Impacts of annealing on structural and photophysical properties of zinc phthalocyanine adsorbed on graphene

• Gautier Creutzer,
• Quentin Fernez,
• Nataliya Kalashnyk,
• Zohreh Safarzadeh,
• Lydia Sosa Vargas,
• Céline Fiorini-Debuisschert,
• Nicolas Fabre and
• Fabrice Charra

Beilstein J. Nanotechnol. 2026, 17, 576–585, doi:10.3762/bjnano.17.39

• treatments, as often shown for example with α and β phases of zinc phthalocyanines (ZnPc), with consequences on molecule orientations relative to the substrate and absorbance efficiency [21] or dynamics of charge migration and charge transfer to substrate [22]. Even inside a given phase, minute structural

• variations in phthalocyanine-based materials can strongly impact their absorption and luminescence spectra, in particular by allowing or not the formation of intermolecular Frenkel charge-transfer excitons [23]. 2D assemblies of self-organized adsorbed conjugated molecules on graphene has attracted

Synthesis of Cu–Mo/TiO₂ and Co–Mo/TiO₂ photocatalysts for the efficient degradation of organic pollutants in water

• Ilse Acosta,
• Brenda Zermeño,
• Edgar Moctezuma,
• Luis F. Garay-Rodríguez and
• Isaías Juárez-Ramírez

Beilstein J. Nanotechnol. 2026, 17, 559–570, doi:10.3762/bjnano.17.37

• -doping TiO2 with the high-valence Mo ions and the Cu or Co ions with low valence can be used to address the shortcomings of individual doping systems to optimize charge transfer and reduce recombination. Metal/metal co-doping has not received much attention; however, it is a promising alternative since

• properties were determined. Finally, the photocatalytic behavior of the materials was studied in the photocatalytic oxidation of ketoprofen (KTP) under UV irradiation, with the aim of studying the charge-transfer improvement. Ketoprofen degradation, adsorption, kinetics, and reaction pathways have been

Electrochemical determination of ciprofloxacin using a MIL-101/reduced graphene oxide-modified electrode

• Nguyen Quang Man,
• Nguyen Ngoc Nghia,
• Nguyen Vinh Phu,
• Vo Thi Khanh Ly,
• Le Lam Son,
• Pham Khac Lieu,
• Le Thi Hong Phong,
• Nguyen Dinh Luyen and
• Dinh Quang Khieu

Beilstein J. Nanotechnol. 2026, 17, 541–554, doi:10.3762/bjnano.17.35

• electrochemical performance of the composite material. This combination can promote efficient analyte adsorption and fast charge transfer at the electrode interface. Consistent with this idea, Gu et al. reported that MIL-101/rGO composites exhibit enhanced electrocatalytic activity toward the reduction of

• results from both figures confirm the successful formation of MIL-101/rGO composites. This structural combination is beneficial for electrochemical applications because rGO improves electrical conductivity and promotes charge transfer. The Raman spectra of GO, rGO, MIL-101, and the MIL-101/rGO composites

• confirms the irreversible nature of the oxidation process (Figure 7c). For an irreversible electrochemical system, the charge-transfer coefficient (α) was assumed to be 0.5, as is common in the literature [30]. From the slope of the ECPR–ln v plot, the product of α and the number of transferred electrons

Fractional shot noise of an SU(N) Kondo system

• Damian Krychowski and
• Stanisław Lipiński

Beilstein J. Nanotechnol. 2026, 17, 515–540, doi:10.3762/bjnano.17.34

• , 15/8, 12/5, 35/12, …} and bN = {2, 1, 2/3, 1/2, 14/5, …}. is the quadratic Casimir operator in the free pseudospin momentum limit (t = 0). We see that, for Q = 1e, the inter-state charge transfer correlator is Qik = QiQk = 0. Correspondingly, successive values of N reach the numbers TχN ≈ aN. In

Probing internal continua and atomic ultrafast charge transfer within size-controlled nanoparticles by post-collision interaction in core-hole clock spectroscopy

