Molecular and mechanical insights into gecko seta adhesion: multiscale simulations combining molecular dynamics and the finite element method

• Yash Jain,
• Saeed Norouzi,
• Tobias Materzok,
• Stanislav N. Gorb and
• Florian Müller-Plathe

Beilstein J. Nanotechnol. 2025, 16, 2055–2076, doi:10.3762/bjnano.16.141

• structure similar to a fiber-reinforced elastomer, with a fibrillar nature that leads to anisotropic mechanical properties [40][41][42]. Rather than explicitly resolving individual fibers and the surrounding amorphous matrix, we represented the spatula with a coarse-grained bead network whose anisotropic

Stereodiscrimination of guests in chiral organosilica aerogels studied by ESR spectroscopy

• Sebastian Polarz,
• Yasar Krysiak,
• Martin Wessig and
• Florian Kuhlmann

Beilstein J. Nanotechnol. 2025, 16, 2034–2054, doi:10.3762/bjnano.16.140

• probes with free rotation are characterized by a spectrum with three narrow lines [36][37]. Anisotropic broadening of the spectrum is indicative for retardation of rotation due to additional intermolecular interactions. The hyperfine coupling of the electron spin with the nuclear spin of 15N provides

Laser ablation in liquids for shape-tailored synthesis of nanomaterials: status and challenges

• Natalie Tarasenka

Beilstein J. Nanotechnol. 2025, 16, 1963–1997, doi:10.3762/bjnano.16.137

• of their impact on the conditions for anisotropic NP formation and growth. The description of the methods developed for the control over nanomaterial morphology is summarized by the vision of the current challenges and development routes of laser ablation in liquids. Keywords: laser ablation in

• achieved. Despite recent advances, there is still a gap in understanding the routes for shape control of the forming nanomaterials hindered by the limited information about the mechanisms of laser ablation process in liquids. The demand for anisotropic nanomaterials is growing, associated with the rapid

• sustainability of the approach due to the introduction of purification steps. In PLAL, the conditions created during laser ablation synthesis are favouring the formation and growth of near-spherical NPs. To date, much less research is performed regarding shape-controlled formation of anisotropic materials. For

Quantum circuits with SINIS structures

• Mikhail Tarasov,
• Mikhail Fominskii,
• Aleksandra Gunbina,
• Artem Krasilnikov,
• Maria Mansfeld,
• Dmitrii Kukushkin,
• Andrei Maruhno,
• Valeria Ievleva,
• Mikhail Strelkov,
• Daniil Zhogov,
• Konstantin Arutyunov,
• Vyacheslav Vdovin,
• Vladislav Stolyarov and
• Valerian Edelman

Beilstein J. Nanotechnol. 2025, 16, 1931–1941, doi:10.3762/bjnano.16.134

• deposition plants with thermal or e-beam evaporation. A much more available and simple deposition equipment is magnetron sputtering, but it provides only isotropic deposition, which is incompatible with anisotropic shadow evaporation. The practical solution for a magnetron sputtering is selective etching of

Beyond the bilayer: multilayered hygroscopic actuation in pine cone scales

• Kim Ulrich,
• Max David Mylo,
• Tom Masselter,
• Fabian Scheckenbach,
• Sophia Fischerbauer,
• Martin Nopens,
• Silja Flenner,
• Imke Greving,
• Linnea Hesse and
• Thomas Speck

Beilstein J. Nanotechnol. 2025, 16, 1695–1710, doi:10.3762/bjnano.16.119

• Thünen Institute of Wood Research, Hamburg, Germany Institute of Materials Physics, Helmholtz-Zentrum Hereon, Geesthacht, Germany 10.3762/bjnano.16.119 Abstract The anisotropic hygroscopic behavior of pine cone scales and its effect on bending motion, with implications for bioinspired actuation, is

• representing the deformation from one state to the other. Using this displacement field allows for the calculation of a strain tensor field, which describes the axis-dependent hygroscopic expansion [29]. Incorporating the anisotropic swelling and shrinkage behavior into in silico models of the pine cone scale

