Nanoarchitectonics to entrap living cells in silica-based systems: encapsulations with yolk–shell and sepiolite nanomaterials

• Celia Martín-Morales,
• Jorge Fernández-Méndez,
• Pilar Aranda and
• Eduardo Ruiz-Hitzky

Beilstein J. Nanotechnol. 2023, 14, 522–534, doi:10.3762/bjnano.14.43

• influence on the characteristics of the final materials. Thus, an optimised protocol yielding biocompatibility and physical stability, as well as suitable transparency to allow for the viability of cyanobacteria was found. Previous results on algae biohybrid systems based on chitosan biocomposites have

• (Table 1). The subsequent qualitative evaluation of the synthesised gels regarding strength, opacity, and stability in cyanobacteria and yeast growth media (BG-11 and apple juice, respectively) after 24 h showed that the optimal conditions were the ones used to produce the G57-4 gel (5% sodium silicate

• gel matrix. This behaviour is highly interesting, since it could be exploited in further studies where post-synthesis pseudohyphal growth of yeast cells can generate an intricate tridimensional network of living cells, providing higher mechanical stability and biological robustness, and even an

Mixed oxides with corundum-type structure obtained from recycling can seals as paint pigments: color stability

• Dienifer F. L. Horsth,
• Julia de O. Primo,
• Nayara Balaba,
• Fauze J. Anaissi and
• Carla Bittencourt

Beilstein J. Nanotechnol. 2023, 14, 467–477, doi:10.3762/bjnano.14.37

• ) coloration of the mixed oxides was confirmed by XPS and visible-light absorption measurements. The colorimetric stability of the oxides in acid and alkaline environments was evaluated. After 240 h of exposure to harsh environments, both pigments demonstrated stability and showed no strong color difference

• and physical stability of the pigments, ensuring greater durability. Furthermore, it reduces environmental problems because it avoids consuming natural raw materials, saving primary resources [10][11]. Inorganic pigments, generally, are less affected by light, ambient temperature, chemicals, and harsh

• safety [13]. Therefore, it is essential to have color intensity and stability to avoid aging in signalization, for example, in motor roads, chemical industries, and hospitals. Chromium oxide green belongs to the class of inorganic green and blue-green pigments [14]. It exhibits the corundum structure and

Conjugated photothermal materials and structure design for solar steam generation

• Chia-Yang Lin and
• Tsuyoshi Michinobu

Beilstein J. Nanotechnol. 2023, 14, 454–466, doi:10.3762/bjnano.14.36

• -withdrawing (EW) groups, such as malononitrile (DCV) and 2-(3-oxo-indan-1-ylidene)malononitrile (INCN) to the DPP core enhances the stability of DPP dyes [27]. In addition, when a thienyl spacer was introduced between the DPP and EW groups, efficient intramolecular charge transfer (ICT) interactions were

• PDA as a PTM to improve the chemical stability and light absorption ability [49]. The Ni1Co3@PDA was dispersed onto the surface of a round commercial sponge by drop casting. The photothermal performance of the Ni1Co3@PDA deposited on the sponge was then evaluated using a kerosene lamp-like setup

• materials, because low cost, reusability, chemical stability, and mass production will be required in the future. Furthermore, by designing the evaporator, it can be applied to various fields, such as seawater desalination, sterilization, and power generation. There is still room for research on how to

Evaluation of electrosynthesized reduced graphene oxide–Ni/Fe/Co-based (oxy)hydroxide catalysts towards the oxygen evolution reaction

• Karolina Cysewska,
• Marcin Łapiński,
• Marcin Zając,
• Jakub Karczewski,
• Piotr Jasiński and
• Sebastian Molin

Beilstein J. Nanotechnol. 2023, 14, 420–433, doi:10.3762/bjnano.14.34

• different kinds of conductive carbon materials [14][15][16][17][18]. Recently, graphene (Gr)/graphene oxide (GO) has attracted the attention of many researchers due to its high surface area, significant chemical stability, high electrical conductivity, and high mechanical strength [12][19]. Combining a

