Synthesis of highly active ETS-10-based titanosilicate for heterogeneously catalyzed transesterification of triglycerides

• Muhammad A. Zaheer,
• David Poppitz,
• Khavar Feyzullayeva,
• Marianne Wenzel,
• Jörg Matysik,
• Radomir Ljupkovic,
• Aleksandra Zarubica,
• Alexander A. Karavaev,
• Andreas Pöppl,
• Roger Gläser and
• Muslim Dvoyashkin

Beilstein J. Nanotechnol. 2019, 10, 2039–2061, doi:10.3762/bjnano.10.200

Sub-wavelength waveguide properties of 1D and surface-functionalized SnO₂ nanostructures of various morphologies

• Venkataramana Bonu,
• Binaya Kumar Sahu,
• Arindam Das,
• Sankarakumar Amirthapandian,
• Sandip Dhara and
• Harish C. Barshilia

Beilstein J. Nanotechnol. 2019, 10, 379–388, doi:10.3762/bjnano.10.37

• the tapered tip of an optical fiber as a probe for endoscopy, which additionally showed no toxicity. In this context, the development of tapered NWs is considered to be an important step, eliminating the difficult attachment exercise and reducing the fear of device decoupling and subsequent loss of

One-step nonhydrolytic sol–gel synthesis of mesoporous TiO₂ phosphonate hybrid materials

• Yanhui Wang,
• P. Hubert Mutin and
• Johan G. Alauzun

Beilstein J. Nanotechnol. 2019, 10, 356–362, doi:10.3762/bjnano.10.35

• spinning (MAS) NMR experiments were performed on a Varian VNMRS 400 MHz (9.4 T) spectrometer using a 3.2 mm Varian T3 HXY MAS probe. Single pulse experiments were carried out with a spinning rate of 20 kHz, a 90° excitation pulse of 3 μs, a recycle delay of 30 s and 100 kHz spinal-64 1H decoupling. 200

Geometrical optimisation of core–shell nanowire arrays for enhanced absorption in thin crystalline silicon heterojunction solar cells

• Robin Vismara,
• Olindo Isabella,
• Andrea Ingenito,
• Fai Tong Si and
• Miro Zeman

Beilstein J. Nanotechnol. 2019, 10, 322–331, doi:10.3762/bjnano.10.31

• advantage of decoupling absorption and collection, by orthogonalising the path of light with respect to the direction of charge carrier collection [14][16][17]. This aspect allows for the use of lower-quality materials, characterised by short minority carrier diffusion length and/or low absorptivity

Disorder in H⁺-irradiated HOPG: effect of impinging energy and dose on Raman D-band splitting and surface topography

• Lisandro Venosta,
• Noelia Bajales,
• Sergio Suárez and
• Paula G. Bercoff

Beilstein J. Nanotechnol. 2018, 9, 2708–2717, doi:10.3762/bjnano.9.253

• latter contribution might have already be present in a small amount in the pristine HOPG, as shown in Figure 1a. Perfect zigzag edges do not contribute to the increase of the D band [5]. Regarding the identification of C–H sp3 bonds originating from hydrogenation of HOPG layers, a decoupling of

Influence of the thickness of an antiferromagnetic IrMn layer on the static and dynamic magnetization of weakly coupled CoFeB/IrMn/CoFeB trilayers

• Deepika Jhajhria,
• Dinesh K. Pandya and
• Sujeet Chaudhary

Beilstein J. Nanotechnol. 2018, 9, 2198–2208, doi:10.3762/bjnano.9.206

• detected. This is because the two FM layers are magnetically identical giving rise to the presence of a dominant acoustic mode and a weak optical mode [30][31]. For tIrMn = 7 nm, the decoupling occurs as indicated by the presence of two independent FMR modes with slightly different values of Hr and ΔH

Interplay between pairing and correlations in spin-polarized bound states

• Szczepan Głodzik,
• Aksel Kobiałka,
• Anna Gorczyca-Goraj,
• Andrzej Ptok,
• Grzegorz Górski,
• Maciej M. Maśka and
• Tadeusz Domański

Beilstein J. Nanotechnol. 2018, 9, 1370–1380, doi:10.3762/bjnano.9.129

• (annihilation) of an electron with spin σ at the i-th site, t is a hopping integral between the nearest neighbors, μ is the chemical potential, and is the number operator. For simplicity, we assume a weak attractive potential U < 0 between itinerant electrons and treat it within the mean-field decoupling

An implementation of spin–orbit coupling for band structure calculations with Gaussian basis sets: Two-dimensional topological crystals of Sb and Bi

