Oxidative chemical vapor deposition of polyaniline thin films

• Yuriy Y. Smolin,
• Masoud Soroush and
• Kenneth K. S. Lau

Beilstein J. Nanotechnol. 2017, 8, 1266–1276, doi:10.3762/bjnano.8.128

• aluminum oxide, mesoporous TiO2, and activated carbon; these oCVD PTh coatings resulted in enhanced charge storage due to preservation of the surface area and pore space within the nanostructures [32]. As a result, PTh-coated carbon electrodes showed a 50% increase in specific capacitance and excellent

Nanotopographical control of surfaces using chemical vapor deposition processes

• Meike Koenig and
• Joerg Lahann

Beilstein J. Nanotechnol. 2017, 8, 1250–1256, doi:10.3762/bjnano.8.126

• and Oh used anodic aluminum oxide membranes as a template for the production of nanotubes with a tunable wall thickness (Figure 1) [11]. Via chemical oxidation polymerization of vaporized pyrroles, polypyrrole was deposited on the walls of the membrane pores which had been pretreated with ferric

• and patterned coatings from a great variety of polymer materials can be created that can be tailored to the respective applications. Polymer structures via masked deposition: polypyrrole nanotubes by deposition using aluminum oxide membranes with a pore size of 100 nm as the template. The wall

The integration of graphene into microelectronic devices

• Guenther Ruhl,
• Sebastian Wittmann,
• Matthias Koenig and
• Daniel Neumaier

Beilstein J. Nanotechnol. 2017, 8, 1056–1064, doi:10.3762/bjnano.8.107

• yields excellent results [4], but this is not a production-relevant approach. A material that is available in mass-production quantities and fulfills both mentioned requirements is aluminum oxide deposited by atomic-layer deposition (ALD). It was demonstrated that graphene encapsulated in Al2O3 could be

Synthesis of coaxial nanotubes of polyaniline and poly(hydroxyethyl methacrylate) by oxidative/initiated chemical vapor deposition

• Alper Balkan,
• Efe Armagan and
• Gozde Ozaydin Ince

Beilstein J. Nanotechnol. 2017, 8, 872–882, doi:10.3762/bjnano.8.89

• and anodic aluminum oxide template (AAO) with pore sizes of 200 nm were used as substrates and were coated simultaneously. Glass slides were used for electrical conductivity measurements and UV–visible spectroscopy (UV–vis). Si wafers were used for Fourier-transform infrared (FTIR) spectrophotometry

Recombinant DNA technology and click chemistry: a powerful combination for generating a hybrid elastin-like-statherin hydrogel to control calcium phosphate mineralization

• Mohamed Hamed Misbah,
• Mercedes Santos,
• Luis Quintanilla,
• Christina Günter,
• Matilde Alonso,
• Andreas Taubert and
• José Carlos Rodríguez-Cabello

Beilstein J. Nanotechnol. 2017, 8, 772–783, doi:10.3762/bjnano.8.80

• aluminum oxide crucible and heated at 20 °C/min under N2 purge (40 mL/min) from 50 to 1000 °C followed by an isothermal step at 1000 °C for 10 min. 6.6 Scanning electron microscopy (SEM) SEM images of the dry ELR/calcium phosphate composites were obtained using an FEI Quanta Field Emission SEM. Samples

Liquid permeation and chemical stability of anodic alumina membranes

• Dmitrii I. Petukhov,
• Dmitrii A. Buldakov,
• Alexey A. Tishkin,
• Alexey V. Lukashin and
• Andrei A. Eliseev

Beilstein J. Nanotechnol. 2017, 8, 561–570, doi:10.3762/bjnano.8.60

• channels blocking. This process intensifies in basic pH due to the high positive charge of the anodic alumina surface. An approach for improving anodic aluminum oxide stability towards dissolution in water by carbon CVD coating of the membrane walls is suggested. Keywords: anodic alumina; carbon-modified

• membranes; membrane stability; microfiltration membranes; ultrafiltration membranes; Introduction Porous anodic aluminum oxide (AAO), developed as a protective coating, has received close attention of the membrane community due to its unusual porous structure represented by piercing cylindrical channels