• are in agreement with the trend of the evolution of η and Eonset determined based on LSV (Figure 5a,b). The stability test of the most promising among studied catalysts was assessed during chronoamperometry measurements at 10 mA∙cm−2geo (Figure 8a). A rapid increase of the potential at the beginning

• phase element (Zview). The OER stability test was carried out by chronoamperometry at a current density of 10 mA·cm−2 for 22 h. The recorded current values were normalized by the geometric area of the nickel electrode (0.25 cm2). All of the potentials were iR-corrected. The equation: η = E(10 mA·cm−2

Plasmonic nanotechnology for photothermal applications – an evaluation

• A. R. Indhu,
• L. Keerthana and
• Gnanaprakash Dharmalingam

Beilstein J. Nanotechnol. 2023, 14, 380–419, doi:10.3762/bjnano.14.33

• tunability of optothermal properties and enhanced stability, these nanostructures show a wide range of applications in optical sensors, steam generation, water desalination, thermal energy storage, and biomedical applications such as photothermal (PT) therapy. The PT effect, that is, the conversion of

• nanocomposites. A detailed investigation of the essential, but often ignored, concept of thermal, chemical, and aggregation stability of nanoparticles is another part of this review. The challenges that remain, as well as prospective directions and chemistries, regarding nanomaterials for PT conversion are

• pondered on in the final section of the article, taking into account the specific requirements from different applications. Keywords: nanoparticle heating; phonons; photothermal; plasmonic; stability; surface plasmon resonance; Review 1 Introduction With an ever-increasing demand for energy and the

Quercetin- and caffeic acid-functionalized chitosan-capped colloidal silver nanoparticles: one-pot synthesis, characterization, and anticancer and antibacterial activities

• Akif Hakan Kurt,
• Elif Berna Olutas,
• Fatma Avcioglu,
• Hamza Karakuş,
• Mehmet Ali Sungur,
• Cansu Kara Oztabag and
• Muhammet Yıldırım

Beilstein J. Nanotechnol. 2023, 14, 362–376, doi:10.3762/bjnano.14.31

• comparable to that in the healthy ARPE-19 cells, suggesting that the effect may not be tissue specific. Another issue that may affect the results of biological applications of NPs in general and should be considered is how the colloidal distribution and stability of the NPs are affected in the cell culture

• medium [74]. Since NPs are exposed to various forces that affect their stability and size in such environments (containing electrolytes, proteins and lipids), they may tend to collapse and aggregate. Although no aggregation and turbidity were observed during the preparation stage with the naked eye and

• in the microscope images of Ch/Q- and Ch/CA-Ag NPs in cell medium (see Supporting Information File 1, Figure S1), the stability of the synthesized NPs and how the size changes in cell culture medium compared to water were also evaluated by UV–vis and zeta potential measurements. An increase in the

Polymer nanoparticles from low-energy nanoemulsions for biomedical applications

• Santiago Grijalvo and
• Carlos Rodriguez-Abreu

Beilstein J. Nanotechnol. 2023, 14, 339–350, doi:10.3762/bjnano.14.29

• component addition or on the thermal history. Nanoemulsions are not to be confused with microemulsions, which are equilibrium systems with thermodynamic stability [4]. Because of their very small drop size, the main mechanism for nanoemulsion destabilization is commonly attributed to Ostwald ripening

• tensions that promote the formation of very small droplets. However, since the colloidal stability is very low, the systems need to be quenched to lower temperatures to obtain kinetically stable nanoemulsions [10][11]. In contrast, the PIC method (also called emulsion inversion point method) [12][13

• were obtained upon solvent removal. High colloidal stability (longer than three months without sedimentation), high encapsulation efficiency (>99%), slow drug release (only 15% of the drug after five days), and low cytotoxicity against HeLa cells (cell viability > 80%) were observed. In vivo tests

Overview of mechanism and consequences of endothelial leakiness caused by metal and polymeric nanoparticles

• Magdalena Lasak and
• Karol Ciepluch

Beilstein J. Nanotechnol. 2023, 14, 329–338, doi:10.3762/bjnano.14.28

• VE-cad–VE-cad interactions between endothelial cells, triggering the phosphorylation of intracellular tyrosine residues Y658 (by an unknown kinase pathway) and Y731 (by Src kinase) [19]. This causes a loss of stability of the ternary complex of the adherens junctions interacting with actin, which are

