Fragmentation of metal(II) bis(acetylacetonate) complexes induced by slow electrons

• Janina Kopyra and
• Hassan Abdoul-Carime

Beilstein J. Nanotechnol. 2023, 14, 980–987, doi:10.3762/bjnano.14.81

• attachment. The reported data may contribute to a better understanding of the physical chemistry underlying the electron–molecule interactions, which is crucial for potential applications of these molecular systems in the deposition of nanoscale structures. Keywords: dissociative electron attachment; gas

• electron beam with an organometallic target (e.g., focused electron beam-induced deposition, FEBID) is a promising technique for direct 3D deposition of high-purity materials with minimum residual carbon in the product on the surface [4][5]. The FEBID precursor molecules adsorb and diffuse on the surface

• . Metal bis(acetylacetonate) complexes are of interest for many thin film fabrication techniques (e.g., chemical vapor deposition [9], atomic layer epitaxy [10], or atomic layer etching [11]) and as precursors for carbon materials, such as carbon nanotubes and carbon onion particles [12], or metal oxide

Isolation of cubic Si₃P₄ in the form of nanocrystals

• Polina K. Nikiforova,
• Sergei S. Bubenov,
• Vadim B. Platonov,
• Andrey S. Kumskov,
• Nikolay N. Kononov,
• Tatyana A. Kuznetsova and
• Sergey G. Dorofeev

Beilstein J. Nanotechnol. 2023, 14, 971–979, doi:10.3762/bjnano.14.80

• 520.8 cm−1. Interestingly, the observed Raman spectrum for SP900 is very similar to that of the product of silicon and phosphorus MBE co-deposition at 3:2 molar ratio [34]. This substance was reported as amorphous; however, it could contain Si3P4 NPs along with other SixPy compounds. Factor group

• Si3P4 phase. Also worth noting was that the synthesis of cubic Si3P4 NPs could be performed immediately after laser-induced or plasma-enhanced chemical vapor deposition of nanosilicon from the silane precursor (since the NPs obtained this way are readily hydrogenated). Additionally, there is preliminary

• (reagent grade) were used for sol preparation; 40% hydrofluoric acid (pure) was used for etching. Si NPs were synthesized by laser-induced chemical vapor deposition using a silane precursor (the average particle diameter was 20 nm [41]). The NPs oxidized when stored in air, and the resultant mass fraction

Low temperature atomic layer deposition of cobalt using dicobalt hexacarbonyl-1-heptyne as precursor

• Mathias Franz,
• Mahnaz Safian Jouzdani,
• Lysann Kaßner,
• Marcus Daniel,
• Frank Stahr and
• Stefan E. Schulz

Beilstein J. Nanotechnol. 2023, 14, 951–963, doi:10.3762/bjnano.14.78

• , Clemens-Winkler-Str. 6c, 09116 Chemnitz, Germany FAP Forschungs- und Applikationslabor Plasmatechnik GmbH, Gostritzer Str. 67B, 01217 Dresden, Germany 10.3762/bjnano.14.78 Abstract In this work, we present the development of an atomic layer deposition (ALD) process for metallic cobalt. The process

• operates at low temperatures using dicobalt hexacarbonyl-1-heptyne [Co2(CO)6HC≡CC5H11] and hydrogen plasma. For this precursor an ALD window in the temperature range between 50 and 110 °C was determined with a constant deposition rate of approximately 0.1 Å/cycle. The upper limit of the ALD window is

• defined by the onset of the decomposition of the precursor. In our case, decomposition occurs at temperatures of 125 °C and above, resulting in a film growth in chemical vapour deposition mode. The lower limit of the ALD window is around 35 °C, where the reduction of the precursor is incomplete. The

Upscaling the urea method synthesis of CoAl layered double hydroxides

• Camilo Jaramillo-Hernández,
• Víctor Oestreicher,
• Martín Mizrahi and
• Gonzalo Abellán

Beilstein J. Nanotechnol. 2023, 14, 927–938, doi:10.3762/bjnano.14.76

• spin-coated on a Si wafer (3000 rpm, 40 s), washed with ethanol and dried afterward. For AFM, the samples were diluted in ethanol and drop-cast on a Si/SiO2 wafer. Si/SiO2 wafers were washed by spin-coating ten droplets of acetone and ten droplets of isopropanol prior to sample deposition. Scanning

Ultralow-energy amorphization of contaminated silicon samples investigated by molecular dynamics