• deionized water was used in experiments, we suggested that the degradation of the membrane occurred by dissolution of the anodic aluminum oxide and its further redeposition on the pore walls. For a detailed determination of the anodic alumina degradation mechanism, chemical dissolution and buffered solution

Properties of Ni and Ni–Fe nanowires electrochemically deposited into a porous alumina template

• Alla I. Vorobjova,
• Dmitry L. Shimanovich,
• Kazimir I. Yanushkevich,
• Sergej L. Prischepa and
• Elena A. Outkina

Beilstein J. Nanotechnol. 2016, 7, 1709–1717, doi:10.3762/bjnano.7.163

• deposited on the flat surface (like a film) or into the narrow and long channels (pores) of an amorphous matrix (aluminum oxide) in the form of NWs. The template Al2O3 is X-ray amorphous (wide peak at 2θ = 25.16°). The XRD patterns of Ni–Fe NWs also demonstrate the polycrystalline nature of the Ni–Fe phase

Nano- and microstructured materials for in vitro studies of the physiology of vascular cells

• Alexandra M. Greiner,
• Adria Sales,
• Hao Chen,
• Sarah A. Biela,
• Dieter Kaufmann and
• Ralf Kemkemer

Beilstein J. Nanotechnol. 2016, 7, 1620–1641, doi:10.3762/bjnano.7.155

• obtain nanofibers from natural proteins such as fibronectin. Recently, an alternative method has been developed where nanofibers of extruded fibronectin through a nanoporous aluminum oxide membrane were obtained. This method is based on a mechanical force to provoke fibrillogenesis (generation of fibers

Nonlinear thermoelectric effects in high-field superconductor-ferromagnet tunnel junctions

• Stefan Kolenda,
• Peter Machon,
• Detlef Beckmann and
• Wolfgang Belzig

Beilstein J. Nanotechnol. 2016, 7, 1579–1585, doi:10.3762/bjnano.7.152

• experimental data (see below). Experiment and Results Our samples were fabricated by e-beam lithography and shadow evaporation. The central part is a tunnel junction between ferromagnetic iron and superconducting aluminum, with a thin aluminum oxide layer as tunnel barrier. An additional copper wire is

Multiwalled carbon nanotube hybrids as MRI contrast agents

• Nikodem Kuźnik and
• Mateusz M. Tomczyk

Beilstein J. Nanotechnol. 2016, 7, 1086–1103, doi:10.3762/bjnano.7.102

• vapor deposition (c-CVD) [20]. This is the most common method of MWCNT synthesis. The inherent consequence of the application of a metal catalyst (e.g., ferrocene, aluminum oxide) is the presence of a nanometallic deposit in the tubes [21]. Thus obtained MWCNTs are already an interesting scaffold for

Determination of Young’s modulus of Sb₂S₃ nanowires by in situ resonance and bending methods

• Liga Jasulaneca,
• Raimonds Meija,
• Alexander I. Livshits,
• Juris Prikulis,
• Subhajit Biswas,
• Justin D. Holmes and
• Donats Erts

Beilstein J. Nanotechnol. 2016, 7, 278–283, doi:10.3762/bjnano.7.25

• . Particular emphasis has been placed on the investigation of structural and optical properties of Sb2S3 thin films [19][20]. Recently, piezoelectricity and ferroelectricity has been demonstrated in individual single-crystalline Sb2S3 NWs embedded in anodic aluminum oxide (AAO) templates [17]. However

• conditions (e.g., clamping) than alignment of the external force. The obtained mean value was then compared to that of bulk material [35]. Experimental The examined Sb2S3 NWs were synthesized inside cylindrical pores of anodic aluminum oxide template (AAO) by a solvent-less technique. The as-synthesized NWs

Surface engineering of nanoporous substrate for solid oxide fuel cells with atomic layer-deposited electrolyte

• Sanghoon Ji,
• Waqas Hassan Tanveer,
• Wonjong Yu,
• Sungmin Kang,
• Gu Young Cho,
• Sung Han Kim,
• Jihwan An and
• Suk Won Cha

