Direct observation of oxygen-vacancy formation and structural changes in Bi₂WO₆ nanoflakes induced by electron irradiation

• Hong-long Shi,
• Bin Zou,
• Zi-an Li,
• Min-ting Luo and
• Wen-zhong Wang

Beilstein J. Nanotechnol. 2019, 10, 1434–1442, doi:10.3762/bjnano.10.141

• } scattering at the extinction positions of Bi2WO6 (red circles in Figure 3a). The red and blue bars are standard peaks for Bi (PDF#85-1329) and WO3 (PDF#85-0807). The inset shows two typical dark-field images during the electron irradiation. HRTEM analysis of the electron-beam-induced products: (a, b) two

Alloyed Pt₃M (M = Co, Ni) nanoparticles supported on S- and N-doped carbon nanotubes for the oxygen reduction reaction

• Stéphane Louisia,
• Yohann R. J. Thomas,
• Pierre Lecante,
• Marie Heitzmann,
• M. Rosa Axet,
• Pierre-André Jacques and
• Philippe Serp

Beilstein J. Nanotechnol. 2019, 10, 1251–1269, doi:10.3762/bjnano.10.125

• Co islands (Supporting Information File 1, Figure S7a,b) were identified using the scanning transmission electron microscopy/high-angle annular dark-field imaging (STEM-HAADF) technique. Energy-dispersive X-ray spectroscopy (EDX) analysis on the N-CNT surface or in the Co aggregates confirmed the

Green fabrication of lanthanide-doped hydroxide-based phosphors: Y(OH)₃:Eu³⁺ nanoparticles for white light generation

• Tugrul Guner,
• Anilcan Kus,
• Mehmet Ozcan,
• Aziz Genc,
• Hasan Sahin and
• Mustafa M. Demir

Beilstein J. Nanotechnol. 2019, 10, 1200–1210, doi:10.3762/bjnano.10.119

• structure indicates two yttrium atoms located at one face of the hexagonal phase and shared oxygen saturated with hydrogens. To investigate the crystal formation of the samples fabricated at 5 min, several low-magnification high-angle annular dark field (HAADF) STEM micrographs were taken and are presented

• nanowires. The level of doping for Y(OH)3:7.5% Eu3+ phosphors produced at 5 min was captured through an annular dark field (ADF) STEM micrograph and the STEM-EELS analysis of the indicated area is presented in Figure 3. Elemental composition maps of Y (red) and Eu (green) along with their composites are

• ≈10 nm thick nanowires. Annular dark field (ADF) STEM micrograph of an agglomerate of nanoparticles synthesized at 5 min with 7.5% doping ratio. STEM-EELS elemental composition maps of the area indicated with a white rectangle: Y (in red) and Eu (in green) maps along with their composite image. (a

Synthesis and characterization of quaternary La(Sr)S–TaS₂ misfit-layered nanotubes

• Marco Serra,
• Erumpukuthickal Ashokkumar Anumol,
• Dalit Stolovas,
• Iddo Pinkas,
• Ernesto Joselevich,
• Reshef Tenne,
• Andrey Enyashin and
• Francis Leonard Deepak

Beilstein J. Nanotechnol. 2019, 10, 1112–1124, doi:10.3762/bjnano.10.111

• plausible explanation and more careful study of this tendency is undertaken by means of DFT calculations vide infra. The tubular morphology of the SrxLa1−xS–TaS2 sample with 10 atom % Sr in the precursor was further confirmed by high-angle annular dark field (HAADF)-STEM analysis as shown in Figure 3 (top

CuInSe₂ quantum dots grown by molecular beam epitaxy on amorphous SiO₂ surfaces

• Henrique Limborço,
• Pedro M.P. Salomé,
• Rodrigo Ribeiro-Andrade,
• Jennifer P. Teixeira,
• Nicoleta Nicoara,
• Kamal Abderrafi,
• Joaquim P. Leitão,
• Juan C. Gonzalez and
• Sascha Sadewasser