• tissue involved and their arrangement, are very limited. The aim of this work is to characterize the anisotropic hygroscopic behavior of pine cone scale tissues and its effect on the bending motion. To this end, we first characterize their sorption behavior using gravimetric water uptake measurements

Bioinspired polypropylene-based functionally graded materials and metamaterials modeling the mistletoe–host interface

• Lina M. Rojas González,
• Naeim Ghavidelnia,
• Christoph Eberl and
• Max D. Mylo

Beilstein J. Nanotechnol. 2025, 16, 1592–1606, doi:10.3762/bjnano.16.113

• the data sheet values were obtained by testing injection-molded test specimens, whereas our specimens were produced by hot pressing. Each method has an effect on the direction of the glass fibers; injection molding results in an anisotropic orientation of the fibers, whereas hot pressing results in

• isotropic orientations [48]. An anisotropic fiber orientation along the direction of tensile testing increases the Young’s modulus compared to an isotropic alignment [49], which also explains why the difference between the pure PP and the glass fiber-reinforced polymer was rather small in our specimens. The

Photochemical synthesis of silver nanoprisms via green LED irradiation and evaluation of SERS activity

• Tuan Anh Mai-Ngoc,
• Nhi Kieu Vo,
• Cong Danh Nguyen,
• Thi Kim Xuan Nguyen and
• Thanh Sinh Do

Beilstein J. Nanotechnol. 2025, 16, 1417–1427, doi:10.3762/bjnano.16.103

• applications. Keywords: light-emitting diodes (LEDs); photochemical synthesis; silver nanoprisms; surface-enhanced Raman scattering (SERS); trisodium citrate; Introduction Anisotropic silver nanoparticles (ASNPs) have attracted increasing attention from research groups worldwide due to their potential

• step of the entire process [3]. During this stage, small silver nanoparticles (seeds) can combine and evolve into anisotropic nanostructures through a chemical process in the presence of hydrogen peroxide (H2O2) and sodium borohydride, commonly referred to as the Mirkin method [4]. Recently

• –vis spectrum exhibited a single absorption peak at 402 nm, characteristic of the in-plane dipole (IPD) resonance of spherical silver nanoparticles. The solution retained its yellow color, indicating that the seed morphology remained largely unchanged and that no formation of anisotropic silver

Electronic and optical properties of chloropicrin adsorbed ZnS nanotubes: first principle analysis

• Prakash Yadav,
• Boddepalli SanthiBhushan and
• Anurag Srivastava

Beilstein J. Nanotechnol. 2025, 16, 1184–1196, doi:10.3762/bjnano.16.87

• than strong charge transfer or dipole interactions [73]. The anisotropic nature of ZnS NTs plays a significant role in the observed orientation-dependent optical responses. Adsorption along orientations such as A induces stronger dipole interactions and greater charge transfer, leading to more

• pronounced bandgap narrowing and enhanced visible light absorption. This anisotropic behavior is consistent with theoretical and experimental studies on nanotube systems, where adsorption-induced optical changes are highly dependent on molecular orientation and the local electronic environment [74]. The

• ), indicating weaker interaction. Orientation C shows multiple peaks across the ultraviolet and visible ranges, suggesting complex adsorption behavior. Orientation D exhibits negligible shifts, dominated by van der Waals forces. These findings demonstrate the anisotropic optical behavior of ZnS NTs, with

Crystalline and amorphous structure selectivity of ignoble high-entropy alloy nanoparticles during laser ablation in organic liquids is set by pulse duration

• Robert Stuckert,
• Felix Pohl,
• Oleg Prymak,
• Ulrich Schürmann,
• Christoph Rehbock,
• Lorenz Kienle and
• Stephan Barcikowski

Beilstein J. Nanotechnol. 2025, 16, 1141–1159, doi:10.3762/bjnano.16.84

• amorphous particles [34]. Additionally, a few sharper reflections from unknown phases, having crystallite sizes between 40 to 50 nm (after anisotropic refinement) could be detected (marked by red arrows in Figure 2B), but due to their weak intensity, an identification was not possible. The presence of those

Soft materials nanoarchitectonics: liquid crystals, polymers, gels, biomaterials, and others

