Ab initio study of adsorption and diffusion of lithium on transition metal dichalcogenide monolayers

• Xiaoli Sun and
• Zhiguo Wang

Beilstein J. Nanotechnol. 2017, 8, 2711–2718, doi:10.3762/bjnano.8.270

• for LIBs [2][3][4][5][6][7][8]. Two-dimensional transition metal dichalcogenides, MX2 (where M and X correspond to transition metal and chalcogen atoms, respectively), have been synthesized using different strategies, such as exfoliation [9][10], physical vapour deposition [11] and chemical vapour

• deposition [12][13][14]. MX2 has received tremendous attention as an alternative to graphite for the anode material in LIBs [15][16]. In particular, MoS2 has been well-investigated as an anode material for LIBs both theoretically and experimentally. A graphene like-MoS2/graphene composite was shown to

Interactions of low-energy electrons with the FEBID precursor chromium hexacarbonyl (Cr(CO)₆)

• Jusuf M. Khreis,
• João Ameixa,
• Filipe Ferreira da Silva and
• Stephan Denifl

Beilstein J. Nanotechnol. 2017, 8, 2583–2590, doi:10.3762/bjnano.8.258

• deposition (FEBID) can be considered an assisted chemical vapour deposition (CVD) technique. However, in the former case the organometallic precursor is not fragmented by thermal energy but instead by a high-energy electron beam. The precursor molecules are delivered to the substrate in the gas phase and

Growth, structure and stability of sputter-deposited MoS₂ thin films

• Reinhard Kaindl,
• Bernhard C. Bayer,
• Roland Resel,
• Thomas Müller,
• Viera Skakalova,
• Gerlinde Habler,
• Rainer Abart,
• Alexey S. Cherevan,
• Dominik Eder,
• Maxime Blatter,
• Fabian Fischer,
• Jannik C. Meyer,
• Dmitry K. Polyushkin and
• Wolfgang Waldhauser

Beilstein J. Nanotechnol. 2017, 8, 1115–1126, doi:10.3762/bjnano.8.113

• [11], tremendous progress on MoS2 growth by chemical vapour deposition (CVD) type synthesis has recently been made [20][22][23][24][25][26]. An alternative fabrication route with industrial scalability and potentially offering MoS2 deposition on a variety of substrates is physical vapour deposition

Study of the correlation between sensing performance and surface morphology of inkjet-printed aqueous graphene-based chemiresistors for NO₂ detection

• F. Villani,
• C. Schiattarella,
• T. Polichetti,
• R. Di Capua,
• F. Loffredo,
• B. Alfano,
• M. L. Miglietta,
• E. Massera,
• L. Verdoliva and
• G. Di Francia

Beilstein J. Nanotechnol. 2017, 8, 1023–1031, doi:10.3762/bjnano.8.103

• printing a LPE graphene suspension dispersed in a water/isopropanol (H2O/IPA) mixture as sensing ink onto paper substrates. Analogous paper-based graphene sensors, relying on different fabrication processes, such as CVD (chemical vapour deposition) grown transferred graphene [13] or inkjet-printed GO

CVD transfer-free graphene for sensing applications

• Chiara Schiattarella,
• Sten Vollebregt,
• Tiziana Polichetti,
• Brigida Alfano,
• Ettore Massera,
• Maria Lucia Miglietta,
• Girolamo Di Francia and
• Pasqualina Maria Sarro

Beilstein J. Nanotechnol. 2017, 8, 1015–1022, doi:10.3762/bjnano.8.102

• surface area. A study on graphene that was synthetized by means of a novel transfer-free fabrication approach and is employed as sensing material is herein presented. Multilayer graphene was deposited by chemical vapour deposition (CVD) mediated by CMOS-compatible Mo. The utilized technique takes

Investigation of growth dynamics of carbon nanotubes

• Marianna V. Kharlamova

Beilstein J. Nanotechnol. 2017, 8, 826–856, doi:10.3762/bjnano.8.85

• summarized. Finally, the growth properties of inner tubes inside SWCNTs filled with fullerene and organometallic molecules are considered. Synthesis of carbon nanotubes The SWCNTs can be synthesized by the arc-discharge, laser ablation and chemical vapour deposition (CVD) techniques. A detailed overview of

Synthesis of graphene–transition metal oxide hybrid nanoparticles and their application in various fields