Beilstein J. Nanotechnol. 2019, 10, 1103–1111, doi:10.3762/bjnano.10.110

• the 530 °C sample. Figure 2a shows a high-resolution cross-section high-angle annular dark-field (HAADF) image of a nanodot. Due to the large density of nanodots in the sample, a superposition of two other nanodots can be observed on the back (left and right sides of the image) of the nanodot under

Ceria/polymer nanocontainers for high-performance encapsulation of fluorophores

• Kartheek Katta,
• Dmitry Busko,
• Yuri Avlasevich,
• Katharina Landfester,
• Stanislav Baluschev and
• Rafael Muñoz-Espí

Beilstein J. Nanotechnol. 2019, 10, 522–530, doi:10.3762/bjnano.10.53

• distribution of ceria nanocrystals on the surface of the capsules. The presence of bright spots in the dark field images (Figure 4b) confirms crystalline domains lying in the detection plane [10]. A corresponding high-resolution image of the hybrid sample NC-CeO2 is shown in Figure 4c,d. The ceria content for

• (NC-CeO2). Vertical lines indicates the position and relative intensity of cubic cerium(IV) oxide crystal phase (ICDD card no. 34-0394). TEM micrographs of CeO2/polystyrene hybrid nanocapsules (sample NC-CeO2): a) bright-field image (inset shows the electron diffraction of the shown capsule); b) dark

• -field image; c, d) high-resolution images at different magnification. Fluorescence spectra of terylene diimide encapsulated in nanocapsules: NC (continuous black line, ambient conditions without cerium oxide), NC(Ar) (dashed red line, argon conditions without cerium oxide), NC-CeO2 (dotted blue line

Study of silica-based intrinsically emitting nanoparticles produced by an excimer laser

• Imène Reghioua,
• Mattia Fanetti,
• Sylvain Girard,
• Diego Di Francesca,
• Simonpietro Agnello,
• Layla Martin-Samos,
• Marco Cannas,
• Matjaz Valant,
• Melanie Raine,
• Marc Gaillardin,
• Nicolas Richard,
• Philippe Paillet,
• Aziz Boukenter,
• Youcef Ouerdane and
• Antonino Alessi

Beilstein J. Nanotechnol. 2019, 10, 211–221, doi:10.3762/bjnano.10.19

• , indicating that the produced particles are amorphous. Figure 3e and 3f show the dark-field STEM images recorded for large nanoparticles and for a group of small ones detected in sample A. In both images we note the presence of several brilliant spots. Such spots are present independent from the particle size

• applications, as discussed in [5][6][13][35][36][37], and the irregular shape might not be an insurmountable problem from an applications point of view [37]. Independent from the employed energy per pulse and from the nanoparticle size, the STEM images evidenced the presence of some bright spots. In dark-field

• keV beam energy. STEM images were acquired with a dark-field annular detector. For all the experiments we used holey-carbon-coated grids on 200 mesh copper from SPI, since these grids allow the characterization of the same zones along the samples with the different techniques. The thin network-shaped

Surface plasmon resonance enhancement of photoluminescence intensity and bioimaging application of gold nanorod@CdSe/ZnS quantum dots

• Siyi Hu,
• Yu Ren,
• Yue Wang,
• Jinhua Li,
• Junle Qu,
• Liwei Liu,
• Hanbin Ma and
• Yuguo Tang

Beilstein J. Nanotechnol. 2019, 10, 22–31, doi:10.3762/bjnano.10.3

• particle per 1 × 1 μm area. The experimental microspectroscopy equipment was used to collect the integrated, white light, dark-field scattering, as well as the PL spectra and the atomic force microscopy techniques. We measured the scattering and the PL emission signal from a single particle. The