Beilstein J. Nanotechnol. 2015, 6, 1805–1810, doi:10.3762/bjnano.6.184

• Manufacturing Systems and Design Engineering Programme, Seoul National University of Science and Technology, Gongneung-ro, Nowon-gu, Seoul 139-743, South Korea 10.3762/bjnano.6.184 Abstract Solid oxide fuel cells with atomic layer-deposited thin film electrolytes supported on anodic aluminum oxide (AAO) are

• density than the thinner BEC cell at 500 °C. Keywords: anodic aluminum oxide; atomic layer deposition; bottom electrode catalyst; mass transport; solid oxide fuel cell; Introduction Recently solid oxide fuel cells with thin film ceramic electrolytes, called thin film solid oxide fuel cells (TF-SOFCs

• research on ways to enlarge the active cell area. In this regard, the use of scalable and porous substrates is one of the ways, among which anodic aluminum oxide (AAO) membranes are considered as prospective substrates due to their compatible thermal expansion properties with ceramic electrolytes, low

Nanotechnology in the real world: Redeveloping the nanomaterial consumer products inventory

• Marina E. Vance,
• Todd Kuiken,
• Eric P. Vejerano,
• Sean P. McGinnis,
• Michael F. Hochella Jr.,
• David Rejeski and
• Matthew S. Hull

Beilstein J. Nanotechnol. 2015, 6, 1769–1780, doi:10.3762/bjnano.6.181

• nanomaterials (silicon and silica), and other (organics, polymers, ceramics, etc.). (b) Claimed elemental composition of nanomaterials listed in the metals category: silver, titanium, zinc, gold, and other metals (magnesium, aluminum oxide, copper, platinum, iron and iron oxides, etc.). (c) Claimed carbonaceous

Effects of swift heavy ion irradiation on structural, optical and photocatalytic properties of ZnO–CuO nanocomposites prepared by carbothermal evaporation method

• Sini Kuriakose,
• D. K. Avasthi and
• Satyabrata Mohapatra

Beilstein J. Nanotechnol. 2015, 6, 928–937, doi:10.3762/bjnano.6.96

• of ZnO. Kumar et al. [35] have irradiated Co doped ZnO thin films, prepared by sol–gel route, with 100 MeV Ni7+ ions and studied the modifications in their structural and optical properties. Kumar et al. [36] studied 130 MeV Ni7+ irradiation induced morphological and optical changes of zinc aluminum

• oxide coated over porous silicon substrates. The changes in the structural and optical properties of ZnO thin films due to 100 MeV Au8+ irradiation were investigated by Agarwal et al. [37]. Even though there have been several studies on the ion-induced evolution of the structural and optical properties

Conformal SiO₂ coating of sub-100 nm diameter channels of polycarbonate etched ion-track channels by atomic layer deposition

• Nicolas Sobel,
• Christian Hess,
• Manuela Lukas,
• Anne Spende,
• Bernd Stühn,
• M. E. Toimil-Molares and
• Christina Trautmann

Beilstein J. Nanotechnol. 2015, 6, 472–479, doi:10.3762/bjnano.6.48

• adjust specific surface properties such as hydrophilicity or catalytic activity. Conform ALD coatings have been reported for various porous materials including powders [18] and porous membranes such as anodic aluminum oxide (AAO) [19][20][21][22][23][24] and track-etched membranes [25][26][27][28]. For

Synthesis of boron nitride nanotubes and their applications

• Saban Kalay,
• Zehra Yilmaz,
• Ozlem Sen,
• Melis Emanet,
• Emine Kazanc and
• Mustafa Çulha

Beilstein J. Nanotechnol. 2015, 6, 84–102, doi:10.3762/bjnano.6.9

• . synthesized BNNTs by means of microwave plasma at a temperature lower than 520 °C [40]. In this technique, a 6–100 nm pore size, aluminum oxide template was used along with microwave plasma. The BNNTs were grown on the surface of this template in the presence of B2H6/Ar and NH3/N2 at 10−4 Pa pressure at 520