• proteins, is determined by the stability, biocompatibility, and solubility of such conjugates, which in turn opens up new perspectives in medical applications [16][42]. Nanotheranostic applications use NPs for diagnostic and therapeutic purposes for serious metabolic, cancer, and neurodegenerative diseases

• , triggering the phosphorylation of intracellular tyrosine residues Y658 (by an unknown kinase pathway) and Y731 (by Src kinase). This causes the loss of stability of the ternary complex of the adherens junctions and the recession of cells. Au NanoEL required actin remodeling. (A) Blocking the RhoA kinase

Bismuth-based nanostructured photocatalysts for the remediation of antibiotics and organic dyes

• Akeem Adeyemi Oladipo and
• Faisal Suleiman Mustafa

Beilstein J. Nanotechnol. 2023, 14, 291–321, doi:10.3762/bjnano.14.26

• carrier separation, high photo-transporter mobility, appropriate physical and chemical properties, sufficient band alignment to meet the kinetic requirements of the target reaction, and anti-corrosion stability in reactive environments [18][19][20]. Figure 1 depicts the mechanism of the photocatalyst. In

• exposure. Since the oxidation rate is still up to 96.3% after four cycles, the photocatalyst showed great performance and stability in the photocatalytic oxidation of the dye. This review provides an overview of the recent nanostructured photocatalytic materials based on bismuth that are employed in the

• is a small (6-coordinate, such as Ti, W, Mo, or Fe) cation. It is another visible-light-driven n-type bismuth-based semiconductor and has received a lot of attention because of its distinctive layered structure, eco-friendliness, high photochemical and thermal stability, and benign visible-light

Biocatalytic synthesis and ordered self-assembly of silica nanoparticles via a silica-binding peptide

• Mustafa Gungormus

Beilstein J. Nanotechnol. 2023, 14, 280–290, doi:10.3762/bjnano.14.25

• the study is that because of its high affinity to SiO2, SiBP can form a dense layer on the particle surface that improves the stability of nanoparticles [36]. These observations support this hypothesis, as smaller and more narrowly distributed particles were obtained with higher SiBP concentrations

Recent progress in cancer cell membrane-based nanoparticles for biomedical applications

• Qixiong Lin,
• Yueyou Peng,
• Yanyan Wen,
• Xiaoqiong Li,
• Donglian Du,
• Weibin Dai,
• Wei Tian and
• Yanfeng Meng

Beilstein J. Nanotechnol. 2023, 14, 262–279, doi:10.3762/bjnano.14.24

• storage time than bare NPs because of the higher colloidal stability of the prepared colloidal particles [53]. In one study, liver cancer cell membrane-encapsulated PLGA NPs maintained a stable size in water and PBS for a long time, while bare PLGA NPs progressively grew larger (Figure 4B) [31]. 3

• oxidation, improve biocompatibility, enhance colloidal stability, and enhance targeting), enabling the ablation of tumor tissues by thermal energy [79]. MDA-MB-231 cell membrane-coated NPs loaded with superparamagnetic iron oxide nanoparticles (SPIONs) and PTX were designed for the combination treatment of

• by enhancing proton relaxation in tissues [120]. Among them, superparamagnetic iron oxides (SPIONs) are widely used with numerous advantages, such as small size, colloidal stability, low toxicity, magnetic heating properties, and enhanced molecular MRI [121]. However, SPIONs cannot be effectively

Nanotechnology – a robust tool for fighting the challenges of drug resistance in non-small cell lung cancer

• Filip Gorachinov,
• Fatima Mraiche,
• Diala Alhaj Moustafa,
• Ola Hishari,
• Yomna Ismail,
• Jensa Joseph,
• Maja Simonoska Crcarevska,
• Marija Glavas Dodov,
• Nikola Geskovski and
• Katerina Goracinova

Beilstein J. Nanotechnol. 2023, 14, 240–261, doi:10.3762/bjnano.14.23

• task limited by extracellular and intracellular challenges. Combinatorial therapy further complicates the right-time, right-place co-delivery of siRNA with other active ingredients due to the differences in the physicochemical properties, delivery, and stability problems. The nanoparticle core for