Characterization and influence of hydroxyapatite nanopowders on living cells

• Przemyslaw Oberbek,
• Tomasz Bolek,
• Adrian Chlanda,
• Seishiro Hirano,
• Sylwia Kusnieruk,
• Julia Rogowska-Tylman,
• Ganna Nechyporenko,
• Viktor Zinchenko,
• Wojciech Swieszkowski and
• Tomasz Puzyn

Beilstein J. Nanotechnol. 2018, 9, 3079–3094, doi:10.3762/bjnano.9.286

• representative SEM images using the ImageJ software [34]. SEM in combination with an X-ray microanalyser (EDS, energy dispersion spectroscopy) was used to carry out chemical pre-analysis. EDS was carried out in dark-field (accelerating voltage = 8 kV, 2 min scan, ca. 10,000 counts) and quantitative analysis was

Accurate control of the covalent functionalization of single-walled carbon nanotubes for the electro-enzymatically controlled oxidation of biomolecules

• Naoual Allali,
• Veronika Urbanova,
• Mathieu Etienne,
• Xavier Devaux,
• Martine Mallet,
• Brigitte Vigolo,
• Jean-Joseph Adjizian,
• Chris P. Ewels,
• Sven Oberg,
• Alexander V. Soldatov,
• Edward McRae,
• Yves Fort,
• Manuel Dossot and
• Victor Mamane

Beilstein J. Nanotechnol. 2018, 9, 2750–2762, doi:10.3762/bjnano.9.257

• 80 kV in order to minimize knock-on damage to the samples. HRSTEM images were recorded using an electron beam with a probe-size of about 0.12 nm. High-angle annular dark-field (HAADF) and bright-field (BF) images were simultaneously recorded with a semi-angle of collection of respectively 45–180 mrad

Low cost tips for tip-enhanced Raman spectroscopy fabricated by two-step electrochemical etching of 125 µm diameter gold wires

• Antonino Foti,
• Francesco Barreca,
• Enza Fazio,
• Cristiano D’Andrea,
• Paolo Matteini,
• Onofrio Maria Maragò and
• Pietro Giuseppe Gucciardi

Beilstein J. Nanotechnol. 2018, 9, 2718–2729, doi:10.3762/bjnano.9.254

• between the dark-field scattering peak, attributed to plasmon excitations, and the position of the maximum integrated SERS background of the tip, confirming that the background is enhanced by the localized plasmon resonance in the apical region. On sharp Au tips, the same authors report an almost flat

High-temperature magnetism and microstructure of a semiconducting ferromagnetic (GaSb)_1−x(MnSb)_x alloy

• Leonid N. Oveshnikov,
• Elena I. Nekhaeva,
• Alexey V. Kochura,
• Alexander B. Davydov,
• Mikhail A. Shakhov,
• Sergey F. Marenkin,
• Oleg A. Novodvorskii,
• Alexander P. Kuzmenko,
• Alexander L. Vasiliev,
• Boris A. Aronzon and
• Erkki Lahderanta

Beilstein J. Nanotechnol. 2018, 9, 2457–2465, doi:10.3762/bjnano.9.230

• probe corrector), a high-angle annular dark field (HAADF) detector, an atmospheric thin-window energy dispersive X-ray (EDX) spectrometer (Phoenix System, EDAX, US) and a post-column Gatan energy filter (GIF), (Gatan, US). The S/TEM was operated at 300 kV. Digital micrograph (Gatan, US) and TIA software

Dumbbell gold nanoparticle dimer antennas with advanced optical properties

• Janning F. Herrmann and
• Christiane Höppener

Beilstein J. Nanotechnol. 2018, 9, 2188–2197, doi:10.3762/bjnano.9.205

• screening, are known to alter the plasmon coupling, and thus, the optical response. Furthermore, antennas with sub-nanometer gaps are more sensitive to deviations from the ideal sphere geometry, gap size fluctuations and morphological changes [27]. Therefore, dark-field spectra are recorded of individual CB