• °C. The diameter of the synthesized BNNTs was the same as the pore size diameter of the aluminum oxide template. The BNNTs were synthesized in a stainless steel autoclave at 380 °C from amorphous boron, NaN3, and CH3CN for 14 h. The obtained product was washed with ethanol, dried and a 5% BNNTs yield

Review of nanostructured devices for thermoelectric applications

• Giovanni Pennelli

Beilstein J. Nanotechnol. 2014, 5, 1268–1284, doi:10.3762/bjnano.5.141

• arrays can also be produced by the simpler and cheaper innovative pattering technique nanosphere lithography [120][121]; The evaporation of Ag or Au through porous aluminum oxide membranes[122][123][124] gives a periodic and almost regular pattern for vertically etched nanowire arrays. A thin evaporation

Impact of thermal frequency drift on highest precision force microscopy using quartz-based force sensors at low temperatures

• Florian Pielmeier,
• Daniel Meuer,
• Daniel Schmid,
• Christoph Strunk and
• Franz J. Giessibl

Beilstein J. Nanotechnol. 2014, 5, 407–412, doi:10.3762/bjnano.5.48

• with non-conductive epoxy to an aluminum oxide substrate which is commonly used for our qPlus sensors, the electrodes are then contacted with conductive epoxy. For the low temperature measurements the substrates where glued again with non-conductive epoxy onto a piece of copper. The copper piece serves

Modeling and optimization of atomic layer deposition processes on vertically aligned carbon nanotubes

• Nuri Yazdani,
• Vipin Chawla,
• Eve Edwards,
• Vanessa Wood,
• Hyung Gyu Park and
• Ivo Utke

Beilstein J. Nanotechnol. 2014, 5, 234–244, doi:10.3762/bjnano.5.25

• dioxide and aluminum oxide. To synthesize our VACNTs, a 3-nm-thick catalyst layer of iron on top of a 20-nm-thick layer of aluminum is deposited through electron beam evaporation onto a silicon wafer. The VACNTs are then grown by chemical vapor deposition in a cold-wall CVD system. The catalyst-covered

• time (see Equation 18). To experimentally validate the pulse time scaling procedure developed from the model, we perform depositions of aluminum oxide on VACNT samples, during which we attempt to keep the penetration depth of each ALD cycle constant over one hundred cycles. In Figure 6c, the oxide

• thickness as a function of the depth within the array is plotted for samples coated with 100 and 200 cycles of aluminum oxide by using a fixed exposure time, and for one sample with 200 cycles, for which the exposure time from the 100th to the 200th cycle was scaled according to Equation 19. As expected, a

3D-nanoarchitectured Pd/Ni catalysts prepared by atomic layer deposition for the electrooxidation of formic acid

• Loïc Assaud,
• Evans Monyoncho,
• Kristina Pitzschel,
• Anis Allagui,
• Matthieu Petit,
• Margrit Hanbücken,
• Elena A. Baranova and
• Lionel Santinacci

Beilstein J. Nanotechnol. 2014, 5, 162–172, doi:10.3762/bjnano.5.16

• intermediates. High catalytic activities are measured for low masses of Pd coatings that were generated by a low number of ALD cycles, probably because of the cluster size effect, electronic interactions between Pd and Ni, or diffusion effects. Keywords: anodic aluminum oxide; atomic layer deposition (ALD

• aluminum oxide (AAO) has been used as nanostructured support for the Pd catalysts. The AAO membranes are attractive because they exhibit a high specific surface area and the pore diameter and length can be tailored easily [27][28]. In this study, the usual two-step anodization process shown in Figure 1a–e

Synthesis of boron nitride nanotubes from unprocessed colemanite

• Saban Kalay,
• Zehra Yilmaz and
• Mustafa Çulha

Beilstein J. Nanotechnol. 2013, 4, 843–851, doi:10.3762/bjnano.4.95

• , hydrogen storage, and the improvement of the mechanical as well as the chemical durability of polymer composites. Experimental Material and methods Colemanite (Ca2B6O11·5H2O) was a gift from Eti Mine Works General Management (Turkey). Iron (III) oxide, iron (II, III) oxide, aluminum oxide, zinc oxide