• Sahar Pakdel,
• Mahdi Pourfath and
• J. J. Palacios

Beilstein J. Nanotechnol. 2018, 9, 1015–1023, doi:10.3762/bjnano.9.94

• decoupling of the TSS requires a minimum of 7 layers [54][55]. In between the semiconductor monolayer and the 7-layered antimonene a crossover occurs, where claims of the existence of a 2D topological insulator have also been reported, but we do not pursue the investigation of this issue here [55]. When TSS

The effect of atmospheric doping on pressure-dependent Raman scattering in supported graphene

• Egor A. Kolesov,
• Mikhail S. Tivanov,
• Olga V. Korolik,
• Olesya O. Kapitanova,
• Xiao Fu,
• Hak Dong Cho,
• Tae Won Kang and
• Gennady N Panin

Beilstein J. Nanotechnol. 2018, 9, 704–710, doi:10.3762/bjnano.9.65

• least partial layer decoupling that results in the presence of biaxial strain [27]. Besides, values of I2D/IG did not indicate a strong doping presence. Thus, the overall greater G and 2D peak position values most likely are strain-related rather than an indication of greater atmosphere-induced doping

Electronic structure, transport, and collective effects in molecular layered systems

• Torsten Hahn,
• Tim Ludwig,
• Carsten Timm and
• Jens Kortus

Beilstein J. Nanotechnol. 2017, 8, 2094–2105, doi:10.3762/bjnano.8.209

• taken to be a graphene monolayer for simplicity, intended as a decoupling layer as discussed in section ’DFT-NEGF transport theory’. The symmetry of the HOMO is clearly visible and is not noticeably reduced by the hybridization with the substrate. Figure 5b shows the absolute value squared |tTS|2 of the

High-stress study of bioinspired multifunctional PEDOT:PSS/nanoclay nanocomposites using AFM, SEM and numerical simulation

• Alfredo J. Diaz,
• Hanaul Noh,
• Tobias Meier and
• Santiago D. Solares

Beilstein J. Nanotechnol. 2017, 8, 2069–2082, doi:10.3762/bjnano.8.207

• ). Using the Euler–Bernoulli beam model interacting with a Kelvin–Voigt spring-dashpot element at the tip–sample junction, decoupling of the conservative and dissipative interactions of the tip–sample junction is possible [73]. In CRFM-DART, the amplitude and phase of the cantilever response are monitored

A comparative study of the nanoscale and macroscale tribological attributes of alumina and stainless steel surfaces immersed in aqueous suspensions of positively or negatively charged nanodiamonds

• Colin K. Curtis,
• Antonin Marek,
• Alex I. Smirnov and
• Jacqueline Krim

Beilstein J. Nanotechnol. 2017, 8, 2045–2059, doi:10.3762/bjnano.8.205

• resistance to shear motion at the solid liquid interface were observed upon an introduction of the +ND. Such changes might result from loosely bound particles enabling some decoupling of the mass of the fluid surrounding the QCM with no significant reductions in the friction energy losses at the interface

Advances and challenges in the field of plasma polymer nanoparticles

• Andrei Choukourov,
• Pavel Pleskunov,
• Daniil Nikitin,
• Valerii Titov,
• Artem Shelemin,
• Mykhailo Vaidulych,
• Anna Kuzminova,
• Pavel Solař,
• Jan Hanuš,
• Jaroslav Kousal,
• Ondřej Kylián,
• Danka Slavínská and
• Hynek Biederman

Beilstein J. Nanotechnol. 2017, 8, 2002–2014, doi:10.3762/bjnano.8.200

• shell. The second strategy relies on spatial separation of the formation of metal NPs and their embedding into polymer or plasma polymer shells, similar to what has been realized in [72][73]. This strategy allows the decoupling of the processes of magnetron sputtering and plasma polymerization and may

Adsorption and electronic properties of pentacene on thin dielectric decoupling layers

• Sebastian Koslowski,
• Daniel Rosenblatt,
• Alexander Kabakchiev,
• Klaus Kuhnke,
• Klaus Kern and
• Uta Schlickum

Beilstein J. Nanotechnol. 2017, 8, 1388–1395, doi:10.3762/bjnano.8.140

• 10.3762/bjnano.8.140 Abstract With the increasing use of thin dielectric decoupling layers to study the electronic properties of organic molecules on metal surfaces, comparative studies are needed in order to generalize findings and formulate practical rules. In this paper we study the adsorption and