• such as cyclodextrin, inulin, and chitosan. These polymers are used alone or combined with amphiphilic polymers for core–shell nanoparticles such as the triblock polymer poly(ʟ-lactide)-poly(ethylene glycol)-poly(ʟ-lactide) (PLLA-PEG-PLLA) to increase the stability and decrease the immunogenicity of

Concentration-dependent photothermal conversion efficiency of gold nanoparticles under near-infrared laser and broadband irradiation

• Vikas,
• Raj Kumar and
• Sanjeev Soni

Beilstein J. Nanotechnol. 2023, 14, 205–217, doi:10.3762/bjnano.14.20

• × 41 nm GNRs show a temperature increase for a longer period of time than GNSs and 25 × 47 nm GNRs. The photothermal stability of the GNPs was examined by measuring the spectral absorbance of GNPs before and after irradiation as shown in Figure S3 (Supporting Information File 1). It is seen that there

A novel approach to pulsed laser deposition of platinum catalyst on carbon particles for use in polymer electrolyte membrane fuel cells

• Bogusław Budner,
• Wojciech Tokarz,
• Sławomir Dyjak,
• Andrzej Czerwiński,
• Bartosz Bartosewicz and
• Bartłomiej Jankiewicz

Beilstein J. Nanotechnol. 2023, 14, 190–204, doi:10.3762/bjnano.14.19

• applications. The method developed still requires additional investigations on production scalability, repeatability, and automation of the Pt deposition process. It is also crucial to test the chemical stability of the material in the working polymer fuel cell system over a long period. Experimental Materials

Combining physical vapor deposition structuration with dealloying for the creation of a highly efficient SERS platform

• Adrien Chauvin,
• Walter Puglisi,
• Damien Thiry,
• Cristina Satriano,
• Rony Snyders and
• Carla Bittencourt

Beilstein J. Nanotechnol. 2023, 14, 83–94, doi:10.3762/bjnano.14.10

• suspension [15]. However, NPs suspensions are hard to handle, suffer from poor stability, and can hardly be reused [6]. In this perspective, major interest has been devoted to developing solid SERS platforms made of nanostructured thin films [15][16]. Among them, nanoporous materials show superior properties

• substrates with better reliability and stability compared to conventional NP-based SERS substrates [25]. The race towards more efficient SERS platforms has led to the development of highly complex synthesis processes which limits their use in practical applications [15][26][27][28][29]. Most reports on

• efficient nanoporous platforms are based on gold due to their high stability towards oxidation. Therefore, heading towards simple and inexpensive approaches to reach the industrial market turns out to be a necessity. The origin of the SERS effect relies on the interaction between an intense electromagnetic

Two-step single-reactor synthesis of oleic acid- or undecylenic acid-stabilized magnetic nanoparticles by thermal decomposition

• Mykhailo Nahorniak,
• Pamela Pasetto,
• Jean-Marc Greneche,
• Volodymyr Samaryk,
• Sandy Auguste,
• Anthony Rousseau,
• Nataliya Nosova and
• Serhii Varvarenko

Beilstein J. Nanotechnol. 2023, 14, 11–22, doi:10.3762/bjnano.14.2

• reduction of nanoparticle diameter below the critical size of 25 nm leads to nanoparticles with superparamagnetic properties [10][11]. Due to the absence of coercive forces in superparamagnetic nanoparticles not exposed to an external magnetic field, they are characterized by good colloidal stability, which

• low stability (i.e., acetate, pentacarbonyl, acetylacetonate) in high-boiling-point solvents in the presence of stabilizing agents (e.g., fatty acids, higher amines, alcohols) or their mixtures [13][14][15]. Although thermal decomposition is a relatively simple method, minor modifications of the

• be adsorbed on the surface of the particles, ensures nanodispersion stability (Figure 1) [31]. Transmission electron microscopy (TEM) micrographs of the prepared nanoparticles confirmed their size between 8 and 16 nm (Figure 2 and Figure 3). The diameter and shape of the nanoparticles depend on the

Electrical and optical enhancement of ITO/Mo bilayer thin films via laser annealing