• Johannes Lütgert,
• Erika Giangrisostomi,
• Nomi L. A. N. Sorgenfrei and
• Alexander Föhlisch

Beilstein J. Nanotechnol. 2026, 17, 505–514, doi:10.3762/bjnano.17.33

• local charge transfer dynamics and internal continuum states. We observe an acceleration of charge transfer times by almost one order of magnitude in thin-shell quantum dots, comprising only one or three double layers of ZnS, before reaching a size-independent limit. This size-dependence is governed by

• the existence of a faster charge transfer channel toward the CdSe core, only accessible for the inner-most shell layers, rather than a quantum confinement effect. By extending the traditional PCI model from free-electron systems to bound-state continua, we further establish a framework for

• -collision-interaction; quantum dots; resonant Auger spectroscopy; Introduction The interplay of electron localization, itinerance, and charge transfer is essential to functional nanoparticles and quantum dots (QDs) [1][2][3][4][5][6]. In terms of electronic structure properties, materials on the nanoscale

Defects and defect-mediated engineering of two-dimensional materials: challenges and open questions

• Arkady V. Krasheninnikov,
• Matthias Batzill,
• Anouar-Akacha Delenda,
• Marija Drndić,
• Chris Ewels,
• Katharina J. Franke,
• Mahdi Ghorbani-Asl,
• Alexander Holleitner,
• Ado Jorio,
• Ute Kaiser,
• Daria Kieczka,
• Hannu-Pekka Komsa,
• Jani Kotakoski,
• Manuel Längle,
• David Lamprecht,
• Yun Liu,
• Steven G. Louie,
• Janina Maultzsch,
• Thomas Michely,
• Katherine Milton,
• Anna Niggas,
• Hanako Okuno,
• Joshua A. Robinson,
• Marika Schleberger,
• Bruno Schuler,
• Alexander Shluger,
• Kazu Suenaga,
• Kristian S. Thygesen,
• Richard A. Wilhelm,
• E. Harriet Åhlgren and
• Carla Bittencourt

Beilstein J. Nanotechnol. 2026, 17, 454–488, doi:10.3762/bjnano.17.31

• valence band maximum and conduction band minimum between bulk and monolayer WS2 affect the relative position of the O2 LUMO responsible for the charge transfer. This can affect the barrier of O2 dissociation and requires further studies. The mechanisms of propagation of oxidation front from the surface of

Polycatecholamine nanocoatings on stainless steel: the effect on attachment of human fibroblasts and platelets

• Paulina Trzaskowska,
• Ewa Rybak,
• Maciej Trzaskowski,
• Kamil Kopeć,
• Jakub Krzemiński,
• Rafał Podgórski,
• Hatice Genc,
• Mehtap Civelek and
• Iwona Cicha

Beilstein J. Nanotechnol. 2026, 17, 365–380, doi:10.3762/bjnano.17.25

• aggregates stabilized by charge transfer, hydrogen bonding and π–π stacking interactions [12][27][28]. Mechanistic studies indicate that the first step of ʟ-tyrosine polymerization involves hydroxylation of the aromatic ring at the C3 position [12][28][29], after which the pathway resembles dopamine

Gold nanoparticle-decorated reduced graphene oxide as a highly effective catalyst for the selective α,β-dehydrogenation of N-alkyl-4-piperidones

• Brenda Flore Kenyim,
• Mihir Tzalis,
• Marilyn Kaul,
• Robert Oestreich,
• Aysenur Limon,
• Chancellin Pecheu Nkepdep and
• Christoph Janiak

Beilstein J. Nanotechnol. 2026, 17, 218–238, doi:10.3762/bjnano.17.15

• facilitate charge transfer between the metal and the support, enhancing the activation of molecular oxygen and promoting the oxidative dehydrogenation (ODH) pathway. This synergistic interaction should not only improve the intrinsic catalytic activity but also allow the catalyst to achieve high efficiency

