Functionalization of vertically aligned carbon nanotubes

• Eloise Van Hooijdonk,
• Carla Bittencourt,
• Rony Snyders and
• Jean-François Colomer

Beilstein J. Nanotechnol. 2013, 4, 129–152, doi:10.3762/bjnano.4.14

• fibers was solved by Feng et al. who made well-aligned MWCNTs/PANI hybrid materials. The methodology is the following: (i) VA-CNTs are grown on a quartz substrate by catalytic pyrolysis, (ii) the film is immersed in an aniline/HCl solution (0 °C, 12 h), (iii) polymerization on the CNTs surfaces. The

• also mention the work of Raravikar et al. [142] who embedded VA-CNTs into a poly(methyl methacrylate) (PMMA) matrix with a two-step strategy. The first step is the fabrication of a VA-CNTs array followed by a MMA monomer infiltration while the subsequent step is in situ polymerization. Finally, we

Polymer blend lithography: A versatile method to fabricate nanopatterned self-assembled monolayers

• Cheng Huang,
• Markus Moosmann,
• Jiehong Jin,
• Tobias Heiler,
• Stefan Walheim and
• Thomas Schimmel

Beilstein J. Nanotechnol. 2012, 3, 620–628, doi:10.3762/bjnano.3.71

• The dependence of the PS island diameter upon the polymerization degree of PS is shown in Figure 4. It can clearly be seen that the average diameter and the width of the diameter distribution decrease with the reducing molar mass of the polymer. When PS of 9.58 kg/mol is used, the average diameter of

Focused electron beam induced deposition: A perspective

• Michael Huth,
• Fabrizio Porrati,
• Christian Schwalb,
• Marcel Winhold,
• Roland Sachser,
• Maja Dukic,
• Jonathan Adams and
• Georg Fantner

Beilstein J. Nanotechnol. 2012, 3, 597–619, doi:10.3762/bjnano.3.70

Synthesis and electrical characterization of intrinsic and in situ doped Si nanowires using a novel precursor

• Wolfgang Molnar,
• Alois Lugstein,
• Tomasz Wojcik,
• Peter Pongratz,
• Norbert Auner,
• Christian Bauch and
• Emmerich Bertagnolli

Beilstein J. Nanotechnol. 2012, 3, 564–569, doi:10.3762/bjnano.3.65

• Research GmbH, Entwicklungszentrum Wolfen, Kunstseidenstrasse 6, D-06766 Bitterfeld-Wolfen Johann Wolfgang von Goethe-University, Max-von-Laue-Strasse 7, D-60438 Frankfurt am Main, Germany 10.3762/bjnano.3.65 Abstract Perchlorinated polysilanes were synthesized by polymerization of tetrachlorosilane under

Colloidal lithography for fabricating patterned polymer-brush microstructures

• Tao Chen,
• Debby P. Chang,
• Rainer Jordan and
• Stefan Zauscher

Beilstein J. Nanotechnol. 2012, 3, 397–403, doi:10.3762/bjnano.3.46

• -initiated atom-transfer radical polymerization (SI-ATRP) to fabricate patterned polymer-brush microstructures. The advantages of the CL technique over other lithographic approaches for the fabrication of patterned polymer brushes are (i) that it can be carried out with commercially available colloidal

• : atom-transfer radical polymerization; colloidal lithography; patterning; self-assembled microsphere monolayer; Introduction It is well known that monodisperse colloidal microspheres easily self-assemble into hexagonally close-packed arrays on surfaces as a result of capillary forces arising from the

• nanoscale, by changing the sphere diameter of the colloid mask. Spherical particles are commercially available with a wide range of sizes and types, or can be synthesized, e.g., by emulsion polymerization for polymer latex spheres or by controlled precipitation for inorganic oxides [12]. Patterned polymer

Ultraviolet photodetection of flexible ZnO nanowire sheets in polydimethylsiloxane polymer

• Jinzhang Liu,
• Nunzio Motta and
• Soonil Lee

Beilstein J. Nanotechnol. 2012, 3, 353–359, doi:10.3762/bjnano.3.41

• conduction band enhance the conductivity of the ZnO nanowires. The UV photoresponse of ZnO nanowires in PDMS can be explained with the help of Figure 5. After polymerization, the PDMS molecule chains of CH3[Si(CH3)2O]nSi(CH3)3, where n is the number of repeating monomer [SiO(CH3)3] units, form a network

Self-assembly of octadecyltrichlorosilane: Surface structures formed using different protocols of particle lithography

