CdSe/ZnS quantum dots as a booster in the active layer of distributed ternary organic photovoltaics

• Gabriela Lewińska,
• Piotr Jeleń,
• Zofia Kucia,
• Maciej Sitarz,
• Łukasz Walczak,
• Bartłomiej Szafraniak,
• Jerzy Sanetra and
• Konstanty W. Marszalek

Beilstein J. Nanotechnol. 2024, 15, 144–156, doi:10.3762/bjnano.15.14

• . The donor–acceptor mixture is dominant in the system. Therefore, the peaks of the QD dopant are not visible. At the same time, it should be noted that in mixtures with quantum dots (except QD480), the clarity of the peaks increases, which may suggest an increase in the degree of crystallinity

• establish absorption spectra and confirm excited states proven by luminescence. The dispersive spectra of the refractive index and extinction coefficient of nanoshell nanolayers and nanoshell:donor:acceptor composites were also determined. The dopant QDs shifted the extinction maximum toward longer

Isolation of cubic Si₃P₄ in the form of nanocrystals

• Polina K. Nikiforova,
• Sergei S. Bubenov,
• Vadim B. Platonov,
• Andrey S. Kumskov,
• Nikolay N. Kononov,
• Tatyana A. Kuznetsova and
• Sergey G. Dorofeev

Beilstein J. Nanotechnol. 2023, 14, 971–979, doi:10.3762/bjnano.14.80

• phosphorus as a dopant. From the outset, phosphorus diffusion through hydrogenated and oxide layers was surmised to be different. In the case of similar previously performed syntheses of Si NPs with an oxide layer [21], phosphorus diffuses deep into the NP cores and distributes rather homogenously with a

Cross-sectional Kelvin probe force microscopy on III–V epitaxial multilayer stacks: challenges and perspectives

• Mattia da Lisca,
• José Alvarez,
• James P. Connolly,
• Nicolas Vaissiere,
• Karim Mekhazni,
• Jean Decobert and
• Jean-Paul Kleider

Beilstein J. Nanotechnol. 2023, 14, 725–737, doi:10.3762/bjnano.14.59

• layer, respectively. Similarly, the tip starts to sense prematurely parts of the space charge inside the last InP:Zn layer. Furthermore, non-ideal abrupt junctions may contribute to this effect, for instance, because of dopant interdiffusion, as will be described in the following section. Finally, the

Metal-organic framework-based nanomaterials as opto-electrochemical sensors for the detection of antibiotics and hormones: A review

• Akeem Adeyemi Oladipo,
• Saba Derakhshan Oskouei and
• Mustafa Gazi

Beilstein J. Nanotechnol. 2023, 14, 631–673, doi:10.3762/bjnano.14.52

Plasmonic nanotechnology for photothermal applications – an evaluation

• A. R. Indhu,
• L. Keerthana and
• Gnanaprakash Dharmalingam

Beilstein J. Nanotechnol. 2023, 14, 380–419, doi:10.3762/bjnano.14.33

Bismuth-based nanostructured photocatalysts for the remediation of antibiotics and organic dyes

• Akeem Adeyemi Oladipo and
• Faisal Suleiman Mustafa

Beilstein J. Nanotechnol. 2023, 14, 291–321, doi:10.3762/bjnano.14.26

• ]. The increased performance was caused by the following factors: (a) surface plasmon resonance caused by the Ag dopant; (b) a decrease in the rate at which photoinduced carriers recombined; (c) high Schottky barriers between the Ag dopant and the host material; and (d) an increase in the visible-light

• pure Bi2WO6 (82.8%), the dopant significantly increased the tetracycline-degrading activity, which reached 94.6% within 1 h of visible light irradiation. Additionally, Irfan et al. [148] used a bi-solvent sol–gel technique to synthesise porous bismuth ferrite nanostructures with various morphological

• account are the quantity and type of dopant. The photocatalytic performance may be impacted if the amount of dopant is greater than the optimum value because it may act as a recombination site for photoinduced charge carriers. Additionally, doping has some drawbacks such as thermal instability and carrier

High–low Kelvin probe force spectroscopy for measuring the interface state density

• Ryo Izumi,
• Masato Miyazaki,
• Yan Jun Li and
• Yasuhiro Sugawara

Beilstein J. Nanotechnol. 2023, 14, 175–189, doi:10.3762/bjnano.14.18

• force spectroscopy; Introduction With the recent miniaturization of semiconductor devices, understanding the physical and electrical properties of semiconductor devices, such as the dopant concentration, dopant distribution, and defect level distribution, at the nanoscale has become important. Among

• have been performed on a variety of sample surfaces, including metals [9][10], semiconductors [11][12][13][14], and insulators [15][16][17]. When a semiconductor sample is measured by KPFM, the measured CPD is related to information about the semiconductor properties such as dopant density, surface

