotechnol. 2016, 7, 1519–1526, doi:10.3762/bjnano.7.145

• spectral region are considered as promising nanostructures for the detection of small amounts of both organic (down to attomoles) and inorganic substances, including semiconductor nanocrystals [18][23][24][25][26][27]. In this approach serving as the basis for surface-enhanced IR spectroscopy, the IR

Large-scale fabrication of achiral plasmonic metamaterials with giant chiroptical response

• Morten Slyngborg,
• Yao-Chung Tsao and
• Peter Fojan

Beilstein J. Nanotechnol. 2016, 7, 914–925, doi:10.3762/bjnano.7.83

• surface or through functionalized surfaces to increase the sensing sensitivity. Besides increasing the sensing sensitivity, these metamaterials may also be commercialized and find applications in surface-enhanced IR spectroscopy, terahertz generation and terahertz circular dichroism spectroscopy

• wavelength above 900 nm (data not shown). These structures may find applications in other areas such as surface enhanced IR spectroscopy [41], terahertz generation [42] or THz-CD spectroscopy [43]. Influence of the scanning angle and of intrinsic spatial structural variations As mentioned above, the

Correlative infrared nanospectroscopic and nanomechanical imaging of block copolymer microdomains

• Benjamin Pollard and
• Markus B. Raschke

Beilstein J. Nanotechnol. 2016, 7, 605–612, doi:10.3762/bjnano.7.53

• enables IR spectroscopy on the nanoscale using broadband [3][4] or tunable light sources [5]. Combined with computational imaging to analyze spectral peak position and lineshape, as well as polarization selection, s-SNOM can probe intermolecular coupling [6], polymorphism [7], molecular orientation

Rigid multipodal platforms for metal surfaces

• Michal Valášek,
• Marcin Lindner and
• Marcel Mayor

Beilstein J. Nanotechnol. 2016, 7, 374–405, doi:10.3762/bjnano.7.34

• typically poorly ordered due to the presence of long alkyl chains as revealed by IR spectroscopy analysis of ß-cyclodextrin and resorcin[4]arene scaffolds. Substitution of these platforms with long dialkylsulfides with a lower affinity to gold improved the lateral mobility of monolayers. The increased

Chemical bath deposition of textured and compact zinc oxide thin films on vinyl-terminated polystyrene brushes

• Nina J. Blumenstein,
• Caroline G. Hofmeister,
• Peter Lindemann,
• Cheng Huang,
• Johannes Baier,
• Andreas Leineweber,
• Stefan Walheim,
• Christof Wöll,
• Thomas Schimmel and
• Joachim Bill

Beilstein J. Nanotechnol. 2016, 7, 102–110, doi:10.3762/bjnano.7.12

• (002) direction. IR spectroscopy measurements indicate that the nonpolar PS brush partially decomposes via a transesterification reaction, resulting in a polar surface. This new surface interacts with the ZnO crystallites, which are simultaneously formed within the solution and assemble in an

Surfactant-controlled composition and crystal structure of manganese(II) sulfide nanocrystals prepared by solvothermal synthesis

• Elena Capetti,
• Anna M. Ferretti,
• Vladimiro Dal Santo and
• Alessandro Ponti

Beilstein J. Nanotechnol. 2015, 6, 2319–2329, doi:10.3762/bjnano.6.238

• comprises both amine and carboxylic acid surfactants, otherwise α-MnS NCs are formed. Whether the carboxylic acid is present as free surfactant or as carboxylate ligand within the Mn precursor is irrelevant to the crystal structure of the resulting NCs. ATR-IR spectroscopy of MnS NCs The attenuated total

Nanofibers for drug delivery – incorporation and release of model molecules, influence of molecular weight and polymer structure

• Jakub Hrib,
• Jakub Sirc,
• Radka Hobzova,
• Zuzana Hampejsova,
• Zuzana Bosakova,
• Marcela Munzarova and
• Jiri Michalek

Beilstein J. Nanotechnol. 2015, 6, 1939–1945, doi:10.3762/bjnano.6.198

• , elemental analysis, IR spectroscopy and melting point measurements. The needle-free electrospinning process was optimized for each type of nanofiber with respect to the different physicochemical properties of polymers. SEM images revealed that the textures of all resultant samples were homogenous and free

The role of low-energy electrons in focused electron beam induced deposition: four case studies of representative precursors

• Rachel M. Thorman,
• Ragesh Kumar T. P.,
• D. Howard Fairbrother and
• Oddur Ingólfsson

Beilstein J. Nanotechnol. 2015, 6, 1904–1926, doi:10.3762/bjnano.6.194

• relatively high energy (400–500 eV). In such surface experiments, the desorbing fragments are analyzed with MS and the composition of the remaining deposit can be analyzed with techniques such as X-ray photoelectron spectroscopy (XPS), reflection-absorption IR spectroscopy (RAIRS), and/or high-resolution