• individual molecules on thin electronically decoupling layers. Depositing pentacene onto h-BN/Rh(111) results in significantly different adsorption characteristics, due to the topographic corrugation of the surface as well as the lateral electric fields it presents. These properties are reflected in the

• to sufficiently separate (electronically decouple) the molecules from the underlying metal substrate by means of thin insulating layers (decoupling layers) [6]. To achieve this, a thin spacer layer with a large band gap of several electronvolts can be used that acts as a tunnel barrier towards the

3D continuum phonon model for group-IV 2D materials

• Morten Willatzen,
• Lok C. Lew Yan Voon,
• Appala Naidu Gandi and
• Udo Schwingenschlögl

Beilstein J. Nanotechnol. 2017, 8, 1345–1356, doi:10.3762/bjnano.8.136

• before, which led to a decoupling of the out-of-plane vibrations. The coupling is a consequence of the finite thickness of the sheet with no mirror symmetry imposed. Thus, our model is sufficiently general to apply to multilayers. Earlier DFT calculations [15] had argued that there is no coupling between

Ultrasmall magnetic field-effect and sign reversal in transistors based on donor/acceptor systems

• Thomas Reichert and
• Tobat P. I. Saragi

Beilstein J. Nanotechnol. 2017, 8, 1104–1114, doi:10.3762/bjnano.8.112

• fields. For stronger magnetic fields, the reduction of the spin mixing due to the Zeeman decoupling of the singlet and triplet levels dominates leading to the MR sign-change typical for USMFE. The polarity of the MR sign-change is controlled by the drain voltage, which can be explained with the

Tailoring bifunctional hybrid organic–inorganic nanoadsorbents by the choice of functional layer composition probed by adsorption of Cu²⁺ ions

• Veronika V. Tomina,
• Inna V. Melnyk,
• Yuriy L. Zub,
• Aivaras Kareiva,
• Miroslava Vaclavikova,
• Gulaim A. Seisenbaeva and
• Vadim G. Kessler

Beilstein J. Nanotechnol. 2017, 8, 334–347, doi:10.3762/bjnano.8.36

• , Aldrich). 13C and 29Si MAS NMR experiments were carried out on a Bruker Avance II 400 spectrometer using 4 mm rotors (ZrO2) spun at 10 kHz. 13C NMR spectra were recorded using 1H→13C CP/MAS, 1H decoupling during acquisition, 3 ms contact time, and 5 s recycling delay. The number of scans was between 768

Tandem polymer solar cells: simulation and optimization through a multiscale scheme

• Fanan Wei,
• Ligang Yao,
• Fei Lan,
• Guangyong Li and
• Lianqing Liu

Beilstein J. Nanotechnol. 2017, 8, 123–133, doi:10.3762/bjnano.8.13

• the proposed multiscale simulation was divided into four parts: optical calculation module, mesoscale simulation module, device scale simulation module, and finally, optimal PCE searching module. Optical decoupling in optical calculation module In tandem polymer solar cells, the two stacked sub-cells

• are optically highly coupled. Thus, an optical decoupling process is required before any evaluation of device performance. In the optical calculation part developed here, the complex refractive index of the blend with varied D/A weight ratios (2:1, 3:2, 1:1, 2:3 and 1:2) in the P3HT/PCBM layer was

Intercalation and structural aspects of macroRAFT agents into MgAl layered double hydroxides

• Dessislava Kostadinova,
• Ana Cenacchi Pereira,
• Muriel Lansalot,
• Franck D’Agosto,
• Elodie Bourgeat-Lami,
• Fabrice Leroux,
• Christine Taviot-Guého,
• Sylvian Cadars and
• Vanessa Prevot

Beilstein J. Nanotechnol. 2016, 7, 2000–2012, doi:10.3762/bjnano.7.191

• caused by dipole–dipole interactions that are too strong to be properly averaged by MAS. However, this is circumvented in the 2D HETCOR spectra by the application of homonuclear 1H decoupling during the 1H evolution period (see details in Experimental). For the same reason, the 2D peak positions in the

• with 128 scans for the copolymer-intercalated LDH, and 32 scans for the PAA-intercalated material. Two-dimensional (2D) 13C{1H} heteronuclear correlation experiments used frequency-switched Lee–Goldburg (FSLG) homonuclear decoupling [58] at a nutation frequency of 75 kHz during the (indirect) 1H

• evolution period to reduce 1H–1H dipolar couplings and increase resolution. The associated frequency scaling factor (0.535) was measured and corrected for, based on a 1H–1H correlation experiment (spin-diffusion with null mixing time) conducted under identical homonuclear decoupling conditions. Contact

