Enhanced photoelectrochemical water splitting performance using morphology-controlled BiVO₄ with W doping

• Xin Zhao and
• Zhong Chen

Beilstein J. Nanotechnol. 2017, 8, 2640–2647, doi:10.3762/bjnano.8.264

• precursor solution. Considering the poor electron conductivity of BiVO4, which leads to a poor photoelectrochemical performance (see Figure S1, Supporting Information File 1), we employed tungsten as a doping element because it has a higher valence than vanadium and an ionic radius close to that of vanadium

Interactions of low-energy electrons with the FEBID precursor chromium hexacarbonyl (Cr(CO)₆)

• Jusuf M. Khreis,
• João Ameixa,
• Filipe Ferreira da Silva and
• Stephan Denifl

Beilstein J. Nanotechnol. 2017, 8, 2583–2590, doi:10.3762/bjnano.8.258

• by electron transmission spectroscopy describing the negative ion states [14], and electron attachment thresholds for Cr(CO)6, Mo(CO)6 and W(CO)6 were reported [15]. Electron attachment to tungsten hexacarbonyl [13] and tungsten hexachloride [16], as well as electron ionization studies with those

Direct writing of gold nanostructures with an electron beam: On the way to pure nanostructures by combining optimized deposition with oxygen-plasma treatment

• Domagoj Belić,
• Mostafa M. Shawrav,
• Emmerich Bertagnolli and
• Heinz D. Wanzenboeck

Beilstein J. Nanotechnol. 2017, 8, 2530–2543, doi:10.3762/bjnano.8.253

• years several methods to purify FEBID deposits have been presented. For instance, in the case of tungsten, it was found that just by applying a smart writing strategy one could produce single-crystal nanowires [47] whereas the use of a supersonic carrier gas can also yield nanostructures of a high

Comparing postdeposition reactions of electrons and radicals with Pt nanostructures created by focused electron beam induced deposition

• Julie A. Spencer,
• Michael Barclay,
• Miranda J. Gallagher,
• Robert Winkler,
• Ilyas Unlu,
• Yung-Chien Wu,
• Harald Plank,
• Lisa McElwee-White and
• D. Howard Fairbrother

Beilstein J. Nanotechnol. 2017, 8, 2410–2424, doi:10.3762/bjnano.8.240

• located at the National Institute of Standards and Technology (NIST). This source passed H2 over a heated tungsten filament to produce a constant flux of AH radicals. The purification system at NIST permitted high-pressure H2 gas to be admitted ( ≈ 1 Torr), resulting in a correspondingly large flux of AH

Robust procedure for creating and characterizing the atomic structure of scanning tunneling microscope tips

• Sumit Tewari,
• Koen M. Bastiaans,
• Milan P. Allan and
• Jan M. van Ruitenbeek

Beilstein J. Nanotechnol. 2017, 8, 2389–2395, doi:10.3762/bjnano.8.238

• structure of the tip apex behind the apex atom. Some studies have been carried out to determine the angular orbital symmetry [21][22] of the front atom of the tip apex by making force gradient images of a CO molecule over a Cu(111) substrate. The images are made with a tungsten tip in non-contact AFM

Optical contrast and refractive index of natural van der Waals heterostructure nanosheets of franckeite

• Patricia Gant,
• Foad Ghasemi,
• David Maeso,
• Carmen Munuera,
• Elena López-Elvira,
• Riccardo Frisenda,
• David Pérez De Lara,
• Gabino Rubio-Bollinger,
• Mar Garcia-Hernandez and
• Andres Castellanos-Gomez

Beilstein J. Nanotechnol. 2017, 8, 2357–2362, doi:10.3762/bjnano.8.235

• determination. We use micro-reflectance spectroscopy to quantitatively characterize the optical contrast of franckeite flakes of different thicknesses transferred to SiO2/Si substrates [25][26]. The sample is illuminated in epi-illumination mode with the white light coming from the tungsten halogen lamp of a

Comprehensive investigation of the electronic excitation of W(CO)₆ by photoabsorption and theoretical analysis in the energy region from 3.9 to 10.8 eV

• Mónica Mendes,
• Khrystyna Regeta,
• Filipe Ferreira da Silva,
• Nykola C. Jones,
• Søren Vrønning Hoffmann,
• Gustavo García,
• Chantal Daniel and
• Paulo Limão-Vieira

Beilstein J. Nanotechnol. 2017, 8, 2208–2218, doi:10.3762/bjnano.8.220

• density functional calculations (TDDFT) on the low-lying excited sates of tungsten hexacarbonyl, W(CO)6. The higher resolution obtained reveals previously unresolved spectral features of W(CO)6. The spectrum shows two higher-energy bands (in the energy ranges of 7.22–8.12 eV and 8.15–9.05 eV), one of them