Thermal treatment of magnetite nanoparticles

• Beata Kalska-Szostko,
• Urszula Wykowska,
• Dariusz Satula and
• Per Nordblad

Beilstein J. Nanotechnol. 2015, 6, 1385–1396, doi:10.3762/bjnano.6.143

• thermal stability of the nanoparticles was tested. Before and after heat treatment, the nanoparticles were examined using transmission electron microscopy, IR spectroscopy, differential scanning calorimetry, X-ray diffraction and Mössbauer spectroscopy. Based on the obtained results, it was observed that

• the fabrication methods determine, to some extent, the sensitivity of the nanoparticles to external factors. Keywords: high temperature corrosion; internal oxidation; IR spectroscopy; metal matrix composites; Mössbauer spectroscopy; X-ray diffraction; Introduction Nanostructured magnetite has become

• MNP-1, surface ligands are rigidly fixed to the sample and do not contain any weakly adsorbed solvents. However, MNP-2 and MNP-3 most likely contain residuals of solvents that gradually evaporate, which is not observed for the samples measured after heat treatment. IR spectroscopy Magnetite

From lithium to sodium: cell chemistry of room temperature sodium–air and sodium–sulfur batteries

• Philipp Adelhelm,
• Pascal Hartmann,
• Conrad L. Bender,
• Martin Busche,
• Christine Eufinger and
• Juergen Janek

Beilstein J. Nanotechnol. 2015, 6, 1016–1055, doi:10.3762/bjnano.6.105

Simple approach for the fabrication of PEDOT-coated Si nanowires

• Mingxuan Zhu,
• Marielle Eyraud,
• Judikael Le Rouzo,
• Nadia Ait Ahmed,
• Florence Boulc’h,
• Claude Alfonso,
• Philippe Knauth and
• François Flory

Beilstein J. Nanotechnol. 2015, 6, 640–650, doi:10.3762/bjnano.6.65

• transmission electron microcopies, energy-dispersive X-ray analysis, and IR spectroscopy. Results and Discussion Effect of tapering on SiNW antireflection The SiNWs, as prepared from an n-type Si substrate according to the process described in the Experimental section, can be seen in Figure 1. The geometry of

Materials and characterization techniques for high-temperature polymer electrolyte membrane fuel cells

• Roswitha Zeis

Beilstein J. Nanotechnol. 2015, 6, 68–83, doi:10.3762/bjnano.6.8

• . MEAs built from binderless electrodes demonstrated a stable cell performance over 900 h of operation [53]. Characterisation techniques for HT-PEMFCs Optical spectroscopy Raman and infrared spectroscopy – Acid-doping process of PBI membranes: Raman and infrared (IR) spectroscopy are powerful tools to

• phosphoric acid species on platinum: IR spectroscopy has been used as a tool to study electrochemical interfaces and to characterize adsorbed species on catalytic surfaces. Habib and Bockris [59] were the first who applied this technique to investigate the adsorption of phosphoric acid on platinum. Their

Localized surface plasmon resonances in nanostructures to enhance nonlinear vibrational spectroscopies: towards an astonishing molecular sensitivity

• Dan Lis and
• Francesca Cecchet

Beilstein J. Nanotechnol. 2014, 5, 2275–2292, doi:10.3762/bjnano.5.237

• chemical selectivity, and to identify specific molecules with no added labels. The two major techniques that have dominated for a long time in this field are infrared (IR) spectroscopy and spontaneous (incoherent) Raman scattering. In IR spectroscopy, IR radiation is absorbed by matter at specific

• . Therefore, to make vibrational techniques more efficient for surface science purposes, many efforts have been made to increase the surface sensitivity of IR and Raman spectroscopies. For instance, from IR spectroscopy is born polarization-modulation IR reflection–absorption spectroscopy (PM-IRRAS) [1], and

Characterization of 10,12-pentacosadiynoic acid Langmuir–Blodgett monolayers and their use in metal–insulator–metal tunnel devices

• Saumya Sharma,
• Mohamad Khawaja,
• Manoj K. Ram,
• D. Yogi Goswami and
• Elias Stefanakos

Beilstein J. Nanotechnol. 2014, 5, 2240–2247, doi:10.3762/bjnano.5.233

• controlled using the KSV NIMA LB Trough controller. For polymerization purposes, the monolayers were exposed to 245 nm UV radiation for 15 min using a UV bench lamp [17]. Optical characterization: A Jasco FTIR 4600 was used to perform IR spectroscopy on the PDA film in transmission mode. IR transparent Si

Influence of surface-modified maghemite nanoparticles on in vitro survival of human stem cells

• Michal Babič,
• Daniel Horák,
• Lyubov L. Lukash,
• Tetiana A. Ruban,
• Yurii N. Kolomiets,
• Svitlana P. Shpylova and
• Oksana A. Grypych

Beilstein J. Nanotechnol. 2014, 5, 1732–1737, doi:10.3762/bjnano.5.183

• . It should be pointed out that the particle size determined by TEM was smaller compared with the size measured by dynamic light scattering. The hydrodynamic size in water was in the range of 50–170 nm. The presence of the coating on the surface of the particles was confirmed by FT-IR spectroscopy [20