• Katsuhiko Ariga

Beilstein J. Nanotechnol. 2025, 16, 1025–1067, doi:10.3762/bjnano.16.77

• liquid crystal semiconductors that exhibit anisotropic conduction of electronic charge carriers. The efficient transport of electronic carriers has been confirmed in nematic, chiral nematic, smectic, and columnar phases. It has been demonstrated that liquid crystals comprising extended π-conjugated units

• system reverts to its original state. It was demonstrated that the gold nanorods are capable of significant lateral diffusion, exhibiting a considerable distance of movement. Hybrid materials comprising anisotropic nanoparticles and polymer brushes were designed and subjected to dynamic control

Time-resolved probing of laser-induced nanostructuring processes in liquids

• Maximilian Spellauge,
• David Redka,
• Mianzhen Mo,
• Changyong Song,
• Heinz Paul Huber and
• Anton Plech

Beilstein J. Nanotechnol. 2025, 16, 968–1002, doi:10.3762/bjnano.16.74

• conventional TTM that describes energy transfer between electrons and the lattice. Although the dynamics of photoexcited hot electrons were expected to uniformly affect the entire specimen within a few picoseconds, the experiment instead observed inhomogeneous and laser-polarization-dependent anisotropic

• key contributors to the observed anisotropic melting behavior. These findings, corroborated by MD simulations that incorporate the TTM (TTM-MD), suggest that energy accumulation in localized hotspots drives anisotropic melting. Nevertheless, direct experimental evidence linking electronic and ionic

Characterization of ion track-etched conical nanopores in thermal and PECVD SiO₂ using small angle X-ray scattering

• Shankar Dutt,
• Rudradeep Chakraborty,
• Christian Notthoff,
• Pablo Mota-Santiago,
• Christina Trautmann and
• Patrick Kluth

Beilstein J. Nanotechnol. 2025, 16, 899–909, doi:10.3762/bjnano.16.68

• analyzing the complex highly anisotropic two-dimensional SAXS patterns of the pores by reducing the analysis to two orthogonal one-dimensional slices of the data. The simultaneous fit of the data enables an accurate determination of the pore geometry and size distribution. The analysis reveals substantial

Heat-induced transformation of nickel-coated polycrystalline diamond film studied in situ by XPS and NEXAFS

• Olga V. Sedelnikova,
• Yuliya V. Fedoseeva,
• Dmitriy V. Gorodetskiy,
• Yuri N. Palyanov,
• Elena V. Shlyakhova,
• Eugene A. Maksimovskiy,
• Anna A. Makarova,
• Lyubov G. Bulusheva and
• Aleksandr V. Okotrub

Beilstein J. Nanotechnol. 2025, 16, 887–898, doi:10.3762/bjnano.16.67

• the dangling bonds and producing the sp2 carbon on the free diamond surface, or diffuse into the Ni bulk, feeding the graphite formation from the side of the catalytic particle [19]. Comparing the morphology of Ni-coated SCDs annealed under similar conditions revealed the anisotropic nature of both

• ). In particular, on the rectangular (110) faces, nickel particles are flatter and more evenly distributed than those on the triangular (111) face. Previous studies showed that the etching of diamond through the reaction with Ni during annealing is an anisotropic process [19][35][36]. In particular, the

• (111) surface, indicating anisotropic diamond etching during heating. Despite these differences, the Raman spectra recorded from the different faces of the annealed microcrystallites were similar, indicating that the carbon coating consisted of graphitic multilayers with a similar structure. The (110

Synchrotron X-ray photoelectron spectroscopy study of sodium adsorption on vertically arranged MoS₂ layers coated with pyrolytic carbon

• Alexander V. Okotrub,
• Anastasiya D. Fedorenko,
• Anna A. Makarova,
• Veronica S. Sulyaeva,
• Yuliya V. Fedoseeva and
• Lyubov G. Bulusheva

Beilstein J. Nanotechnol. 2025, 16, 847–859, doi:10.3762/bjnano.16.64

• hybrid anodes based on MoS2. The diffusion of sodium ions in layered MoS2 is highly anisotropic. It is fast along the basal planes and is not possible through defect-free layers [3]. Thus, when the interlayer channels coincide with the Na+ movement paths, the diffusion distance is shortened, resulting in

