Electrospun one-dimensional nanostructures: a new horizon for gas sensing materials

• Muhammad Imran,
• Nunzio Motta and
• Mahnaz Shafiei

Beilstein J. Nanotechnol. 2018, 9, 2128–2170, doi:10.3762/bjnano.9.202

Preparation of micro/nanopatterned gelatins crosslinked with genipin for biocompatible dental implants

• Reika Makita,
• Tsukasa Akasaka,
• Seiichi Tamagawa,
• Yasuhiro Yoshida,
• Saori Miyata,
• Hirofumi Miyaji and
• Tsutomu Sugaya

Beilstein J. Nanotechnol. 2018, 9, 1735–1754, doi:10.3762/bjnano.9.165

• crosslinking conditions, such as the concentration of the crosslinker, reaction time, and temperature. Polydimethylsiloxane (PDMS) has the known characteristics of being gas and vapor permeable [53][54]. Therefore, we used a thin PDMS mold, with a thickness of 0.5 mm, to allow water to evaporate through the

Nanoporous silicon nitride-based membranes of controlled pore size, shape and areal density: Fabrication as well as electrophoretic and molecular filtering characterization

• Axel Seidenstücker,
• Stefan Beirle,
• Fabian Enderle,
• Paul Ziemann,
• Othmar Marti and
• Alfred Plettl

Beilstein J. Nanotechnol. 2018, 9, 1390–1398, doi:10.3762/bjnano.9.131

• -resolved. For this purpose a second, optically transparent measurement cell was made from PDMS (polydimethylsiloxane). The fluid channels, each being 11 mm in length, 2 mm in width, and 3 mm in height, are mounted in cis (right side) and trans (left side) configuration to the membrane. Again appropriate

Wafer-scale bioactive substrate patterning by chemical lift-off lithography

• Chong-You Chen,
• Chang-Ming Wang,
• Hsiang-Hua Li,
• Hong-Hseng Chan and
• Wei-Ssu Liao

Beilstein J. Nanotechnol. 2018, 9, 311–320, doi:10.3762/bjnano.9.31

• washed with ethanol to remove excess thiol molecules, and blown dry with nitrogen gas. Polydimethylsiloxane (PDMS) stamps with various patterns were fabricated by standard photolithography-created masters. A 10:1 mass ratio of SYLGARD 184 silicone elastomer base and curing agent (Dow Corning, Midland, MI

Patterning of supported gold monolayers via chemical lift-off lithography

• Liane S. Slaughter,
• Kevin M. Cheung,
• Sami Kaappa,
• Huan H. Cao,
• Qing Yang,
• Thomas D. Young,
• Andrew C. Serino,
• Sami Malola,
• Jana M. Olson,
• Stephan Link,
• Hannu Häkkinen,
• Anne M. Andrews and
• Paul S. Weiss

Beilstein J. Nanotechnol. 2017, 8, 2648–2661, doi:10.3762/bjnano.8.265

• functionalization chemistries of Au. Experimental Fabricating patterned polydimethylsiloxane stamps Stamps with topographic features were prepared as previously described [85]. The Sylgard® 184 silicone elastomer kits were purchased from Dow Corning (Midland, MI, USA). The elastomer base and curing agent were mixed

Refractive index sensing and surface-enhanced Raman spectroscopy using silver–gold layered bimetallic plasmonic crystals

• Somi Kang,
• Sean E. Lehman,
• Matthew V. Schulmerich,
• An-Phong Le,
• Tae-woo Lee,
• Stephen K. Gray,
• Rohit Bhargava and
• Ralph G. Nuzzo

Beilstein J. Nanotechnol. 2017, 8, 2492–2503, doi:10.3762/bjnano.8.249

• 0.02 μm (Whatman Anotop 10) syringe filters immediately before use in order to remove nanoparticles in the SOG sol formed by hydrolysis [26]. Polydimethylsiloxane (soft PDMS; Sylgard 184, Dow corning) was prepared in a 10:1 ratio of PDMS base with curing agent. Hard PDMS components, poly(25–30

Increasing the stability of DNA nanostructure templates by atomic layer deposition of Al₂O₃ and its application in imprinting lithography

• Hyojeong Kim,
• Kristin Arbutina,
• Anqin Xu and
• Haitao Liu

Beilstein J. Nanotechnol. 2017, 8, 2363–2375, doi:10.3762/bjnano.8.236

• ). Around the edges of the silicon wafer, the PLLA film was scraped off with a blade and the silicon wafer underneath the PLLA film was revealed (Figure 1d). A polydimethylsiloxane (PDMS) film was placed on top of the PLLA film serving as a flexible backing to assist in the separation of the polymer film

Optical contrast and refractive index of natural van der Waals heterostructure nanosheets of franckeite