• Abdelbaki Hacini,
• Ahmad Hadi Ali,
• Nurul Nadia Adnan and
• Nafarizal Nayan

Beilstein J. Nanotechnol. 2022, 13, 1589–1595, doi:10.3762/bjnano.13.133

• adherence to the substrate, very high thermal stability (up to 600 °C), and high electrical conductivity [14]. Over the last decades, the development of solar cells has grown dramatically. The cells have become larger, thinner, and lighter. This increases the electrical resistivity, which is undesirable

Induced electric conductivity in organic polymers

• Konstantin Y. Arutyunov,
• Anatoli S. Gurski,
• Vladimir V. Artemov,
• Alexander L. Vasiliev,
• Azat R. Yusupov,
• Danfis D. Karamov and
• Alexei N. Lachinov

Beilstein J. Nanotechnol. 2022, 13, 1551–1557, doi:10.3762/bjnano.13.128

• ]. The effect is interpreted as stimulation of metallic state [2]. Poly(diphenylene phthalide) (PDP) was chosen as the object of study being a representative electro-active polymer demonstrating induced electric conductivity. PDP is a carbocyclic polymer with high chemical and thermal stability

Photoelectrochemical water oxidation over TiO₂ nanotubes modified with MoS₂ and g-C₃N₄

• Phuong Hoang Nguyen,
• Thi Minh Cao,
• Tho Truong Nguyen,
• Hien Duy Tong and
• Viet Van Pham

Beilstein J. Nanotechnol. 2022, 13, 1541–1550, doi:10.3762/bjnano.13.127

• . The stability of the MoS2/TNAs heterojunction is higher than that of g-C3N4/TNAs. Keywords: band structure; g-C3N4/TiO2; MoS2/TiO2; photoelectrochemical; water splitting; Introduction Hydrogen energy has become a target pursued in the energy development strategies of many countries and regions

• semiconductors, TiO2 nanotube arrays (TNAs) of 2–100 nm in diameter and 1–2 μm in length, are often used for efficient PEC applications exploiting advantages such as chemical stability, less toxicity and suitable cost [18][19][20][21]. However, there are two disadvantages affecting directly their photocatalytic

• temperature (500 °C for 2 h) in [35] yielded better results better than those of this study. The investigation of the stability of the PEC electrodes from MoS2/TNAs and g-C3N4/TNAs is described in Figure S3, Supporting Information File 1. After every PEC test cycle, we immersed the PEC electrode in DI water

Non-stoichiometric magnetite as catalyst for the photocatalytic degradation of phenol and 2,6-dibromo-4-methylphenol – a new approach in water treatment

• Joanna Kisała,
• Anna Tomaszewska and
• Przemysław Kolek

Beilstein J. Nanotechnol. 2022, 13, 1531–1540, doi:10.3762/bjnano.13.126

• stability of the catalysts). Under acidic conditions, magnetite dissolves according to Equation 2: At pH > 7, however, the effect of hydrolysis is expected to be negligible [27]. The molar fractions of the ionic forms of organic compounds present in the solution at pH 8 were calculated using the software

In search of cytotoxic selectivity on cancer cells with biogenically synthesized Ag/AgCl nanoparticles

• Mitzi J. Ramírez-Hernández,
• Mario Valera-Zaragoza,
• Omar Viñas-Bravo,
• Ariana A. Huerta-Heredia,
• Miguel A. Peña-Rico,
• Erick A. Juarez-Arellano,
• David Paniagua-Vega,
• Eduardo Ramírez-Vargas and
• Saúl Sánchez-Valdes

Beilstein J. Nanotechnol. 2022, 13, 1505–1519, doi:10.3762/bjnano.13.124

• Figure 7, it is remarkable that the reaction products have a higher thermal stability than that of the pineapple peel extract. This behavior can be attributed to two complementary situations. The first is a change in the chemical structure of the organic compounds used in the formation and capping of Ag

• /AgCl nanoparticles as observed by FTIR spectroscopy (Figure 5). The reducing species are oxidized and as a consequence have greater thermal stability. Hence, the higher temperature-shifted TGA curves show the thermal behavior of the modified metabolites during chemical reaction. The results are also