• from the BDP, also the dipolar anti-bonding dimer plasmon (ADP) mode (Figure 4A), which is characteristic for the asymmetric dimer geometry. The experimentally recorded dark-field spectra displayed in Figure 4B–Figure 4H reflect this profile. However, the BDP and ADP peak positions are red-shifted and

• process, the observed light confinement and the post-characterization by means of scanning electron microscopy imaging (SEM image, inset Figure 1C). Since the spontaneous emission rate is taken as a measure for the electromagnetic field enhancement, the influence of the observed changes in the dark-field

High-throughput synthesis of modified Fresnel zone plate arrays via ion beam lithography

• Kahraman Keskinbora,
• Umut Tunca Sanli,
• Margarita Baluktsian,
• Corinne Grévent,
• Markus Weigand and
• Gisela Schütz

Beilstein J. Nanotechnol. 2018, 9, 2049–2056, doi:10.3762/bjnano.9.194

• . This can be attributed to the shifting plasmon resonances of the gold nanowires that make up the zones of the FZPs. A scanning transmission electron microscope (STEM) dark-field overview image of the completed array is shown in Figure 4b. The FZPs mostly exhibited high quality with zones free from

• could pass the inspection via electron microscopy. Hence, the robustness of the fabrication method is supported with a 100% yield. One of these FZPs from the marked region in Figure 4d is depicted in Figure 4e, a higher-magnification STEM dark-field image. The FZP showed similar characteristics to the

• ion beam with a nominal beam size of 16 nm was utilized. By using a step size of 8 nm and a dwell time of 0.2133 the linear dosage was 0.8 pC/µm. The array was fabricated by replicating the pattern in a matrix form with 55 µm steps in the x- and y-directions. Dark-field scanning transmission electron

Self-assembled quasi-hexagonal arrays of gold nanoparticles with small gaps for surface-enhanced Raman spectroscopy

• Emre Gürdal,
• Simon Dickreuter,
• Fatima Noureddine,
• Pascal Bieschke,
• Dieter P. Kern and
• Monika Fleischer

Beilstein J. Nanotechnol. 2018, 9, 1977–1985, doi:10.3762/bjnano.9.188

• -built dark-field spectroscopy setup. A 50× objective (Mitutoyo BD Plan APO SL 50X) was used for imaging and taking the spectra. The samples were illuminated by a laser driven light source (Energetiq EQ-99-FC) at an incident angle of light of about 45°. The spectra were taken with an Andor Shamrock SR

• center-to-center spacing varies slightly from sample to sample. To compare the SERS signal of smaller particles with larger gaps to that of larger particles with small gaps, the optical properties of the samples shown in Figure 2 were further analyzed using dark-field spectroscopy. For every sample, 25

• nanometers, which are fabricated by block copolymer micellar nanolithography combined with electroless deposition. The resulting particle arrangements are compared for samples prepared with 30 min vs 90 min ED. The dark-field scattering intensity is compared for the different nanoparticle sizes. We

Synthesis of rare-earth metal and rare-earth metal-fluoride nanoparticles in ionic liquids and propylene carbonate

• Marvin Siebels,
• Lukas Mai,
• Laura Schmolke,
• Kai Schütte,
• Juri Barthel,
• Junpei Yue,
• Jörg Thomas,
• Bernd M. Smarsly,
• Anjana Devi,
• Roland A. Fischer and
• Christoph Janiak

Beilstein J. Nanotechnol. 2018, 9, 1881–1894, doi:10.3762/bjnano.9.180

• distributions of the nanoparticles were determined by transmission electron microscopy (TEM) and high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) to an average diameter of (11 ± 6) to (38 ± 17) nm for the REF3-NPs from [BMIm][BF4]. The RE-NPs from [BMIm][NTf2] or PC showed

• nanoparticles were determined by transmission electron microscopy (TEM) and high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM). The crystalline phases and the absence of impurities (oxides) in RE-NPs and REF3-NPs were identified by powder X-ray diffraction (PXRD) and selected