• Patricia Gant,
• Foad Ghasemi,
• David Maeso,
• Carmen Munuera,
• Elena López-Elvira,
• Riccardo Frisenda,
• David Pérez De Lara,
• Gabino Rubio-Bollinger,
• Mar Garcia-Hernandez and
• Andres Castellanos-Gomez

Beilstein J. Nanotechnol. 2017, 8, 2357–2362, doi:10.3762/bjnano.8.235

• /spectroscopy, transmission electron microscopy, X-ray diffraction, X-ray photoemission, UV–vis–IR absorption spectroscopy and Raman spectroscopy. More details about this characterization can be found in [15]. The flakes are firstly exfoliated onto a polydimethylsiloxane (Gelfilm, with 150 µm of thickness, by

Fabrication of gold-coated PDMS surfaces with arrayed triangular micro/nanopyramids for use as SERS substrates

• Jingran Zhang,
• Yongda Yan,
• Peng Miao and
• Jianxiong Cai

Beilstein J. Nanotechnol. 2017, 8, 2271–2282, doi:10.3762/bjnano.8.227

• the structures were successfully transferred to a polydimethylsiloxane (PDMS) surface using a reverse nanoimprinting approach. The structured PDMS surface is coated with a thin Au film, and the final substrate is demonstrated as a surface-enhanced Raman spectroscopy (SERS) substrate. Rhodamine 6G (R6G

• approaches. They produced arrays of tipless pyramids using an optical UV curing method. Lee et al. [24] used anodic aluminum oxide as a template for transferring patterns onto the polydimethylsiloxane (PDMS) substrate surfaces using a dry etching method. In this work, the detection of DNA molecules showed a

Parylene C as a versatile dielectric material for organic field-effect transistors

• Tomasz Marszalek,
• Maciej Gazicki-Lipman and
• Jacek Ulanski

Beilstein J. Nanotechnol. 2017, 8, 1532–1545, doi:10.3762/bjnano.8.155

• accumulation of metastable positive charges at the dielectric/semiconductor interface during the bias stressing. A similar behavior of bidirectional Vth shift was also observed in pentacene OFETs on silicon dioxide substrates modified by polydimethylsiloxane and it was assigned to either hole or electron

Assembly of metallic nanoparticle arrays on glass via nanoimprinting and thin-film dewetting

• Sun-Kyu Lee,
• Sori Hwang,
• Yoon-Kee Kim and
• Yong-Jun Oh

Beilstein J. Nanotechnol. 2017, 8, 1049–1055, doi:10.3762/bjnano.8.106

• noble metal nanoparticles on glass substrates via nanoimprinting and dewetting of metallic thin films. Glass templates were made via pattern transfer from a topographic Si mold to an inorganically cross-linked sol–gel (IGSG) resist on glass using a two-layer polydimethylsiloxane (PDMS) stamp followed by

• thick silicon nitride layer using a laser interference lithographic (LIL) method. The topography of the master mold was replicated on a composite stamp consisting of two layers – hard polydimethylsiloxane (PDMS) and flexible 184 PDMS [31]. A 50 µm thick layer of hard PDMS and 2 mm thick layer of 184

Flexible photonic crystal membranes with nanoparticle high refractive index layers

• Torben Karrock,
• Moritz Paulsen and
• Martina Gerken

Beilstein J. Nanotechnol. 2017, 8, 203–209, doi:10.3762/bjnano.8.22

• replication of a 400 nm period linear grating nanostructure into a ≈60 µm thick polydimethylsiloxane membrane and subsequent spin coating of a high refractive index titanium dioxide nanoparticle layer. Samples are prepared with different nanoparticle concentrations. Guided-mode resonances with a quality

• highly flexible photonic crystal slabs by utilizing nanoreplication of a linear grating nanostructure with a period of 400 nm into a polydimethylsiloxane (PDMS) membrane and subsequent spin coating of titanium dioxide (TiO2) nanoparticles. Investigations with 300 nm and 500 nm gratings lead to similar

• structure passes the polarization setup [20]. The light is then captured by the lens and directed from the microscope either to a spectrometer or a camera. Spectral information and photographs are recorded for all samples and all strain states. A 60 µm thick polydimethylsiloxane (PDMS) membrane with a 400

When the going gets rough – studying the effect of surface roughness on the adhesive abilities of tree frogs

• Niall Crawford,
• Thomas Endlein,
• Jonathan T. Pham,
• Mathis Riehle and
• W. Jon P. Barnes

Beilstein J. Nanotechnol. 2016, 7, 2116–2131, doi:10.3762/bjnano.7.201

• the surfaces could only be reproduced as small surfaces (ca 20 × 20 mm). These surfaces, made of polydimethylsiloxane (PDMS) were designed to provide transparent surfaces that would allow contact area to be visible through them as well as to provide standardised topographies whose specific dimensions