• deposition (FEBID); photoabsorption; tungsten hexacarbonyl; Introduction The electronic structure of tungsten hexacarbonyl, W(CO)6, has previously been studied by using a variety of different experimental and theoretical methods, with experiments including vacuum ultraviolet experiments in the wavelength

• *-orbitals, which play a significant role in the stability of carbonyl complexes, and in particular for W(CO)6 where the tungsten oxidation state is zero. W(CO)6 is a precursor molecule used in electron beam induced deposition (EBID) to produce well-defined tungsten-containing nanostructures [21][22

Structural model of silicene-like nanoribbons on a Pb-reconstructed Si(111) surface

• Agnieszka Stępniak-Dybala and
• Mariusz Krawiec

Beilstein J. Nanotechnol. 2017, 8, 1836–1843, doi:10.3762/bjnano.8.185

• substrates. Experimental and Computational Details All the measurements have been done under UHV conditions with a 4He-cooled scanning tunneling microscope (Omicron) working at 4.5 K. For STM/STS measurements electrochemically etched tungsten was used. The Pb/Si(111) sample was prepared in situ by

Synthesis and functionalization of NaGdF₄:Yb,Er@NaGdF₄ core–shell nanoparticles for possible application as multimodal contrast agents

• Dovile Baziulyte-Paulaviciene,
• Vitalijus Karabanovas,
• Marius Stasys,
• Greta Jarockyte,
• Vilius Poderys,
• Simas Sakirzanovas and
• Ricardas Rotomskis

Beilstein J. Nanotechnol. 2017, 8, 1815–1824, doi:10.3762/bjnano.8.183

• from a tungsten incandescent lamp certified by National Physics Laboratory, UK. The measurements were performed in standard 1 cm quartz cuvettes at room temperature. Fourier transform infrared (FTIR) spectra were recorded on an infrared spectrometer (Perkin Elmer Spectrum). Cell culturing and imaging

Three-in-one approach towards efficient organic dye-sensitized solar cells: aggregation suppression, panchromatic absorption and resonance energy transfer

• Jayita Patwari,
• Samim Sardar,
• Bo Liu,
• Peter Lemmens and
• Samir Kumar Pal

Beilstein J. Nanotechnol. 2017, 8, 1705–1713, doi:10.3762/bjnano.8.171

• -circuit photovoltage of the solar cell. The intensity of the incident light (Pin) is 100 mW·cm−2. The wavelength-dependent photocurrent was measured using a custom-made setup, which consists of a Bentham monochromator and two light sources (tungsten and xenon). Results and Discussion In the present study

Luminescent supramolecular hydrogels from a tripeptide and nitrogen-doped carbon nanodots

• Maria C. Cringoli,
• Slavko Kralj,
• Marina Kurbasic,
• Massimo Urban and
• Silvia Marchesan

Beilstein J. Nanotechnol. 2017, 8, 1553–1562, doi:10.3762/bjnano.8.157

• -ozone cleaner (UV-Ozone Procleaner Plus) for 45 mins to make the grid surface more hydrophilic. Then, the six-hour-aged gels were precisely deposited on a TEM grid, dried for 15 min at room temperature, and contrasted by an aqueous tungsten phosphate solution (pH 7.4). The average size or cross-section

Parylene C as a versatile dielectric material for organic field-effect transistors

• Tomasz Marszalek,
• Maciej Gazicki-Lipman and
• Jacek Ulanski

Beilstein J. Nanotechnol. 2017, 8, 1532–1545, doi:10.3762/bjnano.8.155

• of organic electronics. One of the early applications of Parylene C encapsulation layer in an electronic structure was that of a microelectrode insulator [65]. The Parylene C-covered iridium and tungsten microelectrodes were investigated by means of in vivo and in vitro impedance tests. In vitro

Metal oxide nanostructures: preparation, characterization and functional applications as chemical sensors

• Dario Zappa,
• Angela Bertuna,
• Elisabetta Comini,
• Navpreet Kaur,
• Nicola Poli,
• Veronica Sberveglieri and
• Giorgio Sberveglieri

Beilstein J. Nanotechnol. 2017, 8, 1205–1217, doi:10.3762/bjnano.8.122

• 331 cm−1 is a second-order vibration. Thermal oxidation technique: WO3 Thermal oxidation of metallic tungsten films resulted in a disordered mats of tungsten oxide nanowires, covering all the patterned area of the substrates. Figure 5 reports a SEM picture of the nanowires, at 50k magnification