Scanning probe microscopy studies on the adsorption of selected molecular dyes on titania

• Jakub S. Prauzner-Bechcicki,
• Lukasz Zajac,
• Piotr Olszowski,
• Res Jöhr,
• Antoine Hinaut,
• Thilo Glatzel,
• Bartosz Such,
• Ernst Meyer and
• Marek Szymonski

Beilstein J. Nanotechnol. 2016, 7, 1642–1653, doi:10.3762/bjnano.7.156

• oxide substrate [48]. Indeed, the BiPy molecules formed a buffer layer of upright molecules that, by spatial separation of FePc from the TiO2(110) surface, allows for its electronic decoupling. As soon as iron phthalocyanine molecules are deposited on the buffer layer, they adsorb and form molecular

Novel roles for well-known players: from tobacco mosaic virus pests to enzymatically active assemblies

• Claudia Koch,
• Fabian J. Eber,
• Carlos Azucena,
• Alexander Förste,
• Stefan Walheim,
• Thomas Schimmel,
• Alexander M. Bittner,
• Holger Jeske,
• Hartmut Gliemann,
• Sabine Eiben,
• Fania C. Geiger and
• Christina Wege

Beilstein J. Nanotechnol. 2016, 7, 613–629, doi:10.3762/bjnano.7.54

• freedom for a dense decoration with [SA]-enzymes, and a spatial decoupling of the enzymes and the TMV scaffold. About 50% of the CPCys subunits could be decorated with biotin linkers, and virtually all thereof with enzymes (Figure 5B,C), resulting in complete coverage of the TMV sticks by more than a

Orientation of FePt nanoparticles on top of a-SiO₂/Si(001), MgO(001) and sapphire(0001): effect of thermal treatments and influence of substrate and particle size

• Martin Schilling,
• Paul Ziemann,
• Zaoli Zhang,
• Johannes Biskupek,
• Ute Kaiser and
• Ulf Wiedwald

Beilstein J. Nanotechnol. 2016, 7, 591–604, doi:10.3762/bjnano.7.52

• fabricated on MgO buffer layers for heat-assisted magnetic recording. In this experiment, 3–9 nm FePt NPs formed, while C acted as an exchange-decoupling spacer and the NPs reach an imposing MAE of 5.2 MJ·m−3, i.e., about 80% of the L10 FePt bulk value [14]. As just mentioned, if FePt films or NPs are

Rigid multipodal platforms for metal surfaces

• Michal Valášek,
• Marcin Lindner and
• Marcel Mayor

Beilstein J. Nanotechnol. 2016, 7, 374–405, doi:10.3762/bjnano.7.34

• spatial arrangement and position of single molecules. New approaches to create free volume around the functional molecules in the monolayers and to achieve the effective electronic decoupling of individual molecules from the metal surfaces and to get high-performance molecular devices have been discovered

• metal states is limited due to the multipodal architectures comprising sp3-hybridized atoms. This electronic decoupling of the functional subunit is on one hand desired to profit from the optical properties of the subunit but on the other hand it represents a considerable handicap for molecular

• electroluminescence STM experiment (Figure 17) [74]. The rigid tripodal anchor in this molecule not only acts as a robust decoupling spacer but also controls the orientation of the porphyrin molecule in the desired up-right standing position along the tip axial direction. STM images revealed the formation of

Sonochemical co-deposition of antibacterial nanoparticles and dyes on textiles

• Ilana Perelshtein,
• Anat Lipovsky,
• Nina Perkas,
• Tzanko Tzanov and
• Aharon Gedanken

Beilstein J. Nanotechnol. 2016, 7, 1–8, doi:10.3762/bjnano.7.1

• spectrometer, using a 4 nm double-resonance magic angle spinning (MAS) probe. 13C CP-MAS experiments were carried out at a spinning rate of 8 kHz, using a 2.5 ms 1H 90° pulse, 2 K data points, 1 K scans and a 2 ms ramped-CP period. Proton decoupling using the SPINAL composite pulse sequence at a field of 100

Electrospray deposition of organic molecules on bulk insulator surfaces

• Antoine Hinaut,
• Rémy Pawlak,
• Ernst Meyer and
• Thilo Glatzel

Beilstein J. Nanotechnol. 2015, 6, 1927–1934, doi:10.3762/bjnano.6.195

• molecules, their decoupling from the metal surface is desirable. Deposition and analysis on insulating films or crystals is thus mandatory and requires high resolution imaging. Therefore, for the characterization at the atomic-scale, atomic force microscopy (AFM) is mandatory. Numerous experimental AFM