Numerical investigation of depth profiling capabilities of helium and neon ions in ion microscopy

• Patrick Philipp,
• Lukasz Rzeznik and
• Tom Wirtz

Beilstein J. Nanotechnol. 2016, 7, 1749–1760, doi:10.3762/bjnano.7.168

• surface by disordering the surface structure and forming hydrogenated amorphous carbon [4]. Similarly, Ga+ irradiation of polydimethylsiloxane (PDMS) results in micro- and nanopatterns with controlled stiffness for potential applications in tissue engineering [5]. Overall, the properties depend on the

Dielectrophoresis of gold nanoparticles conjugated to DNA origami structures

• Anja Henning-Knechtel,
• Matthew Wiens,
• Mathias Lakatos,
• Andreas Heerwig,
• Frieder Ostermaier,
• Nora Haufe and
• Michael Mertig

Beilstein J. Nanotechnol. 2016, 7, 948–956, doi:10.3762/bjnano.7.87

• ·107 V/m [28][29][30]. A more precise deposition of 2D single layer and 3D multilayer DNA constructs required a higher frequency of approximately 12.5 MHz. This frequency range can be lowered when insulator-based dielectrophoresis is used [19]. In detail, an array of polydimethylsiloxane (PDMS) pillars

Low-cost formation of bulk and localized polymer-derived carbon nanodomains from polydimethylsiloxane

• Juan Carlos Castro Alcántara,
• Mariana Cerda Zorrilla,
• Lucia Cabriales,
• Luis Manuel León Rossano and
• Mathieu Hautefeuille

Beilstein J. Nanotechnol. 2015, 6, 744–748, doi:10.3762/bjnano.6.76

• processes presented shiny and dark residual materials after the polymer combustion and according to micro-Raman spectroscopy of the domains, graphitic nanocrystals and carbon nanotubes have successfully been produced by the combustion of polydimethylsiloxane layers. The fabrication processes and

• promising for the formation of carbon nanoresidues with controlled properties and in applications where high integration is desired. Keywords: carbon nanodomains; nanodots; polydimethylsiloxane; polymer-derived ceramics; Raman spectroscopy; Introduction Silicon-based polymer-derived ceramics (PDC) are of

• residues in a low-cost polymer matrix with many interesting properties in optics and electronics micro-integration: polydimethylsiloxane (PDMS) [6]. In this work, we report the formation of bulk or localized carbon nanodomains obtained from PDMS, a silicon-based polymer by using two different methods

Increasing throughput of AFM-based single cell adhesion measurements through multisubstrate surfaces

• Miao Yu,
• Nico Strohmeyer,
• Jinghe Wang,
• Daniel J. Müller and
• Jonne Helenius

Beilstein J. Nanotechnol. 2015, 6, 157–166, doi:10.3762/bjnano.6.15

• limitation, segmented polydimethylsiloxane (PDMS) masks were developed, allowing the measurement of cell adhesion to multiple substrates. To verify the utility of the masks, the adhesion of four different cell lines, HeLa (Kyoto), prostate cancer (PC), mouse kidney fibroblast and MDCK, to three extracellular

• these approaches are uncommon in biological laboratories. In order to increase the throughput, we chose to modify Petri dishes using polydimethylsiloxane (PDMS) masks with four distinct areas (Figure 1D). The four segments separate the Petri dish surface into four independent 4 × 4 mm2 wells, which

Hybrid spin-crossover nanostructures

• Carlos M. Quintero,
• Gautier Félix,
• Iurii Suleimanov,
• José Sánchez Costa,
• Gábor Molnár,
• Lionel Salmon,
• William Nicolazzi and
• Azzedine Bousseksou

Beilstein J. Nanotechnol. 2014, 5, 2230–2239, doi:10.3762/bjnano.5.232

• nano-patterned polydimethylsiloxane (PDMS) stamp. The luminescence of the isolated dots as a function of temperature increased upon the LS to HS spin transition and decreased as the LS state was restored at low temperatures. The synergy between luminescence and SCO properties in these hybrid systems

The influence of molecular mobility on the properties of networks of gold nanoparticles and organic ligands

• Edwin J. Devid,
• Paulo N. Martinho,
• M. Venkata Kamalakar,
• Úna Prendergast,
• Christian Kübel,
• Tibebe Lemma,
• Jean-François Dayen,
• Tia. E. Keyes,
• Bernard Doudin,
• Mario Ruben and
• Sense Jan van der Molen

Beilstein J. Nanotechnol. 2014, 5, 1664–1674, doi:10.3762/bjnano.5.177

• onto a Si wafer substrate (covered with 300 nm of SiO2) by using a polydimethylsiloxane (PDMS) microcontact printing method [8]. Other suitable types of substrates for the microcontact printing of these samples are glass, quartz, several types of plastics (like polyethylene, polypropylene foils and