• Raman spectrum of WO3 nanowire networks. All identified peaks can be attributed to tungsten trioxide, while there is no sign of alumina (corundum) peaks related to the polycrystalline substrate. This means that tungsten oxide covers the entire substrates. More specifically, the peaks at 707 cm−1 and

• 797cm−1 are related to the stretching vibration of bridging oxygen in (W–O–W) bonds [7], and they are typical peaks of monoclinic tungsten trioxide. The other two major peaks at 262 cm−1 and 322 cm−1 are due to the bending vibration of (O–W–O) bonds [8]. Hydrothermal technique: Nb2O5 During the

First examples of organosilica-based ionogels: synthesis and electrochemical behavior

• Andreas Taubert,
• Ruben Löbbicke,
• Barbara Kirchner and
• Fabrice Leroux

Beilstein J. Nanotechnol. 2017, 8, 736–751, doi:10.3762/bjnano.8.77

• deposited on the grid and dried before microscopy. Scanning electron microscopy (SEM) was done on an FEI Phenom desktop electron microscope operated at 5 kV and on a JEOL JSM-6510 with a tungsten filament operated at 15 kV. Energy dispersive X-ray spectroscopy (EDXS) was done with an Oxford Instrument INCAx

Optimizing qPlus sensor assemblies for simultaneous scanning tunneling and noncontact atomic force microscopy operation based on finite element method analysis

• Omur E. Dagdeviren and
• Udo D. Schwarz

Beilstein J. Nanotechnol. 2017, 8, 657–666, doi:10.3762/bjnano.8.70

• values used for Young’s modulus E, the density ρ, Poisson’s ratio υ, and the damping coefficient η for all materials considered in the modeling, with values for quartz, epoxy glue, and Macor chosen as in [26] while the ones for gold and tungsten were taken from the material library of the simulation

• software [27]. Also note that (i) due to the comparatively low internal damping occurring inside Macor, gold, and tungsten, we do not assign a damping coefficient to any of these materials to speed up the calculations, and that (ii) the sensor is oscillating in vacuum; for experimentation in air, we would

• oscillation behavior are applied at the base of the Macor holder. The difference from this arrangement to the previous one is that we added a tungsten tip that is attached to the free prong using a spherical drop of epoxy glue. To save on computational costs, we represent the tip by a blunt rod of 100 µm

Thickness-modulated tungsten–carbon superconducting nanostructures grown by focused ion beam induced deposition for vortex pinning up to high magnetic fields

• Ismael García Serrano,
• Javier Sesé,
• Isabel Guillamón,
• Hermann Suderow,
• Sebastián Vieira,
• Manuel Ricardo Ibarra and
• José María De Teresa

Beilstein J. Nanotechnol. 2016, 7, 1698–1708, doi:10.3762/bjnano.7.162

• Materiales de Aragón (ICMA), CSIC - Universidad de Zaragoza, 50009 Zaragoza, Spain 10.3762/bjnano.7.162 Abstract We report efficient vortex pinning in thickness-modulated tungsten–carbon-based (W–C) nanostructures grown by focused ion beam induced deposition (FIBID). By using FIBID, W–C superconducting

Sb₂S₃ grown by ultrasonic spray pyrolysis and its application in a hybrid solar cell

• Erki Kärber,
• Atanas Katerski,
• Ilona Oja Acik,
• Arvo Mere,
• Valdek Mikli and
• Malle Krunks

Beilstein J. Nanotechnol. 2016, 7, 1662–1673, doi:10.3762/bjnano.7.158

• were physically isolated by scribing the solar cell. The thickness of the Au layer was around 50 nm. For light soaking of the glass/ITO/TiO2/Sb2S3/P3HT/Au solar cell from the glass side we used a 300 W quartz–tungsten–halogen (QTH) lamp at a distance that resulted in 100 mW·cm−2 irradiance on the solar

• cells: voltage under open circuit conditions (VOC), current density under short-circuit conditions (JSC), the fill factor (FF) and the conversion efficiency (η) under AM1.5 standard conditions. The standard conditions were simulated by using the illumination of a 300 W quartz–tungsten–halogen (QTH) lamp

Hydrophilic silver nanoparticles with tunable optical properties: application for the detection of heavy metals in water

• Paolo Prosposito,
• Federico Mochi,
• Erica Ciotta,
• Mauro Casalboni,
• Fabio De Matteis,
• Iole Venditti,
• Laura Fontana,
• Giovanna Testa and
• Ilaria Fratoddi