• images were recorded with a Gatan UltraScan 1000P detector. High-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) as shown in Figure S4a (Supporting Information File 1) was also performed with this microscope. TEM samples were prepared by drop-casting the diluted material

Toward the use of CVD-grown MoS₂ nanosheets as field-emission source

• Geetanjali Deokar,
• Nitul S. Rajput,
• Junjie Li,
• Francis Leonard Deepak,
• Wei Ou-Yang,
• Nicolas Reckinger,
• Carla Bittencourt,
• Jean-Francois Colomer and
• Mustapha Jouiad

Beilstein J. Nanotechnol. 2018, 9, 1686–1694, doi:10.3762/bjnano.9.160

• performed using an image-corrected Titan G2 FEITM system. For selected samples, cross-section TEM analyses were carried out using an aberration-corrected FEITM Titan ChemiSTEM system (equipped with a Cs probe corrector, a high-angle annular dark-field imaging (HAADF) detector and a four quadrant Super X

A novel copper precursor for electron beam induced deposition

• Caspar Haverkamp,
• George Sarau,
• Mikhail N. Polyakov,
• Ivo Utke,
• Marcos V. Puydinger dos Santos,
• Silke Christiansen and
• Katja Höflich

Beilstein J. Nanotechnol. 2018, 9, 1220–1227, doi:10.3762/bjnano.9.113

• of 8 × 8 nanocones with a distance of 400 nm and a base diameter of 80 nm (Figure 5a). It was fabricated using 50 pA beam current and a dwell time of 8 seconds for each cone. The scattering intensity was measured by dark-field reflection spectroscopy and compared to FDTD simulations. Figure 5b shows

Effect of annealing treatments on CeO₂ grown on TiN and Si substrates by atomic layer deposition

• Silvia Vangelista,
• Rossella Piagge,
• Satu Ek and
• Alessio Lamperti

Beilstein J. Nanotechnol. 2018, 9, 890–899, doi:10.3762/bjnano.9.83

• [25]. Focused ion beam has been used to prepare lamellae of selected samples for transmission electron microscopy (TEM) analysis (cross and plan view, Fei Tecnai G2) in bright or dark field at a voltage of 200 kV. Plan view images are treated with free software to obtain the crystallite size

• orientation of the as-deposited CeO2/Si sample is enhanced after high temperature annealing: In the film there is an increased number of grains with (200) orientation in addition to those with (111) orientation. The plan-view TEM image in dark field of the CeO2/Si sample (Figure 8) is very impressive in

Cyclodextrin-assisted synthesis of tailored mesoporous silica nanoparticles

• Fuat Topuz and
• Tamer Uyar

Beilstein J. Nanotechnol. 2018, 9, 693–703, doi:10.3762/bjnano.9.64

• particles, which were dispersed in water, and a tiny droplet was dried on a TEM grid. The particles were imaged at 300 kV. STEM images were captured using a high-angle annular dark field (HAADF) detector. The chemical compositions of nanoparticles were explored by solid-state 13C NMR using an Inova 500 MHz

Facile phase transfer of gold nanorods and nanospheres stabilized with block copolymers

• Yaroslav I. Derikov,
• Georgiy A. Shandryuk,
• Raisa V. Talroze,
• Alexander A. Ezhov and
• Yaroslav V. Kudryavtsev

Beilstein J. Nanotechnol. 2018, 9, 616–627, doi:10.3762/bjnano.9.58

• patterns and dark field images were used to confirm the crystallinity of Au nanoparticles. The length and diameter distributions of the nanorods and nanospheres were measured by ImageJ 1.50b open source software (Wayne Rasband, NIH, USA). SEM images were obtained on a scanning electron microscope JSM 7401F

Towards 3D crystal orientation reconstruction using automated crystal orientation mapping transmission electron microscopy (ACOM-TEM)