• metallic AuNPs (3–13 nm), assisted by electron donation from rGO’s π-conjugated and oxygenated domains, provide sufficient but not excessive charge transfer to partially activate O2, yet without full reduction to the peroxido form. This balance maintains high selectivity while preventing overoxidation or

• nanoparticles but also sustains dynamic charge transfer (rGO→Au→O2), preserving the redox flexibility of Au sites throughout the catalytic cycle. A very important point to consider when using carbon supports in catalysis is the gold loading in the support. Compared to AC and CB, rGO exhibits a lower bulk

Reduced graphene oxide paper electrode for lithium-ion cells – towards optimized thermal reduction

• Agata Pawłowska,
• Magdalena Baran,
• Stefan Marynowicz,
• Aleksandra Izabela Banasiak,
• Adrian Racki,
• Adrian Chlanda,
• Tymoteusz Ciuk,
• Marta Wolczko and
• Andrzej Budziak

Beilstein J. Nanotechnol. 2026, 17, 24–37, doi:10.3762/bjnano.17.3

• stability of the cell’s performance was improved with increasing reduction temperature. Changes in structural properties revealed by Raman spectroscopy influenced the electrochemical properties of these materials, probably due to the decreased charge transfer resistance and balanced electronic and ionic

Quantum circuits with SINIS structures

• Mikhail Tarasov,
• Mikhail Fominskii,
• Aleksandra Gunbina,
• Artem Krasilnikov,
• Maria Mansfeld,
• Dmitrii Kukushkin,
• Andrei Maruhno,
• Valeria Ievleva,
• Mikhail Strelkov,
• Daniil Zhogov,
• Konstantin Arutyunov,
• Vyacheslav Vdovin,
• Vladislav Stolyarov and
• Valerian Edelman

Beilstein J. Nanotechnol. 2025, 16, 1931–1941, doi:10.3762/bjnano.16.134

• the charge transfer by electrons during tunneling through the tunnel SIN junction and the thermal noise of these same electrons as heat carriers: δIω2 is the power spectral density (PSD) of current fluctuations due to shot noise, δPω2 is the PSD of thermal fluctuations, and ⟨δPωδIω⟩ is the correlation

Piezoelectricity of layered double hydroxides: perspectives regarding piezocatalysis and nanogenerators

• Evgeniy S. Seliverstov,
• Evgeniya A. Tarasenko and
• Olga E. Lebedeva

Beilstein J. Nanotechnol. 2025, 16, 1812–1817, doi:10.3762/bjnano.16.124

• evidence demonstrated that dual oxygen vacancies in Ni/Fe-LDHs create interfacial bonds that mitigate carrier localization effects and unfavorable influences during piezocatalysis and photocatalysis. These features promote exciton dissociation and charge transfer. Furthermore, the strong electronic

• carrier localization effects), or to interfacial electronic interactions that facilitate charge transfer. While these mechanisms may coexist, many publications lack the necessary control experiments (e.g., mechanical stimulation without light/oxidant, photocatalysis without stress, or defect-free samples

Electrical, photocatalytic, and sensory properties of graphene oxide and polyimide implanted with low- and medium-energy silver ions

• Josef Novák,
• Eva Štěpanovská,
• Petr Malinský,
• Vlastimil Mazánek,
• Jan Luxa,
• Ulrich Kentsch and
• Zdeněk Sofer

Beilstein J. Nanotechnol. 2025, 16, 1794–1811, doi:10.3762/bjnano.16.123

• catalytically active sites resulting from the carbonization of the polymer matrix, together with the silver clusters formed during ion implantation, provide suitable conditions for reactant adsorption and efficient charge transfer. Silver ions exhibit strong localized surface plasmon resonance in the visible

• the implanted samples. This suggests that the material itself without any intervention has limited ability to generate reactive oxygen species or facilitate charge transfer, which are both essential for efficient photocatalysis. There is a noticeable increase in the rate constant when low-energy Ag

• ions of 20 keV are implanted. This increase can be explained by the formation of defects in the GO surface layer, which increase the rate of electron excitation and facilitate subsequent charge transfer. At the same time, the implanted Ag ions can act as catalytic centers that improve the process of