Beilstein J. Nanotechnol. 2016, 7, 1654–1661, doi:10.3762/bjnano.7.157

• the lateral displacement is ±0.05 Å. Tungsten tips were chemically etched in a solution of NaOH and glycerol. Characterization of AgNP-3MPS nanoparticles in H2O (synthesis a): (a) UV–vis spectrum; (b) DLS measurements: <2RH> = 8 ± 2 nm; (c) ζ-potential measurements: ζ = −34 ± 5 mV. Absorption spectrum

Experimental and simulation-based investigation of He, Ne and Ar irradiation of polymers for ion microscopy

• Lukasz Rzeznik,
• Yves Fleming,
• Tom Wirtz and
• Patrick Philipp

Beilstein J. Nanotechnol. 2016, 7, 1113–1128, doi:10.3762/bjnano.7.104

• induced by the implantation of rare gas atoms. The latter has been observed among other for gallium nitride [28], silicon [29], iron [30] or steel [31], and tungsten [32] under helium irradiation. The evolution of roughness for Ne+ irradiation of PMMA can be better seen in Figure 2a where the value of RMS

Signal enhancement in cantilever magnetometry based on a co-resonantly coupled sensor

• Julia Körner,
• Christopher F. Reiche,
• Thomas Gemming,
• Bernd Büchner,
• Gerald Gerlach and
• Thomas Mühl

Beilstein J. Nanotechnol. 2016, 7, 1033–1043, doi:10.3762/bjnano.7.96

• each subsystem we used a tungsten tip to hold the respective other subsystem, therefore detuning the coupled system. Figure 3 shows the sensor and magnified images of the free of the FeCNT end before and after frequency matching. Furthermore, the co-resonant oscillation of the nanotube is depicted

Dielectrophoresis of gold nanoparticles conjugated to DNA origami structures

• Anja Henning-Knechtel,
• Matthew Wiens,
• Mathias Lakatos,
• Andreas Heerwig,
• Frieder Ostermaier,
• Nora Haufe and
• Michael Mertig

Beilstein J. Nanotechnol. 2016, 7, 948–956, doi:10.3762/bjnano.7.87

• electrically contacted outside the liquid volume with tungsten needles that are connected to a frequency and voltage synthesizer. DEP is influenced by the complex permittivity of the manipulating object () and its surrounding medium (). This parameter is at low and high frequencies a function of the electrical

• objective and appropriate fluorescence filter sets. A PDMS ring was sealed with silicon oil on the glass substrate in between the electrodes and contact pads. In addition, the microscope was equipped with micromanipulators (Suess MICROTec PH100) that were used to place tungsten needles (SIGNATONE SE-T) on

Modelling of ‘sub-atomic’ contrast resulting from back-bonding on Si(111)-7×7

• Adam Sweetman,
• Samuel P. Jarvis and
• Mohammad A. Rashid

Beilstein J. Nanotechnol. 2016, 7, 937–945, doi:10.3762/bjnano.7.85

• is likely silicon due to prior STM treatment of the tip on the clean Si(111)-7×7 surface (although the tip bulk material is tungsten). In addition, the identity of the passivating end group, which was picked up spontaneously during NC-AFM imaging of the clean surface, is not known. Although CO is a

Microscopic characterization of Fe nanoparticles formed on SrTiO₃(001) and SrTiO₃(110) surfaces

• Miyoko Tanaka

Beilstein J. Nanotechnol. 2016, 7, 817–824, doi:10.3762/bjnano.7.73

• . Electrochemically etched tungsten tips were used. STM images are not highly resolved because vibration and sample drift cannot be completely eliminated due to the relatively non-rigid sample holders that need to be compatible to UTSICS and TEM. TEM images and TED patterns were taken with an acceleration voltage of

Synthesis and applications of carbon nanomaterials for energy generation and storage

• Marco Notarianni,
• Jinzhang Liu,
• Kristy Vernon and
• Nunzio Motta

Beilstein J. Nanotechnol. 2016, 7, 149–196, doi:10.3762/bjnano.7.17

Linear and nonlinear optical properties of hybrid metallic–dielectric plasmonic nanoantennas

• Mario Hentschel,
• Bernd Metzger,
• Bastian Knabe,
• Karsten Buse and
• Harald Giessen

Beilstein J. Nanotechnol. 2016, 7, 111–120, doi:10.3762/bjnano.7.13

• , Utikal et al. [61] buried gold gratings within dielectric waveguides consisting of alumina, indium tin oxide, or tungsten trioxide, respectively, and studied the third harmonic spectra. They found that the overall signal is generated not only by the gold itself, but by the dielectric waveguide as well