• Aaron Kobler and
• Christian Kübel

Beilstein J. Nanotechnol. 2018, 9, 602–607, doi:10.3762/bjnano.9.56

• reported only a few times [18][19]. 2D crystal orientation can be mapped using three methods inside the TEM: Kikuchi diffraction, diffraction pattern reconstruction from conical dark field images and spot Bragg diffraction [22][23]. Kikuchi diffraction was the first to be used in the TEM [22][23]. However

• resolution and quality of crystal orientation data for the TEM. Conical dark field imaging (CDFI) was used in the 3D-orientation mapping in transmission electron microscope (3D-OMiTEM) method to first reconstruct the diffraction pattern and then the 3D crystal structure [19]. Spot Bragg diffraction, in

BN/Ag hybrid nanomaterials with petal-like surfaces as catalysts and antibacterial agents

• Konstantin L. Firestein,
• Denis V. Leybo,
• Alexander E. Steinman,
• Andrey M. Kovalskii,
• Andrei T. Matveev,
• Anton M. Manakhov,
• Irina V. Sukhorukova,
• Pavel V. Slukin,
• Nadezda K. Fursova,
• Sergey G. Ignatov,
• Dmitri V. Golberg and
• Dmitry V. Shtansky

Beilstein J. Nanotechnol. 2018, 9, 250–261, doi:10.3762/bjnano.9.27

• vapours, and (ii) ultraviolet (UV) decomposition of AgNO3 in a suspension of BN NPs. The hybrid microstructures were studied by high-resolution transmission electron microscopy (HRTEM), high-angular dark field scanning TEM imaging paired with energy dispersion X-ray (EDX) mapping, X-ray photoelectron

• means of high-resolution transmission electron microscopy (HRTEM), high-angular dark field scanning TEM (HADF-STEM) imaging and energy-dispersive X-ray spectroscopy (EDX) mapping using a JEM-2100 microscope (JEOL) equipped with an energy-dispersive X-ray spectrometer (Oxford Instruments) and a STEM

Gas-assisted silver deposition with a focused electron beam

• Luisa Berger,
• Katarzyna Madajska,
• Iwona B. Szymanska,
• Katja Höflich,
• Mikhail N. Polyakov,
• Jakub Jurczyk,
• Carlos Guerra-Nuñez and
• Ivo Utke

Beilstein J. Nanotechnol. 2018, 9, 224–232, doi:10.3762/bjnano.9.24

• particles. Additionally, selective area electron diffraction (SAED) on this area clearly shows a diffraction pattern, confirming a crystalline deposit (Figure 3d) with diffraction rings matching the pattern of fcc silver as illustrated by the green rings. In the dark field (DF) STEM images in Figure 4 the

• structure of the deposited crystallites can be affirmed. Dark field scanning transmission electron micrographs of the line deposit. (a) Overview image of the line. By depositing onto a thin carbon membrane, no BSEs are generated, preventing halo formation outside the PE area (lw = line width). (b) Higher

• visible. (c) Raman spectrum of the line deposit. The sp3 and sp2 bands are indicated. Transmission electron micrographs of the carbon membrane after deposition. (a) Typical dark field STEM image of the substrate after deposition, 700 µm away from the deposit. Small crystallites are homogeneously scattered

Bombyx mori silk/titania/gold hybrid materials for photocatalytic water splitting: combining renewable raw materials with clean fuels

• Stefanie Krüger,
• Michael Schwarze,
• Otto Baumann,
• Christina Günter,
• Michael Bruns,
• Christian Kübel,
• Dorothée Vinga Szabó,
• Rafael Meinusch,
• Verónica de Zea Bermudez and
• Andreas Taubert

Beilstein J. Nanotechnol. 2018, 9, 187–204, doi:10.3762/bjnano.9.21

• with optical microscopy. Moreover, the diameter of the AuNPs in the TS_Au5.0 materials is mainly between 7–13 nm, but smaller Au particles are also present. Furthermore, bright field TEM images of TS_Au5.0 show a homogeneous AuNP distribution on the TNP. Dark field STEM images of the HM show a better