Ellipsometry and XPS comparative studies of thermal and plasma enhanced atomic layer deposited Al₂O₃-films

• Jörg Haeberle,
• Karsten Henkel,
• Hassan Gargouri,
• Franziska Naumann,
• Bernd Gruska,
• Michael Arens,
• Massimo Tallarida and
• Dieter Schmeißer

Beilstein J. Nanotechnol. 2013, 4, 732–742, doi:10.3762/bjnano.4.83

• , Germany 10.3762/bjnano.4.83 Abstract We report on results on the preparation of thin (<100 nm) aluminum oxide (Al2O3) films on silicon substrates using thermal atomic layer deposition (T-ALD) and plasma enhanced atomic layer deposition (PE-ALD) in the SENTECH SI ALD LL system. The T-ALD Al2O3 layers were

• not influenced significantly. Initial state energy shifts in all PE-ALD samples are observed which we attribute to a net negative charge within the films. Keywords: Al2O3; ALD; ellipsometry; PE-ALD; XPS; Introduction Thin aluminum oxide (Al2O3) layers deposited by atomic layer deposition (ALD) have

Surface passivation and optical characterization of Al₂O₃/a-SiC_x stacks on c-Si substrates

• Gema López,
• Pablo R. Ortega,
• Cristóbal Voz,
• Isidro Martín,
• Mónica Colina,
• Anna B. Morales,
• Albert Orpella and
• Ramón Alcubilla

Beilstein J. Nanotechnol. 2013, 4, 726–731, doi:10.3762/bjnano.4.82

• study the surface passivation of aluminum oxide/amorphous silicon carbide (Al2O3/a-SiCx) stacks on both p-type and n-type crystalline silicon (c-Si) substrates as well as the optical characterization of these stacks. Al2O3 films of different thicknesses were deposited by thermal atomic layer deposition

• ) was evaluated at a carrier injection level corresponding to 1-sun illumination, which led to values below 10 cm/s. Reflectance values below 2% were measured on textured samples over the wavelength range of 450–1000 nm. Keywords: aluminum oxide (Al2O3); antireflection coating; atomic layer deposition

• ; silicon carbide (SiCx); surface passivation; Introduction Surface passivation has become a relevant issue in high efficiency crystalline silicon (c-Si) solar cells. The importance is even increasing as thinner wafers are used to reduce the cost for photovoltaic applications [1]. Aluminum oxide (Al2O3

Preparation of electrochemically active silicon nanotubes in highly ordered arrays

• Tobias Grünzel,
• Young Joo Lee,
• Karsten Kuepper and
• Julien Bachmann

Beilstein J. Nanotechnol. 2013, 4, 655–664, doi:10.3762/bjnano.4.73

• standard procedure [11]: after the first anodization, the disordered porous aluminum oxide layer obtained is removed in chromic acid, then the ordered porous layer is obtained by a second anodization in the same conditions. The length of the pores is defined by the duration of this second anodization

• /O2, 150 °C (ALD); (d) CuCl2/HCl/H2O, 20 °C; (e) H3PO4/H2O, 45 °C; (f) Li, 670 °C; (g) HCl/H2O, 20 °C; (h) Au sputter, 20 °C. Note that despite the impression which may emanate from this cross-section representation, the aluminum oxide framework remains reticulated and continuous throughout (see

Functionalization of vertically aligned carbon nanotubes

• Eloise Van Hooijdonk,
• Carla Bittencourt,
• Rony Snyders and
• Jean-François Colomer

Beilstein J. Nanotechnol. 2013, 4, 129–152, doi:10.3762/bjnano.4.14

• deposited within the pores of nanoporous templates (for example, anodic aluminum oxide (AAO) membranes) allows design of a wide range of nanostructures with particular geometries, including aligned and monodispersed CNTs [40]. After the catalyst preparation, the next step is the synthesis of the VA-CNTs