• Grégoire R. N. Defoort-Levkov,
• Alan Bahm and
• Patrick Philipp

Beilstein J. Nanotechnol. 2023, 14, 834–849, doi:10.3762/bjnano.14.68

• years, the need to control what happens at the surface of the sample has risen sharply, specifically for semiconductors [3][4], microelectronics [5], and surface patterning [6][7]. Other applications of low-energy beams include the preparation of nanoholes [8][9]. Furthermore, deposition processes are

Silver-based SERS substrates fabricated using a 3D printed microfluidic device

• Phommachith Sonexai,
• Minh Van Nguyen,
• Bui The Huy and
• Yong-Ill Lee

Beilstein J. Nanotechnol. 2023, 14, 793–803, doi:10.3762/bjnano.14.65

• submerged in concentrated HNO3, rinsed with deionized water, and then dried at room temperature to produce the PS substrates. Fabrication of the SERS substrate The deposition of Ag particles on the substrates is based on the SAM method. Colloidal Ag NPs solutions were generated at the methanol/air interface

• homogeneous results because of the even deposition of the self-assembled monolayer of Ag NPs on the PS substrate. Detection of melamine using PS@Ag SERS substrate SERS spectra of MLM solutions at different concentrations (10−7 to 10−3 M) on the PS@Ag substrates were recorded, as shown in Figure 6a. The Raman

In situ magnesiothermic reduction synthesis of a Ge@C composite for high-performance lithium-ion batterie anodes

• Ha Tran Huu,
• Ngoc Phi Nguyen,
• Vuong Hoang Ngo,
• Huy Hoang Luc,
• Minh Kha Le,
• Minh Thu Nguyen,
• My Loan Phung Le,
• Hye Rim Kim,
• In Young Kim,
• Sung Jin Kim,
• Van Man Tran and
• Vien Vo

Beilstein J. Nanotechnol. 2023, 14, 751–761, doi:10.3762/bjnano.14.62

• preparation routes, such as sputtering deposition [20], wet-chemical reduction [21][22], thermal reduction [23], colloidal synthesis [24], and molten-salt synthesis [25], metallothermic, especially magnesiothermic reduction, has been widely applied in the synthesis of group-IV elements to control the

Control of morphology and crystallinity of CNTs in flame synthesis with one-dimensional reaction zone

• Muhammad Hilmi Ibrahim,
• Norikhwan Hamzah,
• Mohd Zamri Mohd Yusop,
• Ni Luh Wulan Septiani and
• Mohd Fairus Mohd Yasin

Beilstein J. Nanotechnol. 2023, 14, 741–750, doi:10.3762/bjnano.14.61

• . To date, many researchers have shown promising results on the synthesis control of CNTs to produce tailored CNT morphologies and properties through conventional furnace-based methods. Progress in CNT synthesis processes has been achieved mostly using chemical vapor deposition (CVD). Various studies

• widely accepted vapor–liquid–solid mechanism, the growth of CNTs occurs in three steps, namely, melting of nickel particles, adsorption of carbon atoms onto the surface of the metallic nickel, and finally, diffusion and deposition of the precipitated carbon, which forms tubular materials by curling of

• large average CNT diameter with high standard deviation suggests different sizes of formed particles, possibly due to the high temperature. Generally, the size of nanoparticles is affected by several factors, including solution concentration, deposition method, quantity, and annealing [25]. At higher

Metal-organic framework-based nanomaterials as opto-electrochemical sensors for the detection of antibiotics and hormones: A review

• Akeem Adeyemi Oladipo,
• Saba Derakhshan Oskouei and
• Mustafa Gazi

Beilstein J. Nanotechnol. 2023, 14, 631–673, doi:10.3762/bjnano.14.52

ZnO-decorated SiC@C hybrids with strong electromagnetic absorption

• Liqun Duan,
• Zhiqian Yang,
• Yilu Xia,
• Xiaoqing Dai,
• Jian’an Wu and
• Minqian Sun

Beilstein J. Nanotechnol. 2023, 14, 565–573, doi:10.3762/bjnano.14.47

• provide locations for the deposition of Zn2+ via electrostatic interactions. Cao et al. [26] have reported the growth of ZnO particles on MWCNTs through a similar mechanism. However, in their case, the functional groups on the MWCNTs were obtained by ultrasonic treatment in concentrated nitric acid. Four

• locations for the deposition of Zn2+ by electrostatic interactions. SCZ1 exhibits the best EM absorption properties. Its values for RLmin and EAB reach −65.4 dB and 7 GHz (10.96–17.96 GHz), respectively, at a small sample thickness and 30 wt % filler load. The effective EM absorption is related to the