Influence of the PDMS substrate stiffness on the adhesion of Acanthamoeba castellanii

• Sören B. Gutekunst,
• Carsten Grabosch,
• Alexander Kovalev,
• Stanislav N. Gorb and
• Christine Selhuber-Unkel

Beilstein J. Nanotechnol. 2014, 5, 1393–1398, doi:10.3762/bjnano.5.152

• cell adhesion area of A. castellanii trophozoites on polydimethylsiloxane (PDMS) substrates with different Young’s moduli (4 kPa, 29 kPa, and 128 kPa), we find significant differences in cell adhesion area as a function of substrate stiffness. In particular, the cell adhesion area of A. castellanii

• polydimethylsiloxane (PDMS) substrates with Young’s moduli of 4 kPa, 29 kPa, and 128 kPa. These Young’s moduli were chosen in order to cover an elasticity range, for which a significant effect of substrate stiffness on the adhesion of mammalian cells has already been reported [1]. We systematically investigated the

• the cellular microenvironment and associated nanobiomechanical cues also for the adhesion of a eukaryotic human pathogen. Experimental Preparation of polydimethylsiloxane (PDMS) substrates Silicone base and curing agent (Sylgard 184, DOW Corning) were mixed thoroughly in a ratio (m/m) of 80:1, 57:1

Organic and inorganic–organic thin film structures by molecular layer deposition: A review

• Pia Sundberg and
• Maarit Karppinen

Beilstein J. Nanotechnol. 2014, 5, 1104–1136, doi:10.3762/bjnano.5.123

Insect attachment on crystalline bioinspired wax surfaces formed by alkanes of varying chain lengths

• Elena Gorb,
• Sandro Böhm,
• Nadine Jacky,
• Louis-Philippe Maier,
• Kirstin Dening,
• Sasha Pechook,
• Boaz Pokroy and
• Stanislav Gorb

Beilstein J. Nanotechnol. 2014, 5, 1031–1041, doi:10.3762/bjnano.5.116

• polydimethylsiloxane semi-spheres) on bioinspired wax surfaces formed by four alkanes of varying chain lengths (C36H74, C40H82, C44H90, and C50H102). All these highly hydrophobic coatings were composed of crystals having similar morphologies but differing in size and distribution/density, and exhibited different

• of beetles. The obtained data are explained by the reduction of the real contact between the setal tips of the insect adhesive pads and the wax surfaces due to the micro- and nanoscopic roughness introduced by wax crystals. Experiments with polydimethylsiloxane semi-spheres showed much higher forces

• on wax samples when compared to insect attachment forces measured on these surfaces. We explain these results by the differences in material properties between polydimethylsiloxane probes and tenent setae of C. septempunctata beetles. Among wax surfaces, force experiments showed stronger insect

A nanometric cushion for enhancing scratch and wear resistance of hard films

• Katya Gotlib-Vainshtein,
• Olga Girshevitz,
• Chaim N. Sukenik,
• David Barlam and
• Sidney R. Cohen

Beilstein J. Nanotechnol. 2014, 5, 1005–1015, doi:10.3762/bjnano.5.114

• control the scratch resistance of oxide surfaces. Titania films of several nm thickness are coated onto substrates of silicon, kapton, polycarbonate, and polydimethylsiloxane (PDMS). The scratch resistance measured by scanning force microscopy is found to be substrate dependent, diminishing in the order

• polydimethylsiloxane (PDMS) using liquid phase deposition [34][35][36]. In this work, we further apply the technique to polycarbonate (PC) substrates, which are used in the lens industry and carry requirement of scratch/wear resistance. In addition to scratch and wear resistance, we demonstrate that the soft polymer

The optimal shape of elastomer mushroom-like fibers for high and robust adhesion

• Burak Aksak,
• Korhan Sahin and
• Metin Sitti

Beilstein J. Nanotechnol. 2014, 5, 630–638, doi:10.3762/bjnano.5.74

• fiber arrays, respectively. The derivation of Equation 3 is detailed in Supporting Information File 1. Their experiments were carried out with polydimethylsiloxane (PDMS) cylindrical and mushroom-like fibers. For cylindrical fibers, a = 10 µm and h = 25 µm. The tip radius for mushroom–like fibers were

Fullerenes as adhesive layers for mechanical peeling of metallic, molecular and polymer thin films

• Maria B. Wieland,
• Anna G. Slater,
• Barry Mangham,
• Neil R. Champness and
• Peter H. Beton

Beilstein J. Nanotechnol. 2014, 5, 394–401, doi:10.3762/bjnano.5.46

• onto the gold using a deposition rate of 1 nm/min. The samples were subsequently removed from UHV and a support layer of polydimethylsiloxane (PDMS) with a thickness of ≈1 mm was deposited from solution onto the samples (see the Experimental section). Mechanical peeling of the PDMS layer removes the