• consistent with Reddy et al. [41], who reported that phytochemicals capped on nanoparticles support thermal stability upon temperature changes. The second situation is the thermal barrier that Ag/AgCl nanoparticles themselves, based on their intrinsic characteristics, provide to the system. This last

Structural studies and selected physical investigations of LiCoO₂ obtained by combustion synthesis

• Monika Michalska,
• Paweł Ławniczak,
• Tomasz Strachowski,
• Adam Ostrowski and
• Waldemar Bednarski

Beilstein J. Nanotechnol. 2022, 13, 1473–1482, doi:10.3762/bjnano.13.121

• improve electrical conductivity and electrochemical performance [5][6][7][9][13][14][15][16][23][24][25][26][27][28][29][30][31][32]. Nanostructured materials can reduce the specific surface current rate as well as improve stability and specific capacity [23][24][25][26][27][28][29]. LiCoO2 has been

Rapid and sensitive detection of box turtles using an electrochemical DNA biosensor based on a gold/graphene nanocomposite

• Abu Hashem,
• M. A. Motalib Hossain,
• Ab Rahman Marlinda,
• Mohammad Al Mamun,
• Khanom Simarani and
• Mohd Rafie Johan

Beilstein J. Nanotechnol. 2022, 13, 1458–1472, doi:10.3762/bjnano.13.120

• the applications of impedance DNA hybridisation biosensors for the detection of a number of analytes [31][32][33][34]. Nanomaterials may significantly enhance biosensor performance, stability, repeatability, and sensitivity [35][36][37][38][39]. Among various nanomaterials, graphene (Gr) [40] and gold

• biosensor exhibited high sensitivity, excellent selectivity, and good stability with the desired detection limit. It might have a promising future for detecting box turtle adulteration in food products and solving the problem of point-of-care application after commercial adaptation. However, attaining good

Facile preparation of Au- and BODIPY-grafted lipid nanoparticles for synergized photothermal therapy

• Yuran Wang,
• Xudong Li,
• Haijun Chen and
• Yu Gao

Beilstein J. Nanotechnol. 2022, 13, 1432–1444, doi:10.3762/bjnano.13.118

• organic PTAs, boron dipyrromethenes (BODIPYs) have attracted increasing attention because of high molar absorption coefficient and photochemical stability [11]. Besides, fabricating BODIPYs with halogenated substituents can improve the photothermal conversion efficiency during PTT [12]. However, BODIPYs

• determined and calculated using the following formula: The morphology of AB-LNPs was obtained on a Hitachi HT7700 transmission electron microscope (TEM, Hitachi, Japan). AB-LNPs were diluted and plated on a carbon-coated copper grid. The stability of AB-LNPs The stability of AB-LNPs was studied by measuring

• (molar ratio of DSPE-DTPA/Au3+/BDP = 2:1:1), the mixture was vortexed for 30 s and further ultrasonicated for 10 min at 25 °C. The acquired green dispersion, designated as AB-LNPs, showed excellent stability with no precipitation after centrifugation. Method B is mixing BDP with preformed LNPs followed

Dry under water: air retaining properties of large-scale elastomer foils covered with mushroom-shaped surface microstructures

• Matthias Mail,
• Stefan Walheim,
• Thomas Schimmel,
• Wilhelm Barthlott,
• Stanislav N. Gorb and
• Lars Heepe

Beilstein J. Nanotechnol. 2022, 13, 1370–1379, doi:10.3762/bjnano.13.113

• air layer under water for more than two weeks. Further, the stability of the air layer under pressure was investigated and these results are compared with the predicted theoretical values for air retention of microstructured surfaces. Here, we could show that they fit to the theoretical predictions

• . Here, we investigate the air retention capabilities of MSM for the first time. We analyzed the long term stability of the kept air layers as well as the behavior of the air layers at different pressures. Materials and Methods 1 Mushroom-shaped microstructured elastomer foil Microstructured elastomer

• persistence To demonstrate the underwater air retention and to analyze the stability of air layers kept by MSM, different samples were submerged in five different immersion depths, here 0.5, 5, 10, 15 and 20 cm. As a measure of the stability in dependence on the immersion depth the lifetime of the air layers