Ambient pressure XPS at MAX IV

• Mattia Scardamaglia,
• Ulrike Küst,
• Alexander Klyushin,
• Rosemary Jones,
• Jan Knudsen,
• Robert Temperton,
• Andrey Shavorskiy and
• Esko Kokkonen

Beilstein J. Nanotechnol. 2025, 16, 1677–1694, doi:10.3762/bjnano.16.118

• photocatalyst, it is essential to combine the photocatalyst’s performance with mechanistic knowledge under operando reaction conditions. APXPS is uniquely suited to investigate such systems. Its surface sensitivity enables the detection of charge transfer processes, reaction intermediates, and active sites

• under operando conditions. Additionally, the kinetics of charge transfer and the role of specific chemical species or components functioning as charge donors or acceptors during photocatalytic reactions can be clarified using APXPS. At MAX IV, external light sources (e.g., UV lamps or solar simulators

• provides unique insight into surface reactions, charge transfer, and interface stability, which are central to the performance and degradation mechanisms of electrochemical systems. Electrochemical interfaces can be studied by APXPS using two primary cell types, namely, membrane-based flow cells and “dip

Influence of laser beam profile on morphology and optical properties of silicon nanoparticles formed by laser ablation in liquid

• Natalie Tarasenka,
• Vladislav Kornev,
• Alena Nevar and
• Nikolai Tarasenko

Beilstein J. Nanotechnol. 2025, 16, 1533–1544, doi:10.3762/bjnano.16.108

• charge and discharge, facilitating the charge transfer processes [47][48][49]. As a result, parameters such as specific capacitance and cycling stability are enhanced [13]. In our case, high values of specific capacitance can be expected because of the developed surface of the silicon NPs prepared by

Laser processing in liquids: insights into nanocolloid generation and thin film integration for energy, photonic, and sensing applications

• Akshana Parameswaran Sreekala,
• Pooja Raveendran Nair,
• Jithin Kundalam Kadavath,
• Bindu Krishnan,
• David Avellaneda Avellaneda,
• M. R. Anantharaman and
• Sadasivan Shaji

Beilstein J. Nanotechnol. 2025, 16, 1428–1498, doi:10.3762/bjnano.16.104

The role of biochar in combating microplastic pollution: a bibliometric analysis in environmental contexts

• Tuan Minh Truong Dang,
• Thao Thu Thi Huynh,
• Guo-Ping Chang-Chien and
• Ha Manh Bui

Beilstein J. Nanotechnol. 2025, 16, 1401–1416, doi:10.3762/bjnano.16.102

• and surface area, compared to other materials [37]. Biochar produced from carbon-, oxygen- and nitrogen-rich straw at low pyrolysis temperatures retains a large number of functional groups, which enhance charge transfer potential and adsorption stability through increased surface charge density

Automated collection and categorisation of STM images and STS spectra with and without machine learning

• Dylan Stewart Barker and
• Adam Sweetman

Beilstein J. Nanotechnol. 2025, 16, 1367–1379, doi:10.3762/bjnano.16.99

• closer to the surface, where the atom binds to the Ag(111), at which point charge transfer from the substrate to the molecule will return it to its neutral state [21]. Whilst carrying out bias spectroscopy over these SnPc molecules, it was found that a switch could occasionally be induced, even if the

Enhancing the photoelectrochemical performance of BiOI-derived BiVO₄ films by controlled-intensity current electrodeposition

• Huu Phuc Dang,
• Khanh Quang Nguyen,
• Nguyen Thi Mai Tho and
• Tran Le

Beilstein J. Nanotechnol. 2025, 16, 1289–1301, doi:10.3762/bjnano.16.94

• higher current densities and larger VO(acac)₂ volumes. This observation suggests that improved crystallinity enhances the structural uniformity of the VO4− tetrahedra, leading to more efficient charge-transfer pathways. Furthermore, the appearance of sharper and more intense Raman peaks with increasing