• states as follows: Here, we consider the charge Qs due to the surface potential Vs. In the case of an n-type semiconductor, the charge Qs as a function of the surface potential Vs is expressed as follows [23][24]: where ND is the dopant density, ni is the intrinsic carrier density, and ε is the

From a free electron gas to confined states: A mixed island of PTCDA and copper phthalocyanine on Ag(111)

• Alfred J. Weymouth,
• Emily Roche and
• Franz J. Giessibl

Beilstein J. Nanotechnol. 2022, 13, 1572–1577, doi:10.3762/bjnano.13.131

• low concentration as a dopant or at higher concentrations as a mixed layer [2]. Perylenetetracarboxylic dianhydride (PTCDA) is an organic molecule that has been investigated for its properties as an organic semiconductor and as a dye. It is straightforward to evaporate in vacuum and, at submonolayer

Recent advances in green carbon dots (2015–2022): synthesis, metal ion sensing, and biological applications

• Aisha Kanwal,
• Naheed Bibi,
• Sajjad Hyder,
• Arif Muhammad,
• Hao Ren,
• Jiangtao Liu and
• Zhongli Lei

Beilstein J. Nanotechnol. 2022, 13, 1068–1107, doi:10.3762/bjnano.13.93

• glutathione, as a dopant for both S and N, and a green source of celery leaves to synthesize CDs. Low-cost celery leaves containing folic acid with many –COOH and –NH2 groups contribute to high QYs. The reported CDs were novel fluorescent paper sensors and showed remarkable sensitivity and selectivity in the

• synthesize hydrophilic CDs [92]. Aqueous ammonia was used as a nitrogen dopant for many natural source materials such as Hylocereus undatus (H. undatus), Chionanthus retusus (C. retusus), Phyllanthus emblica (P. emblica), and Phyllanthus acidus (P. acidus) to obtain N-CDs [93][96]. A good QY up to 31.7% was

• obtained by using EDA as N-dopant with orange juice as carbon source to give N-CDs via hydrothermal decomposition [17]. Das et al. have adopted a new strategy using κ-carrageenan as the carbon source and lemon juice as the sulfur source. Surface quaternization was performed with benzalkonium chloride to

Theoretical investigations of oxygen vacancy effects in nickel-doped zirconia from ab initio XANES spectroscopy at the oxygen K-edge

• Dick Hartmann Douma,
• Lodvert Tchibota Poaty,
• Alessio Lamperti,
• Stéphane Kenmoe,
• Abdulrafiu Tunde Raji,
• Alberto Debernardi and
• Bernard M’Passi-Mabiala

Beilstein J. Nanotechnol. 2022, 13, 975–985, doi:10.3762/bjnano.13.85

• Nanotechnologies, Institut National de Recherche en Sciences Exactes et Naturelles (IRSEN), Brazzaville, Congo 10.3762/bjnano.13.85 Abstract In this study, we present theoretical X-ray absorption near-edge structure (XANES) spectra at the K-edge of oxygen in zirconia containing Ni dopant atoms and O vacancies at

• semiconducting or insulating materials doped randomly or uniformly with magnetic impurities in the oxide matrix. A typical example are thin films of uniformly Fe-doped ZrO2 where dopant concentrations, x, from the diluted regime (i.e., x = 1–5 atom % [2]) to very high concentrations (up to x ≈ 25 atom %) have

• photoelectron spectroscopy (XPS) [26], XANES spectra [27], and synchrotron radiation measurements [4], where it was suggested that for every two dopant atoms of Fe in zirconia, one single O vacancy is created. It is, thus, expected that in similarity to the effect of Fe doping in zirconia, substitutional Ni in

Ultrafast signatures of magnetic inhomogeneity in Pd_1−xFe_x (x ≤ 0.08) epitaxial thin films

• Andrey V. Petrov,
• Sergey I. Nikitin,
• Lenar R. Tagirov,
• Amir I. Gumarov,
• Igor V. Yanilkin and
• Roman V. Yusupov

Beilstein J. Nanotechnol. 2022, 13, 836–844, doi:10.3762/bjnano.13.74

• of the iron dopant leads to a development of a temperature dependence of ΔR/R(Δt) responses, both qualitative (the appearance of new relaxation components) and quantitative (changes in their amplitudes and time constants). While two decaying exponents are sufficient to describe the relaxation of the

A chemiresistive sensor array based on polyaniline nanocomposites and machine learning classification

• Jiri Kroutil,
• Alexandr Laposa,
• Ali Ahmad,
• Jan Voves,
• Vojtech Povolny,
• Ladislav Klimsa,
• Marina Davydova and
• Miroslav Husak