Ionic liquid-assisted formation of cellulose/calcium phosphate hybrid materials

• Ahmed Salama,
• Mike Neumann,
• Christina Günter and
• Andreas Taubert

Beilstein J. Nanotechnol. 2014, 5, 1553–1568, doi:10.3762/bjnano.5.167

• confirmed by XRD (Figure 8) because the XRD patterns can – at least partly – be assigned to chlorapatite. XRD and IR spectroscopy (Figure 9) further show that in the presence of GAA not HAP or ClAP forms initially, but dicalcium phosphate anhydrate (monetite CaHPO4, DCPA). This is interesting because DCPA

• melting point, not well suited. Other ILs such as acetates or formates would likely be more suitable candidates. TGA/DTA (Figure 10, Table 5) and IR spectroscopy (Figure 9) show that the mineralization of calcium phosphate in the presence of NaOH yields materials with significantly lower degrees of

Electron-beam induced deposition and autocatalytic decomposition of Co(CO)₃NO

• Florian Vollnhals,
• Martin Drost,
• Fan Tu,
• Esther Carrasco,
• Andreas Späth,
• Rainer H. Fink,
• Hans-Peter Steinrück and
• Hubertus Marbach

Beilstein J. Nanotechnol. 2014, 5, 1175–1185, doi:10.3762/bjnano.5.129

• insight into the underlying reaction(s), chemically more sensitive methods like XPS and IR spectroscopy may be helpful. The apparent cobalt thickness observed on the thick Fe seed layers is 7.4 ± 0.8 nm; the average growth rate is 0.35 ± 0.05 Å/min. It is likely, however, that the growth on Fe seeds

Adsorption and oxidation of formaldehyde on a polycrystalline Pt film electrode: An in situ IR spectroscopy search for adsorbed reaction intermediates

• Zenonas Jusys and
• R. Jürgen Behm

Beilstein J. Nanotechnol. 2014, 5, 747–759, doi:10.3762/bjnano.5.87

• adsorption/oxidation of formaldehyde on a polycrystalline Pt film electrode under experimental conditions optimizing the chance for detecting weakly adsorbed reaction intermediates. Employing in situ IR spectroscopy in an attenuated total reflection configuration (ATR-FTIRS) with p-polarized IR radiation to

• [13][14][15], or ii) dissociatively adsorb to form COad, resulting in higher COad coverages and hence enhanced surface poisoning [16]. Early in situ IR spectroscopy studies of C1 molecule oxidation had demonstrated the formation of adsorbed CO in the reaction, which was identified as reaction

• dehydrogenated species, e.g., by spectroscopic observation, however, is still missing. In two early in situ IR spectroscopy studies on methanol oxidation, the authors reported the observation of weak bands at 1215 and 1270 cm−1, which they attributed to adsorbed –CHxOH [42] or –COH [43] intermediates

Thermal stability and reduction of iron oxide nanowires at moderate temperatures

• Annalisa Paolone,
• Marco Angelucci,
• Stefania Panero,
• Maria Grazia Betti and
• Carlo Mariani

Beilstein J. Nanotechnol. 2014, 5, 323–328, doi:10.3762/bjnano.5.36

• by scanning electron microscopy. Conclusion: This complementary spectroscopy–microscopy study allows to assess the temperature limits of these Fe2O3 nanowires during operation, malfunctioning or abuse in advanced Li-ion based batteries. Keywords: IR spectroscopy; iron oxide; nanowires; scanning

• conclusive about which iron oxide is obtained after the loss of O2. Therefore, we used infrared and XPS spectroscopy in order to identify the phase changes that are induced by the thermal treatment. Infrared (IR) spectroscopy measurements were performed at room temperature (rt) on sample 2 and on two samples

En route to controlled catalytic CVD synthesis of densely packed and vertically aligned nitrogen-doped carbon nanotube arrays

• Slawomir Boncel,
• Sebastian W. Pattinson,
• Valérie Geiser,
• Milo S. P. Shaffer and
• Krzysztof K. K. Koziol

Beilstein J. Nanotechnol. 2014, 5, 219–233, doi:10.3762/bjnano.5.24

• the nanotube products, which ranged from 0.0 to 3.0 wt %, was controlled through the concentration of pyrazine in the feedstock. Moreover, as revealed by Raman/FT-IR spectroscopy, the incorporation of nitrogen atoms into the nanotube walls was found to be proportional to the number of deviations from

Continuous parallel ESI-MS analysis of reactions carried out in a bespoke 3D printed device

• Jennifer S. Mathieson,
• Mali H. Rosnes,
• Victor Sans,
• Philip J. Kitson and
• Leroy Cronin

Beilstein J. Nanotechnol. 2013, 4, 285–291, doi:10.3762/bjnano.4.31

• and improve the reactionware, for example, by including heat exchangers. For the in-line ESI-MS setup we intend to further utilise the split product stream by including other in-line techniques, such as UV–vis and IR spectroscopy. To further develop the 3D printing technology we are currently