Performance optimization of a microwave-coupled plasma-based ultralow-energy ECR ion source for silicon nanostructuring

• Joy Mukherjee,
• Safiul Alam Mollick,
• Tanmoy Basu and
• Tapobrata Som

Beilstein J. Nanotechnol. 2025, 16, 484–494, doi:10.3762/bjnano.16.37

• the increase in bombardment time, more silicon and oxygen atoms are sputtered. Due to the presence of the ripples, the surface becomes anisotropic. The consequence of such an anisotropic nature of the surface is investigated and discussed in the upcoming section. Application of nanopatterned Si

Vortex lattices of layered HTSCs at different vortex–vortex interaction potentials

• Valerii P. Lenkov,
• Anastasia N. Maksimova,
• Anna N. Moroz and
• Vladimir A. Kashurnikov

Beilstein J. Nanotechnol. 2025, 16, 362–370, doi:10.3762/bjnano.16.27

• interaction potential of which is identical in shape to the interaction potential in ferromagnetic superconductors. The modeling results can also be useful for analyzing vortex configurations in a layered anisotropic HTSC in an inclined magnetic field. Methods Calculations were performed using the Monte Carlo

• method within the framework of a two-dimensional model of a layered HTSC [24][25][26]. Most of the HTSCs applicable in practice are strongly anisotropic substances characterized by the anisotropy parameter γ > 10. Examples of such HTSCs are YBa2Cu3O7−δ (γ ≈ 10) and Bi2Sr2CaCu2O8−δ (γ ≈ 200) [1]. Such

Facile synthesis of size-tunable L-carnosine-capped silver nanoparticles and their role in metal ion sensing and catalytic degradation of p-nitrophenol

• Akash Kumar,
• Ridhima Chadha,
• Abhishek Das,
• Nandita Maiti and
• Rayavarapu Raja Gopal

Beilstein J. Nanotechnol. 2024, 15, 1576–1592, doi:10.3762/bjnano.15.124

• , which confirms that the nanoparticles are spherical and monodispersed. However, silver nanoparticles with anisotropic shape were reported to have two absorption bands, namely transverse and longitudinal [24]. Furthermore, the color of the anisotropic nanosilver is different from yellow, which is also

Ultrablack color in velvet ant cuticle

• Vinicius Marques Lopez,
• Wencke Krings,
• Juliana Reis Machado,
• Stanislav Gorb and
• Rhainer Guillermo-Ferreira

Beilstein J. Nanotechnol. 2024, 15, 1554–1565, doi:10.3762/bjnano.15.122

• ultrastructure consisting of randomly oriented anisotropic micropillars accounts for its significant absorptivity [27]. Peacock spiders feature microstructures in specific body regions that exhibit ultrablack coloration with high absorbance. Interestingly, these microstructures are absent in other dark body

Nanoarchitectonics with cetrimonium bromide on metal nanoparticles for linker-free detection of toxic metal ions and catalytic degradation of 4-nitrophenol

• Akash Kumar and
• Raja Gopal Rayavarapu

Beilstein J. Nanotechnol. 2024, 15, 1312–1332, doi:10.3762/bjnano.15.106

• degrading 94.37% of 4-NP within 1 min. In contrast, silver nanospheres effectively detected Hg2+, Cu2+, and Fe3+ at concentrations as low as 1 ppm and degraded 90.78% of 4-NP within 30 min. Moreover, anisotropic gold nanorods (CTAB-AuNR1 and CTAB-AuNR2) showed promising sensing capabilities towards Cu2

• -modified isotropic and anisotropic CTAB-AgNPs were used to detect cobalt ions. The author found that only rod-shaped particles enabled visual detection of cobalt [25]. Yagyu et al. showed the efficient removal of radioactive cesium using Prussian blue [26]. Also, 4-nitrophenol was degraded using CTAB

• CTAB-capped gold and silver nanoparticles without linker/buffer for catalysis and detection heavy metals is a current need. In this work, we have developed a linker-free nanosensor with CTAB as capping agent on both isotropic and anisotropic gold and silver nanoparticles. The CTAB-capped metal