Beilstein J. Nanotechnol. 2022, 13, 411–423, doi:10.3762/bjnano.13.34

• concentration due to PANI doping and the formation of charge transfer complexes [20]. The decrease of electrical resistance is caused by the greater mobility of the dopant ions, related to the development of PANI chains. Furthermore, the swelling effect contributes to the change in resistivity [21]. Statistical

Measurement of polarization effects in dual-phase ceria-based oxygen permeation membranes using Kelvin probe force microscopy

• Kerstin Neuhaus,
• Christina Schmidt,
• Liudmila Fischer,
• Wilhelm Albert Meulenberg,
• Ke Ran,
• Joachim Mayer and
• Stefan Baumann

Beilstein J. Nanotechnol. 2021, 12, 1380–1391, doi:10.3762/bjnano.12.102

• time dependence was shown to vary with dopant concentration (e.g., abundance of oxygen vacancies in ceria) and also depends on the ratio of grain boundary/grain bulk [22][23][24][25]. Single ceria grains in a mixed ion/electron-conductive composite have so far not been addressed by AFM-based

Plasmon-enhanced photoluminescence from TiO₂ and TeO₂ thin films doped by Eu³⁺ for optoelectronic applications

• Marcin Łapiński,
• Jakub Czubek,
• Katarzyna Drozdowska,
• Anna Synak,
• Wojciech Sadowski and
• Barbara Kościelska

Beilstein J. Nanotechnol. 2021, 12, 1271–1278, doi:10.3762/bjnano.12.94

• literature [31][32]. The Eu3+ doublet is characterized by greater intensity and dominates over the Eu2+ lines. For quantitative analysis, integral intensities of europium doublets were compared. The Eu3+/Eu2+ ratio was ca. 90%:10%. Total amount of dopant in a sample was calculated to ca. 5%, on the basis of

• survey spectra. The amount of luminescent dopant in both titanium dioxide and tellurium dioxide matrixes should be sufficient to observe luminescence from the thin films. According to literature, percentage of luminescent ions in the host material should not exceed 10%. Otherwise, emission quenching may

Nickel nanoparticle-decorated reduced graphene oxide/WO₃ nanocomposite – a promising candidate for gas sensing

• Ilka Simon,
• Alexandr Savitsky,
• Rolf Mülhaupt,
• Vladimir Pankov and
• Christoph Janiak

Beilstein J. Nanotechnol. 2021, 12, 343–353, doi:10.3762/bjnano.12.28

• supported on reduced graphene oxide paves the way for their application as dopant in other metal oxide gas sensors. Experimental Due to the sensitivity of the precursor substances towards moisture and oxidation, all experiments were carried out in a purified argon (grade 99.998 vol %) or nitrogen (grade

Mapping of integrated PIN diodes with a 3D architecture by scanning microwave impedance microscopy and dynamic spectroscopy

• Rosine Coq Germanicus,
• Peter De Wolf,
• Florent Lallemand,
• Catherine Bunel,
• Serge Bardy,
• Hugues Murray and
• Ulrike Lüders

Beilstein J. Nanotechnol. 2020, 11, 1764–1775, doi:10.3762/bjnano.11.159

• , determined by our analytic procedure [32], as a function of VDC for both n- and p-type semiconductor materials. Using the complete metal–oxide–semiconductor equations, the Poisson–Boltzmann equation is solved for various active dopant concentration values ranging from 1015 to 1019 atoms·cm−3. In the sMIM

• fact, as expected, the amplitude of the measured local capacitance variation (∂C/∂V amplitude) increases when the doping level decreases. This behaviour allows for the localization of the P/N and I/N semiconductor junctions. As a result, the ∂C/∂V data allows for the discrimination among the dopant

• a comprehensive analysis of the overall architecture of the device for both FEOL and BEOL layers. It is important to emphasize that this result shows that, in complement to other AFM-based nanoscale electrical modes and to the local dopant density information, data regarding the BEOL layers is also

Atomic defect classification of the H–Si(100) surface through multi-mode scanning probe microscopy

• Jeremiah Croshaw,
• Thomas Dienel,
• Taleana Huff and
• Robert Wolkow

Beilstein J. Nanotechnol. 2020, 11, 1346–1360, doi:10.3762/bjnano.11.119

• speculated a variety of origins for this defect, including a negatively charged As dopant [58], Si-vacancy hydrogen complexes [9], and B dopants [59][60]. Crystal vacancies have previously been identified in other materials using scanning probe microscopy including Ga vacancies in GaAs [61], As vacancies in

Effect of localized helium ion irradiation on the performance of synthetic monolayer MoS₂ field-effect transistors

• Jakub Jadwiszczak,
• Pierce Maguire,
• Conor P. Cullen,
• Georg S. Duesberg and
• Hongzhou Zhang