• the BiVO4(326) photoanode at 1.23 V vs RHE was 47%, which was higher than that under other conditions. This indicates that the formation of films with larger surface areas reduces the charge recombination rate and facilitates faster charge transfer rates. AC impedance measurements were performed on

• the photoanodes to assess their charge transfer capabilities. As shown in Figure 5d, BiVO4(326) exhibited a smaller impedance arc under illumination, indicating a minimal charge-transfer resistance. This is favorable for the rapid utilization of photogenerated holes in water oxidation reactions

Electronic and optical properties of chloropicrin adsorbed ZnS nanotubes: first principle analysis

• Prakash Yadav,
• Boddepalli SanthiBhushan and
• Anurag Srivastava

Beilstein J. Nanotechnol. 2025, 16, 1184–1196, doi:10.3762/bjnano.16.87

• functional theory (DFT) to explore the sensing capabilities of a ZnS (3,3) nanotube (ZnS NT) for detecting chloropicrin (CP, CCl3NO2), a highly toxic gas. To elucidate the sensing mechanism, we systematically analyze the adsorption configurations, Mulliken charge transfer, band structure, density of states

• adsorption energy ranges from −0.389 to −0.657 eV, indicating weak physisorption. The Mulliken charge transfer varies between 0.06e and 0.109e, confirming effective but nondestructive interaction. A favorable recovery time of ≈3.533 μs at room temperature, along with a significant red shift in the absorption

• highly toxic chemical warfare agent, remains an area with untapped potential. Addressing this gap, the present work constructs an armchair ZnS NT to investigate its adsorption configurations, charge transfer, band structure, density of states, optical absorption, and optical conductivity using a density

Synthesis of biowaste-derived carbon-dot-mediated silver nanoparticles and the evaluation of electrochemical properties for supercapacitor electrodes

• Navya Kumari Tenkayala,
• Chandan Kumar Maity,
• Md Moniruzzaman and
• Subramani Devaraju

Beilstein J. Nanotechnol. 2025, 16, 933–943, doi:10.3762/bjnano.16.71

• the PG-CDs-AgNPs are displayed in Figure 5d. The charge-transfer resistance (Rct) in the high-frequency range is indicated by the semicircle diameter [39][40]. How facile electrons or ions can be moved throughout the electrode and electrolyte–electrode system is shown by the Rct [39][40]. The straight

• -CDs-AgNPs has a greater slope suggests that these particles have optimal supercapacitive properties and electrochemical activity. In the three-electrode investigation, PG-CDs-AgNPs showed better electrochemical activity overall in terms of capacitive performance, charge-transfer activity, and

Insights into the electronic and atomic structures of cerium oxide-based ultrathin films and nanostructures using high-brilliance light sources

• Paola Luches and
• Federico Boscherini

Beilstein J. Nanotechnol. 2025, 16, 860–871, doi:10.3762/bjnano.16.65

• photoemission, as compared to non-resonant photoemission. Synchrotron radiation-based resonant photoemission has facilitated an accurate determination of the dependence of Ce3+ concentration on dimensionality [23]. The technique has also provided an accurate description of the charge transfer processes and

• minimal changes with the same thermal treatments in vacuum [49]. The study allowed the authors to conclude that in 2 ML films vertical confinement and/or charge transfer from the platinum substrate, determine a higher reducibility than in 10 ML films [49]. This is evidenced by the greater Ce3

• supporting oxide was found to decrease with decreasing NP size [53], possibly due to a stronger interaction between Ag and cerium oxide in smaller NPs, resulting from a greater charge transfer per atom [54]. A further possibility offered by synchrotrons is to measure spatially resolved Ce M-edge absorption

Synchrotron X-ray photoelectron spectroscopy study of sodium adsorption on vertically arranged MoS₂ layers coated with pyrolytic carbon

• Alexander V. Okotrub,
• Anastasiya D. Fedorenko,
• Anna A. Makarova,
• Veronica S. Sulyaeva,
• Yuliya V. Fedoseeva and
• Lyubov G. Bulusheva