• ChaMarra K. Saner,
• Kathie L. Lusker,
• Zorabel M. LeJeune,
• Wilson K. Serem and
• Jayne C. Garno

Beilstein J. Nanotechnol. 2012, 3, 114–122, doi:10.3762/bjnano.3.12

• masks of latex and silica spheres. The meniscus sites of water residues at the base of latex spheres furnish local containers for self-polymerization reactions to generate multilayer surface structures. Optimized structures with nearly the thickness of an ideal monolayer were achieved by using annealed

Surface functionalization of aluminosilicate nanotubes with organic molecules

• Wei Ma,
• Weng On Yah,
• Hideyuki Otsuka and
• Atsushi Takahara

Beilstein J. Nanotechnol. 2012, 3, 82–100, doi:10.3762/bjnano.3.10

• through surface-initiated polymerization. In addition, the assembly of conjugated molecules, 2-(5’’-hexyl-2,2’:5’,2’’-terthiophen-5-yl)ethylphosphonic acid (HT3P) and 2-(5’’-hexyl-2,2’:5’,2’’-terthiophen-5-yl)ethylphosphonic acid 1,1-dioxide (HT3OP), on the imogolite nanotube surface was achieved by

• water content increases and there is a risk of formation of multilayers due to the uncontrolled polymerization of the multifunctional organosilanes [17][18]. Phosphorus derivatives are much less sensitive to nucleophilic substitution than silicon derivatives are, because phosphorus has a higher

• polymer chains are in situ grown from the surface by means of surface-initiated polymerization, and the grafting density is higher compared to the “grafting to” and “grafting through” approaches. The “grafting from” process can be performed with various polymerization techniques, from anionic and cationic

Improvement of the oxidation stability of cobalt nanoparticles

• Celin Dobbrow and
• Annette M. Schmidt

Beilstein J. Nanotechnol. 2012, 3, 75–81, doi:10.3762/bjnano.3.9

• , respectively. Cobalt nanoparticles with a brush-like shell of linear polycaprolactone (Co@PCL) were obtained by a ring-opening polymerization process of ε-caprolactone starting from ricinolic acid-capped cobalt [13]. Polystyrene coated particles (Co@PS) were accessed by replacing the fatty acid stabilizer

• during the thermolysis of Co2(CO)8 with carboxylic acid-telechelic polystyrene, which was obtained by atom transfer radical polymerization (ATRP) [14] (see Supporting Information File 1 for details). All synthetic steps involved were performed under argon in order to prevent premature oxidation. The

• an analogous investigation of oxidation kinetics. Polycaprolactone coated cobalt nanoparticles (Co@PCL) Co@PCL particles employed in this study were prepared according to a recently published method from ricinolic acid coated cobalt nanoparticles by surface-initiated ring-opening polymerization of CL

Approaches to nanostructure control and functionalizations of polymer@silica hybrid nanograss generated by biomimetic silica mineralization on a self-assembled polyamine layer

• Jian-Jun Yuan and
• Ren-Hua Jin

Beilstein J. Nanotechnol. 2011, 2, 760–773, doi:10.3762/bjnano.2.84

• novel external stimuli-responsive smart surface [47], with the superhydrophobic surface being switched into a superhydrophilic state by means of UV irradiation. Experimental Materials LPEI with an average polymerization degree of around 505 was synthesized by the hydrolysis of the corresponding

An MCBJ case study: The influence of π-conjugation on the single-molecule conductance at a solid/liquid interface

• Wenjing Hong,
• Hennie Valkenier,
• Gábor Mészáros,
• David Zsolt Manrique,
• Artem Mishchenko,
• Alexander Putz,
• Pavel Moreno García,
• Colin J. Lambert,
• Jan C. Hummelen and
• Thomas Wandlowski

Beilstein J. Nanotechnol. 2011, 2, 699–713, doi:10.3762/bjnano.2.76

• glue was adjusted to be less than 500 μm. Next, the sample was conditioned overnight at 60 °C for epoxy polymerization. The freely suspended part of the wire was notched with a scalpel blade under an optical microscope to fabricate a constriction point. The as-prepared sample sheets were cleaned in

Surface induced self-organization of comb-like macromolecules

• Konstantin I. Popov,
• Vladimir V. Palyulin,
• Martin Möller,
• Alexei R. Khokhlov and
• Igor I. Potemkin

Beilstein J. Nanotechnol. 2011, 2, 569–584, doi:10.3762/bjnano.2.61

• modification of backbone units or by copolymerization with a monomer of the required functionality. The second approach involves the synthesis of active centers along the backbone (the synthesis of macroinitiators) and subsequent growth of side chains from these centers by polymerization (the so-called