SERS performance of GaN/Ag substrates fabricated by Ag coating of GaN platforms

• Magdalena A. Zając,
• Bogusław Budner,
• Malwina Liszewska,
• Bartosz Bartosewicz,
• Łukasz Gutowski,
• Jan L. Weyher and
• Bartłomiej J. Jankiewicz

Beilstein J. Nanotechnol. 2023, 14, 552–564, doi:10.3762/bjnano.14.46

• substrates using pulsed laser deposition (PLD) and magnetron sputtering (MS) and their evaluation as potential substrates for surface-enhanced Raman spectroscopy (SERS) are reported. Ag layers of comparable thicknesses were deposited using PLD and MS on nanostructured GaN platforms. All fabricated SERS

• : GaN/Ag; magnetron sputtering; nanofabrication; pulsed laser deposition; SERS substrates; surface-enhanced Raman spectroscopy (SERS); Introduction Surface-enhanced Raman spectroscopy (SERS) is a highly sensitive and specific technique with multiplexing capabilities [1][2][3][4]. It is considered for

• physical vapor deposition (PVD) methods have been tested to replace MS in coating GaN platforms with plasmonic metals. Pulsed laser deposition (PLD) is an interesting and still not fully explored alternative for the fabrication of SERS substrates [37][38]. Hence, our studies reported herein aimed to

On the use of Raman spectroscopy to characterize mass-produced graphene nanoplatelets

• Keith R. Paton,
• Konstantinos Despotelis,
• Naresh Kumar,
• Piers Turner and
• Andrew J. Pollard

Beilstein J. Nanotechnol. 2023, 14, 509–521, doi:10.3762/bjnano.14.42

• extinction at 660 nm and using an extinction coefficient of 4237 mL·mg−1·m−1 [28] yielded a concentration of 0.028 mg·mL−1. To characterize the thickness of the particles in GNPref, the dispersion was drop-cast on to a cleaned Si/SiO2 (300 nm thick oxide layer) wafer. Before deposition, the dispersion was

Molecular nanoarchitectonics: unification of nanotechnology and molecular/materials science

• Katsuhiko Ariga

Beilstein J. Nanotechnol. 2023, 14, 434–453, doi:10.3762/bjnano.14.35

• synthesize 8-carbon armchair graphene nanoribbons and nanographene C66 with periodic vacancies on the surface (Figure 8) [124]. Detailed processes of the surface synthesis of 5,8-dibromobenzene molecules kept at room temperature after deposition on Au(111) were disclosed through STM observations

Evaluation of electrosynthesized reduced graphene oxide–Ni/Fe/Co-based (oxy)hydroxide catalysts towards the oxygen evolution reaction

• Karolina Cysewska,
• Marcin Łapiński,
• Marcin Zając,
• Jakub Karczewski,
• Piotr Jasiński and
• Sebastian Molin

Beilstein J. Nanotechnol. 2023, 14, 420–433, doi:10.3762/bjnano.14.34

• catalytic activity of the catalysts with and without GO were studied. The catalysts were fabricated via a two-step electrodeposition. The first step included the deposition of GO flakes, which, in the second step, were reduced during the simultaneous deposition of NiFe or CoNiFe. As a result, NiFe-GO and

• the surface of nickel foam. The chronoamperometric graph recorded during the deposition is presented in Figure 1a. Each synthesis (except that of GO) began with a fast increase of the cathodic current, which is associated with the formation of the new catalyst phase on the surface of the substrate [25

• ]. Afterwards, the current density tended to stabilize for NiFe and CoNiFe, which may be associated with the steady-state formation of the catalyst film on the metallic surface. The addition of cobalt to NiFe resulted in a lower overall current density during the synthesis process. In the case of the deposition

Plasmonic nanotechnology for photothermal applications – an evaluation

• A. R. Indhu,
• L. Keerthana and
• Gnanaprakash Dharmalingam

Beilstein J. Nanotechnol. 2023, 14, 380–419, doi:10.3762/bjnano.14.33

Bismuth-based nanostructured photocatalysts for the remediation of antibiotics and organic dyes

• Akeem Adeyemi Oladipo and
• Faisal Suleiman Mustafa

Beilstein J. Nanotechnol. 2023, 14, 291–321, doi:10.3762/bjnano.14.26

• techniques have been developed to synthesise 3-D Bi-based nanostructures with different morphologies, including solvothermal/hydrothermal and sol–gel processes, mechanical exfoliation, solid-state reactions, chemical vapour deposition, and microwave-assisted techniques [106]. These 3-D photocatalysts have