New design of operational MEMS bridges for measurements of properties of FEBID-based nanostructures

• Bartosz Pruchnik,
• Krzysztof Kwoka,
• Ewelina Gacka,
• Dominik Badura,
• Piotr Kunicki,
• Andrzej Sierakowski,
• Paweł Janus,
• Tomasz Piasecki and
• Teodor Gotszalk

Beilstein J. Nanotechnol. 2024, 15, 1273–1282, doi:10.3762/bjnano.15.103

• (Si3N4) layer was deposited via CVD. The 40 nm thick platinum paths were then patterned by lift-off photolithography. The opMEMS bridge body was defined photolithographically with a feature size of 2 µm, etched by dry oxygen plasma etching (DRIE) and then released by KOH anisotropic wet silicon etching

• only for the visual assessment of the shape and dimensions of a structure, but also for the observation of movement and deflection of an opMEMS. At the same time, the ion beam allows for local doping of the substrate and anisotropic milling. The NanoLab 600i also provides three gas injection systems

A low-kiloelectronvolt focused ion beam strategy for processing low-thermal-conductance materials with nanoampere currents

• Annalena Wolff,
• Nico Klingner,
• William Thompson,
• Yinghong Zhou,
• Jinying Lin and
• Yin Xiao

Beilstein J. Nanotechnol. 2024, 15, 1197–1207, doi:10.3762/bjnano.15.97

• the ion incidence angle and associated changes in interaction volume shape as well as heat generation need to be investigated further. The ion beam usually hits the sample at glancing angles during TEM lamella preparation and cross-sectioning, which leads to anisotropic changes in the interaction

Quantum-to-classical modeling of monolayer Ge₂Se₂ and its application in photovoltaic devices

• Anup Shrivastava,
• Shivani Saini,
• Dolly Kumari,
• Sanjai Singh and
• Jost Adam

Beilstein J. Nanotechnol. 2024, 15, 1153–1169, doi:10.3762/bjnano.15.94

• investigated structure exhibits strongly anisotropic optical properties for which the parametric values depend on the direction of the chosen plane. Dielectric function and absorption coefficient The static dielectric constants (real part of εr at ω = 0), along the in-plane (XX) and out-of-plane (ZZ) direction

Photocatalytic methane oxidation over a TiO₂/SiNWs p–n junction catalyst at room temperature

• Qui Thanh Hoai Ta,
• Luan Minh Nguyen,
• Ngoc Hoi Nguyen,
• Phan Khanh Thinh Nguyen and
• Dai Hai Nguyen

Beilstein J. Nanotechnol. 2024, 15, 1132–1141, doi:10.3762/bjnano.15.92

• recombination of charge carriers is mainly attributed to the anisotropic movement of generated electron–hole pairs in semiconductors. Therefore, the implementation of a driving force could remarkably accelerate the oriented motion of electrons and holes, which could suppress recombination and eventually improve

Effect of wavelength and liquid on formation of Ag, Au, Ag/Au nanoparticles via picosecond laser ablation and SERS-based detection of DMMP

• Sree Satya Bharati Moram,
• Chandu Byram and
• Venugopal Rao Soma

Beilstein J. Nanotechnol. 2024, 15, 1054–1069, doi:10.3762/bjnano.15.86

• detection of DMMP (1.2 ppm V) in the vapor phase using Glass_Ag_Au NPs, 3D fractal microstructure substrates developed by corner lithography and anisotropic wet etching of silicon using the 785 nm as the Raman excitation. When UV excitation was utilized during the measurements, the Raman peak intensities

Atomistic insights into the morphological dynamics of gold and platinum nanoparticles: MD simulations in vacuum and aqueous media

• Evangelos Voyiatzis,
• Eugenia Valsami-Jones and
• Antreas Afantitis

Beilstein J. Nanotechnol. 2024, 15, 995–1009, doi:10.3762/bjnano.15.81

• clusters consisting of 1157 atoms [51]. Some light on the microscopic origin of the anisotropic growth of gold NPs has been cast via molecular dynamics simulations [52]. In a similar way, Lümmen and Kraska investigated the homogeneous nucleation and cluster growth of Pt clusters from supersaturated vapour