• strategy enables control of different parameters such as grafting density, chemical composition, polymerization degree of side chains and the backbone, polydispersity, etc. Achievement of the desired set of these parameters is quite a complicated task, e.g., due to the steric repulsion of side chains in

• PBA side chains (polymerization degree n = (12 ± 1)−(140 ± 12)) adsorbed from good solvent on mica, SFM results for the bending modulus are approximated by the exponents ν = 2.7 ± 0.2 [100], which is close to the theoretical prediction of 3. The difference between the experimental and theoretical

Inorganic–organic hybrid materials through post-synthesis modification: Impact of the treatment with azides on the mesopore structure

• Miriam Keppeler,
• Jürgen Holzbock,
• Johanna Akbarzadeh,
• Herwig Peterlik and
• Nicola Hüsing

Beilstein J. Nanotechnol. 2011, 2, 486–498, doi:10.3762/bjnano.2.52

• the application of diol/polyol-modified silanes [1][2][3][14][15][16][17][18]. Nakanishi and Lindén relied on polymerization-induced phase separation during sol–gel processing to form monolithic bodies with a hierarchical organisation of the pore structure at the meso- and macroscopic length scale [16

Platinum nanoparticles from size adjusted functional colloidal particles generated by a seeded emulsion polymerization process

• Nicolas Vogel,
• Ulrich Ziener,
• Achim Manzke,
• Alfred Plettl,
• Paul Ziemann,
• Johannes Biskupek,
• Clemens K. Weiss and
• Katharina Landfester

Beilstein J. Nanotechnol. 2011, 2, 459–472, doi:10.3762/bjnano.2.50

• , Germany Department of Solid State Physics, University of Ulm, Albert-Einstein-Allee 11, 89081 Ulm, Germany Central Facility of Electron Microscopy, University of Ulm, Albert-Einstein-Allee 11, 89081 Ulm, Germany 10.3762/bjnano.2.50 Abstract The benefits of miniemulsion and emulsion polymerization are

• combined in a seeded emulsion polymerization process with functional seed particles synthesized by miniemulsion polymerization. A systematic study on the influence of different reaction parameters on the reaction pathway is conducted, including variations of the amount of monomer fed, the ratio of

• initiator to monomer and the choice of surfactant and composition of the continuous phase. Critical parameters affecting the control of the reaction are determined. If carefully controlled, the seeded emulsion polymerization with functional seed particles yields monodisperse particles with adjustable size

Plasmonic nanostructures fabricated using nanosphere-lithography, soft-lithography and plasma etching

• Manuel R. Gonçalves,
• Taron Makaryan,
• Fabian Enderle,
• Stefan Wiedemann,
• Alfred Plettl,
• Othmar Marti and
• Paul Ziemann

Beilstein J. Nanotechnol. 2011, 2, 448–458, doi:10.3762/bjnano.2.49

• , and epoxy resin cast on that sample could still not be detached. For the preparation of an anti-adhesive coating the same plasma etching system was used. By plasma polymerization of the process gas CHF3, a fluoro-carbon film was deposited on the previously prepared quartz substrate. This technique

Fabrication and spectroscopic studies on highly luminescent CdSe/CdS nanorod polymer composites

• Jana Bomm,
• Andreas Büchtemann,
• Angela Fiore,
• Liberato Manna,
• James H. Nelson,
• Diana Hill and
• Wilfried G. J. H. M. van Sark

Beilstein J. Nanotechnol. 2010, 1, 94–100, doi:10.3762/bjnano.1.11

• thermal polymerization process leads to luminescence quenching and as a result nanocomposites with photoluminescence (PL) quantum efficiency (QE) of less than 40% were obtained [6][7][8]. Here we present two different methods to fabricate nanorod polymer composites: (a) UV-polymerization and (b) a radical

Sensing surface PEGylation with microcantilevers

• Natalija Backmann,
• Natascha Kappeler,
• Thomas Braun,
• François Huber,
• Hans-Peter Lang,
• Christoph Gerber and
• Roderick Y. H. Lim

Beilstein J. Nanotechnol. 2010, 1, 3–13, doi:10.3762/bjnano.1.2

• RF ≈ lN3/5 where l is the monomer length and N is the degree of polymerization [39], the size of a single 20 kDa mPEG–SH chain is given by RF ≈ 14.4 nm as calculated from l ~ 0.37 nm [42] and N ~ 450. Considering the height (L ~ 26 nm) of the PEG layer and the grafting distances (s ~ 18 nm) as