• between 1-D CdS and 0-D Bi components were developed. The bandgap values were altered, and the absorption in the visible-to-infrared range was enhanced after the deposition of Bi quantum dots on CdS. To degrade the antibiotic tetracycline, a Bi/CdS heterostructure photocatalyst was used. The optimised

Biocatalytic synthesis and ordered self-assembly of silica nanoparticles via a silica-binding peptide

• Mustafa Gungormus

Beilstein J. Nanotechnol. 2023, 14, 280–290, doi:10.3762/bjnano.14.25

• revealed a hexagonal close-packed structure (insets in Figure 5a,c). In fact, the tendency of the particles formed with NH3 + 1 mM SiBP to assemble into ordered structures was visible on samples not prepared by vertical deposition but simply by dripping on a surface and vacuum drying (Figure 3d). The

• Table 2 with a final volume of 10 mL. The particles were assembled by a vertical deposition method. For SEM analysis, the particles were assembled on regular microscope cover slides. For UV–vis spectroscopy analysis, the particles were assembled on quartz slides. One end of the slide was attached to a

• ). All SEM analyses were performed using a SU5000 SEM (Hitachi, Japan) at 10 kV accelerating voltage. UV–vis absorbance spectroscopy The particles were assembled on quartz slides by vertical deposition as described before. UV–vis absorbance analysis was made using a T80+ UV–vis spectrophotometer (PG

Nanotechnology – a robust tool for fighting the challenges of drug resistance in non-small cell lung cancer

• Filip Gorachinov,
• Fatima Mraiche,
• Diala Alhaj Moustafa,
• Ola Hishari,
• Yomna Ismail,
• Jensa Joseph,
• Maja Simonoska Crcarevska,
• Marija Glavas Dodov,
• Nikola Geskovski and
• Katerina Goracinova

Beilstein J. Nanotechnol. 2023, 14, 240–261, doi:10.3762/bjnano.14.23

• barriers by the use of different groups of particles carrying various functional modalities. Tasciotti et al. proposed a multistage delivery system composed of stage-1 mesoporous silica particles with improved deposition in the vascular endothelium, optimized for crossing the endothelial barrier through

A novel approach to pulsed laser deposition of platinum catalyst on carbon particles for use in polymer electrolyte membrane fuel cells

• Bogusław Budner,
• Wojciech Tokarz,
• Sławomir Dyjak,
• Andrzej Czerwiński,
• Bartosz Bartosewicz and
• Bartłomiej Jankiewicz

Beilstein J. Nanotechnol. 2023, 14, 190–204, doi:10.3762/bjnano.14.19

• carbon substrate and the chemical synthesis of PtNPs during catalyst fabrication. Platinum was deposited on carbon particles at room temperature using a pulsed laser deposition (PLD) system equipped with an ArF excimer laser (λ = 193 nm). The uniform deposition of PtNPs on carbon supports was achieved

• thanks to a specially designed electromechanical system that mixed the carbon support particles during platinum deposition. In the studies, Vulcan XC-72R carbon black powder, a popular material used as support in the anodes and cathodes of PEMFCs, and a porous carbon material with a high degree of

• ; ORR; PEMFCs; PLD deposition; Pt catalyst; rotating ring-disk electrode (RRDE); SEM; TEM; XPS; Introduction Fuel cells, which cleanly and efficiently convert the chemical energy of hydrogen or other fuels to electrical energy, are a good alternative to dirty and wasteful combustion engines for

Formation of nanoflowers: Au and Ni silicide cores surrounded by SiO_x branches

• Feitao Li,
• Siyao Wan,
• Dong Wang and
• Peter Schaaf

Beilstein J. Nanotechnol. 2023, 14, 133–140, doi:10.3762/bjnano.14.14

• small pieces were ready for thin film deposition. Metallic bilayers of Au and Ni of three different thickness ratios and a total thickness of 20 nm were deposited onto the SiO2/Si substrate by electron beam evaporation (CS400ES, VON ARDENNE) at a working pressure of 1 × 10−6 mbar. The Au layer was

• always deposited after the Ni layer to prevent the oxidation of the Ni layer. The bilayer thicknesses of different systems were 15 nm Au/5 nm Ni, 10 nm Au/10 nm Ni and 5 nm Au/15 nm Ni, and the thickness of each layer was controlled by a quartz balance during the deposition. Thermal annealing was carried