• Arpita Jana,
• Elke Scheer and
• Sebastian Polarz

Beilstein J. Nanotechnol. 2017, 8, 688–714, doi:10.3762/bjnano.8.74

• graphene from graphite by micromechanical cleavage [1]. Later, graphene was prepared in bulk from graphite utilising various approaches, including micromechanical exfoliation of pyrolytic graphite [31][32][33] (the scotch tape method), epitaxial growth [34], chemical vapour deposition (CVD) [35][36], and

Graphene functionalised by laser-ablated V₂O₅ for a highly sensitive NH₃ sensor

• Margus Kodu,
• Artjom Berholts,
• Tauno Kahro,
• Mati Kook,
• Peeter Ritslaid,
• Helina Seemen,
• Tea Avarmaa,
• Harry Alles and
• Raivo Jaaniso

Beilstein J. Nanotechnol. 2017, 8, 571–578, doi:10.3762/bjnano.8.61

• monolayer per laser pulse are the advantages worth mentioning. The method of PLD has recently been applied to improve the nitrogen dioxide (NO2) sensing properties of chemical vapour deposition (CVD) grown, single-layer graphene in our previous work, using ZrO2 and Ag for functionalisation [14]. In the

Diffusion of dilute gas in arrays of randomly distributed, vertically aligned, high-aspect-ratio cylinders

• Wojciech Szmyt,
• Carlos Guerra and
• Ivo Utke

Beilstein J. Nanotechnol. 2017, 8, 64–73, doi:10.3762/bjnano.8.7

• molecules diffusing between vertically aligned carbon nanotubes. Our findings are important for the correct modelling and optimisation of gas-based deposition techniques, such as atomic layer deposition or chemical vapour deposition, frequently used for surface functionalisation of high-aspect-ratio

• the coating of nanotubes or nanowires with thin films employing techniques such as chemical vapour deposition (CVD) [11] or atomic layer deposition (ALD) [12][13]. Our recent study constitutes an example of the coating of vertically aligned carbon nanotubes (VACNTs) with monocrystalline anatase using

Ferromagnetic behaviour of ZnO: the role of grain boundaries

• Boris B. Straumal,
• Svetlana G. Protasova,
• Andrei A. Mazilkin,
• Eberhard Goering,
• Gisela Schütz,
• Petr B. Straumal and
• Brigitte Baretzky

Beilstein J. Nanotechnol. 2016, 7, 1936–1947, doi:10.3762/bjnano.7.185

• technologies such as wet-chemistry methods or chemical vapour deposition (CVD) sometimes yielded ferromagnetic ZnO and sometimes they did not. It was of course a challenge for solid-state physics and materials science to explain such strange behaviour and to develop the methods to predict (at least

Active and fast charge-state switching of single NV centres in diamond by in-plane Al-Schottky junctions

• Christoph Schreyvogel,
• Vladimir Polyakov,
• Sina Burk,
• Helmut Fedder,
• Andrej Denisenko,
• Felipe Fávaro de Oliveira,
• Ralf Wunderlich,
• Jan Meijer,
• Verena Zuerbig,
• Jörg Wrachtrup and
• Christoph E. Nebel

Beilstein J. Nanotechnol. 2016, 7, 1727–1735, doi:10.3762/bjnano.7.165

• (i.e., without optically active defect centres such as NV centres) was grown homoepitaxially onto the substrate using an ellipsoidal shaped microwave plasma-enhanced chemical vapour deposition (MWPECVD) reactor [22]. After growth, the substrate was removed by laser cutting, the epi-layer mechanically

Enhanced detection of nitrogen dioxide via combined heating and pulsed UV operation of indium oxide nano-octahedra

• Oriol Gonzalez,
• Sergio Roso,
• Xavier Vilanova and
• Eduard Llobet

Beilstein J. Nanotechnol. 2016, 7, 1507–1518, doi:10.3762/bjnano.7.144

• numbers. This could be the case if such sensors were to integrate widespread personal or indoor air monitors. Experimental The indium oxide nano-octahedra were grown onto silicon substrates via a vapour-phase transport method using a horizontal chemical vapour deposition (CVD) furnace. Substrates were

NO gas sensing at room temperature using single titanium oxide nanodot sensors created by atomic force microscopy nanolithography

• Li-Yang Hong and
• Heh-Nan Lin

Beilstein J. Nanotechnol. 2016, 7, 1044–1051, doi:10.3762/bjnano.7.97

• chemical vapour deposition [11][15][16][23], thermal deposition [12], solution growth [19], and electrospinning [24]. Alternatively, a lithographic approach is also suitable for producing the sensing metal oxide material. Previously, atomic force microscopy (AFM) nano-oxidation has been utilized for the