Beilstein J. Nanotechnol. 2025, 16, 847–859, doi:10.3762/bjnano.16.64

• of this component is lower in the PyC-MoS2 spectrum measured after the total 30 min sodiation process. This is due to the lower charge transfer from sodium to the PyC component in the hybrid film as compared to the free PyC film, caused by its diffusion into the MoS2 component. According to the XPS

• that the PyC films transferred onto the surface of the SiO2/Si substrate and the MoS2 film have the same structure. After sodium deposition on the PyC film for 10 min and then 20 min, the sp2 peak shifts by 0.5 and 0.6 eV, respectively, towards higher binding energies. This shift is due to the charge

• transfer from sodium to the carbon layers. For PyC-MoS2, the shifts of the C 1s line caused by sodium deposition are smaller. A new high-energy component (Na-sp2) appearing at 286 and 285 eV in the spectra of sodiated PyC and PyC-MoS2 films, respectively, is due to carbon bonding with sodium. The intensity

Facile one-step radio frequency magnetron sputtering of Ni/NiO on stainless steel for an efficient electrode for hydrogen evolution reaction

• Ha Huu Do,
• Khac Binh Nguyen,
• Phuong N. Nguyen and
• Hoai Phuong Pham

Beilstein J. Nanotechnol. 2025, 16, 837–846, doi:10.3762/bjnano.16.63

• spectroscopy (EIS) was carried out at a voltage of −200 mV to confirm the HER kinetics. Figure 6c shows the Nyquist plots of the various electrodes accompanied by an equivalent circuit (inset of Figure 6c). Ni/NiO/SS-10 has a charge transfer resistance (Rct) of 5.35 Ω, which is much smaller than that of SS

Morphology and properties of pyrite nanoparticles obtained by pulsed laser ablation in liquid and thin films for photodetection

• Akshana Parameswaran Sreekala,
• Bindu Krishnan,
• Rene Fabian Cienfuegos Pelaes,
• David Avellaneda Avellaneda,
• Josué Amílcar Aguilar-Martínez and
• Sadasivan Shaji

Beilstein J. Nanotechnol. 2025, 16, 785–805, doi:10.3762/bjnano.16.60

• phase, where the accumulation of minority carriers near the interface leads to recombination and electron flow into the surface. Over time, a steady state is reached when the rate of hole influx at the interface balances charge transfer and recombination, resulting in a stable photocurrent. When the

• light is turned off, the process stops, and only residual electron movement remains. As the electron flux decays, any leftover holes are consumed by recombination and charge transfer, causing the current to return to zero with a negative overshoot. This justification suggests that since both the

Thickness dependent oxidation in CrCl₃: a scanning X-ray photoemission and Kelvin probe microscopies study

• Shafaq Kazim,
• Rahul Parmar,
• Maryam Azizinia,
• Matteo Amati,
• Muhammad Rauf,
• Andrea Di Cicco,
• Seyed Javid Rezvani,
• Dario Mastrippolito,
• Luca Ottaviano,
• Tomasz Klimczuk,
• Luca Gregoratti and
• Roberto Gunnella

Beilstein J. Nanotechnol. 2025, 16, 749–761, doi:10.3762/bjnano.16.58

• showed that oxygen adsorption on cleaved surfaces facilitates the formation of a stable structure with charge transfer signatures, as identified by high-resolution photoemission spectroscopy [8]. It remains unclear whether similar effects occur in exfoliated thin flakes. Like in other materials, the

• at 576 eV appeared because of the presence of Cl vacancies and the subsequent formation of reactive sites for the dissociation [16] of molecular oxygen to induce a stable phase of Cr–O–Cl [8]. We realized that the low-binding-energy component in Cr 2p3/2 is arising because of charge transfer effects

• . This turns the system from a surface Mott–Hubbard insulator to a charge-transfer [8] one in spite of Cr being an early transition metal [32]. What can be presumed from the present study is that Cl–O exchange following Cl vacancy formation is limited in very thin layers because of the limited diffusion