Characterisation of a micrometer-scale active plasmonic element by means of complementary computational and experimental methods

• Ciarán Barron,
• Giulia Di Fazio,
• Samuel Kenny,
• Silas O’Toole,
• Robin O’Reilly and
• Dominic Zerulla

Beilstein J. Nanotechnol. 2023, 14, 110–122, doi:10.3762/bjnano.14.12

• on a sapphire substrate via physical vapour deposition (PVD). After this, two separate AFMs are used to machine channels in the silver film to create the desired constriction, which in this case measures 10 μm. The tip of the AFM is held at a set loading force in contact with the thin metal film and

• deposition substrate for a thin silver film of 48 nm. The incident angles were referenced to the air–prism interface. The sinusoidal current was generated using a function generator with a current buffer to ensure impedance matching to the system under investigation. A transimpedance-amplified photodiode

Antimicrobial and mechanical properties of functionalized textile by nanoarchitectured photoinduced Ag@polymer coating

• Jessica Plé,
• Marine Dabert,
• Helene Lecoq,
• Sophie Hellé,
• Lydie Ploux and
• Lavinia Balan

Beilstein J. Nanotechnol. 2023, 14, 95–109, doi:10.3762/bjnano.14.11

• investigated [26], with specific emphasis on AgNPs [27]. Textiles have been successfully functionalized with AgNPs using a variety of both physical and chemical deposition techniques [28]. To name a few, Mei et al. [29] used magnetic sputtering to deposit AgNPs onto polyimide textiles; OhadiFar et al. [30

• adhesion, etc.) [32][33]. The deposition techniques are also costly, time-consuming and restrictive (under vacuum, numerous steps, toxic chemicals, etc.), which limits industrial scale-up options. Nanometal-polymer coatings offer an interesting alternative to the aforementioned metallized textiles. Such

Combining physical vapor deposition structuration with dealloying for the creation of a highly efficient SERS platform

• Adrien Chauvin,
• Walter Puglisi,
• Damien Thiry,
• Cristina Satriano,
• Rony Snyders and
• Carla Bittencourt

Beilstein J. Nanotechnol. 2023, 14, 83–94, doi:10.3762/bjnano.14.10

• complexity and the high cost of gold restrict its use in devices. Here, we report on a novel two-step approach that combines the deposition of a silver–aluminum thin film with dealloying to design and fabricate efficient SERS platforms. The magnetron sputtering technique was used for the deposition of the

• tuning deposition (i.e., the alloy chemical composition) and dealloying (i.e., dealloying media) parameters to reach the best SERS properties. These are reported for samples dealloyed in HCl and with 30 atom % of silver at the initial state with a detection limit down to 10−10 mol·L−1 for a solution of

• resulting signal intensity tends to strongly vary due to surface contamination [30]. In this paper, a simple synthesis method to design bimodal porous silver substrate for SERS is reported. Magnetron co-sputtering of a silver and aluminum target was used for the deposition of the precursor alloy thin film

Liquid phase exfoliation of talc: effect of the medium on flake size and shape

• Samuel M. Sousa,
• Helane L. O. Morais,
• Joyce C. C. Santos,
• Ana Paula M. Barboza,
• Bernardo R. A. Neves,
• Elisângela S. Pinto and
• Mariana C. Prado

Beilstein J. Nanotechnol. 2023, 14, 68–78, doi:10.3762/bjnano.14.8

• acceleration and duration, and sample deposition) were kept constant. Four different media were employed to exfoliate talc. Aqueous solutions of sodium cholate at 1 and 6 mg/mL (with the talc powder concentration adapted to keep the cholate/talc ratio constant), an aqueous solution of Triton-X100, and pure

• APTES molecules. This step is crucial to ensure that talc flakes of all sizes adhere to the substrate and do not stack. Talc deposition is achieved employing spread coating of the solution onto the functionalized substrate. A drop that covers all the substrate is deposited on the surface and allowed to

Solvent-induced assembly of mono- and divalent silica nanoparticles

• Bin Liu,
• Etienne Duguet and
• Serge Ravaine

Beilstein J. Nanotechnol. 2023, 14, 52–60, doi:10.3762/bjnano.14.6

• deposition on TEM grids. Co-assembly of one- and two-patch silica nanoparticles The incubation of the nanoparticles in a 7:3 (vol/vol) THF/salty water mixture was carried out in 15 mL tubes under rolling motion at 60 rpm and at room temperature. The composition of the mixtures is given in Table 1