Nitrogen-doped graphene films from chemical vapor deposition of pyridine: influence of process parameters on the electrical and optical properties

• Andrea Capasso,
• Theodoros Dikonimos,
• Francesca Sarto,
• Alessio Tamburrano,
• Giovanni De Bellis,
• Maria Sabrina Sarto,
• Giuliana Faggio,
• Angela Malara,
• Giacomo Messina and
• Nicola Lisi

Beilstein J. Nanotechnol. 2015, 6, 2028–2038, doi:10.3762/bjnano.6.206

• hydrogen flow, due to a higher graphitization level and to a lower defect density. iii) The electrical conductivity is also linked to the doping level, which is however less pronounced above 1000 °C. Conclusion Graphene films were grown by chemical vapour deposition (CVD) using pyridine as liquid carbon

Pt- and Pd-decorated MWCNTs for vapour and gas detection at room temperature

• Hamdi Baccar,
• Atef Thamri,
• Pierrick Clément,
• Eduard Llobet and
• Adnane Abdelghani

Beilstein J. Nanotechnol. 2015, 6, 919–927, doi:10.3762/bjnano.6.95

• synthesised by catalytic chemical vapour deposition and their purity was higher than 95% (NanocylTM NC3100). These multiwalled carbon nanotubes (MWCNT) were up to 50 μm in length and their outer and inner diameters ranged from 3–15 nm and 3–7 nm, respectively. The MWCNTs were dispersed in N,N

Structure and mechanism of the formation of core–shell nanoparticles obtained through a one-step gas-phase synthesis by electron beam evaporation

• Andrey V. Nomoev,
• Sergey P. Bardakhanov,
• Makoto Schreiber,
• Dashima G. Bazarova,
• Nikolai A. Romanov,
• Boris B. Baldanov,
• Bair R. Radnaev and
• Viacheslav V. Syzrantsev

Beilstein J. Nanotechnol. 2015, 6, 874–880, doi:10.3762/bjnano.6.89

• synthesised using solution methods and usually involve two steps: synthesis of the core structure followed by coating the core structure with the shell material. Gas-phase synthesis techniques exist and usually involve chemical vapour deposition (CVD) or pulsed laser deposition (PLD) [1][2]. However these

Low-cost formation of bulk and localized polymer-derived carbon nanodomains from polydimethylsiloxane

• Juan Carlos Castro Alcántara,
• Mariana Cerda Zorrilla,
• Lucia Cabriales,
• Luis Manuel León Rossano and
• Mathieu Hautefeuille

Beilstein J. Nanotechnol. 2015, 6, 744–748, doi:10.3762/bjnano.6.76

• Universitaria, D.F. México, México 10.3762/bjnano.6.76 Abstract We present two simple alternative methods to form polymer-derived carbon nanodomains in a controlled fashion and at low cost, using custom-made chemical vapour deposition and selective laser ablation with a commercial CD-DVD platform. Both

• through the chemical vapour deposition (CVD) technique by using alcohols as reagent for carbon sources. For instance, aliphatic alcohols or mixtures of ethanol and methanol with other substances such as ferrocenes may also be used, depending on the type of the desired carbon nanodomains [4][5]. Laser

• enabled by low-cost custom-made platforms: chemical vapour deposition at 900 °C and selective laser ablation (SLA). In both procedures, it has been found that the combustion of PDMS successfully formed residual nanomaterials of different compositions and ordering depending on the formation conditions

Filling of carbon nanotubes and nanofibres

• Reece D. Gately and
• Marc in het Panhuis

Beilstein J. Nanotechnol. 2015, 6, 508–516, doi:10.3762/bjnano.6.53

• nanotubes (MWCNTs) with an inside diameter as small as 0.4 nm [3] and an outside diameter of up to 200 nm [4]. It has been shown that the inside diameter of MWCNTs produced using chemical vapour deposition is proportional to the size of the metal catalyst used during production [5]. Their high specific

• produced by catalytic thermal chemical vapour deposition using a floating catalyst, henceforth referred to as vapour-grown CNFs (VGCNFs) [24]. This technique can be used to produce partitioned, stacked nanocones or partitioned nanotubes. VGCNFs are produced (depending on the structure of the catalyst) with

Release behaviour and toxicity evaluation of levodopa from carboxylated single-walled carbon nanotubes