Beilstein J. Nanotechnol. 2020, 11, 1329–1335, doi:10.3762/bjnano.11.117

• significant n-dopant densities and suppressing the unwanted crystal structure amorphization which results from high irradiation doses. At high IR values (red group), we observe the emergence of a weak ambipolar response in our transfer curves. At these ratios, the device starts to enter a regime where more

Hybridization vs decoupling: influence of an h-BN interlayer on the physical properties of a lander-type molecule on Ni(111)

• Maximilian Schaal,
• Takumi Aihara,
• Marco Gruenewald,
• Felix Otto,
• Jari Domke,
• Roman Forker,
• Hiroyuki Yoshida and
• Torsten Fritz

Beilstein J. Nanotechnol. 2020, 11, 1168–1177, doi:10.3762/bjnano.11.101

• -BN on Ni(111) exhibits an atomically flat morphology [18][19]. DBP is a promising molecule in the field of organic electronics, for example, as an electron donor [20][21][22][23] or acceptor [24] in organic photovoltaic applications, and as a dopant in organic light emitting diodes [25]. For our

Hexagonal boron nitride: a review of the emerging material platform for single-photon sources and the spin–photon interface

• Stefania Castelletto,
• Faraz A. Inam,
• Shin-ichiro Sato and
• Alberto Boretti

Beilstein J. Nanotechnol. 2020, 11, 740–769, doi:10.3762/bjnano.11.61

• /compatibility of the active quantum source and the device in use, and they have limitations in terms of scalability. The type of point defects that should be addressed is also a key element and is generally substitutional dopants, native vacancies, and dopant-vacancy complexes. The space of possible defects is

Structural optical and electrical properties of a transparent conductive ITO/Al–Ag/ITO multilayer contact

• Aliyu Kabiru Isiyaku,
• Ahmad Hadi Ali and
• Nafarizal Nayan

Beilstein J. Nanotechnol. 2020, 11, 695–702, doi:10.3762/bjnano.11.57

• fraction of Sn is low because it is the dopant element in ITO. The low content of Al is attributed to the very thin layer. The EDXS spectra of the films before and after annealing are shown in Figure 2. The surface morphology of the IAAI and ITO films was studied using atomic force microscopy (AFM) of an

Electrochemically derived functionalized graphene for bulk production of hydrogen peroxide

• Munaiah Yeddala,
• Pallavi Thakur,
• Anugraha A and
• Tharangattu N. Narayanan

Beilstein J. Nanotechnol. 2020, 11, 432–442, doi:10.3762/bjnano.11.34

• nature of the dopant and its position in the host lattice, it has been well reported that one can engineer the electrochemical activity of nanographitic systems and the catalytic reaction pathways [31][38][39][40]. Very recently, oxidized graphitic structures were identified for their efficacy towards

Charge-transfer interactions between fullerenes and a mesoporous tetrathiafulvalene-based metal–organic framework

• Manuel Souto,
• Joaquín Calbo,
• Samuel Mañas-Valero,
• Aron Walsh and
• Guillermo Mínguez Espallargas

Beilstein J. Nanotechnol. 2019, 10, 1883–1893, doi:10.3762/bjnano.10.183

• since the fullerene is acting as a dopant introducing charge carriers within the framework. However, this enhancement in conductivity is lower in comparison to other reported systems [14][35] probably due to the low ratio between C60 and TTF (1:4) and the long distances between the TTF moieties (9.6 Å

Nanoarchitectonics meets cell surface engineering: shape recognition of human cells by halloysite-doped silica cell imprints

• Elvira Rozhina,
• Ilnur Ishmukhametov,
• Svetlana Batasheva,
• Farida Akhatova and
• Rawil Fakhrullin

Beilstein J. Nanotechnol. 2019, 10, 1818–1825, doi:10.3762/bjnano.10.176

• loaded with anionic molecules (including bioactive compounds), and the loading efficiency can be significantly increased by using vacuum pumping [29]. Halloysite has already shown its potential in cells surface engineering of microbial cells [30][31]. Here we used halloysite as a dopant for artificial

• silica shells deposited on viable human HeLa cells. Halloysite nanotubes were chosen as dopant because of their biocompatibilty and rather large lumen sizes suitable for loading various drugs and even enzymes [32]. In the future, the procedure developed here can be extended to other nanotubular particles

Materials nanoarchitectonics at two-dimensional liquid interfaces

• Katsuhiko Ariga,
• Michio Matsumoto,
• Taizo Mori and
• Lok Kumar Shrestha

Beilstein J. Nanotechnol. 2019, 10, 1559–1587, doi:10.3762/bjnano.10.153

• nanoarchitectonics (controlled single atom/ion transfer) to regulate the number of dopant atoms in one-dimensional solid electrolyte nanodots (α-Ag2+δS) [127]. The nanoarchitectonic construction of one-dimensional nanowires from II–VI semiconductors was demonstrated for the use as wavelength division multiplexer as