• Julia M. Tan,
• Jhi Biau Foo,
• Sharida Fakurazi and
• Mohd Zobir Hussein

Beilstein J. Nanotechnol. 2015, 6, 243–253, doi:10.3762/bjnano.6.23

• suggests that the newly synthesized nanohybrid is a promising drug delivery system for the delivery of LD to nervous system. Experimental Materials Short, carboxyl single-walled carbon nanotubes (SWCNT–COOH) produced by chemical vapour deposition with a diameter of 1–2 nm an purity of 90% (w/w %) were

Liquid-phase exfoliated graphene: functionalization, characterization, and applications

• Mildred Quintana,
• Jesús Iván Tapia and
• Maurizio Prato

Beilstein J. Nanotechnol. 2014, 5, 2328–2338, doi:10.3762/bjnano.5.242

• large-scale and low-cost production of graphene for the development of applications. Recently, using chemical vapour deposition (CVD) techniques (as reported in [4]), it was possible to produce transferable, large graphene sheets that were included in transparent conductive films for mobile phones [5

UHV deposition and characterization of a mononuclear iron(III) β-diketonate complex on Au(111)

• Irene Cimatti,
• Silviya Ninova,
• Valeria Lanzilotto,
• Luigi Malavolti,
• Luca Rigamonti,
• Brunetto Cortigiani,
• Matteo Mannini,
• Elena Magnano,
• Federica Bondino,
• Federico Totti,
• Andrea Cornia and
• Roberta Sessoli

Beilstein J. Nanotechnol. 2014, 5, 2139–2148, doi:10.3762/bjnano.5.223

• in relation with their use as metallic precursors in coating technology, such as chemical vapour deposition (CVD) and atomic layer deposition (ALD) [21][22]. For instance, the reactivity of CuII(hfac)2, hfac− = hexafluoroacetylacetonate, was found to critically depend on the nature of the molecule

Photodetectors based on carbon nanotubes deposited by using a spray technique on semi-insulating gallium arsenide

• Domenico Melisi,
• Maria Angela Nitti,
• Marco Valentini,
• Antonio Valentini,
• Teresa Ligonzo,
• Giuseppe De Pascali and
• Marianna Ambrico

Beilstein J. Nanotechnol. 2014, 5, 1999–2006, doi:10.3762/bjnano.5.208

• the chemical, mechanical and electrical properties make CNTs also suitable to fabricate a wide range of radiation detectors for space applications, high energy physics and medical instrumentation [7][8][9]. The common technique obtain CNT films is chemical vapour deposition (CVD), but some deposition

Carbon-based smart nanomaterials in biomedicine and neuroengineering

• Antonina M. Monaco and
• Michele Giugliano

Beilstein J. Nanotechnol. 2014, 5, 1849–1863, doi:10.3762/bjnano.5.196

• made of one (i.e., single-walled CNTs, SWCNTs) or several (i.e., multi-walled CNTs, MWCNTs) layers of graphene. They are obtained by a variety of methods, including chemical vapour deposition (CVD) and arc-discharge, and their electronic properties depend solely on geometric parameters, such as

Growth and structural discrimination of cortical neurons on randomly oriented and vertically aligned dense carbon nanotube networks

• Christoph Nick,
• Sandeep Yadav,
• Ravi Joshi,
• Christiane Thielemann and
• Jörg J. Schneider

Beilstein J. Nanotechnol. 2014, 5, 1575–1579, doi:10.3762/bjnano.5.169

• . These neuron cells attach preferentially on the CNT sidewalls of the vertically aligned CNT architecture instead than onto the tips of the individual CNT pillars. Keywords: carbon nanotube; chemical vapour deposition; interface; neuron; scaffold; Findings Biochemically functionalised carbon nanotubes

• islands of vertically aligned up to 500 µm in length CNT structures. For the fabrication of both types of CNTs a water-assisted catalytically driven chemical vapour deposition (CVD) growth process was employed [23]. Two different morphologies of CNT arrays were grown depending on the CVD conditions

Review of nanostructured devices for thermoelectric applications

• Giovanni Pennelli

Beilstein J. Nanotechnol. 2014, 5, 1268–1284, doi:10.3762/bjnano.5.141

• approaches are based on the crystalline growth of nanowires by means of chemical vapour deposition (CVD) techniques. The most common CVD technique for the fabrication of silicon nanowires is the vapor–liquid–solid (VLS) growth [74][75], developed in particular by the group of Lieber at Harvard [76][77][78